Patent Grant
10107492
The present invention relates to a biomass-mixed, pulverized coal-fired burner that burns biomass fuel together with pulverized coal in a mixed state and to a fuel combustion method.
Recently, a need exists to promote planned performance of steps against global warming. Of the total greenhouse effect gases discharged in Japan, energy-derived CO2 emissions account for about 90% in recent years. Moreover, of the total power generated, coal-fired power plant discharges 50% CO2. Thus, coal-fired power plants are required to promote the use of new types of energy having low environmental impact.
Organic substances repeat a cycle of decomposition, absorption, and release. Equilibrium can thus be achieved for the amount of CO2 discharged by biomass energy by having a source of absorbing the equal amount of CO2. In this way, biomass is a carbon neutral fuel and thus biomass power generation carries the weight of expectations as new energy, which can reduce the amount of used fossil fuels and the amount of CO2 emissions. Easily collectable woody biomass includes wood pellets and wood chips.
Additionally, use of the biomass fuel as auxiliary fuel in the coal-fired boiler reduces the amount of NOx contained in combustion exhaust gases because the biomass fuel contains a low nitrogen content.
Against this background, coal-fired boilers are required to introduce the biomass-mixed combustion system so as to promote the use of new energy.
Among boilers using biomass, there is a biomass-mixed fired boiler that burns pulverized fuel which is a mixture of pulverized coal and biomass fuel. A typical system uses a conventional pulverized coal-fired boiler and manufactures a mixed fuel of pulverized coal and biomass by, for example, adding a woody biomass material to a roller or other type of mill that crushes coal into fine powder. The system then conveys the mixed fuel on conveyance air and burns the mixed fuel using the pulverized coal burner.
The roller mill pulverizes coal into fine particles of commonly 200 μm or less, preferably about 70 μm, in order to improve combustion efficiency of the burner. At this time the coal and the biomass fuel are treated together, thus the biomass fuel is also pulverized into fine particles. The produced mixed fuel has an aggravated product grain size results with a resultant increase in the amount of coarse components of 100 μm or more. The product fuel has a grain size distribution expanded both in coarse and fine directions. Further, fine pulverization of the biomass fuel requires a great power, which increases the unit requirement.
In addition, the woody biomass fuel and the pulverized coal have combustion characteristics different from each other. For example, the woody biomass has a volatile content twice as high as that of coal. The wood pellet has a calorific value of ⅔ of that of coal and the wood chip has a calorific value of ½ of that of coal. The wood pellet and the wood chip have an ash content of 1/10 or less of that of coal. Meanwhile, the woody biomass fuel and the pulverized coal require different amount of air for combustion. Thus, when the woody biomass and the pulverized coal are co-fired with certain amount of air, depending on the mixing ratio of the woody biomass and the pulverized coal, the combustion condition will not always be preferable. The biomass fuel mixing ratio (calorific value ratio) in the pulverized coal boiler is 3% in terms of actual industrial applications and the limit is estimated to be about 5%.
To burn the woody biomass fuel efficiently, a biomass fired burner can be employed so that the pulverized coal and the woody biomass fuel will be burned separately.
The finer the woody biomass is pulverized, the more the power is required in pulverization, which increases the unit requirement. On the other hand, the woody biomass fuel is easier to burn than coal if particle diameters are the same, which eliminates the need for making small the pulverized grain size.
When a biomass fired burner is used together with a pulverized coal-fired burner, a pulverizing mill can be operated under conditions suitable for the woody biomass fuel independently of the pulverized coal. A boiler can be operated with a suitable mixed fuel burning ratio selected as against the pulverized coal fuel.
Patent Document 1 discloses a biomass fired burner that is applied to a biomass-mixed fired boiler that loads pulverized coal and woody biomass fuel through respective lines into a furnace for combustion. The disclosed biomass fired burner includes a biomass fuel jet nozzle. The biomass fuel jet nozzle includes: a disperser disposed at a center of the biomass fuel jet nozzle, the disperser preventing uneven flow of the biomass fuel; a venturi disposed upstream inside the nozzle, the venturi increasing flow velocity of the fuel to thereby cause biomass fuel particles to collide with the disperser; a flame stabilizer disposed at a leading end of the biomass fuel jet nozzle, the flame stabilizer having a stepped enlarging structure for sharply expanding the biomass fuel stream; and a combustion air nozzle disposed on the outside of the biomass fuel jet nozzle, the combustion air nozzle supplying a secondary air swirl flow.
The biomass fired burner is optimized for burning a predetermined amount of biomass fuel. The number of biomass fired burners to be installed may be determined according to the amount of biomass fuel to be processed required in the furnace to which the burners are applied. The arrangement disclosed in Patent Document 1 has a mixed fuel burning ratio of 15%.
Patent Document 2 discloses a boiler that includes a biomass-mixed fired burner burning pulverized coal and biomass fuel and a boiler that includes a starting or auxiliary burner that functions also as a biomass fuel burning burner that burns biomass fuel supplied intermittently thereto. Patent Document 2 does not, however, describe any specific configuration of the biomass fired burner, problems encountered during its use, solving means, and the like.
Patent Document 3 discloses a pulverized coal fired burner. The disclosed burner is adapted to pulverized coal that has a greater calorific value, a greater amount of air required for combustion, and greater specific gravity than those of the biomass fuel and thus has a small optimum grain size. Accordingly, the burner in Patent Document 3 cannot be directly used for burning the woody biomass fuel.
Patent Document 1: JP-A-2005-291534
Patent Document 2: JP-A-2005-291524
Patent Document 3: JP-A-H09-26112
The greater the amount of biomass is burned, the more ideal the biomass used as the auxiliary fuel in, for example, a biomass-mixed, pulverized coal-fired burner is. Unfortunately, however, a supply of the biomass material is not necessarily steady currently.
It is an object of the present invention to provide a biomass-mixed, pulverized coal-fired burner capable of burning biomass fuel as auxiliary fuel in large quantities and burning only pulverized coal when the biomass fuel is not sufficiently available, and to provide a fuel combustion method.
To achieve the foregoing object, an aspect of the present invention provides a biomass-mixed, pulverized coal-fired burner, comprising: a biomass fuel jet nozzle having a biomass fuel jet port that supplies biomass fuel conveyed by biomass fuel primary air as a biomass fuel stream into a fuel jet nozzle; a fuel jet nozzle including a fuel conveying pipe that introduces pulverized coal fuel conveyed by pulverized coal fuel primary air as a pulverized coal fuel stream to thereby form a flow path for the pulverized coal fuel stream, and a fuel jet port through which the pulverized coal fuel stream is jetted together with the biomass fuel supplied inside of the fuel conveying pipe from the biomass fuel jet nozzle; a secondary air nozzle having a secondary air jet port that surrounds an opening in the fuel jet port, the secondary air jet port jetting secondary air; and a tertiary air nozzle having a tertiary air jet port that surrounds the secondary air jet port, the tertiary air jet port jetting a tertiary air swirl flow.
In addition, another aspect of the present invention provides a fuel combustion method comprising: burning biomass fuel and pulverized coal fuel using the biomass-mixed, pulverized coal-fired burner according to the aspect of the present invention.
The biomass fuel jet nozzle has a biomass fuel jet port that jets the biomass fuel stream into an inside of the fuel conveying pipe included in the fuel jet nozzle.
The fuel jet nozzle includes: a fuel swirl vane disposed inside the fuel conveying pipe, the fuel swirl vane changing a fuel stream as a mixture of the pulverized coal fuel stream and the biomass fuel stream into a whirling swirl flow to thereby, through a centrifugal force, such that a pulverized coal fuel component in the fuel stream is distributed with a higher concentration on an outer circumferential wall side of the fuel conveying pipe and a biomass fuel component in the fuel stream is distributed inside of the pulverized coal fuel component; a flame stabilizer disposed at a pipe end of the fuel jet port, the flame stabilizer opening in a funnel shape; and a fuel baffle plate disposed on a pipe inner wall at a position upstream of the flame stabilizer, the fuel baffle plate restricting a swirl of the fuel stream jetted from the fuel jet port. As a result, the biomass fuel stream jetted from the fuel jet port is supplied so as to be enveloped by the pulverized coal fuel stream.
Additionally, the secondary air jetted from the secondary air jet port forms a buffer stream between the fuel stream jetted from the fuel jet port and the tertiary air swirl flow.
In the biomass-mixed, pulverized coal-fired burner according to the aspect of the present invention, the biomass fuel stream conveyed by air is supplied into the fuel jet nozzle to which the pulverized coal fuel stream is supplied and turned into a swirl with the pulverized coal fuel stream inside the fuel jet nozzle. Based on the centrifugal force involved, a fuel stream is formed having the pulverized coal fuel component gathering at a portion thereof close to the outer surface side and the biomass fuel component residing thereinside before the fuel stream is jetted from the fuel jet port.
The flame stabilizer having a funnel-shaped opening and a step is disposed at a pipe end of the fuel jet port. The flame stabilizer allows the fuel to be dispersed in the furnace and generates a relatively large reverse flow range. This facilitates ignition of the burner and holding of the flame.
The flame stabilizer acts strongly on the pulverized coal fuel stream distributed at an outer shell of the fuel stream, so that the pulverized coal combustion flame spreads from the fuel jet port at a wide spread angle. In contrast, the flame stabilizer acts weakly on the biomass fuel stream resident on the inside of the pulverized coal fuel stream, so that the biomass fuel stream is jetted into the furnace with a smaller spread angle so as to be enveloped by the pulverized coal fuel stream.
The secondary air is supplied to an outer periphery of the fuel stream and the tertiary air is supplied to an outer periphery of the secondary air.
The fuel stream is guided to the flame stabilizer and jetted to spread into the furnace. In this case, the secondary and tertiary air for combustion jetted from the jet ports for the combustion air is diverted outwardly to thereby retard mixing of the pulverized coal fuel and the air and burn the mixture in a reducing atmosphere, so that NOx can be reduced.
The biomass fuel is ignited reliably in a flame of the pulverized coal having favorable flame holding performance to thereby hold its flame. Thus, the biomass fuel can burn steadily over a wide range of mixing ratios from low to high relative to the pulverized coal fuel. The biomass-mixed, pulverized coal-fired burner according to the aspect of the present invention is capable of burning favorably even at a mixed fuel burning ratio of 60% by weight of the biomass fuel (a ratio by weight of biomass fuel component in fuel) and of burning only the pulverized coal.
The biomass-mixed, pulverized coal-fired burner according to the aspect of the present invention includes a supply path for the pulverized coal fuel and a supply path for the biomass fuel independent of each other. This allows the biomass fuel and the pulverized coal fuel to be pulverized into respective suitable grain sizes. For example, pulverizing the biomass fuel so as to exhibit a grain size distribution of about 2 mm or under, which can be prepared without an excess power supply, improves energy efficiency. Additionally, up to a point in the fuel jet nozzle at which the biomass fuel and the pulverized coal fuel meet, an optimum amount of conveying primary air can be individually selected for each of the biomass fuel and the pulverized coal fuel. It is, however, noted that the fuel stream jetted into the furnace is conveyed by primary air that combines the two types of air.
The biomass-mixed, pulverized coal-fired burner according to the aspect of the present invention is capable of burning the biomass fuel in large quantities as the auxiliary fuel for the pulverized coal. The biomass-mixed, pulverized coal-fired burner burns the biomass fuel in a reducing atmosphere, which reduces generation of NOx. Thanks to carbon neutrality of the biomass fuel, the biomass-mixed, pulverized coal-fired burner can practically prevent the amount of CO2 from increasing in the atmosphere, as compared with the combustion of fossil fuels.
Furthermore, a biomass-mixed, pulverized coal-fired boiler to which the biomass-mixed, pulverized coal-fired burner according to the aspect of the present invention is applied can reduce coal consumption, the amount of NOx in exhaust gases, and the amount of CO2 emissions originated from fossil fuels through the use of the biomass fuel as the auxiliary fuel.
An embodiment of the present invention will be described below with reference to the accompanying drawings.
Reference is made to
The biomass fuel jet nozzle 20 supplies biomass fuel conveyed by biomass fuel primary air to an intermediate position of the fuel jet nozzle 30. The biomass fuel jet nozzle 20 includes a biomass fuel introducing pipe 21, a biomass fuel reflecting plate 22, a biomass fuel conveying pipe 23, and a biomass fuel jet port 24.
The fuel jet nozzle 30 jets pulverized coal fuel conveyed by pulverized coal fuel primary air, together with the biomass fuel introduced to the intermediate position of the fuel jet nozzle 30, into a furnace. The fuel jet nozzle 30 includes a pulverized coal fuel introducing pipe 31, a pulverized coal fuel reflecting plate 32, a fuel conveying pipe 33, and a fuel jet port 34. The biomass fuel is supplied to a pipe axis portion of the fuel conveying pipe 33 by way of the biomass fuel jet port 24. A pulverized coal fuel stream is supplied along a pipe wall of the fuel conveying pipe 33.
The fuel jet nozzle 30 further includes a fuel swirl vane 35 at an intermediate portion of the fuel conveying pipe 33 downstream of the biomass fuel jet port 24. The fuel swirl vane 35 comprises a plurality of swirl vanes disposed in a flow path for the fuel in the fuel conveying pipe 33. The swirl vanes are inclined relative to the pipe axis. The swirl vanes rotate the fuel stream that flows therein about the pipe axis and use a centrifugal force to make a fuel concentration lower at a center side and higher on an outer circumferential side and make a concentration distribution substantially uniform in a circumferential direction.
The fuel stream that is a mixture of the pulverized coal fuel stream and the biomass fuel stream contacts the fuel swirl vane 35 and forms a swirl flow having fuel components distributed according to their specific gravity. Specifically, under the centrifugal force, the fuel stream that has flowed past the fuel swirl vane 35 has a higher concentration of a pulverized coal fuel component on the pipe wall side of the fuel conveying pipe 33 with a biomass fuel component being distributed inside of the pulverized coal component.
The fuel jet nozzle 30 further includes a fuel baffle plate 36 disposed on a pipe inner wall at a position upstream of the fuel jet port 34 located at a leading end of the fuel conveying pipe. The fuel baffle plate 36 comprises a plurality of flat plates, each flat plate being disposed at substantially equal intervals in the circumferential direction and extending along the pipe axis. The fuel baffle plate 36 can reduce a swirl force of the fuel stream that flows therethrough to thereby change the swirl flow substantially into an axial flow. The number, size, and inclination relative to the pipe axis of the flat plates constituting the fuel baffle plate 36 may be determined as appropriate according to the swirl force of the fuel stream and a spread angle after jetting.
The fuel jet nozzle 30 further includes a fuel flame stabilizer 37 disposed at the fuel jet port 34. The fuel flame stabilizer 37 has a funnel-shaped widening ring that widens a jet stream outwardly. As shown in
The fuel stream jetted into the furnace from the fuel jet port 34 is formed by an action of the fuel swirl vane 35 such that the biomass fuel stream is enveloped by the pulverized coal fuel stream.
The secondary air nozzle 40 is disposed so as to surround the fuel jet nozzle 30. The secondary air nozzle 40 includes a secondary air introducing pipe 41, a secondary air conveying pipe 42, and a secondary air widening ring 43. The secondary air nozzle 40 draws swirling secondary air from a spirally formed wind box not shown and supplies the secondary air into the furnace by way of a secondary air supply port formed around the fuel jet port 34. The secondary air is supplied to the outside of the fuel stream jetted from the fuel jet port 34 via the secondary air widening ring 43 disposed at the secondary air supply port.
The tertiary air nozzle 50 is disposed so as to surround the secondary air nozzle 40. The tertiary air nozzle 50 includes a tertiary air introducing pipe 51, a tertiary air throat 52, a tertiary air widening ring 53, and a tertiary air swirl vane 54. The tertiary air nozzle 50 draws swirling tertiary air from the spirally formed wind box not shown and supplies the tertiary air to the outside of the fuel stream by way of a tertiary air supply port formed so as to surround the secondary air supply port. Swirl strength of the tertiary air can be adjusted with the tertiary air swirl vane 54 disposed at a draw-in port.
It is noted that the secondary air exists between the fuel stream and the tertiary air to thereby assume a buffer stream that retards interference therebetween.
The auxiliary fuel nozzle 10 includes an auxiliary fuel conveying pipe 11 disposed at an axial position of the biomass-mixed, pulverized coal-fired burner 1 and an auxiliary fuel jet port 12. The auxiliary fuel nozzle 10 assumes a fuel supply pipe used for supplying auxiliary or starting liquid or gas fuel when a pulverized coal system fails. The addition of the auxiliary fuel nozzle 10 enhances operating stability.
Additionally, the biomass-mixed, pulverized coal-fired burner 1 according to the embodiment further includes, though not shown, a pilot burner and a flame detector.
The biomass fuel jet nozzle 20 and the fuel jet nozzle 30 in the embodiment require an amount of primary air that results in the biomass fuel flowing at a flow velocity of 14.5 m/s or higher to ensure that the biomass fuel does not stagnate in the horizontally disposed piping. Preferably, however, the flow velocity of the biomass fuel stream is held below about 22 m/s, because excessively high flow velocities degrade ignition performance and flame holding performance.
The biomass fuel jet nozzle 20 includes the biomass fuel conveying pipe 23 disposed in a horizontal direction and the biomass fuel introducing pipe 21 connected substantially perpendicularly to the biomass fuel conveying pipe 23 via a bent section 28. The biomass fuel stream flowing from the biomass fuel introducing pipe 21 collides against the flat biomass fuel reflecting plate 22 disposed at the bent section 28 and is thereby bent substantially at 90°.
The bent section 28, if formed with a bent pipe, causes the introduced biomass fuel stream to be smoothly bent. Thus, heavy fuel particles in the stream tend to reside on an outer circumferential side of the bent pipe due to a centrifugal force, so that a fuel distribution inside the pipe becomes uneven circumferentially at an outlet of the bent pipe. The nozzle according to the embodiment causes the biomass fuel stream to collide with the flat biomass fuel reflecting plate 22 to thereby disturb the stream, thereby enhancing uniformity of the fuel distribution in the circumferential direction inside the pipe.
The biomass fuel stream conveyed by the primary air flows past the bent section 28 provided with the biomass fuel reflecting plate 22, which reduces unevenness in the circumferential direction. The biomass fuel stream is then supplied to the intermediate position of the fuel conveying pipe 33 from the biomass fuel jet port 24.
The fuel jet nozzle 30 in the embodiment includes the fuel conveying pipe 33 disposed in a horizontal direction and the pulverized coal fuel introducing pipe 31 connected substantially perpendicularly to the fuel conveying pipe 33 via a bent section 38. The pulverized coal fuel stream conveyed by the primary air and flowing from the pulverized coal fuel introducing pipe 31 collides against the flat pulverized coal fuel reflecting plate 32 disposed at the bent section 38 and is thereby bent substantially at 90°. This can enhance uniformity of the fuel distribution in the circumferential direction inside the pipe.
The pulverized coal fuel stream undergoes, together with the biomass fuel stream supplied midway in the fuel conveying pipe 33, an adjustment of a fuel concentration distribution in the fuel stream by the fuel swirl vane 35 disposed downstream in the fuel conveying pipe 33.
The fuel swirl vane 35 comprises a plurality of swirl vanes disposed in the flow path in the fuel conveying pipe 33. The swirl vanes are inclined relative to the pipe axis. The swirl vanes change the fuel stream that flows therein into a swirl flow whirling around the axis, thereby causing a component having high specific gravity to reside heavily on the outer circumferential side and making the concentration distribution substantially uniform in the circumferential direction.
The pulverized coal fuel stream and the biomass fuel stream, which have been changed into a swirl flow by the fuel swirl vane 35, are mixed with each other to become a fuel stream that is conveyed to the downstream side, the fuel stream having the pulverized coal component gathering at a portion thereof close to the outer surface and the biomass fuel component residing thereinside.
The fuel baffle plate 36 is disposed on the pipe inner wall at an end of the fuel conveying pipe 33 immediately upstream of the fuel jet port 34. The fuel baffle plate 36 reduces a swirl force of the fuel stream conveyed through the fuel conveying pipe 33, thereby reducing the spread angle of the fuel stream jetted from the fuel jet port 34. Meanwhile, the fuel stream is spread into the furnace by the funnel-shaped opening in the fuel flame stabilizer 37 so as to be mixed well with the secondary air or the tertiary air.
The fuel baffle plate 36 comprises a plurality of flat plates, each flat plate being disposed at substantially equal intervals in the circumferential direction and extending substantially in parallel with the pipe axis. The number, size, orientation, and the like of the flat plates constituting the fuel baffle plate 36 may be determined as appropriate according to the swirl force of the pulverized coal fuel stream and the spread angle after jetting.
In the jetted fuel stream, the pulverized coal fuel is distributed so as to envelope the biomass fuel. Even after the fuel stream is released into the furnace, a condition is maintained in which the pulverized coal fuel covers the biomass fuel like a sheath, so that the biomass fuel burns in a condition of being enveloped by a pulverized coal flame. This achieves reliable ignition and flame holding performance of the biomass fuel.
The secondary air and the tertiary air are mixed with the fuel stream that spreads from the fuel jet port 34 into the furnace and function as part of combustion air to burn the pulverized coal fuel and the biomass fuel.
The secondary air is supplied as a buffer stream into an inside of the tertiary air stream supplied in a large quantity. The supplied secondary air delays the pulverized coal fuel stream to meet a tertiary air swirl flow. A condition in which the fuel concentration is high is thereby sustained. Thus, the secondary air has actions of achieving stable ignition performance and improving flame holding performance. In addition, combustion time with low oxygen conditions is ensured, so that NOx can be reduced even more effectively.
In the biomass-mixed, pulverized coal-fired burner 1 shown in
In the biomass-mixed, pulverized coal-fired burner 1 according to the embodiment, the biomass fuel is supplied to the inside of the pulverized coal fuel. As a result, the biomass fuel is readily ignited in the flame of the pulverized coal burned earlier and the biomass fuel flame is stably held. This results in minor restrictions on a mixing ratio of the biomass fuel and the pulverized coal fuel, allowing a large amount of biomass fuel to be burned. Under a condition of a short supply of biomass fuel, the biomass-mixed, pulverized coal-fired burner 1 may be used as a pulverized coal-fired burner that burns only the pulverized coal. It is noted that, when only the pulverized coal is burned, preferably, a small amount of air is supplied to the biomass fuel jet nozzle 20 in order to prevent the pulverized coal fuel from flowing back to the biomass fuel conveying pipe 23.
The conventional pulverized coal-fired burner generally requires that coal be pulverized in order to enhance combustion efficiency, the coal being typically pulverized into fine particles of commonly 200 μm or less, preferably about 70 μm, for use with the conventional pulverized coal burner.
When, for example, only the pulverized coal fuel that has been processed such that fuel particle diameters of 74 μm or less account for 80% is burned, it has been determined that the biomass-mixed, pulverized coal-fired burner according to the embodiment can burn the pulverized coal such that a load factor to a rated value falls within a range of 40% to 100%, if A/C (fuel conveying air flow rate (Nm3/h) to fuel (kg/h): unit Nm3/kg) is adjusted to fall within a range of 1.7 to 3.0.
With the biomass fuel, however, electric power for pulverization increases sharply at smaller grain sizes involved in pulverizing the material, aggravating economy. In addition, the biomass fuel is easier to burn than the coal for the same particle diameter, which allows the pulverized grain size to be made larger. As a result, preferably, the biomass fuel is pulverized to a grain size distribution of substantially 2 mm or under.
In the biomass-mixed, pulverized coal-fired burner 1 according to the embodiment, the pulverized coal fuel resident outside the fuel stream to be jetted into the furnace is burned with the secondary air and the tertiary air and the biomass fuel resident inside the fuel stream is ignited and its flame is stably held in the pulverized coal flame. A pulverizing mill dedicated to the biomass fuel is employed to process the biomass fuel into granular particles having a grain size different from that of the pulverized coal. The biomass fuel particles are conveyed by an air stream independent of the pulverized coal and supplied to the biomass-mixed, pulverized coal-fired burner 1.
As such, the biomass fuel can be burned with high efficiency under an optimum combustion condition over a wide range of mixed fuel burning ratios.
Referring to
It is noted that a range with a load factor of less than 50% is not recommended, in which steady ignition or steady flame holding cannot be obtained because of a low fuel concentration in the biomass fuel.
In
A biomass-mixed, pulverized coal-fired boiler capable of combustion at a high mixed fuel burning ratio of biomass can be provided by applying the biomass-mixed, pulverized coal-fired burner according to the present invention to a new or existing boiler. The biomass-mixed, pulverized coal-fired boiler to which the biomass, pulverized coal-fired burner of the embodiment is applied burns a large volume of woody biomass fuel to thereby save coal consumption and reduce the amount of CO2 emissions derived from fossil fuels. Since the biomass-mixed, pulverized coal-fired burner burns the biomass fuel in a reducing atmosphere, the amount of NOx in exhaust gases can be reduced.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2012-063031 | Mar 2012 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2013/058117 | 3/21/2013 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2013/141312 | 9/26/2013 | WO | A |
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| Number | Date | Country | |
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