Patent Application
20230352800
The present invention relates to a bipolar battery and a method of manufacturing the same.
In recent years, power generation facilities using natural energy such as sunlight and wind power have been increasing. In such a power generation facility, an amount of power generation cannot be controlled, and thus a power load is leveled using a storage battery. That is, when the amount of power generation is larger than a consumption, a difference is charged into the storage battery, and when the amount of power generation is smaller than a consumption, a difference is discharged from the storage battery. As the above-described storage battery, lead-acid batteries are frequently used for economic efficiency, safety, and the like. Among them, bipolar lead-acid batteries have been attracting attention from the viewpoint of energy density.
This bipolar lead-acid battery is formed by connecting in series a plurality of cell members assembled by alternately stacking the plurality of cell members, in each of which an electrolyte layer is interposed between a positive electrode having a positive active material layer and a negative electrode having a negative active material layer, and a plurality of frame units made of resin incorporating the cell members.
In this bipolar lead-acid battery, the electrolyte layer constituting the cell member in a cell is impregnated with an electrolytic solution. Therefore, it is necessary to prevent electrolytic solution leakage out of the cell.
For example, a conventional sealed bipolar battery assembly disclosed in JP Patent Publication No. 6571091 B2 is known as a battery assembly having a seal structure for preventing electrolytic solution leakage to the outside.
The sealed bipolar battery assembly disclosed in JP Patent Publication No. 6571091 B2 includes a casing frame in which a first current collector and a second current collector are arranged. Further, two end caps are attached to mate with a top and a bottom of the casing frame. An electrolytic solution region is defined by the first current collector, the second current collector, the casing frame, and the end caps.
In order to prevent the electrolytic solution leakage to the outside, a plurality of plastic seals and adhesive seals are placed around each of the first current collector and the second current collector between the casing frame and the end caps, and the casing frame and the end caps are joined by welding joints using hot-plate welding or other welding technology.
However, the conventional sealed bipolar battery assembly disclosed in JP Patent Publication No. 6571091 B2 has the following problem.
That is, in the sealed bipolar battery assembly disclosed in JP Patent Publication No. 6571091 B2, as the seal structure for sealing the electrolytic solution leakage to the outside from between the casing frame and the end caps, it is necessary to place the plurality of plastic seals and adhesive seals around each of the first current collector and the second current collector between the casing frame and the end caps, and to join together the casing frame and the end caps by the welding joints using the hot-plate welding or other welding technology. Thus, a problem is that the seal structure is complicated.
In view of such a problem, an object of the present invention is to provide a bipolar battery and a method of manufacturing the same capable of reliably preventing electrolytic solution leakage out of a cell by means of a simple seal structure.
To solve the above-described problem, the present invention provides embodiments of a bipolar battery having the following configurations.
The present invention also provides embodiments of a method of manufacturing a bipolar battery having the following configurations.
With a bipolar battery according to embodiments of the present invention, each of the plurality of frame units is configured by the frame unit made of a light transmissive resin material. The two frame units made of a light transmissive resin material adjacent in the stacking direction of the cell members are welded and joined via the joining member made of a light absorbing resin material.
As a result, the two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members are sealed to eliminate a gap, and it is possible to reliably prevent electrolytic solution leakage out of the cell by means of a simple seal structure.
In addition, the joining by welding the two frame units made of the light transmissive resin material via the joining member made of the light absorbing resin material has increased airtightness compared to a joining method using an adhesive. Furthermore, when the two frame units made of the light transmissive resin material are joined together, burrs are less likely to be generated, and a possibility that burrs enter the cell can be reduced.
Because each of the plurality of frame units is configured by the frame unit made of the same light transmissive resin material, there is no difference in thermal expansion coefficient between the frame units, joining reliability between the two frame units made of the light transmissive resin material adjacent in the stacking direction can be improved, and it is possible to reliably prevent electrolytic solution leakage out of the cell.
In addition, with a bipolar battery according to embodiments of the present invention, each of the two frame units made of a light transmissive resin material adjacent in the stacking direction includes a joining surface extending along a direction perpendicular to the stacking direction. The joining surfaces of the two frame units made of a light transmissive resin material adjacent in the stacking direction are welded and joined via the joining member made of a light absorbing resin material. As a result, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal structure.
In addition, with a bipolar battery according to embodiments of the present invention, each of the two frame units made of a light transmissive resin material adjacent in the stacking direction includes a joining surface extending along the stacking direction. The joining surfaces of the two frame units made of a light transmissive resin material adjacent in the stacking direction are welded and joined via the joining member made of a light absorbing resin material. As a result, a width of the joining surface extending along the stacking direction can be made larger than a width of the joining surface extending along the direction perpendicular to the stacking direction. Thus, a creepage distance of the electrolytic solution leakage out of the cell can be made larger than a creepage distance when using the joining surface extending along the direction perpendicular to the stacking direction, and electrolytic solution sealing performance can be further improved.
In addition, with a bipolar battery according to embodiments of the present invention, a resin component of the light transmissive resin material serving as a base material is a thermoplastic resin, and a resin component of the light absorbing resin material serving as a base material is a thermoplastic resin and contains a light absorbing agent. The two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members, where the resin component of the light transmissive resin material serves as the base material being the thermoplastic resin, are welded and joined via the joining member made of the light absorbing resin material, where the resin component of the light absorbing resin material serving as the base material is the thermoplastic resin and contains the light absorbing agent. The two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal structure.
In addition, with a bipolar battery according to embodiments of the present invention, the light transmissive resin material uses as a base material a thermoplastic resin exhibiting a transmittance between 50% and 95% inclusive with respect to light having a wavelength selected from a range between 380 nm and 2000 nm inclusive. The light absorbing resin material contains a light absorbing agent in a thermoplastic resin as a base material, to exhibit an absorbance between 5% and 60% inclusive with respect to light having a wavelength selected from a range between 380 nm and 2000 nm inclusive. The two frame units made of the light transmissive resin material as described are joined via the joining member made of the light absorbing resin material as described. The two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal structure.
In addition, with a bipolar battery according to embodiments of the present invention, the thermoplastic resin contains at least one of an acrylonitrile-butadiene-styrene resin or a polypropylene resin. As a result, the two frame units made of the light transmissive resin material using as the base material the thermoplastic resin containing at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin are joined via the joining member made of the light absorbing resin material containing the light absorbing agent in the thermoplastic resin containing at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin. The two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal structure.
In addition, with a bipolar battery according to embodiments of the present invention, the joining member made of a light absorbing resin material has a sheet shape. As a result, the two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members are welded and joined via the sheet-shaped joining member made of the light absorbing resin material. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal structure.
In addition, a bipolar battery according to embodiments of the present invention is a bipolar lead-acid battery in which the positive electrode has a positive-electrode lead layer and the negative electrode has a negative-electrode lead layer. As a result, in the bipolar lead-acid battery, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal structure.
In addition, a method of manufacturing a bipolar battery according to embodiments of the present invention includes the frame unit arranging step of stacking and arranging the plurality of frame units in the stacking direction of the cell members, each of the plurality of frame units being configured by the frame unit made of a light transmissive resin material, the joining member arranging step of arranging the joining member made of a light absorbing resin material between the two frame units made of a light transmissive resin material adjacent in the stacking direction of the cell members, and the joining step of welding and joining together at the welded portion the two frame units made of a light transmissive resin material adjacent in the stacking direction of the cell members. The welded portion is formed by emitting the light to pass through one of the two frame units made of a light transmissive resin material to the joining member made of a light absorbing resin material, which causes the joining member made of a light absorbing resin material and the two frame units made of a light transmissive resin material to be melted and solidified.
As a result, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of a simple seal method using laser welding and a simple seal structure.
In addition, with a method of manufacturing a bipolar battery according to embodiments of the present invention, in the joining member arranging step, the joining member made of a light absorbing resin material is arranged between joining surfaces respectively provided on the two frame units made of a light transmissive resin material adjacent in the stacking direction, the joining surfaces extending along a direction perpendicular to the stacking direction. In the joining step, the joining surfaces of the two frame units made of a light transmissive resin material adjacent in the stacking direction are joined at the welded portion. As a result, the two frame units made of the light transmissive resin material adjacent in the stacking direction can be joined by joining the joining surfaces extending in the direction perpendicular to the stacking direction at the welded portion by laser welding. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal method and the simple seal structure.
In addition, with a method of manufacturing a bipolar battery according to embodiments of the present invention, in the joining member arranging step, the joining member made of a light absorbing resin material is arranged between joining surfaces respectively provided on the two frame units made of a light transmissive resin material adjacent in the stacking direction, the joining surfaces extending along the stacking direction. In the joining step, the joining surfaces of the two frame units made of a light transmissive resin material adjacent in the stacking direction are joined at the welded portion. As a result, a width of the joining surface extending along the stacking direction can be made larger than a width of the joining surface extending along the direction perpendicular to the stacking direction. Thus, a creepage distance of the electrolytic solution leakage out of the cell can be made larger than a creeping distance when using the joining surface extending along the direction perpendicular to the stacking direction, and electrolytic solution sealing performance can be further improved.
In addition, with a method of manufacturing a bipolar battery according to embodiments of the present invention, the joining member made of a light absorbing resin material has a sheet shape. As a result, in the joining member arranging step, the sheet-shaped joining member made of the light absorbing resin material is arranged between the two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members. In the joining step, the two frame units made of the light transmissive resin material adjacent in the stacking direction of the cell members are welded and joined at the welded portion formed by emitting the light to pass through one of the two frame units made of the light transmissive resin material to the sheet-shaped joining member made of the light absorbing resin material, which causes the joining member made of the light absorbing resin material and the two frame units made of the light transmissive resin material to be melted and solidified. It is possible to reliably prevent electrolytic solution leakage out of the cell by means of the simple seal method using laser welding and the simple seal structure.
Although embodiments of a bipolar battery according to the present invention will be described based on the drawings, the present invention is not limited to the following embodiments described based on the drawings.
A bipolar battery and a method of manufacturing the same according to a first embodiment of the present invention will be described with reference to
A bipolar battery 100 (also referred to as a bipolar storage battery) according to the first embodiment of the present invention illustrated in
The plurality of cell members 150 are arranged to be stacked at intervals in a stacking direction (the vertical direction in
The plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130 respectively form a plurality of cells 160 (also called spaces) respectively incorporating the plurality of cell members 150.
Each of the internal frame units 110 includes a substrate 111 (also called a bipolar plate) having a rectangular planar shape, in which the positive electrode 151 is disposed on one surface and the negative electrode 152 is disposed on the other surface, and a rim 112 having a quadrangular frame shape provided on an outer peripheral edge of the substrate 111. The substrate 111 of each of the internal frame units 110 is arranged between the cell members 150 adjacent in the stacking direction (the vertical direction in
The substrate 111 is integrated with the inside of the rim 112. The substrate 111 is positioned at one end (e.g., a lower end) of the rim 112 in a thickness direction (the vertical direction in
The first end frame unit 120 includes a first end plate 121 having a rectangular planar shape, and a rim 122 having a quadrangular frame shape is provided on an outer periphery of the first end plate 121. The first end frame unit 120 surrounds the negative electrode 152 of the cell member 150 and a side surface of the cell member 150, on one end side (e.g., the lower end side in
The first end plate 121 of the first end frame unit 120 is arranged in parallel with the substrates 111 of the internal frame units 110, and the rim 122 is arranged to be in contact with the rim 112 of the internal frame unit 110 positioned adjacent thereto. That is, the rim 122 includes a joining surface 122a facing the rim 112 of the internal frame unit 110 in the stacking direction (the vertical direction in
The second end frame unit 130 includes a second end plate 131 having a rectangular planar shape, and a rim 132 having a quadrangular frame shape is provided around the second end plate 131. The second end plate 131 is integrated with the inside of the rim 132. The second end frame unit 130 surrounds the positive electrode 151 of the cell member 150 on the other end side (the upper end side in
The second end plate 131 is arranged in parallel with the substrates 111 of the internal frame units 110, and the rim 132 is arranged to contact the rim 112 of the internal frame unit 110 positioned adjacent thereto. That is, the rim 132 includes a joining surface 132a facing the rim 112 of the internal frame unit 110 in the stacking direction (the vertical direction in
The second end plate 131 has a thickness larger than the thickness of the substrate 111. The rim 132 has the same thickness as the thickness of the second end plate 131.
The positive-electrode lead layer 101 is disposed on one surface of the substrate 111. The negative-electrode lead layer 102 is disposed on the other surface of the substrate 111. A positive active material layer 103 is disposed on the positive-electrode lead layer 101. A negative active material layer 104 is disposed on the negative-electrode lead layer 102.
An electrolyte layer 105 made of a glass fiber mat or the like impregnated with an electrolytic solution such as sulfuric acid is disposed between the positive active material layer 103 and the negative active material layer 104 facing each other.
The negative-electrode lead layer 102 is disposed on the other surface of the first end plate 121. The negative active material layer 104 is disposed on the negative-electrode lead layer 102 on the first end plate 121. The electrolyte layer 105 made of a glass fiber mat or the like impregnated with an electrolytic solution such as sulfuric acid is disposed between the negative active material layer 104 on the first end plate 121 and the facing positive active material layer 103 of the substrate 111.
The positive-electrode lead layer 101 is disposed on one surface of the second end plate 131. The positive active material layer 103 is disposed on the positive-electrode lead layer 101 on the second end plate 131. The electrolyte layer 105 made of a glass fiber mat or the like impregnated with an electrolytic solution such as sulfuric acid is disposed between the positive active material layer 103 on the second end plate 131 and the facing negative active material layer 104 of the substrate 111.
The negative-electrode lead layer 102 on the first end plate 121 is provided with a negative electrode terminal 107 that is electrically connected with the outside of the first end plate 121. The positive-electrode lead layer 101 on the second end plate 131 is provided with a positive electrode terminal 106 that is electrically connected with the outside of the second end plate 131.
That is, the bipolar battery 100 according to the first embodiment includes the plurality of cell members 150, each including the positive electrode 151 having the positive active material layer 103, the negative electrode 152 having the negative active material layer 104, and the electrolyte layer 105 interposed between the positive electrode 151 and the negative electrode 152. The plurality of cell members 150 are arranged to be stacked at intervals. The plurality of frame units (the plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130) respectively forming the plurality of cells 160 respectively incorporate the plurality of cell members 150.
The cell members 150 adjacent in the stacking direction are electrically connected in series. Therefore, the substrate 111 interposed between the cell members 150 adjacent in the stacking direction includes means of electrically connecting the positive-electrode lead layer 101 and the negative-electrode lead layer 102.
In the bipolar battery 100 according to the first embodiment, each of the plurality of frame units (the plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130) is configured by a frame unit made of a light transmissive resin material.
Specifically, the first end frame unit 120 at one end (the lower end in
Here, a resin component of the light transmissive resin material serving as a base material is a thermoplastic resin. A thermoplastic resin that exhibits a transmittance between 50% and 95% inclusive with respect to light having a wavelength (approximately between 380 nm and 2000 nm inclusive) selected from a range of visible light (approximately between 380 nm and 780 nm inclusive) and near-infrared light (approximately between 780 nm and 2000 nm inclusive) may be used as the base material.
In addition, a resin component of a light absorbing resin material to be described later serving as a base material is a thermoplastic resin that contains a light absorbing agent. The thermoplastic resin serving as the base material may contain the light absorbing agent to exhibit an absorbance between 5% and 60% inclusive with respect to light having a wavelength (approximately between 380 nm and 2000 nm inclusive) selected from a range of visible light (approximately between 380 nm and 780 nm inclusive) and near-infrared light (approximately between 780 nm and 2000 nm inclusive).
Examples of the thermoplastic resin applicable as the light transmissive resin material and the light absorbing resin material include acrylonitrile butadiene styrene (ABS) resin, polycarbonate (PC), polystyrene (PS), acrylic resin (PMMA), cyclic polyolefin (COP), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polybutylene terephthalate (PBT), polyacetal (POM), and polyphenylene sulfide (PPS), and combinations thereof. PP and ABS resin are particularly preferable.
Although the light transmissive resin material and the light absorbing resin material may use different thermoplastic resins as their base materials, it is preferable to use the same thermoplastic resin because there is no difference in melting point and thermal expansion coefficient, and joining reliability is increased.
As the light absorbing agent, for example, conventionally known dyes, pigments, and the like can be used. Examples include a cyanine compound, a phthalocyanine compound, a dithiol metal complex, a naphthoquinone compound, a diimmonium compound, an azo compound, a naphthalocyanine compound, a nickel dithiolene complex, a squarylium dye, a quinone-based compound, quinacridone, dioxane, benzimidazolone, carbon black, titanium oxide, a ferrite compound such as nickel-iron ferrite, manganese-zinc ferrite, nickel-zinc ferrite, or copper-zinc ferrite, nickel, iron particles, gold particles, and copper particles. One of these components can be used singly, or two or more of them can be used in combination.
In particular, in a case where light (e.g., a laser beam) in a visible light region (approximately between 380 nm and 780 nm inclusive) is used, for example, a phthalocyanine compound, quinacridone, dioxane, benzimidazolone, titanium oxide, gold particles, copper particles, or the like is preferably applied as the light absorbing agent. In a case where light in a near-infrared region (approximately between 780 nm and 2000 nm inclusive) is used, for example, a phthalocyanine compound, nickel, iron particles, manganese-zinc ferrite, nickel-zinc ferrite, copper-zinc ferrite, titanium oxide, or the like is preferably applied as the light absorbing agent.
As the light absorbing agent, any shape such as a spherical form, a powdery form, or a granular form can be used as well as a particulate form. An average particle size of the light absorbing agent is preferably within a range of approximately 0.01 μm to 2 μm. For measurement of the average particle size, for example, a primary particle size of the light absorbing agent in an observation sample may be measured at a predetermined magnification (for example, 100,000 times) using a transmission electron microscope, and an average value thereof may be used. In a case where the shape of the light absorbing agent is not spherical, a major axis and a minor axis may be measured, and a value calculated as (a sum of the major axis and the minor axis)/2 may be used as the average particle size.
In the bipolar battery 100 according to the first embodiment, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction (the vertical direction in
Specifically, in order from one side to the other side in the stacking direction (from a lower side to an upper side in
In addition, the joining surface 112a provided on the rim 112 of the internal frame unit 110 (a frame unit made of the light transmissive resin material) and the joining surface 112a provided on the rim 112 of the other internal frame unit 110 (a frame unit made of the light transmissive resin material) adjacent to the internal frame unit 110 (a frame unit made of the light transmissive resin material) in the stacking direction are joined at the welded portion 140. The welded portion 140 is formed over an entire periphery of the rims 112 and 112.
Furthermore, the joining surface 112a provided on the rim 112 of the other internal frame unit 110 (a frame unit made of the light transmissive resin material) and the joining surface 132a provided on the rim 132 of the second end frame unit 130 (a frame unit made of the light transmissive resin material) adjacent to the other internal frame unit 110 (a frame unit made of the light transmissive resin material) in the stacking direction are joined at the welded portion 140. The welded portion 140 is formed over an entire periphery of the rims 112 and 132.
Here, as described above, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material are melted and solidified at the respective welded portions 140 via the joining members 141 (see
When the bipolar battery 100 is manufactured, first, the joining member 141 made of the light absorbing resin material is arranged on the joining surface 122a provided on the rim 122 of the first end frame unit 120 (a frame unit made of the light transmissive resin material) on the one side (the lowermost side in
Next, as illustrated in
Another joining member 141 made of the light absorbing resin material is arranged on the joining surface 112a provided on the rim 112 of the internal frame unit 110 (a frame unit made of the light transmissive resin material), and the other internal frame unit 110 (a frame unit made of the light transmissive resin material) is further arranged on the joining member 141 made of the light absorbing resin material.
Next, as illustrated in
Lastly, another joining member 141 made of the light absorbing resin material is arranged on the joining surface 112a provided on the rim 112 of the internal frame unit 110 (a frame unit made of the light transmissive resin material), and the second end frame unit 130 (a frame unit made of the light transmissive resin material) is further arranged on the joining member 141 made of the light absorbing resin material.
Although not illustrated in the drawings, a laser beam is emitted to pass through the rim 132 of the second end frame unit 130 (a frame unit made of the light transmissive resin material) to the joining member 141 made of the light absorbing resin material from above the rim 132. As a result, the second end frame unit 130 (a frame unit made of the light transmissive resin material) and the internal frame unit 110 (a frame unit made of the light transmissive resin material) are melted and solidified via the joining member 141 made of the light absorbing resin material, to be joined at the welded portion 140.
The bipolar battery 100 is completely manufactured by injecting the electrolytic solution of the electrolyte layer 105 into the cell 160 through an injection port (not illustrated) after joining together the plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130 as described above.
That is, the method of manufacturing the bipolar battery 100 includes a frame unit arranging step of stacking and arranging the plurality of frame units (the plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130) in the stacking direction of the cell members 150, each of the plurality of frame units being configured by the frame unit made of the light transmissive resin material. The method of manufacturing the bipolar battery 100 also includes a joining member arranging step of arranging the joining members 141 made of the light absorbing resin material between the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150. The method of manufacturing the bipolar battery 100 further includes a joining step of welding and joining together at the welded portions 140 the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150, the welded portions 140 being formed by emitting the laser beams to pass through one of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to the joining members 141 made of the light absorbing resin. This causes the joining members 141 made of the light absorbing resin material and the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to be melted and solidified.
Here, the respective joining members 141 made of the light absorbing resin material are formed in a quadrangular frame shape such that the respective welded portions 140 are formed over the entire peripheries of the rims 122 and 112, 112 and 112, and 112 and 132. A width a1 of each of the joining members 141 made of the light absorbing resin material in the direction perpendicular to the stacking direction is preferably determined as appropriate in consideration of a width W1 of each of the joining surfaces 112a, 122a, and 132a and a joining strength of each of the welded portions 140. In addition, a thickness t1 of each of the joining members 141 made of the light absorbing resin material in the stacking direction is preferably determined as appropriate in consideration of the joining strength of each of the welded portions 140.
In addition, it is preferable that a region irradiated with the laser beam in the direction perpendicular to the stacking direction is substantially an entire region of the width a1 of each of the joining members 141 made of the light absorbing resin material in the direction perpendicular to the stacking direction.
Moreover, the laser beam preferably has a wavelength selected from the range between 380 nm and 2000 nm inclusive (furthermore, between 380 nm and 1200 nm inclusive, and particularly between 380 nm and 500 nm inclusive, and between 1000 nm and 1200 nm inclusive).
As described above, with the bipolar battery 100 according to the first embodiment, each of the plurality of frame units (the plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130) is configured by the frame unit made of the light transmissive resin material.
The two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are melted and solidified at the welded portions 140 via the joining members 141 (see
As a result, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are welded and joined at the welded portions 140 via the joining members 141 (see
In addition, the welded portions 140 at which the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material are melted and solidified via the joining members 141 made of the light absorbing resin material to be welded and joined together have increased airtightness compared to a joining method using an adhesive. Furthermore, when the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material are joined together, burrs are less likely to be generated, and a possibility that burrs enter the cells 160 can be reduced.
Because all of the plurality of frame units 110, 120, and 130 are configured by the frame units made of the same light transmissive resin material, there is no difference in thermal expansion coefficient between the frame units, the joining reliability by the welded portions 140 can be improved, and it is possible to reliably prevent electrolytic solution leakage out of the cells 160.
In addition, with the bipolar battery 100 according to the first embodiment, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction respectively include the joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a extending along the direction perpendicular to the stacking direction. The joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction are melted and solidified at the welded portions 140 via the joining members 141 made of the light absorbing resin material, to be welded and joined together. As a result, the joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction, the joining surfaces extending in the direction perpendicular to the stacking direction, can be joined at the welded portions 140. Thus, it is possible to reliably prevent the electrolytic solution leakage out of the cells 160 by means of the simple seal structure.
In addition, with the bipolar battery 100 according to the first embodiment, the resin component of the light transmissive resin material serving as the base material is the thermoplastic resin, and the resin component of the light absorbing resin material serving as the base material is the thermoplastic resin and contains the light absorbing agent. As a result, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150, the resin component of the light transmissive resin material serving as the base material being the thermoplastic resin, are welded and joined via the joining members 141 made of the light absorbing resin material, the resin component of the light absorbing resin material serving as the base material being the thermoplastic resin and containing the light absorbing agent. The two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of the simple seal structure.
In addition, with the bipolar battery 100 according to the first embodiment, the light transmissive resin material uses as the base material the thermoplastic resin exhibiting the transmittance between 50% and 95% inclusive with respect to the light having the wavelength selected from the range between 380 nm and 2000 nm inclusive. The light absorbing resin material contains the light absorbing agent in the thermoplastic resin as the base material to exhibit absorbance between 5% and 60% inclusive with respect to the light having the wavelength selected from the range between 380 nm and 2000 nm inclusive. As a result, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material using as the base material the thermoplastic resin exhibiting the transmittance between 50% and 95% inclusive with respect to the light having the wavelength selected from the range between 380 nm and 2000 nm inclusive are joined via the joining members 141 made of the light absorbing resin material containing the light absorbing agent in the thermoplastic resin as the base material to exhibit absorbance between 5% and 60% inclusive with respect to the light having the wavelength selected from the range between 380 nm and 2000 nm inclusive. The two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are sealed to eliminate the gap, and it is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of the simple seal structure.
In addition, with the bipolar battery 100 according to the first embodiment, the thermoplastic resin may contain at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin. As a result, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material using as the base material the thermoplastic resin containing at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin are joined via the joining members 141 made of the light absorbing resin material containing the light absorbing agent in the thermoplastic resin containing at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin. The two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of the simple seal structure.
In addition, with the bipolar battery 100 according to the first embodiment, the joining members 141 made of the light absorbing resin material have a sheet shape. As a result, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are welded and joined via the sheet-shaped joining members 141 made of the light absorbing resin material. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of the simple seal structure.
In addition, the method of manufacturing the bipolar battery 100 according to the first embodiment includes the frame unit arranging step of stacking and arranging the plurality of frame units 110, 120, and 130 in the stacking direction of the cell members 150, each of the plurality of internal frame units 110, the first end frame unit 120, and the second end frame unit 130 being configured by the frame unit made of the light transmissive resin material, the joining member arranging step of arranging the joining members 141 made of the light absorbing resin material between the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150, and the joining step of welding and joining together at the welded portions 140 the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150. The welded portions 140 are formed by emitting the laser beams to pass through one of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to the joining members 141 made of the light absorbing resin material, which causes the joining members 141 made of the light absorbing resin material and the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to be melted and solidified.
As a result, it is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of a simple seal method using laser welding and a simple seal structure.
In addition, with the method of manufacturing the bipolar battery according to the first embodiment, in the joining member arranging step, the joining members 141 made of the light absorbing resin material are arranged between the joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a respectively provided on the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction. The joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a extend along the direction perpendicular to the stacking direction. In the joining step, the joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction are joined at the welded portions 140. As a result, the joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction and the joining surfaces 122a and 112a, 112a and 112a, and 112a and 132a extending in the direction perpendicular to the stacking direction can be joined at the welded portions 140 by laser welding. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of the simple seal method and the simple seal structure.
In addition, with the method of manufacturing the bipolar battery according to the first embodiment, the joining members 141 made of the light absorbing resin material have a sheet shape. As a result, in the joining member arranging step, the sheet-shaped joining members 141 made of the light absorbing resin material are arranged between the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150. In the joining step, the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material adjacent in the stacking direction of the cell members 150 are welded and joined at the welded portions formed by emitting the laser beams to pass through one of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to the sheet-shaped joining members 141 made of the light absorbing resin material, and by causing the joining members 141 made of the light absorbing resin material and the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to be melted and solidified. It is possible to reliably prevent electrolytic solution leakage out of the cells 160 by means of the simple seal method using laser welding and the simple seal structure.
A bipolar battery and a method of manufacturing the same according to a second embodiment of the present invention will be described with reference to
A bipolar battery 200 (also referred to as a bipolar storage battery) according to the second embodiment of the present invention illustrated in
The plurality of cell members 250 are arranged to be stacked at intervals in a stacking direction (e.g., vertical direction in
The plurality of internal frame units 210, the first end frame unit 220, and the second end frame unit 230 respectively form a plurality of cells 260 (also called spaces) respectively incorporating the plurality of cell members 250.
Each of the internal frame units 210 includes a substrate 211 (also called a bipolar plate) having a rectangular planar shape, and in which the positive electrode 251 is disposed on one surface and the negative electrode 252 is disposed on the other surface, a first rim 212 having a quadrangular shape provided at a position away from an outer peripheral edge of the substrate 211 toward an inner peripheral side by a predetermined distance, and a second rim 213 having a quadrangular shape provided on the outer peripheral edge of the substrate 211. The substrate 211 is arranged between the cell members 250 adjacent in the stacking direction (the vertical direction in
The first rim 212 of one (the upper one in
The outer side surface of the first rim 212 of the one (the upper one in
The joining surfaces 212a and 213a extend along the stacking direction of the cell members 250.
In addition, the first end frame unit 220 includes a first end plate 221 having a rectangular planar shape, and a rim 222 having a quadrangular shape is provided on an outer periphery of the first end plate 221. The first end frame unit 220 surrounds the negative electrode 252 of the cell member 250 and an outer side surface of the first rim 212 of the above-described other internal frame unit 210 positioned adjacent thereto in the stacking direction, on one end side (the lower end side in
The first end plate 221 has substantially the same thickness as the substrate 211. The rim 222 is formed thicker than the first end plate 221 in the stacking direction and is formed to protrude from an outer peripheral edge of the first end plate 221 toward the other side (the upper side in
The first end plate 221 of the first end frame unit 220 is arranged in parallel with the substrate 211 of the internal frame unit 210 positioned adjacent thereto in the stacking direction, and the rim 222 is arranged to face the outer side surface of the first rim 212 of the internal frame unit 210. A surface of the rim 222 of the first end frame unit 220 facing the outer side surface of the first rim 212 of the internal frame unit 210 serves as a joining surface 222a. In addition, the surface of the first rim 212 of the internal frame unit 210 facing the inner side surface of the rim 222 of the first end frame unit 220 serves as the joining surface 212a. The joining surfaces 222a and 212a extend along the stacking direction of the cell members 250.
In addition, the second end frame unit 230 includes a second end plate 231 having a rectangular planar shape, and a rim 232 having a quadrangular shape is provided at a position away from an outer peripheral edge of the second end plate 231 toward an inner peripheral side by a predetermined distance. The second end frame unit 230 surrounds the positive electrode 251 of the cell member 250 and a side surface of the cell member 250, on the other end side (the upper end side in
The second end plate 231 has substantially the same thickness as the substrate 211. The rim 232 is formed thicker than the second end plate 231 in the stacking direction and is formed to protrude from a surface on one side (the lower side in
The second end plate 231 of the second end frame unit 230 is arranged in parallel with the substrate 211 of the internal frame unit 210 positioned adjacent thereto in the stacking direction, and the rim 232 is arranged to face an inner side surface of the second rim 213 of the internal frame unit 210. A surface of the rim 232 of the second end frame unit 230 facing the inner side surface of the second rim 213 of the internal frame unit 210 serves as a joining surface 232a. In addition, the surface of the second rim 213 of the internal frame unit 210 facing the outer side surface of the rim 232 of the second end frame unit 230 serves as the joining surface 213a. The joining surfaces 232a and 213a extend along the stacking direction of the cell members 250.
The positive-electrode lead layer 201 is disposed on one surface (the lower surface in
An electrolyte layer 205 made of a glass fiber mat or the like impregnated with an electrolytic solution such as sulfuric acid is disposed between the positive active material layer 203 and the negative active material layer 204 facing each other.
The negative-electrode lead layer 202 is also disposed on the other surface of the first end plate 221 of the first end frame unit 220. The negative active material layer 204 is disposed on the negative-electrode lead layer 202 of the first end plate 221. The electrolyte layer 205 made of a glass fiber mat or the like impregnated with an electrolytic solution such as sulfuric acid is disposed between the negative active material layer 204 on the first end plate 221 and the facing positive active material layer 203 of the substrate 211.
The positive-electrode lead layer 201 is also disposed on one surface (the lower surface in
The negative-electrode lead layer 202 on the first end plate 221 of the first end frame unit 220 is provided with a negative electrode terminal 207 that is electrically connected with the outside of the first end plate 221. The positive-electrode lead layer 201 on the second end plate 231 of the second end frame unit 230 is provided with a positive electrode terminal 206 that is electrically connected with the outside of the second end plate 231.
That is, the bipolar battery 200 according to the second embodiment includes the plurality of cell members 250, each including the positive electrode 251 having the positive active material layer 203, the negative electrode 252 having the negative active material layer 204, and the electrolyte layer 205 interposed between the positive electrode 251 and the negative electrode 252. The plurality of cell members 250 are arranged to be stacked at intervals. The plurality of frame units (the plurality of internal frame units 210, the first end frame unit 220, and the second end frame unit 230) respectively forming the plurality of cells 260 respectively incorporate the plurality of cell members 250.
The cell members 250 adjacent in the stacking direction are electrically connected in series. Therefore, the substrate 211 interposed between the cell members 250 adjacent in the stacking direction includes means of electrically connecting the positive-electrode lead layer 201 and the negative-electrode lead layer 202.
In the bipolar battery 200 according to the second embodiment, each of the plurality of frame units (the plurality of internal frame units 210, the first end frame unit 220, and the second end frame unit 230) is configured by a frame unit made of a light transmissive resin material.
Specifically, the first end frame unit 220 at one end (the lower end in
Here, a resin component of the light transmissive resin material serving as a base material is a thermoplastic resin, and the thermoplastic resin that exhibits a transmittance between 50% and 95% inclusive with respect to light having a wavelength (approximately between 380 nm and 2000 nm inclusive) selected from a range of visible light (approximately between 380 nm and 780 nm inclusive) and near-infrared light (approximately between 780 nm and 2000 nm inclusive) may be used as the base material.
In addition, a resin component of a light absorbing resin material to be described later serving as a base material is a thermoplastic resin that contains a light absorbing agent. The thermoplastic resin serving as the base material may contain the light absorbing agent to exhibit an absorbance between 5% and 60% inclusive with respect to light having a wavelength (approximately between 380 nm and 2000 nm inclusive) selected from a range of visible light (approximately between 380 nm and 780 nm inclusive) and near-infrared light (approximately between 780 nm and 2000 nm inclusive).
Examples of the thermoplastic resin applicable as the light transmissive resin material and the light absorbing resin material include acrylonitrile butadiene styrene (ABS) resin, polycarbonate (PC), polystyrene (PS), acrylic resin (PMMA), cyclic polyolefin (COP), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polybutylene terephthalate (PBT), polyacetal (POM), and polyphenylene sulfide (PPS), and combinations thereof. PP and ABS resin are particularly preferable.
Although the light transmissive resin material and the light absorbing resin material may use different thermoplastic resins as their base materials, it is preferable to use the same thermoplastic resin because there is no difference in melting point and thermal expansion coefficient, and joining reliability is increased.
As the light absorbing agent, for example, conventionally known dyes, pigments, and the like can be used. Examples include a cyanine compound, a phthalocyanine compound, a dithiol metal complex, a naphthoquinone compound, a diimmonium compound, an azo compound, a naphthalocyanine compound, a nickel dithiolene complex, a squarylium dye, a quinone-based compound, quinacridone, dioxane, benzimidazolone, carbon black, titanium oxide, a ferrite compound such as nickel-iron ferrite, manganese-zinc ferrite, nickel-zinc ferrite, or copper-zinc ferrite, nickel, iron particles, gold particles, and copper particles. One of these components can be used singly, or two or more of them can be used in combination.
In particular, in a case where light (e.g., a laser beam) in a visible light region (approximately between 380 nm and 780 nm inclusive) is used, for example, a phthalocyanine compound, quinacridone, dioxane, benzimidazolone, titanium oxide, gold particles, copper particles, or the like is preferably applied as the light absorbing agent. In a case where light (laser beam) in a near-infrared region (approximately between 780 nm and 2000 nm inclusive) is used, for example, a phthalocyanine compound, nickel, iron particles, manganese-zinc ferrite, nickel-zinc ferrite, copper-zinc ferrite, titanium oxide, or the like, or some combination thereof, is preferably applied as the light absorbing agent.
As the light absorbing agent, any shape such as a spherical form, a powdery form, or a granular form can be used as well as a particulate form. An average particle size of the light absorbing agent is preferably within a range of approximately 0.01 μm to 2 μm. For measurement of the average particle size, for example, a primary particle size of the light absorbing agent in an observation sample may be measured at a predetermined magnification (for example, 100,000 times) using a transmission electron microscope, and an average value thereof may be used. In a case where the shape of the light absorbing agent is not spherical, a major axis and a minor axis may be measured, and a value calculated as (the sum of the major axis and the minor axis)/2 may be used as the average particle size.
In the bipolar battery 200 according to the second embodiment, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction (the vertical direction in
Specifically, in order from one side to the other side in the stacking direction (from the lower side to the upper side in
In addition, the joining surface 213a provided on the second rim 213 of the internal frame unit 210 (a frame unit made of the light transmissive resin material) and the joining surface 212a provided on the first rim 212 of the other internal frame unit 210 (a frame unit made of the light transmissive resin material) adjacent to the internal frame unit 210 (a frame unit made of the light transmissive resin material) in the stacking direction are melted and solidified at the welded portion 240, to be welded and joined together. The welded portion 240 is formed over an entire periphery of the second rim 213 and the first rim 212.
Furthermore, the joining surface 213a provided on the second rim 213 of the other internal frame unit 210 (a frame unit made of the light transmissive resin material) and the joining surface 232a provided on the rim 232 of the second end frame unit 230 (a frame unit made of the light transmissive resin material) adjacent to the other internal frame unit 210 (a frame unit made of the light transmissive resin material) in the stacking direction are melted and solidified at the welded portion 240, to be welded and joined together. The welded portion 240 is formed over an entire periphery of the second rim 213 and the rim 232.
Here, as described above, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material are melted and solidified at the respective welded portions 240 via the joining members 241 (see
When the bipolar battery 200 is manufactured, first, as illustrated in
Specifically, the first end frame unit 220 (a frame unit made of the light transmissive resin material), the internal frame unit 210 (a frame unit made of the light transmissive resin material), the other internal frame unit 210 (a frame unit made of the light transmissive resin material), and the second end frame unit 230 (a frame unit made of the light transmissive resin material) are arranged in this order from the one side to the other side in the stacking direction (from the lower side to the upper side in
Next, as illustrated in
Specifically, the joining member 241 made of the light absorbing resin material is arranged between the joining surface 222a provided on the rim 222 of the first end frame unit 220 (a frame unit made of the light transmissive resin material) and the joining surface 212a provided on the first rim 212 of the internal frame unit 210 (a frame unit made of the light transmissive resin material) adjacent thereto in the stacking direction.
In addition, the joining member 241 made of the light absorbing resin material is arranged between the joining surface 213a provided on the second rim 213 of the internal frame unit 210 (a frame unit made of the light transmissive resin material) and the joining surface 212a provided on the first rim 212 of the other internal frame unit 210 (a frame unit made of the light transmissive resin material) adjacent thereto in the stacking direction.
Furthermore, the joining member 241 made of the light absorbing resin material is arranged between the joining surface 213a provided on the second rim 213 of the other internal frame unit 210 (a frame unit made of the light transmissive resin material) and the joining surface 232a provided on the rim 232 of the second end frame unit 230 (a frame unit made of the light transmissive resin material) adjacent thereto in the stacking direction.
The respective joining members 241 made of the light absorbing resin material are formed in a quadrangular frame shape such that the respective welded portions 240 are formed over the entire peripheries of the rim 222, the first rim 212, the second rim 213, the first rim 212, the second rim 213, and the rim 232. A width a2 of each of the joining members 241 made of the light absorbing resin material along the stacking direction is preferably determined as appropriate in consideration of a width W2 of each of the joining surfaces 222a, 212a, 213a, and 232a and a joining strength of each of the welded portions 240. In addition, a thickness t2 of each of the joining members 241 made of the light absorbing resin material in the stacking direction is preferably determined as appropriate in consideration of the joining strength of each of the welded portions 240.
Next, the plurality of welded portions 240 are generated by laser welding, and the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are joined together. That is, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are welded and joined at the welded portions 240 formed by emitting laser beams to pass through one of the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material to the joining members 241 made of the light absorbing resin material, which causes the joining members 241 made of the light absorbing resin material and the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material to be melted and solidified (a joining step).
Specifically, as illustrated in
Note that it is preferable that a region irradiated with the laser beam C along the stacking direction is substantially an entire region of the width a2 of the joining member 241 made of the light absorbing resin material along the stacking direction.
Moreover, the laser beam C preferably has a wavelength selected from the range between 380 nm and 2000 nm inclusive (furthermore, between 380 nm and 1200 nm inclusive, and particularly between 380 nm and 500 nm inclusive, and between 1000 nm and 1200 nm inclusive).
In addition, as illustrated in
Note that it is preferable that a region irradiated with the laser beam D along the stacking direction is substantially an entire region of the width a2 of the joining member 241 made of the light absorbing resin material along the stacking direction similarly to the laser beam C.
Moreover, the laser beam D preferably has a wavelength selected from the range between 380 nm and 2000 nm inclusive (furthermore, between 380 nm and 1200 nm inclusive, and particularly between 380 nm and 500 nm inclusive, and between 1000 nm and 1200 nm inclusive).
Furthermore, although not illustrated in the drawings, on the other side in the stacking direction, a laser beam is emitted to pass through the second rim 213 of the other internal frame unit 210 (a frame unit made of the light transmissive resin material) to the joining member 241 made of the light absorbing resin material arranged between the joining surface 213a of the other internal frame unit 210 (a frame unit made of the light transmissive resin material, the upper internal frame unit 210 in
Note that it is also preferable that a region irradiated with the laser beam along the stacking direction is also substantially an entire region of the width a2 of the joining member 241 made of the light absorbing resin material along the stacking direction similarly to the laser beams C and D.
Moreover, the laser beam also preferably has a wavelength selected from the range between 380 nm and 2000 nm inclusive (furthermore, between 380 nm and 1200 nm inclusive, and particularly between 380 nm and 500 nm inclusive, and between 1000 nm and 1200 nm inclusive).
The bipolar battery 200 is completely manufactured by injecting the electrolytic solution of the electrolyte layer 205 into the cell 260 through an injection port (not illustrated) after the joining step of the plurality of internal frame units 210, the first end frame unit 220, and the second end frame unit 230.
As described above, with the bipolar battery 200 according to the second embodiment, each of the plurality of frame units (the plurality of internal frame units 210, the first end frame unit 220, and the second end frame unit 230) is configured by the frame unit made of the light transmissive resin material.
The two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are melted and solidified at the welded portions 240 via the joining members 241 (see
As a result, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are joined at the welded portions 240 via the joining members 241 (see
In addition, the welded portions 240 at which the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material are melted and solidified via the joining members 241 made of the light absorbing resin material to be welded and joined together have increased airtightness compared to a joining method using an adhesive. Furthermore, when the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material are joined together, burrs are less likely to be generated, and a possibility that burrs enter the cells 260 can be reduced.
Because all of the plurality of frame units 210, 220, and 230 are configured by the frame units made of the same light transmissive resin material, there is no difference in thermal expansion coefficient between the frame units, the joining reliability by the welded portions 240 can be improved, and it is possible to reliably minimize or prevent electrolytic solution leakage out of the cells 260.
In addition, with the bipolar battery 200 according to the second embodiment, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction respectively include the joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a extending along the stacking direction. The joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a of the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction are joined at the welded portions 240. As a result, the joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a of the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction, the joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a extending along the stacking direction, can be joined at the welded portions 240. Thus, it is possible to reliably prevent the electrolytic solution leakage out of the cells 260 by means of the simple seal structure.
In addition, with the bipolar battery 200 according to the second embodiment, the resin component of the light transmissive resin material serving as the base material is the thermoplastic resin, and the resin component of the light absorbing resin material serving as the base material is the thermoplastic resin and contains the light absorbing agent. As a result, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250, the resin component of the light transmissive resin material serving as the base material being the thermoplastic resin, are welded and joined via the joining members 241 made of the light absorbing resin material, the resin component of the light absorbing resin material serving as the base material being the thermoplastic resin and containing the light absorbing agent. The two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 260 by means of the simple seal structure.
In addition, with the bipolar battery 200 according to the second embodiment, the light transmissive resin material uses as the base material the thermoplastic resin exhibiting transmittance between 50% and 95% inclusive with respect to the light having the wavelength selected from the range between 380 nm and 2000 nm inclusive. The light absorbing resin material contains the light absorbing agent in the thermoplastic resin as the base material to exhibit absorbance between 5% and 60% inclusive with respect to the light having the wavelength selected from the range between 380 nm and 2000 nm inclusive. As a result, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material as described are joined via the joining members 241 made of the light absorbing resin material as described. The two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are sealed to eliminate the gap, and it is possible to reliably prevent the electrolytic solution leakage out of the cells 260 by means of the simple seal structure.
In addition, with the bipolar battery 200 according to the second embodiment, the thermoplastic resin contains at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin. As a result, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material using as the base material the thermoplastic resin containing at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin are joined via the joining members 241 made of the light absorbing resin material containing the light absorbing agent in the thermoplastic resin containing at least one of the acrylonitrile-butadiene-styrene resin or the polypropylene resin. The two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are sealed to eliminate the gap. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 260 by means of the simple seal structure.
In addition, with the bipolar battery 200 according to the second embodiment, the joining members 241 made of the light absorbing resin material have a sheet shape. As a result, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are welded and joined via the sheet-shaped joining members 241 made of the light absorbing resin material. Thus, it is possible to reliably prevent electrolytic solution leakage out of the cells 260 by means of the simple seal structure.
In addition, the method of manufacturing the bipolar battery 200 according to the second embodiment includes the frame unit arranging step of stacking and arranging the plurality of frame units 210, 220, and 230 in the stacking direction of the cell members 250, each of the plurality of internal frame units 210, the first end frame unit 220, and the second end frame unit 230 being configured by the frame unit made of the light transmissive resin material. The method also includes the joining member arranging step of arranging the joining members 241 made of the light absorbing resin material between the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250. The method also includes the joining step of welding and joining together at the welded portions 240 the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250. The welded portions 240 are formed by emitting the laser beams to pass through one (220, 210, and 210) of the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material to the joining members 241 made of the light absorbing resin material, which causes the joining members 241 made of the light absorbing resin material and the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material to be melted and solidified.
As a result, it is possible to reliably prevent electrolytic solution leakage out of the cells 260 by means of a simple seal method using laser welding and a simple seal structure.
In addition, with the method of manufacturing the bipolar battery according to the second embodiment, in the joining member arranging step, the joining members 241 made of the light absorbing resin material are arranged between the joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a respectively provided on the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction. The joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a extend along the stacking direction. In the joining step, the joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a of the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction are joined at the welded portions 240.
As a result, the width of each of the joining surfaces 222a and 212a, 213a and 212a, and 213a and 232a extending along the stacking direction can be made larger than the width of the joining surface extending along the direction perpendicular to the stacking direction. Thus, a creepage distance of the electrolytic solution leakage out of the cells 260 can be made larger than a creepage distance when using the joining surface extending along the direction perpendicular to the stacking direction, and electrolytic solution sealing performance can be further improved.
In addition, with the method of manufacturing the bipolar battery according to the second embodiment, the joining members 241 made of the light absorbing resin material have a sheet shape. As a result, in the joining member arranging step, the sheet-shaped joining members 241 made of the light absorbing resin material are arranged between the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250. In the joining step, the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material adjacent in the stacking direction of the cell members 250 are welded and joined at the welded portions 240 formed by emitting the laser beams to pass through one of the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material to the sheet-shaped joining members 241 made of the light absorbing resin material. This causes the joining members 241 made of the light absorbing resin material and the two frame units 220 and 210, 210 and 210, and 210 and 230 made of the light transmissive resin material to be melted and solidified. It is possible to reliably prevent electrolytic solution leakage out of the cells 260 by means of the simple seal method using laser welding and the simple seal structure.
Although the embodiments of the present invention have been described above, the present invention is not limited thereto, and various modifications and improvements can be made therein.
For example, in the bipolar battery 100 according to the first embodiment, the two internal frame units 110 are provided. However, the number may be one or may be three or more.
In addition, in the bipolar battery 200 according to the second embodiment, the two internal frame units 210 are provided. However, the number may be one or may be three or more.
In addition, the electrical connection means provided in the substrate 111 and substrate 211 in the bipolar battery 100 and bipolar battery 200 according to the first and second embodiments is not limited to a specific method. For example, opposite surfaces of the substrate may be electrically connected by causing the entire substrate to contain conductive particles or conductive fibers. A conductive member that enables electrical connection may also be incorporated in the substrate.
Moreover, in the method of manufacturing the bipolar battery 100 according to the first embodiment, the laser beams are emitted to pass through one (e.g., frame units 110, 110, and 130) of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to the joining members 141 made of the light absorbing resin material. However, light other than the laser beam may be emitted to pass through one of the two frame units 120 and 110, 110 and 110, and 110 and 130 made of the light transmissive resin material to the joining members 141 made of the light absorbing resin material. The same applies to the method of manufacturing the bipolar battery 200 according to the second embodiment.
In addition, the bipolar battery 100 according to the first embodiment is the bipolar lead-acid battery in which the positive electrode 151 has the positive-electrode lead layer 101, and the negative electrode 152 has the negative-electrode lead layer 102. However, the bipolar battery may use a metal other than lead for the positive electrode 151 and the negative electrode 152. The same applies to the bipolar battery 200 according to the second embodiment.
Because the bipolar battery and the method of manufacturing the same according to the present invention can reliably prevent the electrolytic solution leakage out of the cell by means of the simple seal structure, both high energy density and long-term reliability can be achieved, and the bipolar battery and the method of manufacturing the same can be extremely advantageously used in various industries.
The following is a list of reference signs used in this specification and in the drawings.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2020-212892 | Dec 2020 | JP | national |
This application is a continuation of PCT Application No. PCT/JP2021/043237, filed Nov. 25, 2021, the disclosure of which is incorporated herein in its entirety by reference.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2021/043237 | Nov 2021 | US |
| Child | 18339019 | US |
