The invention relates generally to semiconductor device and integrated circuit fabrication and, in particular, to fabrication methods, device structures, and design structures for a bipolar junction transistor.
Bipolar junction transistors may be utilized in integrated circuits designed for high-frequency applications and in integrated circuits designed for high-power applications such as power amplifiers. Generally, a bipolar junction transistor is comprised of three distinct semiconductor regions that define terminals, namely an emitter, a collector, and a base disposed between the emitter and collector. An NPN bipolar junction transistor includes a layer of p-type semiconductor material constituting the base and two layers of n-type semiconductor material constituting the emitter and collector. The layers of n-type semiconductor material are sandwiched between the two layers of n-type semiconductor material. The conductivity types of the semiconductor materials for the emitter, base and collector in a PNP bipolar junction transistor are reversed. Generally, the differing conductivity types of the emitter, base, and collector form a pair of p-n junctions, namely a collector-base junction and an emitter-base junction. A voltage applied across the emitter-base junction controls the movement of charge carriers between the collector and emitter.
Improved fabrication methods, device structures, and design structures are needed for a bipolar junction transistor.
In an embodiment of the invention, a method is provided for fabricating a bipolar junction transistor. The method includes forming a first layer comprised of a first semiconductor material and disposed on substrate containing a first terminal (e.g., a collector), forming a second layer comprised of a second semiconductor material and disposed on the first layer, and forming a patterned hardmask layer on the second layer. A trench is formed that extends through the patterned hardmask layer, the first layer, and the second layer and into the substrate. The trench defines a section of the first layer and a section of the second layer stacked with the section of the first layer. The method further includes etching the substrate and the section of the second layer selective to the section of the first layer and the patterned hardmask layer so that the section of the second layer is narrowed relative to the section of the first layer to define a second terminal (e.g., an emitter) and a portion of the trench in the substrate is widened to undercut the section of the first layer.
In an embodiment of the invention, a device structure is provided for a bipolar junction transistor. The device structure includes a base layer comprised of a first semiconductor material and disposed on a substrate. The device structure includes a first terminal in the substrate and a second terminal comprised of a second semiconductor material. The first terminal is coextensive with the trench isolation region and the second terminal is disposed on the base layer. A trench isolation region extends into the substrate and laterally beneath the base layer so that a portion of the base layer overhangs the trench isolation region.
According to another embodiment of the present invention, a design structure is provided for a bipolar junction transistor that is readable by a machine used in design, manufacture, or simulation of an integrated circuit. The design structure includes a base layer comprised of a first semiconductor material and disposed on a substrate. The design structure includes a first terminal in the substrate and a second terminal comprised of a second semiconductor material. The first terminal is coextensive with the trench isolation region and the second terminal is disposed on the base layer. A trench isolation region extends into the substrate and laterally beneath the base layer so that a portion of the base layer overhangs the trench isolation region. The design structure may comprise a netlist. The design structure may also reside on storage medium as a data format used for the exchange of layout data of integrated circuits. The design structure may reside in a programmable gate array.
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate various embodiments of the invention and, together with a general description of the invention given above and the detailed description of the embodiments given below, serve to explain the embodiments of the invention.
With reference to
A base layer 12 is formed as a continuous additive film on the top surface 10a of substrate 10. The base layer 12 may be comprised of a semiconductor material, such as silicon-germanium (SiGe) in an alloy with a content of silicon (Si) ranging from 95 atomic percent to 50 atomic percent and a content of germanium (Ge) ranging from 5 atomic percent to 50 atomic percent. The germanium content of the base layer 12 may be uniform across the thickness of base layer 12 or graded and/or stepped across the thickness of base layer 12. If the germanium content is stepped, thicknesses of the base layer 12, such as respective thicknesses directly contacting the substrate 10 and adjacent to the top surface 12a, may lack germanium and may therefore be entirely comprised of silicon. The base layer 12 may comprise a dopant, such as a p-type dopant selected from Group III of the Periodic Table (e.g., boron) in a concentration that is effective to impart p-type conductivity and, optionally, carbon (C) to suppress the outdiffusion of the p-type dopant.
Base layer 16 may be formed using a low temperature epitaxial (LTE) growth process, such as vapor phase epitaxy (VPE) that may be conducted at a growth temperature ranging from 400° C. to 850° C. Single crystal semiconductor material (e.g., single crystal silicon and/or single crystal SiGe) is epitaxially grown or deposited on the exposed top surface 10a of substrate 10.
An emitter layer 14 is formed as a continuous additive film on the top surface 12a the base layer 12. The emitter layer 14 may be comprised of a different semiconductor material than base layer 12 and may have an opposite conductivity type from the base layer 12. For example, the emitter layer 14 may lack germanium that is present in at least a portion of the base layer 12. In a representative embodiment, the emitter layer 14 may be comprised of a semiconductor material, such as silicon, and may contain an n-type dopant in a concentration effective to impart n-type conductivity.
The base layer 12 and emitter layer 14 each have an epitaxial relationship with the substrate 10 and are grown using an epitaxial growth technique, such as vapor phase epitaxy. The crystal structure of the substrate 10 serves as a crystalline template for the growth of the crystal structure of the base layer 12. The crystal structure of the base layer 12 serves as a crystalline template for the growth of the crystal structure of the emitter layer 14.
A hardmask layer 15 comprised of a dielectric material, such as silicon dioxide (SiO2), may be formed on a top surface 14a of emitter layer 14. A mask layer 16 may be applied on the top surface of the hardmask layer 15 and patterned with photolithography to define openings 16a, 16b. To that end, the mask layer 16 may comprise a light-sensitive material, such as a photoresist, that is applied as a coating by a spin coating process, pre-baked, exposed to light projected through a photomask, baked after exposure, and developed with a chemical developer to form an etch mask that features the openings 16a, 16b. The openings 16a, 16b in the mask layer 16 are extended into the hardmask layer 15 with an etching process having a suitable etch chemistry. The mask layer 16 may be removed after the hardmask layer 15 is patterned. If comprised of a photoresist, the mask layer 16 may be removed by ashing or solvent stripping, followed by a conventional cleaning process.
Trenches 18, 20 are defined that extend completely through the emitter layer 14, completely through the base layer 12, and to a shallow depth, d1, into the substrate 10. The trenches 18, 20 are formed in alignment with the openings 16a, 16b in the hardmask layer 15. A section 22 of base layer 12 and a section 24 of emitter layer 14 are positioned between the sidewall 17 of trench 18 and the sidewall 19 of trench 20. The sidewalls 17, 19 of the trenches 18, 20 may be vertically oriented (i.e., aligned normal to the top surface 10a of the substrate). The sidewalls 17, 19 may be interconnected to surround the sections 22, 24 or, alternatively, the trenches 18, 20 may be parallel and lack any interconnection. Sidewall 17 may be separated from sidewall 19 by a distance equal to a width, w1.
The etching process forming the trenches 18, 20 may comprise a wet chemical etching process or a dry etching process, such as reactive-ion etching (RIE). The etching process, which may be conducted in a single etching step or multiple steps, relies on one or more etch chemistries to etch the semiconductor materials of layers 12, 14 and substrate 10 while substantially not etching the dielectric material of the hardmask layer 15, and may comprise one or more timed etches. The hardmask 15 covers and preserves the sections 22, 24 during the etching process forming the trenches 18, 20.
With reference to
A collector 34 is laterally bounded in the substrate 10 between the surfaces 26, 28 of the cavities 30, 32. The collector 34 is comprised of the semiconductor material of the substrate 10, and may be selectively implanted with an impurity to further enhance its electrical conductivity. In one embodiment, the collector 34 may comprise n-type semiconductor material and may optionally be implanted with an n-type dopant to enhance its electrical conductivity relative to the bulk of the substrate 10.
The section 24 of emitter layer 14 is also narrowed when the cavities 30, 32 are defined in substrate 10 by widening and deepening the portion of the trenches 18, 20 in the substrate 10 because the emitter layer 14 is also undercut relative to the hardmask layer 15. The section 24 of emitter layer 14 includes sidewalls 25, 27 that are separated by a width w2. The section 22 of base layer 12 includes side surfaces 21, 23 that are separated by a width, w3, that is greater than the width w2 of section 24. The surfaces 26, 28, which are coextensive with the collector 34, are separated by a varying distance that is less than or equal to w3. In one embodiment, the width, w3, of the section 22 of base layer 12 may be at least two times greater than the minimum separation between the surfaces 26, 28, and the width, w3, of the section 22 of base layer 12 at least two times greater than the width w2, of the section 24 of emitter layer 14. The surfaces 21, 23, which are depicted as vertical, may have a different geometrical shape, such as a faceted shape or an inclined shape.
To narrow the section 24 of emitter layer 14 and form the cavities 30, 32, the semiconductor materials of the emitter layer 14 and the substrate 10 may be etched by a wet chemical etching process, a dry etching process, or a combination of wet chemical and dry etching processes selective to the respective materials of the hardmask layer 15 and the base layer 12. The semiconductor materials of the substrate 10 and emitter layer 14 are etched selective to the materials of the base layer 12 and the hardmask layer 15. The selective etching may originate from the use of a composition-sensitive etchant that etches the semiconductor materials of emitter layer 14 and the substrate 10 at higher rates than the materials of the base layer 12 and hardmask layer 15. In an alternative embodiment, the etching process used to narrow the section 24 of emitter layer 14 may be different from the etching process used to form the cavities 30, 32. In the representative embodiment, a thin portion of the base layer 12 having a composition similar to the composition of the substrate 10 and bordering the cavities 30, 32 is removed over a thickness, d2, by the etching process. The hardmask layer 15 may be removed after the section 24 of emitter layer 14 is narrowed and the cavities 30, 32 are formed.
The etching process may be controlled by selecting factors such as the etchant chemistry, duration, etc. Each etching process may be combined with implantation damage to the semiconductor material and/or impurity-doping of the semiconductor material to alter etch rates and, thereby, the profile of the cavities 30, 32 and the profile for the sidewalls 25, 27 of section 24. The etching process may further rely on wafer orientation and anisotropic etching processes that exhibit different etch rates for different crystallographic directions (as specified, for example, by Miller indices) in a single-crystal semiconductor material. In one embodiment, the vertical and lateral etch rates may be the same when the cavities 30, 32 are formed.
In an embodiment, the etching process may rely on orientation-dependent or anisotropic etching that exhibits different etch rates for different crystallographic directions (as specified, for example, by Miller indices) in a semiconductor material. As an example, if the substrate 10 and emitter layer 14 are comprised of silicon, then the anisotropic etching process may comprise a wet chemical etching process that uses an etchant comprising tetramethylammonium hydroxide (TMAH), ammonium hydroxide (NH4OH), ethylenediamine pyrocatechol (EDP), or potassium hydroxide (KOH). To provide a substrate orientation suitable for an anisotropic etching process, before the mask layer 16 (
The section 24 of emitter layer 14 (i.e., the emitter in the completed device structure), the section 22 of base layer 12, and the cavities 30, 32 bounding the collector 34 are defined using a single mask layer 16 and hardmask layer 15. The terminals of the bipolar junction transistor are self-aligned relative to each other when formed using the hardmask layer 15. This process flow eliminates a mask normally used to define an emitter window in which an emitter is formed and may save multiple masks, which may reduce production costs by eliminating photolithography and etching processes. In addition, selective epitaxy is not required to grow the collector because the collector is defined in the substrate 10 when the cavities 30, 32 are etched, or to grow the base layer 12 because the base layer 12 is deposited non-selectively as a continuous layer and then etched to define section 22.
With reference to
A dielectric layer 40 is formed on the layer 36 and a directional anisotropic etching process, such as RIE, is used to preferentially remove the electrical insulator of dielectric layer 40 from horizontal surfaces, such as the surfaces 31, 33, selective to the dielectric material constituting dielectric layer 36. The dielectric layer 40 is retained on horizontal or partially horizontal surfaces, including surfaces 26, 28, that are hidden inside the cavities 30, 32. After etching, the dielectric layer 40 is discontinuous and includes spacers 38 formed on the sidewalls 25, 27 of the section 24 of emitter layer 14, sections on the sidewalls 21, 23 of the section 22 of base layer 12, and sections on the surfaces 26, 28 in the substrate 10 bordering the cavities 30, 32. Dielectric layer 40 may be comprised of an electrical insulator, such as Si3N4, that is conformally deposited by CVD. The selective removal of the dielectric layer 40 exposes the dielectric layer 36 on surfaces 31, 33, the top surface 24a of section 24 of emitter layer 14, and the top surface 22a of the section 22 of base layer 12 not covered by section 24.
Sections 44 of base layer 12, which overhang the cavities 30, 32 and the trench isolation regions subsequently formed in the cavities 30, 32, are not covered by the section 24 of emitter layer 14 and the spacers 38. These sections 44 of base layer 12 may be modified to increase their electrical conductivity by, for example, implanting the sections 44 with ions comprising a p-type dopant at a kinetic energy and dose selected to provide a concentration effective to impart p-type conductivity. A thermal anneal may be used to activate the dopant and alleviate implantation damage. These sections 44 of base layer 12 may define an extrinsic base in the device structure.
With reference to
Sections 50 of a silicide layer are formed on contact area 42 and may be subsequently used in the process flow to contact the collector 34. Sections 51 of the silicide layer are formed on the top surface 22a of the section 22 of base layer 12 not covered by section 24 and may be subsequently used in the process flow to contact section 22. A section 52 of the silicide layer is formed on the top surface 24a of section 24 of emitter layer 14 and may be subsequently used in the process flow to contact section 24. Sections 53 of the silicide layer are formed on the surfaces 31, 33 inside the cavities 30, 32.
The sections 50-53 of the silicide layer may be formed by a silicidation process that involves one or more annealing steps to form a silicide phase by reacting a layer of silicide-forming metal and the semiconductor material contacting the silicide-forming metal. The layer of a silicide-forming metal is deposited by, for example, a CVD process or a physical vapor deposition (PVD) process. Candidate refractory metals for the silicide-forming metal include, but are not limited to, titanium (Ti), cobalt (Co), or nickel (Ni). A capping layer comprised of a metal nitride, such as sputter-deposited titanium nitride (TiN), may be applied to cap the silicide-forming metal.
An initial annealing step of the silicidation process may form a metal-rich silicide that consumes the silicide-forming metal and then form silicides of lower metal content that grow by consuming the metal-rich silicides. For example, the initial annealing step may be conducted by heating the silicide-forming metal utilizing rapid thermal annealing (RTA) at an annealing temperature, which may be contingent on the type of refractory metal, of about 400° C. to about 900° C. The silicide layer does not form on surfaces that are covered by the dielectric layer 40 and spacers 38, which promotes self-alignment of the silicide layer and the sectioning.
Following the initial annealing step, any non-converted silicide-forming metal and the optional capping layer may be removed with, for example, one or more wet chemical etches. The sections 50-53 of silicide may then be subjected to an additional annealing step to form a lower-resistance silicide phase. The annealing temperature of the additional annealing step may be greater than the annealing temperature of the initial annealing step.
With reference to
Portions of the dielectric layer 60 may at least partially fill the cavities 30, 32 to define trench isolation regions 66, 68 that laterally flank the collector 34. The trench isolation regions 66, 68 will have dimensions and locations that reproduce the dimensions, geometrical shape, and locations of cavities 30, 32. As a result, the sections 44 of the base layer 14 overhang the trench isolation regions 66, 68.
A sub-collector 58, which is comprised of a doped region of the semiconductor material of substrate 10, extends laterally from the sub-collector 58 beneath the trench isolation regions 66, 68. The sub-collector 58 couples the collector 34 with the sections 50 of the silicide layer and the contacts 62. The sub-collector 58 may be formed by implanting the substrate 10 with ions of an impurity before an epitaxial layer is formed on the substrate 10. The semiconductor material of the sub-collector 58 has the same conductivity type as the semiconductor material of the collector 34.
The resulting device structure is a bipolar junction transistor 70 characterized by a vertical architecture that includes the collector 34, an intrinsic base defined by the portion of section 22 of base layer 12 between the emitter and collector 34, and an emitter defined by the section 24 of emitter layer 14. The section 24 of base layer 12 functioning as the intrinsic base is coextensive with the collector 34 along a junction 72. The section 24 of emitter layer 14 functioning as the emitter is coextensive with the section 24 of base layer 12 along a junction 74. Sections 44 of base layer 12 that are peripheral to the section 24 of base layer 12 may define an extrinsic base that is directly coupled with the intrinsic base. The bipolar junction transistor 70 may be characterized as a heterojunction bipolar transistor (HBT) if two or all three of the emitter, the collector 34, and the intrinsic base are comprised of different semiconductor materials.
In an alternative embodiment, the function and identity of the emitter and the collector as terminals may be exchanged to provide a collector-up configuration for the bipolar junction transistor 70 rather than the emitter-up configuration. In a collector-up configuration, the collector 34 would operate as an emitter and the section 24 of emitter layer 14 would function as a collector. In addition, the sub-collector 58 would function as a sub-emitter that couples the emitter with the contact area 42.
Contacts 62 extend through the dielectric layer 60 to contact the sections 50 of silicide layer and, thereby, to be coupled with the collector 34 of bipolar junction transistor 70. Contacts 63 extend through the dielectric layer 60 to contact the sections 51 of silicide layer and, thereby, to be coupled with the sections 44 of base layer 12 (i.e., the extrinsic base of bipolar junction transistor 70). Contacts 64 extend through the dielectric layer 60 to contact the section 52 of silicide layer and, thereby, to be coupled with the section 24 of emitter layer 14 (i.e., the emitter of bipolar junction transistor 70).
In an alternative embodiment, the sections 53 of silicide layer may be used to contact the collector 34, instead of sections 50, by displacing the contacts 62 laterally to intersect sections 53. Otherwise, these sections 53 of the silicide layer may be non-functional and merely buried in the dielectric layer 60.
During the front-end-of-line (FEOL) portion of the fabrication process, the device structure of the bipolar junction transistor 70 is replicated across at least a portion of the surface area of the substrate 10. In BiCMOS integrated circuits, complementary metal-oxide-semiconductor (CMOS) transistors may be formed using other regions of the substrate 10. As a result, both bipolar and CMOS transistors may be available on the same substrate 10. Standard back-end-of-line (BEOL) processing follows, which includes formation of dielectric layers, via plugs, and wiring for an interconnect structure coupled by the local interconnect structure with the bipolar junction transistor 70, as well as other similar contacts for additional device structures like bipolar junction transistor 70 and CMOS transistors included in other circuitry fabricated on the substrate 10.
The emitter, intrinsic base, and collector (i.e., the terminals) of the bipolar junction transistor 70 are self-aligned, which may provide high performance, and are formed by a series of photolithography and etch events in the different stages of the process flow. The self-alignment of these three terminals is done with use of a single mask, which contrasts with the multiple masks required in existing constructions for a vertical bipolar junction transistor. The width of the emitter (i.e., section 24 of the emitter layer 14) is established by lithography and etching, which may be used to fashion a comparatively wide emitter for power amplifier applications. The base layer 12 can be made comparatively thick, which may also be beneficial for power amplifier applications. The dimensions of the base layer 12, the emitter layer 14, and the collector 34 are independently controllable in the device construction.
With reference to
The etching process used to form the cavities 30, 32 in the substrate 10 penetrates through the base layer 12 to the shallow depth, d1, into the substrate 10 (
With reference to
Design flow 100 may vary depending on the type of representation being designed. For example, a design flow 100 for building an application specific IC (ASIC) may differ from a design flow 100 for designing a standard component or from a design flow 100 for instantiating the design into a programmable array, for example a programmable gate array (PGA) or a field programmable gate array (FPGA) offered by Altera® Inc. or Xilinx® Inc.
Design process 104 preferably employs and incorporates hardware and/or software modules for synthesizing, translating, or otherwise processing a design/simulation functional equivalent of the components, circuits, devices, or logic structures shown in
Design process 104 may include hardware and software modules for processing a variety of input data structure types including netlist 106. Such data structure types may reside, for example, within library elements 108 and include a set of commonly used elements, circuits, and devices, including models, layouts, and symbolic representations, for a given manufacturing technology (e.g., different technology nodes, 32 nm, 45 nm, 90 nm, etc.). The data structure types may further include design specifications 110, characterization data 112, verification data 114, design rules 116, and test data files 118 which may include input test patterns, output test results, and other testing information. Design process 104 may further include, for example, standard mechanical design processes such as stress analysis, thermal analysis, mechanical event simulation, process simulation for operations such as casting, molding, and die press forming, etc. One of ordinary skill in the art of mechanical design can appreciate the extent of possible mechanical design tools and applications used in design process 104 without deviating from the scope and spirit of the invention. Design process 104 may also include modules for performing standard circuit design processes such as timing analysis, verification, design rule checking, place and route operations, etc.
Design process 104 employs and incorporates logic and physical design tools such as HDL compilers and simulation model build tools to process design structure 102 together with some or all of the depicted supporting data structures along with any additional mechanical design or data (if applicable), to generate a second design structure 120. Design structure 120 resides on a storage medium or programmable gate array in a data format used for the exchange of data of mechanical devices and structures (e.g., information stored in an IGES, DXF, Parasolid XT, JT, DRG, or any other suitable format for storing or rendering such mechanical design structures). Similar to design structure 102, design structure 120 preferably comprises one or more files, data structures, or other computer-encoded data or instructions that reside on transmission or data storage media and that when processed by an ECAD system generate a logically or otherwise functionally equivalent form of one or more of the embodiments of the invention shown in
Design structure 120 may also employ a data format used for the exchange of layout data of integrated circuits and/or symbolic data format (e.g., information stored in a GDSII (GDS2), GL1, OASIS, map files, or any other suitable format for storing such design data structures). Design structure 120 may comprise information such as, for example, symbolic data, map files, test data files, design content files, manufacturing data, layout parameters, wires, levels of metal, vias, shapes, data for routing through the manufacturing line, and any other data required by a manufacturer or other designer/developer to produce a device or structure as described above and shown in
The methods as described above are used in the fabrication of integrated circuit chips. The resulting integrated circuit chips can be distributed by the fabricator in raw wafer form (e.g., as a single wafer that has multiple unpackaged chips), as a bare die, or in a packaged form. In the latter case, the chip is mounted in a single chip package (e.g., a plastic carrier, with leads that are affixed to a motherboard or other higher level carrier) or in a multichip package (e.g., a ceramic carrier that has either or both surface interconnections or buried interconnections). In any case the chip is then integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either (a) an intermediate product, such as a motherboard, or (b) an end product. The end product can be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device, and a central processor.
A feature may be “connected” or “coupled” to or with another element may be directly connected or coupled to the other element or, instead, one or more intervening elements may be present. A feature may be “directly connected” or “directly coupled” to another element if intervening elements are absent. A feature may be “indirectly connected” or “indirectly coupled” to another element if at least one intervening element is present.
The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.
Number | Date | Country | |
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Parent | 14070989 | Nov 2013 | US |
Child | 14677303 | US |