The present disclosure relates to the field of bipolar plates for fuel cells.
Conventional electrochemical fuel cells convert fuel and oxidant, generally both in the form of gaseous streams, into electrical energy and a reaction product. A common type of electrochemical fuel cell for reacting hydrogen and oxygen comprises a polymeric ion (proton) transfer membrane, with fuel and air being passed over respective sides of the membrane. Protons (i.e. hydrogen ions) are conducted through the membrane, balanced by electrons conducted through a circuit connecting the anode and cathode of the fuel cell. To increase the available voltage, a stack may be formed comprising a number of such membranes arranged with separate anode and cathode fluid flow paths. Such a stack is typically in the form of a block comprising numerous individual fuel cell plates held together by end plates at either end of the stack.
Because the reaction of fuel and oxidant generates heat as well as electrical power, a fuel cell stack requires cooling once an operating temperature has been reached. Cooling may be achieved by forcing air through the cathode fluid flow paths. In an open cathode stack, the oxidant flow path and the coolant path are the same, i.e. forcing air through the stack both supplies oxidant to the cathodes and cools the stack.
According to a first aspect of the invention, there is provided a bipolar plate for a fuel cell, the bipolar plate comprising:
In this way a common coolant/oxidant can be used for both cooling the plates and providing the oxidant to the cathode side of the electrode without requiring any complicated passageways or conduits.
The cavity may have at least one coolant/oxidant inlet port at a first peripheral edge of the bipolar plate for receiving the coolant/oxidant. The cavity may have at least one coolant/oxidant outlet port at a second peripheral edge for exhausting at least a portion of the coolant/oxidant. The use of a common inlet port and/or common outlet port on peripheral edges can provide easy access for the coolant/oxidant to and/or from the bipolar plate.
The bipolar plate may comprise two flow paths between the at least one coolant/oxidant inlet port and the coolant/oxidant outlet port:
The cathode sheet may comprise a coolant/oxidant distribution structure, which may comprise at least one profiled portion for distributing the coolant/oxidant and at least one punched through section that defines the opening between the cavity and the cathode surface. In this way, the coolant/oxidant within the cavity can be conveniently provided to the distribution structure for distributing across the cathode surface.
The coolant/oxidant distribution structure may comprise a first punched through section that defines an inlet opening from the cavity and a second punched through section that defines an outlet opening from the cavity. The coolant/oxidant distribution structure may comprise one or more fluid flow channels. The fluid flow channels may extend between respective inlet openings and outlet openings. In some embodiments, only a subset of the fluid flow channels may comprise punched through sections/openings. For example, alternate fluid flow channels may comprise either an inlet opening or an outlet opening.
The bipolar plate may comprise a plurality of fluid flow channels. Alternate (including a first) fluid flow channels may comprise an inlet opening at one end and be closed at the opposing end. The other (including a second) fluid flow channels may comprise an outlet opening at one end and be closed at the opposing end. The inlet openings may be nearer to a coolant/oxidant inlet port than a coolant/oxidant outlet port. The outlet openings may be nearer to a coolant/oxidant outlet port than a coolant/oxidant inlet port. In this way, the coolant/oxidant can pass through a gas diffusion layer in order to pass from the inlet opening to the outlet opening, thereby improving the exposure of the coolant/oxidant at the cathode surface of the bipolar plate.
One or more restrictions to air flow may be provided in the cavity between the anode sheet and the cathode sheet in order to increase the pressure of the coolant/oxidant at the inlet openings. The one or more restrictions to air flow may comprise a baffle. The one or more restrictions to air flow may be provided in the cavity on a single side of alternate fluid flow channels. In this way, through-channels that provide for relatively unimpeded fluid flow between an inlet port and an outlet port can be provided as alternate fluid flow paths through the bipolar plate.
The dimensions of the fluid flow channels may vary along the length of the bipolar plate and/or across the width of the bipolar plate. Varying the dimensions of the fluid flow channels can allow tuning of electrode activity across the surface of the electrode so as to improve electrode efficiency.
The profiled section may abut the anode sheet, thereby providing support for the cavity between the anode sheet and cathode sheet.
The at least one coolant/oxidant inlet port may comprise an open peripheral edge of the cavity between the anode sheet and the cathode sheet. The at least one coolant/oxidant outlet port may comprise an open peripheral edge of the cavity between the anode sheet and the cathode sheet.
The cathode sheet may comprise cathode sheet corrugations running along its longitudinal edges. The anode sheet may comprise anode sheet corrugations running along its longitudinal edges. The cathode sheet corrugations may abut the anode sheet corrugations thereby defining a plurality of coolant/oxidant inlet ports to the cavity and a plurality of coolant/oxidant outlet ports from the cavity. In this way support can be provided for the cavity between the anode sheet and cathode sheet.
The size of the openings in the cathode sheet may vary along the length of the bipolar plate and/or across the width of the bipolar plate. Varying the dimensions of the openings can allow tuning of electrode activity across the surface of the electrode so as to improve electrode efficiency. The cross sectional area of one or more of the openings may be smaller than the cross sectional area of a gallery provided by a corresponding fluid flow channel, which may depend on specific fluid/air requirements.
There may be provided a fuel cell plate assembly comprising:
There may be provided a fuel cell stack comprising a plurality of any fuel cell plate assemblies disclosed herein.
There may be provided a fuel cell stack comprising a plurality of fuel cell plate assemblies as described herein.
A description is now given, by way of example only, with reference to the accompanying drawings, in which:
One or more embodiments disclosed herein relate to a bipolar plate for a fuel cell, the bipolar plate having an anode sheet defining an outer anode surface, and a cathode sheet defining an outer cathode surface. A cavity between the anode sheet and the cathode sheet that is configured to receive coolant/oxidant for cooling the anode and cathode sheets and also provide at least a portion of the coolant/oxidant to the exterior of the cathode sheet through one or more openings in the cathode sheet. In this way a common coolant/oxidant can be used for both cooling the plates and providing the oxidant to the cathode side of the electrode without requiring any complicated passageways or conduits.
The end of the bipolar plate 102 that is shown in
As is known in the art, the active area 105 is the area of the gas diffusion layers (GDLs) that are in contact with the electrode surfaces such that the electrodes are provided with the necessary reactant gasses to promote proton exchange through the membrane.
The port 104 receives the fluid in a direction that is through the thickness of the bipolar plate 102. In addition to providing the fluid to the electrode, the port 104 also passes the fluid to an adjacent fuel cell assembly in a fuel cell stack as the ports of the bipolar plates are aligned when the stack is constructed.
In this example, the bipolar plate 102 has a plurality of fluid flow channels 106, which are discontinuous and extend across a lateral width of the bipolar plate 102. In this way, the fluid can be laterally dispersed across the width of the active area 105 when the fluid enters the fluid flow channels 106.
As will be discussed in more detail below, the fluid passes along the longitudinal length of the bipolar plate 102 through a gas diffusion layer. However, one or more optional port channels 108 can provide a fluid connection between the port 104 and the active area 105. The port channels 108 can be provided as grooves in the bipolar plate 102.
The relationship between the port channels 108 and the fluid diffusion layer will be described in more detail below with reference to
In addition, one or more optional connecting channels 107 can also transport the fluid between successive fluid flow channels 106 along the length of the bipolar plate 102. Such connecting channels 107 can also be provided as grooves in the bipolar plate 102. The connecting channels 107 may alternate between connecting different ends of the fluid flow channels 106 so as to provide a winding or inter-digitized path along the longitudinal length of the bipolar plate 102. This can encourage the fluid to penetrate a large proportion of the fluid diffusion layer so that it is presented evenly to the electrode.
The bipolar plate comprises an anode sheet 180 and a cathode sheet 182. The outer surface of the anode sheet 180 will be referred to as an anode surface and the outer surface of the cathode sheet 182 will be referred to as a cathode surface.
There is a cavity 184 between the anode sheet 180 and the cathode sheet 182. In some examples, the anode sheet 180 and the cathode sheet 182 can be individually press moulded and stamped, before being spot welded together to provide the bipolar plate 102 of
The fluid flow channels 106 in the cathode sheet 184 include at least one opening 186 that extends between the cathode surface and the cavity 182. The opening puts the cavity 182 in fluid communication with the cathode surface. In this example, each fluid flow channel 106 in the cathode sheet 182 is punched through at each end so as to provide an inlet opening from the cavity 184 to the cathode surface and an outlet opening from the cathode surface to the cavity 184. The fluid flow channel 106 extends between the inlet opening and the outlet opening. The inlet opening will be the opening in the fluid flow channel 106 that is nearest to the side of the bipolar plate that receives the coolant/oxidant. Similarly, the outlet opening will be the opening in the fluid flow channel 106 that is furthest from the side of the bipolar plate that receives the coolant/oxidant.
Coolant/oxidant can pass into the cavity 184 through one or more coolant/oxidant inlet ports in a first peripheral edge 188 of the bipolar plate 102. Some of the coolant/oxidant that enters the coolant/oxidant inlet port then passes through the cavity 184 and out of one or more coolant/oxidant outlet ports in a second peripheral edge 190 of the bipolar plate 102. In addition, some of the coolant/oxidant that enters the cavity 184 passes through an inlet opening in a fluid flow channel 106 and is exposed to the cathode surface of the bipolar plate 102. The coolant/oxidant that passes straight through the cavity 184 can cool the anode and cathode sheets 180, 182. The second peripheral edge 190 of the bipolar plate is opposite to the first peripheral edge 188 of the bipolar plate in this example.
The bipolar plate according to this embodiment of the invention defines two flow paths between the coolant/oxidant inlet port and the coolant/oxidant outlet port: a first flow path that is entirely enclosed by both the anode sheet 180 and the cathode sheet 182; and a second flow path that passes through two openings 186 in the cathode sheet 182 so as to expose the coolant/oxidant to the cathode surface of the cathode plate 182.
As will be appreciated from the description that follows, the coolant/oxidant that is exposed to the cathode surface can diffuse through a cathode gas diffusion layer (GDL) in order to provide oxidant to the cathode of the membrane electrode assembly (MEA). Any coolant/oxidant that does not enter the cathode GDL can pass back into the cavity 184 through the outlet opening in the fluid flow channel 106, before exiting the bipolar plate 102 through the second peripheral edge 190 of the bipolar plate 102.
In this way, the first peripheral edge 188 can provide a common inlet for coolant/oxidant, which can, depending upon its path through the bipolar plate 102 to the second peripheral edge 190, both cool the anode and cathode sheets 180, 182 and provide oxidant to the cathode GDL of a neighbouring MEA.
The fluid flow channels 106 in the cathode sheet 182 may be referred to as a coolant/oxidant distribution structure having at least one profiled portion (the sides of the fluid flow channels that extend away from the plane of the cathode sheet 182) and at least one punched through section (the openings 186 in the ends of the fluid flow channels 106). The profiled section of the coolant/oxidant distribution structure in this example abuts corresponding fluid flow channels 106 in the anode sheet 108 thereby providing support for the cavity 184 between the cathode sheet 182 and anode sheet 180.
In this example, the bipolar plate 102 has a single coolant/oxidant inlet port and a single coolant/oxidant outlet port that extends for most of the length of the bipolar plate 102. This is in contrast to the bipolar plate shown in
It will be appreciated that in some examples the openings 186 through the cathode sheet 182 not need be provided in pairs as the coolant/oxidant can be consumed at the electrode. Therefore, a flow path from the cathode surface to the coolant/oxidant outlet port may not be required and the flow path to the cathode surface can be provided as a dead-end.
Another example of an alternative arrangement of the openings 186 in the cathode sheet 182 is described below with reference to
The fluid flow channels 106 in the anode sheet 180 do not have openings as coolant/oxidant is not required at the anode side of the MEA.
The anode GDL 210 has an extending region 212 that extends between the port 104 of the bipolar plate 102 and the active area 105. The tab 212 is outside the footprint of the active area 105. The extending region will be referred to as a tab 212. The tab 212 extends from the main body of the anode GDL 210, which in this example is generally co-located with the active area 105. The tab 212 of the anode GDL can communicate the hydrogen received at the port 104 to the active area 105. As identified above, the port channels 108 shown in
The adhesive is selected such that penetration of the adhesive into the tab 212 of the anode GDL 210 is minimal, thereby not significantly impeding fluid transport through the anode GDL 210.
In other embodiments, molded sub-gaskets can be used instead of the adhesive. For example, a molded sub-gasket could be provided with the laminate layer 418 that is discussed below with reference to
The 4-layer MEA 418 is positioned over the second track of adhesive 316. It can be seen from
The active area is defined within the periphery of the 4-layer MEA 418 as an outer band of the 4-layer MEA 418 is positioned over the adhesive 316, which prevents the transport of the anode gas (hydrogen) to the electrode. It will be appreciated that the placement of the adhesive can be controlled so as to minimise the displacement of the adhesive into the intended active area 105.
As shown in
As can be seen in
A section view of the cavity 584 between the anode sheet 580 and the cathode sheet 582 is shown in
In some examples, the geometries of the bipolar plate 102 could include features that offer varying surface areas to be in contact with the GDLs 210, 418. For example, the dimensions of the fluid flow channels 106 may vary along the length of the bipolar plate 102 and/or across the width of the bipolar plate 102. In this way, the surface area of the cathode surface and/or anode that is in contact with the respective GDL 210, 418 between the fluid flow channels also varies along or across the bipolar plate 102. Alternatively, or additionally, the size of the openings 186 in the cathode sheet 182 may vary along the length of the bipolar plate 102 and/or across the width of the bipolar plate 102. Varying the dimensions of features of the bipolar plate 102 in this way can allow tuning of electrode activity across the surface of the electrode so as to improve electrode efficiency.
The bipolar plates may comprise a separate anode sheet 602a and a cathode sheet 602b that are only joined together, for example resistance, laser or adhesive bonded together shortly before the bipolar plate 102 enters the build point. This is shown in
As can also be seen in
Use of these corrugations can form a rigid plateau to resist deflection through the force applied by gaskets in the fuel cell assembly, but still allow an uninterrupted air passage for the cathode oxidant and cooling air.
Located on either side of the build point are a stack of anode GDLs 210 and a stack of 4-layer MEAs 418.
It will be appreciated that each of the construction steps illustrated by
Finally, clips 1358, 1360 can be attached to each side of the fuel cell stack 1362 to keep the fuel cell plate assemblies together at the intended working dimension in order to provide a completed fuel cell stack 1361.
One side face of the fuel cell stack 1361 can be referred to as an coolant/oxidant inlet face 1363, which comprises the inlet ports in the first peripheral edges of the bipolar plates. The opposing side face can be referred to as an coolant/oxidant outlet face 1365, which comprises the outlet ports in the second peripheral edges of the bipolar plates. In accordance with the above description, it will be appreciated that oxidant enters the fuel cell stack through the coolant/oxidant inlet face 1363, either passes through the cavity to cool the anode and cathode sheets or is exposed to the cathode GDL through openings in the cathode sheet, before any unconsumed coolant/oxidant exits the fuel cell stack though the coolant/oxidant outlet face 1365.
In this example, the first fluid flow channel 1606a has an inlet opening 1658 in the cathode sheet 1682 and an opposing closed end 1659. The closed end does not have an outlet opening. The second fluid flow channel 1606b has an outlet opening 1654 in the cathode sheet 1682 and an opposing closed end with no inlet opening. With this arrangement of openings 11658, 1654, air passes from the first fluid channel 1606a to the second fluid flow channel 1606b through the adjacent gas diffusion layer (GDL) (not shown in
Optionally, an obstruction 1653 to direct air flow between the air inlet ports on a first peripheral edge of the bipolar plate and the air outlet ports on a second peripheral edge of the bipolar plate can be provided in order to increase the air pressure at the air inlet opening 1658 thereby encouraging the air to flow through the GDL from the first fluid flow channel 1606a to the second fluid flow channel 1606b. The obstruction in this example is a baffle 1653 that provides a restriction to air flow from the cavity 1657 between the anode sheet and cathode sheet to the air outlet port.
The bipolar plate 1600 of
The bipolar plate 1600 can be considered as having three flow paths between the air inlet port and the air outlet port:
The first flow path 1655, 1651 and the third flow path 1655 can run at a slightly elevated pressure compared to the second (through-cooling) channel 1656. The openings/apertures 1658, 1654 can be diametrically featured across the bipolar plate 1600, in order to become inlet and outlet apertures for the galleries in the cathode flow field. Alternate fluid flow channels 1606a may be provided with air inlet openings 1658. The other/interleaved fluid flow channels 1606b may be provided with air outlet openings 1654.
The subsequent pressure differential between air inlet and outlet openings 1658 and 1654 can promote air flow across the cathode surface of the bipolar plate 1606. Similarly, baffle plates 1653 can be positioned in alternate cooling channels 1656 along the bipolar plate 1600.
The embodiment of
Number | Date | Country | Kind |
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1209385.2 | May 2012 | GB | national |
This patent application claims priority to International Patent Application PCT/GB2013/051313 filed on May 20, 2013, which claims priority to United Kingdom Patent Application 1209385.2 filed on May 28, 2012, the contents of which are incorporated here in their entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/GB2013/051313 | 5/20/2013 | WO | 00 |