Claims
- 1. A compound of the formula ##STR4## wherein R.sub.1 and R.sub.2 are trivalent aromatic radicals having vicinal carbon atoms from which stem the valence bonds to which the anhydride moieties are attached and selected from the group consisting of phenyl and naphthyl and A is a divalent polynuclear aromatic selected from the group consisting of naphthalene anthracene, diphenyl-Z, dinaphthyl-Z, dibenzofuran, fluorene, carbazole, and dibenzothiophene wherein Z is O, S, C.sub.1 to C.sub.3 alkylidene or a single valence bond, the point of attachment to said trivalent aromatic radicals of the carbonyl bridges between said trivalent and divalent aromatic radicals being other than ortho to said vicinal carbon atoms.
- 2. The compound of claim 1 wherein R.sub.1 and R.sub.2 are ##STR5##
- 3. The compound of claim 1 wherein R.sub.1 and R.sub.2 are identical.
- 4. The compound of claim 1 wherein R.sub.1 and R.sub.2 are naphthyl selected from the group consisting of ##STR6##
- 5. The compound of claim 1 wherein A is ##STR7## in which Z is O, S, C.sub.1 to C.sub.3 alkylidene or a single valence bond.
- 6. The compound of claim 1 wherein A is selected from the group consisting of ##STR8## in which Z is O, S, C.sub.1 to C.sub.3 alkylidene or a single valence bond.
- 7. The compound of claim 1 wherein A is selected from the group consisting of ##STR9##
- 8. The compound of claim 1 wherein A is ##STR10##
- 9. The compound of claim 1 wherein A is selected from the group consisting of ##STR11## in which Y is NH, O, or S.
- 10. The compound of claim 1 wherein A is 4', 4'-biphenylylene.
- 11. The compound of claim 1 wherein A is 4,4'-oxybisphenylene.
- 12. The compound of claim 1 wherein A is 4,4'-isopropylidenebisphenylene.
- 13. The compound of claim 1 wherein A is 4,4'-ethylenebisphenylene.
- 14. The compound of claim 1 wherein A is 2,7-fluorenylene.
- 15. The compound of claim 1 wherein A is 3,6-dibenzofuranylene.
- 16. A compound of formula ##STR12##
- 17. A compound of formula ##STR13## wherein X is selected from the group consisting of a valence bond, oxygen, sulfur or C.sub.1 -C.sub.3 alkylene.
- 18. A compound of formula ##STR14##
- 19. A process which comprises the reaction, in the presence of a Friedel-Crafts catalyst, of at least two molar equivalents of at least one aromatic tricarboxylic acid derivative selected from the group consisting of ##STR15## where R.sub.1 and R.sub.2 are trivalent aromatic radicals having vicinal carbon atoms from which stem the valence bonds to which the anhydride moieties are attached and selected from the group consisting of phenyl and naphthyl, and wherein X is halogen, the point of attachment to said trivalent aromatic radicals of the carbonyl bridge between said trivalent aromatic radical and said halogen being other than ortho to said vicinal carbon atoms, with one molar equivalent of a compound of formula
- (b) H-A-H
- wherein A is a divalent polynuclear aromatic selected from the group consisting of naphthalene anthracene, diphenyl-Z, dinaphthyl-Z, dibenzofuran, fluorene, carbazole, and dibenzothiophene wherein Z is O, S, C.sub.1 and C.sub.3 alkylidene or a single valence bond to produce a compound of formula ##STR16## wherein the point of attachment to said trivalent aromatic radicals of the carbonyl bridges between said trivalent and divalent aromatic radicals being other than ortho to said vicinal carbon atoms.
- 20. The process of claim 19 wherein said catalyst is ferric chloride.
- 21. The process of claim 19 wherein said reaction is carried out in the molten state.
- 22. The process of claim 19 wherein the molar ratio a:b lies within the range from about 2:1 to about 4:1.
- 23. The process of claim 19 wherein R.sub.1 and R.sub.2 are identical and wherein the valence bonds of A are contained in separate nuclei.
- 24. The process of claim 19 wherein R.sub.1 and R.sub.2 are selected from the group consisting of phenyl or naphthyl and A is selected from the group consisting of anthracene, diphenyl-Z, dinaphthyl-Z, dibenzofuran, fluorene, carbazole and dibenzothiophene wherein Z is O, S, or a single valence bond.
CROSS REFERENCE TO RELATED APPLICATIONS
This is a continuation-in-part of copending application, Ser. No. 123,036 filed Mar. 10, 1971 now abandoned.
Foreign Referenced Citations (2)
Number |
Date |
Country |
1,565,700 |
May 1969 |
FR |
2,211,327 |
Jun 1973 |
DT |
Non-Patent Literature Citations (2)
Entry |
Drechsler et al., Journal fur Praktische Chemie, vol. 27(4), pp. 152-165 (1965). |
Gilman et al., J.A.C.S. vol. 61, pp. 2836-2841 (1939). |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
123036 |
Mar 1971 |
|