Patent Application
20220000747
The present disclosure relates to cosmetic products for treatment of a keratinous material, wherein the product comprises an organic silicon compound as a first component and an acid as a second component, as well as the use of the cosmetic product.
External stressing of the hair due to chemical materials from a variety of different sources poses challenges for the development of cosmetic care products. Air and water pollution adversely affect skin and hair. The most important air pollutants include polycyclic aromatic hydrocarbons, volatile organic compounds, nitrogen oxide (NOx), particles and cigarette smoke. The presence of other air pollutants and to UV radiation can reinforce the effect of various air pollutants.
It is known that the toxicity of gaseous pollutants of the air, such as sulfur dioxide, ozone and nitrogen oxides, especially depends on their initiator activity for free radicals, which causes damages in living beings. Free radicals are metabolic products that also occur naturally in the body. In large quantities, free radicals can pander to irritations and inflammations and accelerate the aging process. Such cases are referred to as oxidative damage. Free radicals can also cause hair damage, evinced, for example, by a reduction in the shine as well as of the grip and/or fading of the hair color.
Furthermore, frequently changing customer requests regarding a certain finish of the hair are linked to a recurrent chemical stress on the hair.
Organic compounds of silica from the group of silanes are described in the state of the art, which comprise at least one hydroxy group and/or hydrolysable group. Due to the presence of hydroxy groups and/or hydrolysable groups, silanes are reactive substances that hydrolyze or oligomerize or polymerize in the presence of water. When using on a keratinous material, oligomerization or polymerization of the silanes initiated by the presence of water eventually causes the formation of a film that can provide protection.
Cosmetic products for the treatment of a keratinous material are provided herein. In an embodiment, a cosmetic product includes
a) at least one organic silicon compound and
b) organic and/or inorganic acid with a pKS value of from about −6 to about 5.
The following detailed description is merely exemplary in nature and is not intended to limit the disclosure or the application and uses of the subject matter as described herein.
Furthermore, there is no intention to be bound by any theory presented in the preceding background or the following detailed description.
The objective forming the basis of the present disclosure includes providing a product with an improved care and/or protective properties. In particular, the objective underlying the present disclosure was to provide a cosmetic product that improves the effect of the organic silicon compound used.
This objective is achieved by employing a cosmetic product for treating a keratinous material, comprising
a) at least one organic silicon compound and
b) an organic and/or inorganic acid with a pKs value of about −6 to about 5.
Keratinous material includes hair, skin, nails (such as fingernails and/or toenails). Wool, furs and feathers also fall under the definition of keratinous material.
Preferably, a keratinous material is understood to be human hair, human skin and human nails, especially fingernails and toenails. Especially preferably, keratinous material is understood to be human hair in particular.
As the first ingredient essential to the invention, the cosmetic product for the treatment of a keratinous material contains at least one organic silicon compound. Preferred organic silicon compounds are selected from silanes with one, two or three silicon atoms, where the organic silicon compound comprises one or more hydroxyl groups and/or hydrolyzable groups per molecule.
Organic silicon compounds, alternatively called organosilicon compounds, are compounds which either have a direct silicon-carbon bond (Si—C) or in which the carbon is bonded to the silicon atom via an oxygen, nitrogen or sulfur atom. The organic silicon compounds are compounds containing one to three silicon atoms. Organic silicon compounds preferably contain one or two silicon atoms.
According to IUPAC rules, the term silane stands for a group of chemical compounds based on a silicon skeleton and hydrogen. In organic silanes, the hydrogen atoms are completely or partially replaced by organic groups such as (substituted) alkyl groups and/or alkoxy groups. In organic silanes, some of the hydrogen atoms may also be replaced by hydroxy groups.
Composition (a) contains at least one organic silicon compound selected from silanes having one, two or three silicon atoms, wherein the organic silicon compound comprises one or more hydroxyl groups or hydrolyzable groups per molecule.
As part of a particularly preferred embodiment, the product for the treatment of a keratinous material features at least one organic silicon compound, selected from silanes having one, two or three silicon atoms, the organic silicon compound further comprising one or more basic groups and one or more hydroxyl groups or hydrolyzable groups per molecule.
This basic group can be, for example, an amino group, an alkylamino group or a dialkylamino group, which is preferably connected to a silicon atom via a linker. The basic group is preferably an amino group, a C1-C6 alkylamino group or a Di(C1-C6) alkylamino group.
The hydrolyzable group(s) is (are) preferably a C1-C6 alkoxy group, especially an ethoxy group or a methoxy group. It is preferred when the hydrolyzable group is directly bonded to the silicon atom. For example, if the hydrolyzable group is an ethoxy group, the organic silicon compound preferably contains a structural unit R′R″R′″SiO—CH2—CH3. The radicals R′, R″ and R′″ represent the three remaining free valences of the silicon atom.
Particularly good results could be obtained if the product for the treatment of a keratinous material contains at least one organic silicon compound of formula (I) and/or (II).
The compounds of formulae (I) and (II) are organic silicon compounds selected from silanes having one, two or three silicon atoms, the organic silicon compound comprising one or more hydroxyl groups and/or hydrolysable groups per molecule.
In another specifically preferred embodiment, the product for the treatment of a keratinous material contains at least one organic silicon compound of formula (I) and/or (II).
R1R2N-L-Si(OR3)a(R4)b (I),
(R5O)c(R6)dSi-(A)e-[NR7-(A′)]f-[O-(A″)]g-[NR8-(A′″)]h-Si(R6′)d′(OR5′)c′ (II),
-(A″″)-Si(R6″)d″(OR5″)c″ (III),
The substituents R1, R2, R3, R4, R5, R5′, R5″, R6, R6′, R6″, R7, R8, L, A, A′, A″, A′″ and A″″ in the compounds of formula (I) and (II) are explained below as examples: Examples of a C1-C6 alkyl group are the groups methyl, ethyl, propyl, isopropyl, n-butyl, s-butyl and t-butyl, n-pentyl and n-hexyl. Propyl, ethyl and methyl are preferred alkyl radicals. Examples of a C2-C6 alkenyl group are vinyl, allyl, but-2-enyl, but-3-enyl and isobutenyl, preferred C2-C6 alkenyl radicals are vinyl and allyl. Preferred examples of a hydroxy C1-C6 alkyl group are a hydroxymethyl, a 2-hydroxyethyl, a 2-hydroxypropyl, a 3-hydroxypropyl, a 4-hydroxybutyl group, a 5-hydroxypentyl and a 6-hydroxyhexyl group; a 2-hydroxyethyl group is particularly preferred. Examples of an amino C1-C6 alkyl group are the aminomethyl group, the 2-aminoethyl group, the 3-aminopropyl group. The 2-aminoethyl group is particularly preferred. Examples of a linear double-bonded C1-C20 alkylene group include the methylene group (—CH2—), the ethylene group (—CH2—CH2—), the propylene group (—CH2—CH2—CH2—) and the butylene group (—CH2—CH2—CH2—CH2—). The propylene group (—CH2—CH2—CH2—) is particularly preferred. From a chain length of 3 C atoms, double-bonded alkylene groups can also be branched. Examples of branched double-bonded C3-C20 alkylene groups are (—CH2—CH(CH3″ and (—CH2—CH(CH3)—CH2—).
In the organic silicon compounds of the formula (I)
R1R2N-L-Si(OR3)a(R4)b (I),
the radicals R1 and R2 independently of one another represent a hydrogen atom or a C1-C6 alkyl group. In particular, the radicals R1 and R2 both represent a hydrogen atom.
In the middle part of the organic silicon compound is the structural unit or the linker -L- which stands for a linear or branched, double-bonded C1-C20 alkylene group.
Preferably -L- stands for a linear, double-bonded C1-C20 alkylene group. Further preferably -L- stands for a linear double-bonded C1-C6 alkylene group. Particularly preferred—L stands for a methylene group (—CH2—), an ethylene group (—CH2—CH2—), propylene group (—CH2—CH2—CH2—) or butylene (—CH2—CH2—CH2—CH2—). In particular, L stands for a propylene group (—CH2—CH2—CH2—)
The organic silicon compounds of formula (I)
R1R2N-L-Si(OR3)a(R4)b (I),
carry the silicon-containing grouping —Si(OR3)a(R4)b at one end.
In the terminal structural unit —Si(OR3)a(R4)b, R3 is hydrogen or C1-C6 alkyl group, and R4 is C1-C6 alkyl group. Particularly preferred, R3 and R4 independently of each other represent a methyl group or an ethyl group.
Here a stands for an integer from 1 to 3, and b stands for the integer 3-a. If a stands for the number 3, then b is equal to 0. If a stands for the number 2, then b is equal to 1. If a stands for the number 1, then b is equal to 2.
The best protection from the negative effects of water and/or air pollutants (“Anti-pollution” effect) and the best care of stressed hair could be obtained, if the composition for the treatment of a keratinous material contains at least one organic silicon compound of the formula (I), in which the radicals R3, R4 independently represent a methyl group or an ethyl group.
Especially well-suited organic silicon compounds of the formula (I) are:
The aforementioned organic silicon compound of formula (I) is commercially available.
(3-aminopropyl)trimethoxysilane, for example, can be purchased from Sigma-Aldrich. (3-aminopropyl)triethoxysilane is also commercially available from Sigma-Aldrich.
In a further embodiment, the product for the treatment of a keratinous material contains at least one organic silicon compound of formula (II)
(R5O)c(R6)dSi-(A)e-[NR7-(A′)]f-[O-(A″)]g-[NR8-(A′″)]h-Si(R6′)d′(OR5′)c′ (II).
The organosilicon compounds of formula (II) each carry the silicon-containing groups (R5O)c(R6)dSi— and —Si(R6′)d′(OR5′)c at both ends.
In the central part of the molecule of formula (II) there are the groups -(A)e- and —[NR7-(A′)]f- and —[O-(A″)]g- and —[NR8-(A′″)]h-. Here, each of the radicals e, f, g and h can independently of one another stand for the number 0 or 1, with the proviso that at least one of the radicals e, f, g and h is different from 0. In other words, an organic silicon compound of formula (II) contains at least one grouping from the group of -(A)- and —[NR7-(A′)]- and —[O-(A″)]- and —[NR8-(A′″)]-.
In the two terminal structural units (R5O)c(R6)dSi— and —Si(R6′)d′(OR5′)c, the radicals R5, R5′, R5″ independently of one another represent a hydrogen atom or a C1-C6 alkyl group. The radicals R6, R6′ and R6″ independently represent a C1-C6 alkyl group.
Here a stands for an integer from 1 to 3, and d stands for the integer 3-c. If c stands for the number 3, then d is equal to 0. If c stands for the number 2, then d is equal to 1. If c stands for the number 1, then d is equal to 2.
Analogously c′ stands for a whole number from 1 to 3, and d′ stands for the whole number 3-c′. If c′ stands for the number 3, then d′ is 0. If c′ stands for the number 2, then d′ is 1. If c′ stands for the number 1, then d′ is 2.
A very high anti-pollution effect of the product for the treatment of a keratinous material can be obtained if the radicals c and c′ both stand for the number 3. In this case d and d′ both stand for the number 0.
In a further preferred embodiment, the product for the treatment of a keratinous material contains at least one organic silicon compound of formula (II)
(R5O)c(R6)dSi-(A)e-[NR7-(A′)]f-[O-(A″)]g-[NR8-(A′″)]h-Si(R6′)d′(OR5′)c′ (II),
where
If c and c′ are both the number 3 and d and d′ are both the number 0, the organic silicon compound of the present disclosure corresponds to formula (IIa)
(R5O)3Si-(A)e-[NR7-(A′)]f-[O-(A″)]g-[NR8-(A′″)]h-Si(OR5′)3 (IIa).
The radicals e, f, g and h can independently stand for the number 0 or 1, whereby at least one radical from e, f, g and h is different from zero. The abbreviations e, f, g and h thus define which of the groupings -(A)e- and —[NR7-(A′)]f- and —[O-(A″)]g- and —[NR8-(A′″)]h- are located in the middle part of the organic silicon compound of formula (II).
In this context, the presence of certain groupings has proved to be particularly beneficial in terms of increasing the ‘anti-pollution’ effect. Particularly good results were obtained when at least two of the radicals e, f, g and h stand for the number 1. Especially preferred e and f both stand for the number 1. Furthermore, g and h both stand for the number 0.
If e and f both stand for the number 1 and g and h both stand for the number 0, the organic silicon compounds correspond to formula (IIb)
(R5O)c(R6)dSi-(A)-[NR7-(A′)]-Si(R6′)d′(OR5′)c′ (IIb).
The radicals A, A′, A″, A′″ and A″ ″ independently represent a linear or branched double-bonded C1-C20 alkylene group. Preferably the radicals A, A′, A″, A′″ and A″″ independently of one another represent a linear, double bond C1-C20 alkylene group. Further preferably the radicals A, A′, A″, A′″ and A″ ″ independently represent a linear double bond C1-C6 alkylene group. In particular, the radicals A, A′, A″, A′″ and A″ ″ independently of one another represent a methylene group (—CH2—), an ethylene group (—CH2—CH2—), a propylene group (—CH2—CH2—CH2—) or a butylene group (—CH2—CH2—CH2—CH2—). In particular, the radicals A, A′, A″, A′″ and A″″ stand for a propylene group (—CH2—CH2—CH2—).
If the radical f represents the number 1, then the organic silicon compound of formula (II) contains a structural grouping —[NR7-(A′)]-.
If the radical h represents the number 1, then the organic silicon compound of formula (II) contains a structural grouping —[NR8-(A′″)]-.
Herein, the radicals R7 and R8 independently represent a hydrogen atom, a C1-C6 alkyl group, a hydroxy C1-C6-alkyl group, a C2-C6 alkenyl group, an amino-C1-C6-alkyl group or a grouping of the formula (III)
(A″″)-Si(R6″)d″(OR5″)c″ (III).
Very preferably, R7 and R8 independently represent a hydrogen atom, a methyl group, a 2-hydroxyethyl group, a 2-alkenyl group, a 2-aminoethyl group or a grouping of formula (III).
If the radical f represents the number 1 and the radical h represents the number 0, the organic silicon compound contains the grouping [NR7-(A′)] but not the grouping —[NR8-(A′″)]. If the radical R7 now stands for a grouping of the formula (III), the product for the treatment of a keratinous material contains an organic silicone compound with 3 reactive silane groups.
In a further preferred embodiment, the product for the treatment of a keratinous material contains at least one organic silicon compound of formula (II)
(R5O)c(R6)dSi-(A)e-[NR7-(A′)]f-[O-(A″)]g-[NR8-(A′″)]h-Si(R6′)d′(OR5′)c′ (II),
where
In a further preferred embodiment, the product for the treatment of a keratinous material contains at least one organic silicon compound of formula (II), wherein
Organic silicon compounds of the formula (II) which are well suited for solving the problem are
The aforementioned organic silicon compounds of formula (II) are commercially available.
Bis(trimethoxysilylpropyl)amine with the CAS number 82985-35-1 can be purchased from Sigma-Aldrich.
Bis[3-(triethoxysilyl)propyl]amine, also designated as 3-(Triethoxysilyl)-N-[3-(triethoxysilyl)propyl]-1-propanamine, with the CAS number 13497-18-2 is, for example, commercially available from Sigma-Aldrich or can be commercially obtained from Evonik under the product name Dynasylan 1122.
N-methyl-3-(trimethoxy silyl)-N-[3-(trimethoxysilyl)propy 1]-1-propanamine is alternatively referred to as bis(3-trimethoxysilylpropyl)-N-methylamine and can be purchased commercially from Sigma-Aldrich or Fluorochem.
3-(triethoxysilyl)-N,N-bis[3-(triethoxysilyl)propyl]-1-propanamine with the CAS number 18784-74-2 can be purchased for example from Fluorochem or Sigma-Aldrich.
It has also proved beneficial if the product for the treatment of a keratinous material contains at least one organic silicon compound of the formula (IV)
R9Si(OR10)k(R11)m (IV).
The compounds of formula (IV) are organic silicon compounds selected from silanes having one, two or three silicon atoms, the organic silicon compound comprising one or more hydroxyl groups and/or hydrolysable groups per molecule.
The organic silicon compound(s) of formula (IV) may also be called a silane of the alkyl-alkoxy-silane or alkyl-hydroxy-silane type,
R9Si(OR10)k(R11)m (IV),
where
In a further preferred embodiment, the product for the treatment of a keratinous material contains, in addition to the organic silicon compound(s) of formula (I), at least one more organic silicon compound of formula (IV)
R9Si(OR10)k(R11)m (IV),
where
In a similarly preferred embodiment, the product for the treatment of a keratinous material contains, in addition to the organic silicon compound(s) of formula (II), at least one more organic silicon compound of formula (IV)
R9Si(OR10)k(R11)m (IV),
where
In a further preferred embodiment, the product for the treatment of a keratinous material contains, in addition to the organic silicon compound(s) of formula (I) and (II), at least one more organic silicon compound of formula (IV)
R9Si(OR10)k(R11)m (IV),
where
In the organic silicon compounds of formula (IV), the radical R9 represents a C1-C12 alkyl group. This C1-C12 alkyl group is saturated and can be linear or branched. Preferably R9 stands for a linear C1-C8 alkyl group. Preferably R9 stands for a methyl group, an ethyl group, an n-propyl group, an n-butyl group, an n-pentyl group, an n-hexyl group, an n-octyl group or an n-dodecyl group. Particularly preferred, R9 stands for a methyl group, an ethyl group or an n-octyl group.
In the organic silicon compounds of formula (IV), the radical R10 represents a hydrogen atom or a C1-C6 alkyl group. Especially preferably, R10 stands for a methyl group or an ethyl group.
In the organic silicon compounds of formula (IV), the radical R11 represents a C1-C6 alkyl group. Especially preferably, R11 stands for a methyl group or an ethyl group.
Furthermore, k stands for a whole number from 1 to 3, and m stands for the whole number 3-k. If k stands for the number 3, then m is equal to 0. If k stands for the number 2, then m is equal to 1. If k stands for the number 1, then m is equal to 2.
A very high protective effect can be achieved if the product for the treatment of a keratinous material contains at least one organic silicon compound of the formula (IV) in which the radical k stands for the number 3. In this case the rest m stands for the number 0.
Organic silicon compounds of the formula (IV) which are well suited for solving the problem are
as well as propyltrimethoxysilane, propyltriethoxysilane, octadecyltrimethoxysilane and/or octadecyltriethoxysilane.
The organic silicon compounds described above are reactive compounds.
In this context, it has proved to be specifically preferable, if the product contains (3-Aminopropyl)triethoxysilane, i.e. an aminopropyl triethoxysilane (AMEO), and/or 3-(Triethoxysilyl)-N-[3-(triethoxysilyl)propyl]-1-propane amine, i.e. a Bis(triethoxysilylpropyl)amine, as organic silicon compound.
According to the preferred embodiment of the present invention, the organic silicon compound of the formula (I), particularly the (3-Aminopropyl)triethoxysilane, in a quantity of about 0.01 to about 10% by weight, preferably from about 0.02 to about 8% by weight more preferably from about 0.05 to about 6% by weight, most preferably from about 0.1 to about 4% by weight, based on the total weight of the cosmetic product, contained in the cosmetic product, and/or the organic silicon compound of the formula (II), especially the 3-(Triethoxysilyl)-N-[3-(triethoxysilyl)propyl]-1-propane amine, is contained in a quantity of about 0.01 to about 10% by weight, preferably from about 0.02 to about 9% by weight, more preferably from about 0.05 to about 8% by weight, most preferably from about 0.1 to about 7% by weight, based on the total weight of the cosmetic product.
It has been observed that it is possible to obtain particularly sturdy and uniform films on the keratinous material even if the product contains two structurally different organic silicon compounds.
In a further preferred embodiment, product is exemplified in that the it contains at least one organic silicon compound of formula (I) and at least one organic silicon compound of formula (IV).
In an explicitly specifically preferred embodiment, a product is exemplified in that it contains at least one organic silicon compound of the formula (I), which is selected from the group of (3-Aminopropyl)triethoxysilane and (3-Aminopropyl)trimethoxysilane, and additionally contains at least one organic silicon compound of the formula (IV), which is selected from the group of methyltrimethoxysilane, methyltriethoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, propyltrimethoxysilane, propyltriethoxysilane, hexyltrimethoxysilane and hexyltriethoxysilane.
In a further preferred embodiment, a product is exemplified in that the product—based on the total weight of the product—contains:
In the case of organic silicon components with at least one hydrolysable group, the addition of small quantities of water already leads to hydrolysis. The hydrolysis products and/or organic silicon compounds with at least one hydroxy group can react with each other in a condensation reaction. For this reason, the product can contain organosilicon compounds with at least one hydrolysable group as well as their hydrolysis and/or condensation products. When using organosilicon compounds with at least one hydroxyl group, the product can contain organic silicon compounds with at least one hydroxyl group as well as their condensation products.
A condensation product is understood to mean a product that is created due to the reaction of at least two organic silicon compounds each with at least one hydroxyl group or hydrolysable group per molecule on splitting of water and/or splitting of an alkanol. The condensation products can, for example, be dimers, or even trimers or oligomers, where in the condensation products are always in balance with the monomers. Depending on the water quantity added or consumed in the hydrolysis, the balance shifts from monomeric organic silicon compounds to condensation product.
In the context of the present invention, specifications in weight-%—unless otherwise specified—always in relation to the total weight of the cosmetic product.
As the second important component essential for the invention, the cosmetic product for treatment of a keratinous material contains, as a further component b) an organic and/or inorganic acid with a pKS value of from about −6 to about 5. In the course of the work leading to this invention, it was observed that for achieving a particularly good care effect, it is especially advantageous, if the organic silicon compounds, for example (3-aminopropyl)triethoxysilane, i.e. an aminopropyl triethoxysilane (AMEO), or for example 3-(triethoxysilyl)-N-[3-(triethoxysilyl)propyl]-1-propanamine, i.e. a Bis(triethoxysilylpropyl) amine, is combined with an organic and/or inorganic acid with a pKS value of from about −6 to about 5. In particular, it is seen that on addition of an acid with a pKS value from about −6 to about 5, the film formation completes sooner and the retained films have a finer structure.
According to preferred embodiments of the present invention, the inorganic acid is a mineral acid, which is selected from the group of hydrochloric acid, nitric acid and sulfuric acid.
According to the preferred embodiments, the pKS value of the inorganic or organic acid lies between about 0.5 and about 4.5, more preferably between about 0 and about 3.
The preferred organic acids are one or more carboxylic acids and/or acidic amino acids. Preferably, the organic acid is selected from the group of acetic acid, benzoic acid, ascorbic acid, citric acid, lactic acid, a sulfuric acid alkyl ester, aspartic acid and glutamic acid.
It was found that the combination of the acids on one hand and the organosilicon compound, for example the aminopropyl triethoxysilane (AMEO) and/or the bis(triethoxysilylpropyl) amine on the other is very powerful in providing a care and protection effect. An acidic cosmetic composition comprising the said silanes, which cover the hair surface, is particularly effective in achieving the task underlying the invention. According to the preferred embodiments, the pH value of the cosmetic product lies in the range from about 1.5 to about 8, preferably from about 2 to about 7, more preferred from about 2.5 to about 6, most preferred from about 3 to about 5.
According to a preferred embodiment, the component b) comprising the acid with another skin moisturizer is added in the cosmetic product. The other skin moisturizer is selected from group of glycerin, urea, hyaluronic acid, silanol ester of hyaluronic acid, panthenol, taurine, ceramide, phytosterole, aloe vera extracts, creatine, creatinine, sodium hyaluronate, polysaccharides, biosaccharides gum-1, cucumber extracts, butylene glycol, propylene glycol, methyl propanediol, ethylhexyl glycerin, sorbitol, natural betaine compounds, lactates, especially sodium lactate, and/or ethylhexyloxyglycerin. Particularly, the selection of these other skin moisturizers enhances the care character of the cosmetic product.
According to a preferred embodiment of the present invention, the quantity of the acid content in cosmetic product is from about 0.005 to about 10% by weight, preferably from about 0.01 to about 8% by weight, more preferably from about 0.015 to about 6% by weight, most preferably from about 0.02 to about 4% by weight, in relation to the total weight of the cosmetic product.
The product for the treatment of a keratinous material can comprise especially an agent for cleaning a keratinous material, an agent for care of a keratinous material, an agent for care and cleaning of a keratinous material and/or an agent for temporary shaping of a keratinous material.
Other components of the hair treatment product shall be described hereafter, which can be contained in the products besides the above-described mandatory ingredients.
It can be preferable that the product for the treatment of a keratinous material further comprise about 0.001 to about 20% by weight of at least one quaternary compound. This applies especially for products for care of a keratinous material and for products for care and cleaning of a keratinous material.
It is preferred that the at least one quaternary compound be selected from at least one of the groups of
i) the monoalkyl quats and/or
ii) the ester quats and/or
iii) the quaternary imidazoline of the formula (Tkat2).
In which the radical R independently stands for a saturated or unsaturated, linear or branched hydrocarbon radical with a chain length from about 8 to about 30 carbon atoms and A stands for a physiologically compatible anion, and/or
iv) the amidoamines and/or cationized amidoamines and/or
v) poly(methacryloyloxyethyltrimethyl ammonium compounds) and/or
vi) quaternized cellulose derivatives, especially polyquaternium 10, polyquaternium-24, polyquaternium-27, polyquaternium-67, polyquaternium-72 and/or
vii) Cationic alkyl polyglycosides and/or
viii) Cationized honey and/or
ix) Cationic guar derivatives and/or
x) Chitosan and/or
xi) polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid, mainly polyquaternium-7 and/or
xii) Copolymers of the vinyl pyrrolidone with quaternized derivatives of the dialkylaminoalkylacrylates and methacrylates, especially polyquaternium-11 and/or
xiii) vinylpyrrolidone-vinylimidazoliummethochloride-copolymers, especially polyquaternium-16 and/or
xiv) Quaternized polyvinyl alcohol and/or
and mixtures thereof.
It is especially preferred that the hair treatment product contain a cationic homopolymer, which falls under the INCI designation polyquaternium-37, as quaternary compounds.
It can be preferable that the product for the treatment of a keratinous material further comprise one solidifying compound, preferably selected from the group of waxes, synthetic polymers and mixtures thereof.
In order to cope with the different requirements for the product for the treatment of a keratinous material in the form of one agent for temporary shaping of a keratinous material (=Styling material), a multitude of synthetic polymers has already been developed as solidifying compounds, which can be used in the product for the treatment of a keratinous material. Waxes are used alternatively or additionally as solidifying compounds. Ideally, the polymers and/or waxes when used on the keratinous material leave a polymer film that lends a strong hold to the hairstyle on the one hand, is however sufficiently flexible on the other, so that it does not break on being stressed.
The synthetic polymers can be divided in cationic, anionic, anionic and amphoteric solidifying polymers.
Suitable synthetic polymers comprise, for example, polymers with the following INCI designation. Acrylamide/Ammonium Acrylate Copolymer, Acrylamides/DMAPA Acrylates/Methoxy PEG Methacrylate Copolymer, Acrylamidopropyltrimonium Chloride/Acrylamide Copolymer, Acrylamidopropyltrimonium Chloride/Acrylates Copolymer, Acrylates/Acetoacetoxyethyl Methacrylate Copolymer, Acrylates/Acrylamide Copolymer, Acrylates/Ammonium Methacrylate Copolymer, Acrylates/t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates/C1-2 Succinates/Hydroxyacrylates Copolymer, Acrylates/Lauryl Acrylate/Stearyl Acrylate/Ethylamine Oxide Methacrylate Copolymer, Acrylates/Octylacrylamide Copolymer, Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer, Acrylates/Stearyl Acrylate/Ethylamine Oxide Methacrylate Copolymer, Acrylates/VA Copolymer, Acrylates/Hydroxy esters Acrylates Copolymer, Acrylates/VP Copolymer, Adipic Acid/Diethylenetriamine Copolymer, Adipic Acid/Dimethylaminohydroxypropyl Diethylenetriamine Copolymer, Adipic Acid/Epoxypropyl Diethylenetriamine Copolymer, Adipic Acid/Isophthalic Acid/Neopentyl Glycol/Trimethylolpropane Copolymer, Allyl Stearate/VA Copolymer, Aminoethylacrylate Phosphate/Acrylates Copolymer, Aminoethylpropanediol-Acrylates/Acrylamide Copolymer, Aminoethylpropanediol-AMPD-Acrylates/Diacetoneacrylamide Copolymer, Ammonium VA/Acrylates Copolymer, AMPD-Acrylates/Diacetoneacrylamide Copolymer, AMP-Acrylates/Allyl Methacrylate Copolymer, AMP-Acrylates/C1-18 Alkyl Aerylates/C1-8 Alkyl Acrylamide Copolymer, AMP-Acrylates/Diacetoneacrylamide Copolymer, AMP-Acrylates/Dimethylaminoethylmethacrylate Copolymer, Bacillus/Rice Bran Extract/Soybean Extract Ferment Filtrate, Bis-Butyloxyamodimethicone/PEG-60 Copolymer, Butyl Acrylate/Ethylhexyl Methacrylate Copolymer, Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer, Butylated PVP, Butyl Ester of Ethylene/MA Copolymer, Butyl Ester of PVM/MA Copolymer, Calcium/Sodium PVM/MA Copolymer, Corn Starch/Acrylamide/Sodium Acrylate Copolymer, Diethylene Glycolamine/Epichlorohydrin/Piperazine Copolymer, Dimethicone Cross polymer, Diphenyl Amodimethicone, Ethyl Ester of PVM/MA Copolymer, Hydrolyzed Wheat Protein/PVP Cross polymer, Isobutylene/Ethylmaleimide/Hydroxy ethylmaleimide Copolymer, Isobutylene/MA Copolymer, Isobutyl methacrylate/Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isopropyl Ester of PVM/MA Copolymer, Lauryl Acrylate Cross polymer, Lauryl Methacrylate/Glycol Dimethacrylate Cross polymer, MEA-Sulfite, Methacrylic Acid/Sodium Acrylamidomethyl Propane Sulfonate Copolymer, Methacryloyl Ethyl Betaine/Acrylates Copolymer, Octylacrylamide/Acrylates/Butylaminoethyl Methacrylate Copolymer, PEG/PPG-25/25 Dimethicone/Acrylates Copolymer, PEG-8/SMDI Copolymer, Polyacrylamide, Polyacrylate-6, Polybeta-Alanine/Glutaric Acid Cross polymer, Polybutylene Terephthalate, Polyester-1, Polyethylacrylate, Polyethylene Terephthalate, Polymethacryloyl Ethyl Betaine, Polypentaerythrityl Terephthalate, Polyperfluoroperhydrophenanthrene, Polyquaternium-1, Polyquaternium-2, Polyquaternium-4, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-11, Polyquaternium-12, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, Polyquaternium-50, Polyquaternium-55, Polyquaternium-56, Polysilicone-9, Polyurethane-1, Polyurethane-6, Polyurethane-10, Polyvinyl Acetate, Polyvinyl Butyral, Polyvinylcaprolactam, Polyvinylformamide, Polyvinyl Imidazolinium Acetate, Polyvinyl Methyl Ether, Potassium Butyl Ester of PVM/MA Copolymer, Potassium Ethyl Ester of PVM/MA Copolymer, PPG-70 Poly glyceryl-10 Ether, PPG-12/SMDI Copolymer, PPG-51/SMDI Copolymer, PPG-10 Sorbitol, PVM/MA Copolymer, PVP, PVP/VA/Itaconic Acid Copolymer, PVP/VA/Vinyl Propionate Copolymer, Rhizobian Gum, Rosin Acrylate, Shellac, Sodium Butyl Ester of PVM/MA Copolymer, Sodium Ethyl Ester of PVM/MA Copolymer, Sodium Polyacrylate, Sterculia Urens Gum, Terephthalic Acid/Isophthalic Acid/Sodium Isophthalic Acid Sulfonate/Glycol Copolymer, Trimethylolpropane Triacrylate, Trimethylsiloxysilyl carbamoyl Pullulan, VA/Crotonates Copolymer, VA/Crotonates/Methacryloxybenzophenone-1 Copolymer, VA/Crotonates/Vinyl Neodecanoate Copolymer, VA/Crotonates/Vinyl Propionate Copolymer, VA/DBM Copolymer, VA/Vinyl Butyl Benzoate/Crotonates Copolymer, Vinylamine/Vinyl Alcohol Copolymer, Vinyl Caprolactam/VP/Dimethylaminoethyl Methacrylate Copolymer, VP/Acrylates/Lauryl Methacrylate Copolymer, VP/Dimethylaminoethyl methacrylate Copolymer, VP/DMAPA Acrylates Copolymer, VP/Hexadecene Copolymer, VP/VA Copolymer, VP/Vinyl Caprolactam/DMAPA Acrylates Copolymer, Yeast Palmitate and Styrene/VP Copolymer. Cellulose ethers, such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose are also suitable.
Also Homopolyacryl acid (INCI: Carbomer), which is commercially available under the name Carbopol® in different versions, is suitable as a solidifying compound.
Preferably, the solidifying compound comprises a vinylpyrrolidone-containing polymer. Particularly preferably, the solidifying compound comprises a polymer selected from the group of polyvinylpyrrolidone (PVP), vinylpyrrolidone-vinylacetate-copolymer (VP/VA copolymer), vinyl caprolactam/VP/dimethylaminoethyl methacrylate copolymer (INCI), VP/DMAPA acrylates copolymer (INCI) and mixtures thereof.
A similarly preferred solidifying compound is octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer (INCI), which is sold under the name “Amphomer®” by Akzo Nobel.
Accordingly, it is particularly preferable, that the solidifying compound comprises a synthetic polymer selected from the group of polyvinylpyrrolidone (PVP), vinylpyrrolidone-vinylacetate-copolymer (VP/VA copolymer), vinyl caprolactam/VP/dimethylaminoethyl methacrylate copolymer (INCI), VP/DMAPA acrylates copolymer (INCI), octylacrylamide/acrylates/butylaminoethyl methacrylate copolymer (INCI) and mixtures thereof.
According to other preferred embodiments of the present invention, the cosmetic product contains at least one cationic surfactant as component d). Specially preferred, this is a cationic surfactant of the formula (V),
wherein
R12, R3, R4 independently represent an C1-C6-Alkyl group, a C2-C6-alkenyl group or a C2-C6-hydroxyalkyl group,
R15 represents a C8-C28-alkyl group, preferably a C10-C22-alkyl group and
X− stands for a physiologically compatible anion,
And/or the cosmetic product preferably contains at least one cationic surfactant of the formula (VI),
wherein
R16 represents a C1-C6 alkyl group
R7, R18 independently represent a C7-C27-alkyl group, preferably an C10-C22-alkyl group and
X− stands for a physiologically compatible anion,
And/or the cosmetic product preferably contains at least one cationic surfactant of the formula (VII),
wherein
R19, R20, independently represent an C1-C6-Alkyl group and a C2-C6-hydroxyalkyl group,
R21, R22 independently represent a C7-C27-alkyl group, preferably an C10-C22-alkyl group and
X− stands for a physiologically compatible anion,
And/or the cosmetic product preferably contains at least one cationic surfactant of the formula (VIII),
NR23R24R25 (VIII)
wherein
R23, R24 independently represent an C1-C6-alkyl group, a C2-C6-alkenyl group or a C2-C6-hydroxyalkyl group,
R25 represents a C8-C28-alkyl group, preferably a C10-C22-alkyl group and
The cationic surfactants of the formula (VIII) are amino derivatives, what are called pseudo quats. The organic radicals R23, R24 and R25 are directly connected to the nitrogen atom in that case. In the acidic pH range, these are cationized i.e. the nitrogen atom is then protonized. The physiologically compatible counter-ions are then available as counter ions. Steamidopropyl dimethylamine is especially preferably offered with the cationic surfactants of the formula (VIII).
According to a preferred embodiment of the present invention, the quantity of cationic surfactant is about 0.1 to about 30% by weight, preferably from about 0.5 to about 20% by weight, more preferably from about 1 to about 10% by weight based on the total weight of the cosmetic product.
According to a preferred embodiment of the present invention, the cationic surfactant comprises a hydrophobic head group with a cationic charge and one or two hydrophobic end parts, wherein the hydrophobic end part or the hydrophobic end parts represent straight chained or branched, saturated or mono- or poly-unsaturated alkyl groups, which preferably feature a chain length of C6 to C30, preferably C8 to C26, especially preferred C10 to C22. According to a further preferred embodiment, the cationic surfactant features an ester function, an ether function, a ketone function, an alcohol function or an amide function.
According to preferred embodiment of the present invention, the cosmetic product contains one or more anionic surfactants, preferably selected from the group of
Particularly preferred anionic surfactants are straight-chain or branched alkyl ether sulfates containing an alkyl radical with from about 8 to about 18 and in particular with from about 10 to about 16 C atoms and from about 1 to about 6 and in particular 2 to 4 ethylene oxide units, specifically preferred, the surfactant mix of anionic and amphoteric/zwitterionic surfactants sodium lauryl ether sulfate (INCI: Sodium laureth sulfate) and specifically preferred sodium lauryl ether sulfate with 2 ethylene oxide units.
Amphoteric surfactants, which are also designated zwitterionic surfactants, are those surface-active compounds which carry at least one quaternary ammonium group and at least one —COO− or —SO3− group in the molecule. Amphoteric/zwitterionic surfactants are also those surface-active compounds which, apart from a C8-C24 alkyl or acyl group, contain at least one free amino group and at least one —COOH— or —SO3H— group in the molecule and are capable of forming internal salts.
According to preferred embodiment of the present invention, the amphoteric surfactants in the cosmetic product are selected from the group of
The especially suitable amphoteric/zwitterionic surfactants also include the surfactants cocamidopropylbetaine and di-sodium cocoamphodiacetate known under the INCI designation.
According to preferred embodiment of the present invention, the non-ionic surfactant is selected from the group of
According to a preferred embodiment of the present invention, the cosmetic product contains two structurally mutually different surfactants. It is particularly preferred that the cosmetic product contain two structurally mutually different surfactants, wherein preferably the cosmetic product contains two structurally mutually different cationic surfactants, or the cosmetic product contains a cationic surfactant and a non-ionic surfactant.
The cosmetic composition can, additionally or alternatively to a synthetic polymer, contain at least one natural or synthetic wax, which has a melting point above 37° C., as solidifying compound.
As natural or synthetic waxes, solid paraffin or isoparaffins, vegetable waxes such candelila wax, carnauba wax, esparto grass wax, Japan wax, cork wax, sugar cane wax, ouricury wax, montan wax, sunflower wax, fruit waxes and animal waxes such as beeswaxes and other insect waxes, whale wax, shellac wax, wool wax and brushing grease, furthermore mineral waxes such as Ceresin and Ozokerite or the petrochemical waxes such as petrolatum, paraffin wax, microwaxes from polyethylene or polypropylene and polyethylene glycol waxes can be used. It can be advantageous to use hydrated or hardened waxes. Furthermore, chemically modified waxes, especially resin waxes, for example montan ester waxes, sasol waxes and hydrated jojoba waxes can also be used.
Furthermore, in addition to the mandatory contained components the triglycerides of saturated and unsaturated hydroxylized C 16-30 fatty acids, such as hardened triglyceride fats (hydrated palm oil, hydrated coconut oil, hydrated castor oil), glyceryl tribehenate or glyceryl tri-12 hydroxy stearate, are suitable in the cosmetic product.
The wax components can also be selected from the group of ester from saturated, unbranched alkane carboxylic acids of a chain length of from about 22 to about 24 C atoms and saturated, unbranched alcohols of a chain length of from about 22 to about 24 C atoms, if the wax components or the totality of the wax components are solid at room temperature. Silicone waxes, such as stearyltrimethylsilane/stearyl alcohol can also be eventually advantageous.
Natural, chemically modified and synthetic waxes can be used alone or in combination. Thus, even several waxes can be used. Moreover, a series of wax mixes, possibly in mixture with other additives, is also commercially available. Examples of usable mixtures are the ones available under the names “Special wax 7686 OE’ (a mixture of cetyl palmitate, bees wax, micro crystalline wax and polyethylene with a melting range of 73-75° C., manufacturer: Kahl & Co), Plywax® GP 200 (a mixture of stearyl alcohol and polyethylene glycol stearate with melting point of 47-51° C.; manufacturer: Croda) and “Weichceresin® FL 400” (a vaseline/vaseline oil/wax mixture with a melting point of 50-54° C.; manufacturer: Parafluid Mineralölgesellschaft).
The wax selected from Carnauba wax (INCI: Copemicia Cerifera Cera) bees wax (INCI: Beeswax), Petrolatum (INCI), micro crystalline wax and especially mixtures therefrom are preferred.
Preferred mixtures comprise the combination of Carnauba wax (INCI: Copernicia Cerifera Cera), Petrolatum and micro crystalline wax or the combination of bees wax (INCI: Beeswax) and Petrolatum.
The wax or the wax components should be solid at 25° C. and should melt in the range of >37° C.
The product for the treatment of a keratinous material contains the solidifying compound preferably in a total quantity of about 0.5 to about 50% by weight, preferably 1 to 40% by weight, more preferred from about 1.5 to about 30% by weight, still more preferred about 2 to about 25% by weight, based on the total weight of the cosmetic composition.
Other suitable ingredients comprise non-ionic polymers, anionic polymers, waxes, protein hydrolysates, oligopeptide, vitamins, pro-vitamins, vitamin precursors, betaines, biochinones, Purine (derivative), vegetable extracts, silicones, ester oils, structuring agent, thickening agents, electrolytes, swelling agents, dyes, anti-dandruff agents, complexing agents, opacifiers, pearlizing agents, pigments, stabilizers, propellants, antioxidants, perfume oils and/or preservatives.
In the preferred embodiments 1 to 334, the preferred organic silicon compounds with preferred acids are combined with each other in a cosmetic product as invented.
The combinations of the above tables represent the combinations of the active ingredients, which are combined in cosmetic products with other above-described components.
The active ingredients combination from at least one organic silicon compound and an inorganic and/or organic acid can already be contained in the product for the treatment of a keratinous material. In this embodiment, the product for the treatment of a keratinous material is already sold in ready-to-use form. In order to provide a formulation that is as stable as possible during storage, the product itself is preferably packaged with low or no water.
Alternatively, the at least one organic silicon compound is added to a base comprising all ingredients of the product for the treatment of a keratinous material with the exception of the at least one organic silicon compound, maximum 12 hours, preferably maximum 6 hours, more preferably maximum 3 hours, even more preferably maximum 1 hour before using the product for the treatment of a keratinous material.
Furthermore, alternatively, the organic silicon compound and another component b) is added to a cosmetic product just shortly before use, i.e. from about 1 minute to about 12 hours, preferably from about 2 minutes to about 6 hours, especially preferably from about 1 minute to about 3 hours, most especially preferably from about 1 minute to about 1 hour.
In another alternative, the organic silicon compound is added to an aqueous solution, which is applied to the hair and in the second step, an aqueous solution or a cosmetic product, which contains the other component b), is applied on the hair.
The user can for example stir or shake an agent (α), which contains the organic silicon compound(s), first with an agent (β), which comprises the remaining ingredients of the product for the treatment of a keratinous material. The user can now apply this mixture of (a) and (β) to the keratinous materials—either directly after their production or after a short reaction time of about 1 minute to about 20 minutes. The agent (β) can contain water, especially water in a quantity >30% by weight, based on the total weight of the product for the treatment of keratinous materials.
Another object of the present registration is the use of a cosmetic product as invented for treatment of a keratinous material, for care of keratinous material, for reducing/prevention of damaging effects of air and water pollutants on keratinous material and/or for temporary shaping of keratinous material.
Regarding other preferred embodiments of the use, what was said about the cosmetic product is applicable mutatis mutandis.
While at least one exemplary embodiment has been presented in the foregoing detailed description, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the various embodiments in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing an exemplary embodiment as contemplated herein. It being understood that various changes may be made in the function and arrangement of elements described in an exemplary embodiment without departing from the scope of the various embodiments as set forth in the appended claims.
This application is a U.S. National-Stage entry under 35 U.S.C. § 371 based on International Application No. PCT/EP2019/079780, filed Oct. 31, 2019, which was published under PCT Article 21(2) and which claims priority to German Application No. 10 2018 127 197.2, filed Oct. 31, 2018, which are all hereby incorporated in their entirety by reference.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2019/079780 | 10/31/2019 | WO | 00 |
