This invention relates to a method of operating a blast furnace by blowing a solid reducing material such as pulverized coal or the like and a flammable gaseous reducing material such as LNG or the like together with a combustible gas into the blast furnace through tuyeres thereof.
Recently, global warming is pointed out associated with the increase of carbon dioxide emission, which is a significant issue even in the iron industry. As to such an issue, an operation with a low reduction agent ratio (total amount of a reducing material blown through tuyeres and coke charged from a top of the furnace per 1 ton of pig iron to be produced) is driven forward in recent blast furnaces. In the blast furnace, coke and pulverized coal are mainly used as a reducing material. Therefore, in order to attain the operation with a low reduction agent ratio and hence the suppression of carbon dioxide emission, it is effective to replace coke or the like with a reducing material having a high hydrogen content ratio such as waste plastic, LNG, heavy oil or the like.
Patent Document 1 discloses a method wherein the reduction agent ratio is decreased by using a plurality of lances and blowing a solid reducing material, a gaseous reducing material and a combustible gas through the respective lances to promote the heating of the solid reducing material to thereby improve the combustion efficiency and hence suppress the generation of unburned powder or coke breeze for improving air permeability. Patent Document 2 discloses a technique wherein coaxially multiple-tube type lances are used and a combustible gas is blown through an inner tube and a gaseous reducing material and a solid reducing material are blown from a gap between inner tube and outer tube. Patent Document 3 proposes a lance wherein plural small-size tubes are arranged in parallel around a main lance tube. Patent Document 4 discloses multiple nozzles in which plural blowing tubes are arranged in parallel at interval outside a fuel feeding tube when a combustible gas and a fuel are blown into a smelting reduction furnace, whereby a mixed state of the combustible gas and the fuel can be always maintained even if one of the nozzles is wear-damaged.
Patent Document 1: JP-A-2007-162038
Patent Document 2: JP-A-2011-174171
Patent Document 3: JP-A-H11-12613
Patent Document 4: JP-U-H03-38344
The blast furnace operation method disclosed in Patent Document 1 has an effect of increasing a combustion temperature and reducing a specific consumption of a reducing material as compared to a method of blowing only a solid reducing material (pulverized coal) through tuyeres in a point of also blowing a gaseous reducing material, but the effect is still insufficient. Also, the multiple-tube type lance disclosed in Patent Document 2 requires the cooling of the lance, so that the outer blowing rate should be made faster. To this end, a gap between the inner tube and the outer tube should be made narrow, and hence the predetermined gas amount cannot be flown and there is a risk of not obtaining a required combustibility. On the other hand, in order to establish the gas amount and the flow rate, the lance diameter should be made large, which brings about the decrease of blast volume fed from a blowpipe. As a result, a risk of breaking the surrounding refractories is increased in association with the decrease of amount of molten iron tapped or the increase of plug-in diameter for the lance.
In the technique disclosed in Patent Document 3 is used a lance formed by arranging the plural small-size tubes around the main tube, so that there are problems that not only a risk of clogging the small-size tubes due to the decrease of the cooling ability is enhanced but also the process cost of a lance becomes higher. Also, this technique has a problem that pressure loss and the diameter become larger because the multiple tubes are changed into parallel tubes on the way.
As previously mentioned, hot air is supplied to the blast furnace from the tuyeres thereof, but the solid reducing material and the combustible gas are also blown into the furnace with this hot air. In the lance disclosed in Patent Document 4, the solid reducing material and the combustible gas are blown with the coaxially double-tubed lance, but a single tube lance blowing the gaseous reducing material is further arranged in parallel to the double-pipe lance. In such a lance, the occupying area of the lance to the sectional area of the blast pipe and tuyere is large to bring about the increase of running cost associated with the increase of blast pressure or the decrease of visual field in a furnace-monitoring window disposed in a back face of the tuyere. Furthermore, a size of a portion for inserting the lance into the blowpipe (guide tube) is made large to decrease an adhesion area between the guide tube portion and the blowpipe, and hence there is a problem that peeling of the guide tube portion is apt to be easily caused.
It is an object of the invention to propose a blast furnace operation method effective for attaining the improvement of the productivity and the decrease of specific consumption of a reducing material by simultaneously establishing the increase of cooling ability and the improvement of combustibility without increasing the outer diameter of the lance as well as the structure of the lance used in the operation of this method.
The blast furnace operation method according to aspects of the invention developed for achieving the above object includes a method of operating a blast furnace by blowing at least a solid reducing material and a combustible gas into the furnace through tuyeres with a lance inserted into a blowpipe, wherein a tube-bundle type lance obtained by bundling a plurality of blowing tubes is used and when only a solid reducing material or two kinds of a solid reducing material and a combustible gas or three kinds of a solid reducing material, a combustible gas and a gaseous reducing material is simultaneously blown into an inside of the blast furnace through a tube for blowing the solid reducing material, a tube for blowing the combustible gas and a tube for blowing the gaseous reducing material in the tube-bundle type lance, two or more tube-bundle type lances are inserted into the blowpipe to approximate their front ends to each other and blowing is performed so that the respective blowout streams interfere with each other in the blowpipe.
In the invention are provided the following features as a preferable means:
(1) the tube-bundle type lance is constructed by bundling three parallel blowing tubes and housing them into an outer tube of the lance;
(2) the tube-bundle type lance is constructed by passing a tube for blowing the solid reducing material through a central portion of the lance and alternately winding both of a spiral tube for blowing the combustible gas and a spiral tube for blowing the gaseous reducing material around the solid reducing material blowing tube to integrally unite them;
(3) when at least solid reducing material and combustible gas are simultaneously blown through the respective tubes of the two tube-bundle type lances, a blowing stream of the solid reducing material is flown outside a blowing stream of the combustible gas passing through a central portion of the blowpipe;
(4) when at least solid reducing material and combustible gas are simultaneously blown through the respective lances of the two tube-bundle type lances, blowing is performed by arranging the lances so that two blowing streams of the solid reducing material blown from the respective tube-bundle type lances do not collide with each other, while the blowing streams of the solid reducing material collide with a blowing stream of the combustible gas;
(5) when at least solid reducing material and combustible gas are simultaneously blown through the respective lances of the two tube-bundle type lances, the blowing streams of the solid reducing material blown from the respective tube-bundle type lances do not collide with each other, while they converge and collide with blowing streams of the combustible gas blown from the respective tube-bundle type lances to thereby separate the two blowing streams of the solid reducing material;
(6) when at least solid reducing material and combustible gas are simultaneously blown through the respective lances of the two tube-bundle type lances, blowing streams of the solid reducing material blown from the respective tube-bundle type lances collide with each other, while blowing streams of the gaseous reducing material and the combustible gas not converging nor colliding with the blowing stream of the solid reducing material are blown so as to introduce into the outside of the blowing stream of the solid reducing material in the central portion of the blowpipe.
According to the blast furnace operation method of an embodiment of the invention, when the solid reducing material and either one or both of the gaseous reducing material and the combustible gas are simultaneously blown into the blast furnace from the tuyeres through a lance inserted into the blowpipe, two or more tube-bundle type lances are used, whereby a diameter of each of the blowing tubes itself can be maintained at a large scale without increasing the outer diameter of the lance, so that it can be attained to establish the increase of cooling ability and the improvement of the combustibility, and hence the specific consumption of the reducing material can be decreased.
In the invention, the tube-bundle type lance is preferably used by alternately winding spiral blowing tube for the combustible gas and spiral blowing tube for the gaseous reducing material around a blowing tube for the solid reducing material passing through the cylindrical central portion and integrally uniting them, whereby the blowing stream of the gaseous reducing material and the blowing stream of the combustible gas are flown in a state of revolving around the blowing stream of the solid reducing material, and hence the blowing can be performed while diffusing the solid reducing material to more further improve the combustion efficiency of the solid reducing material.
According to the invention, front ends of the two tube-bundle type lances inserted into the blowpipe are preferably approximated to each other and are converged so as to interfere their blowout directions with each other, for example, the lances are arranged so as to sandwich the combustible gas between the solid reducing materials and surround the outside thereof with the combustible gas, so that the combustion efficiency of the solid reducing material can be more improved.
Furthermore, according to the invention, the lances are preferably arranged so that the blowing streams of the solid reducing material do not collide with each other and the combustible gas collides with the blowing stream of the solid reducing material from the other lance, whereby the combustion efficiency of the solid reducing material is further improved.
A preferable embodiment of the blast furnace operation method according to the invention will be described below.
In order to compare the combustibility between the multiple-tube type lance and the tube-bundle type lance, combustion experiment is performed with a combustion experiment device shown in
In this combustion experiment, a single tube lance, a coaxially multiple tube lance (multiple-tube type lance) and a tube-bundle type lance prepared by bundling plural blowing tubes (preferably 2-3 tubes) at a parallel state and housing them in an outer tube along its axial direction are used as the lance 4. Then, the combustion rate, pressure loss in lance, lance surface temperature and outer diameter of lance are measured as to (1) a case that only the pulverized coal is blown through the single tube lance, (2) a case that the pulverized coal is blown from an inner tube of the conventional multiple-tube type lance, and oxygen is blown from a gap between the inner tube and the middle tube and LNG is blown from a gap between the middle tube and the outer tube, and (3) a case that pulverized coal and one or more of LNG and oxygen are blown through the respective blowing tubes of the tube-bundle type lance. The combustion rate is measured by changing a blowing rate of oxygen. The combustion rate is determined from an unburned amount of an unburned char recovered from behind the raceway with a probe.
a) shows an example of the conventional multiple-tube type lance, and
In the tube-bundle type lance of
In the experiment, pulverized coal (PC) is blown through the tube 21 and LNG is blown through the tube 22 and oxygen is blown through the tube 23 in the tube-bundle type lance prepared by bundling three blowing tubes at a parallel state and housing in the outer tube of the lance 4 as shown in
When the blowing is performed with the tube-bundle type lances 4, the lances are arranged so that the blowing streams interfere with each other in the front ends of the lances and, for example, it is preferable that streams of LNG and oxygen are adjusted so as to converge and collide with the blowing stream of pulverized coal. In
As a structure of a front end of the each blowing tube can be used a structure of obliquely cutting the front end or a structure of bending the front end. When the front end of the blowing tube is cut out obliquely, the diffusion state of LNG or oxygen blown can be changed. Also, when the front end of the blowing tube is bent, the direction of LNG or oxygen stream blown can be changed.
In a preferable embodiment of the invention, the tube-bundle type lances 4 to be inserted into the blowpipe 12 are arranged by approximating front ends of two or more lances to each other in the vicinity of axial center of the blowpipe so that the respective blowout directions converge and interfere with each other in the blowpipe 12 and at least the blowing stream of the solid reducing material and the blowing stream of the combustible gas interfere with each other at a constant relation. For example, as shown in
In a more preferable embodiment of the invention, a pair of the two tube-bundle type lances are used, for example, by arranging the position of the oxygen blowing tube 23 so as to sandwich the oxygen stream blown with the pulverized coal stream (PC) as shown in
In this connection, for example, when the two single tube lances are used instead of the tube-bundle type lances, the lances should be arranged at an intersecting state so that the pulverized coal streams blown through the two single tube lances do not collide or mix with each other as shown in
However, when the two tube-bundle type lances are used, it is possible to arrange the lances so as to render into (a) a case that the oxygen stream blown is sandwiched between the two pulverized coal streams (Pattern A), (b) a case that the respective pulverized coal streams blown through the two tube-bundle type lances do not converge and collide with each other but converge and collide with the oxygen streams blown through the separate lances without being separated therewith (Pattern B) or (c) a case that the respective pulverized coal streams blown through the two tube-bundle type lances converge and collide with each other, while they converge and collide with the LNG streams and oxygen streams blown through the respective blowing tubes at a position not colliding therewith and flow outside the streams of the pulverized coals blown (Pattern C).
Then, combustion experiment is performed with respect to the examples shown in
As another example of the tube-bundle type lance 4 used in the invention may be used a lance, for example, prepared by alternately winding a spiral blowing tube for combustible gas and a spiral blowing tube for gaseous reducing material to a cylindrical blowing tube for solid reducing material passing through a central portion and integrally uniting them as shown in
In the blast furnace operation method using the above tube-bundle type lance according to aspects of the invention, the pulverized coal (solid reducing material), LNG (gaseous reducing material) and oxygen (combustible gas) are blown into the tuyeres with the plural tube-bundle type lances 4 so that their blowout streams interfere to each other, whereby the blowing effect can be improved without extremely increasing the outer diameter of the lance to establish the increase of the cooling ability and the improvement of the combustibility, and hence the specific consumption of the reducing material can be decreased.
By using the tube-bundle type lance prepared by arranging the spiral blowing tube for the gaseous reducing material and the spiral blowing tube for the combustible gas around the cylindrical blowing tube for the solid reducing material (pulverized coal) passing through the central portion and integrally uniting them are flown the LNG (gaseous reducing material) stream and oxygen (combustible gas) stream in a state of revolving around the pulverized coal (solid reducing material) stream, whereby the pulverized coal (solid reducing material) can be blown diffusely to more further improve the combustion rate of the pulverized coal (solid reducing material).
Although the aforementioned embodiment is explained by using LNG as a gaseous reducing material, it is possible to use a town gas. In addition to the town gas and LNG, propane gas, hydrogen as well as converter gas, blast furnace gas and coke-oven gas produced in the ironworks can be used as the other gaseous reducing material. Moreover, shale gas may be utilized in equivalence to LNG. The shale gas is a natural gas obtained from a shale stratum, which is called as a non-conventional natural gas resource because it is produced in a place different from the conventional gas field.
1: blast furnace, 2: blowpipe, 3: tuyere, 4: lance, 5: raceway, 6: pulverized coal (solid reducing material), 7: clumpy coke, 8: char, 9: LNG (gaseous reducing material), 21: first tube, 22: second tube, 23: third tube
Number | Date | Country | Kind |
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2013-077524 | Apr 2013 | JP | national |
This is the U.S. National Phase application of PCT International Application No. PCT/JP2014/058793, filed Mar. 27, 2014, and claims priority to Japanese Patent Application No. 2013-077524, filed Apr. 3, 2013, the disclosures of each of these applications being incorporated herein by reference in their entireties for all purposes.
Filing Document | Filing Date | Country | Kind |
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PCT/JP2014/058793 | 3/27/2014 | WO | 00 |