Claims
- 1. A polymer mixture with improved impact strength and elongation at fracture without significant reduction in tensile strength which comprises a polyphenylene ether, a fluorine-containing olefinic homopolymer or copolymer and a vinylaromatic-alkyl(meth)acrylate copolymer, characterised in that the polymer mixture comprises:
- A. 30-70% by weight of a polyphenylene ether,
- B. 30-70% by weight of a fluorine-containing olefinic homopolymer or copolymer, the weight percentages of A and B being calculated with respect to the sum of the quantities by weight of A plus B,
- C. 1-80 parts by weight of a non-linear vinylaromatic alkyl(meth)acrylate copolymer, and
- D. 1-20 parts by weight of an, optionally partially hydrogenated, block copolymer having one or more blocks derived from conjugated diene units and having one or more blocks derived from vinylaromatic units.
- 2. A polymer mixture as claimed in claim 1, characterised in that as constituent C the polymer mixture comprises a copolymer having non-linear structure built up from a polyalkyl(meth)acrylate main chain with polystyrene side chains.
- 3. A polymer mixture as claimed in claim 1, characterized in that the polymer mixture comprises as constituent C a copolymer having a non-linear structure built up from a polystyrene main chain with polyalkyl(meth)acrylate side chains.
- 4. A polymer mixture as claimed in claim 1, characterised in that the polymer mixture comprises 1-50 parts by weight of constituent C per 100 parts by weight of A plus B.
- 5. A polymer mixture as claimed in claim 1, characterised in that the polymer mixture comprises as constituent B a homopolymer or copolymer which is built up for more than 25 mol % from units derived from vinyl fluoride, vinylidene fluoride or a mixture thereof.
- 6. A polymer mixture as claimed in claim 5, characterised in that constituent B consists of polyvinylidene fluoride, polyvinyl fluoride or of a mixture of polyvinylidene fluoride and polyvinyl fluoride.
- 7. A polymer mixture as claimed in claim 5, characterised in that constituent B is a copolymer built up on the one hand from units derived from vinylidene fluoride, vinyl fluoride or vinylidene fluoride and vinyl fluoride and on the other hand from units derived from hexafluoropolypropylene, chlorotrifluoroethylene, tetrafluoroethylene or a mixture of any of the foregoing.
- 8. A polymer mixture as claimed in claim 5, characterised in that constituent B is a copolymer of vinylidene fluoride and vinyl fluoride.
- 9. A polymer mixture as claimed in claim 5, characterized in that the polymer mixture comprises as constituent B a homopolymer or copolymer which is built up for more than 45 mol % from units derived from vinyl fluoride, vinylidene fluoride or mixtures of the foregoing.
- 10. A polymer mixture as claimed in claim 1, characterized in that the alkyl(meth)acrylate portion of constituent C is selected from the group consisting of alkyl acrylates, alkyl(meth)acrylates and mixtures of the foregoing wherein the alkyl group comprises 1-6 carbon atoms.
- 11. A polymer mixture as claimed in claim 10 characterized in that the alkyl(meth)acrylate is selected from the group consisting of methylmethacrylate, ethylmethacrylate, methacrylate, ethacrylate and mixtures of the foregoing.
- 12. A polymer mixture as claimed in claim 11, characterized in that the ratio of vinyl aromatic units to alkyl(meth)acrylate units is between 5:95 to 95:5.
- 13. A polymer mixture as claimed in claim 12, characterized in that the ratio of vinyl aromatic units to alkylmethacrylate units is between 25:75 to 75:25.
- 14. A polymer mixture as claimed in claim 2, characterized in that the alkyl(meth)acrylate portion of constituent C is selected from the group consisting of alkyl acrylates, alkyl(meth)acrylates and mixtures of the foregoing wherein the alkyl group comprises 1-6 carbon atoms.
- 15. A polymer mixture as claimed in claim 14, characterized in that the alkyl(meth)acrylate is selected from the group consisting of methylmethacrylate, ethylmethacrylate, methacrylate, ethacrylate and mixtures of the foregoing.
- 16. A polymer mixture as claimed in claim 15, characterized in that the ratio of vinyl aromatic units to alkyl(meth)acrylate units is between 5:95 to 95:5.
- 17. A polymer mixture as claimed in claim 16, characterized in that the ratio of vinyl aromatic units to alkyl(meth)acrylate units is between 25:75 to 75:25.
- 18. A polymer mixture with improved impact strength and elongation at fracture without significant reduction in tensile strength consisting essentially of:
- (1) a polyphenylene ether;
- (2) a fluorine-containing olefin polymer or copolymer;
- (3) a non-linear vinyl aromatic alkyl(meth)acrylate copolymer; and
- (4) a block copolymer having one or more blocks derived from conjugated diene units and having one or more blocks derived from vinyl aromatic units.
- 19. A polymer mixture with improved impact strength and elongation at fracture without significant reduction in tensile strength which comprises a polyphenylene ether, a fluorine-containing olefinic homopolymer or copolymer and a vinylaromatic-alkyl(meth)acrylate copolymer, characterized in that the polymer mixture comprises:
- A. 30-70% by weight of a polyphenylene ether,
- B. 30-70% by weight of a fluorine-containing olefinic homopolymer or copolymer, the weight percentages of A and B being calculated with respect to the sum of the quantities by weight of A plus B,
- C. 1-50 parts by weight of a non-linear vinylaromatic alkyl(meth)-acrylate copolymer, and
- D. 1-20 parts by weight of an, optionally partially dehydrogenated, block copolymer having one or more blocks derived from conjugated diene units and having one or more blocks derived from vinylaromatic units.
- 20. A polymer mixture as claimed in claim 19, characterized in that component A is present in an amount of about 45 parts by weight, component B is present in an amount of about 55 parts by weight, component C is present in an amount of about 43 parts by weight and component D is present in an amount of about 14.5 parts by weight.
Priority Claims (1)
Number |
Date |
Country |
Kind |
8701625 |
Jul 1987 |
NLX |
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Parent Case Info
This is a continuation of application Ser. No. 211,962 filed Jun. 27, 1988, now abandoned.
US Referenced Citations (6)
Foreign Referenced Citations (2)
Number |
Date |
Country |
0076539 |
Apr 1983 |
EPX |
0076539 |
Sep 1982 |
FRX |
Continuations (1)
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Number |
Date |
Country |
Parent |
211962 |
Jun 1988 |
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