Patent Application
20240092805
The following disclosure relates to a novel boron-containing compound and an electrolyte solution additive for a secondary battery including the same.
Since a lithium secondary battery has higher energy density than other batteries and allows for small size and light weight, it is highly likely to be used as a power supply of portable electronic devices. A lithium secondary battery may include a positive electrode, a negative electrode, and an electrolyte solution.
Recently, as a demand for a secondary battery having high power and high capacity like a secondary battery for automobiles increases, it is necessary to develop a lithium secondary battery provided with an electrolyte solution which may secure high thermal and chemical stability to improve ignition or explosion.
An embodiment is directed to providing a novel compound containing boron.
Another embodiment is directed to providing an electrolyte solution additive for a secondary battery including a boron-containing compound.
Still another embodiment is directed to providing an electrolyte solution including the electrolyte solution additive for a secondary battery, and a secondary battery including the same.
In one general aspect, a compound represented by the following Chemical Formula 1 is provided:
wherein
X1 and X2 are independently of each other a substituted or unsubstituted compound represented by the above Chemical Formula 2;
X3 and X4 are independently of each other hydrogen, halogen, substituted or unsubstituted C1-15 alkyl, substituted or unsubstituted C2-15 alkenyl, or the substituted or unsubstituted compound represented by the above Chemical Formula 2; and
n and m are independently of each other an integer of 0 to 15, and A is a bond or —C(═O)—.
In another general aspect, an electrolyte solution additive for a secondary battery includes a compound represented by the following Chemical Formula 1:
wherein X1, X2, X3, and X4 are as defined above.
In another general aspect, an electrolyte solution for a secondary battery includes the electrolyte solution additive for a secondary battery.
In another general aspect, a protective film of an electrode includes the electrolyte solution additive for a secondary battery.
In still another general aspect, a secondary battery includes the electrolyte solution for a secondary battery. Other features and aspects will be apparent from the following detailed description, the drawings, and the claims.
Example 1 by linear sweep voltammetry analysis.
The embodiments of the present disclosure may be modified in many different forms and the scope of the disclosure should not be limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the disclosure to those skilled in the art. Furthermore, unless explicitly described otherwise, “comprising” any components will be understood to imply the inclusion of other components but not the exclusion of any other components.
One embodiment provides a compound represented by the following Chemical Formula 1:
wherein
X1 and X2 are independently of each other a substituted or unsubstituted compound represented by the above Chemical Formula 2;
X3 and X4 are independently of each other hydrogen, halogen, substituted or unsubstituted C1-15 alkyl, substituted or unsubstituted C2-15 alkenyl, or the substituted or unsubstituted compound represented by the above Chemical Formula 2; and
n and m are independently of each other an integer of 0 to 15, and A is a bond or —C(═O)—.
Here, “substituted” may be being independently of each other substituted by one or more of —OH, —CN, —NH2, —NO2, halogen, straight chain or branched chain C1-20 alkyl, straight chain or branched chain C1-20 alkylamino, straight chain or branched chain C2-20 alkenyl, straight chain or branched chain C1-20 alkoxy, straight chain or branched chain C1-20 alkylcarbonyl, C3-20 cycloalkyl, 3- to 10-membered heterocycloalkyl containing one or more heteroatoms selected from the group consisting of N, O, and S, C5-20 aryl, and 5-to 10-membered heteroaryl containing one or more heteroatoms selected from the group consisting of N, O, and S, but is not necessarily limited thereto.
In one embodiment, X1 and X2 may be independently of each other the substituted or unsubstituted compound represented by the above Chemical Formula 2;
X3 and X4 may be independently of each other hydrogen, halogen, substituted or unsubstituted C1 -10 alkyl, substituted or unsubstituted C2-10 alkenyl, or the substituted or unsubstituted compound represented by the above Chemical Formula 2; and
n and m may be independently of each other an integer of 0 to 10, and A may be a bond.
X3 and X4 may be independently of each other substituted or unsubstituted C1-8 alkyl, substituted or unsubstituted C1-5 alkyl, substituted or unsubstituted C1-3 alkyl, substituted or unsubstituted C2-8 alkyl, substituted or unsubstituted C2-6 alkenyl, substituted or unsubstituted C2-5 alkenyl, or substituted or unsubstituted C2-3 alkenyl. Here, the alkenyl includes the case in which an unsaturated carbon is directly connected or an unsaturated carbon is connected via alkylene. For example, the unsaturated carbon may exist at the very end of a chain.
n and m may be independently of each other an integer of 0 to 8, an integer of 0 to 5, an integer of 0 to 3, an integer of 0 to 2, or 0, 1, or 2. Otherwise, the compound represented by the above Chemical Formula 2 may be
The compound represented by the above Chemical Formula 1 may be any one selected from the group consisting of the following compounds represented by the following chemical formulae:
Another embodiment provides an electrolyte solution additive for a secondary battery including a compound represented by the following Chemical Formula 1:
wherein
X1 and X2 are independently of each other a substituted or unsubstituted compound represented by the above Chemical Formula 2;
X3 and X4 are independently of each other hydrogen, halogen, substituted or unsubstituted C1-15 alkyl, substituted or unsubstituted C2-15 alkenyl, or the substituted or unsubstituted compound represented by the above Chemical Formula 2; and
n and m are independently of each other an integer of 20 to 15, and A is a bond or —C(═O)—.
Here, the above descriptions may apply to X1, X2, X3, X4, n, and m.
The electrolyte solution additive for a secondary battery may include an oligomer, a polymer, a polymerization initiator, a solvent, and the like, prepared from a monomer, using the compound represented by Chemical Formula 1 as the monomer. The oligomer may be bonded through a polymerization reaction to form a network.
The oligomer or the polymer prepared from the monomer may have a weight average molecular weight of, for example, about 1,000 to 30,000, about 1,000 to 25,000, about 1,000 to 20,000, about 5,000 to 20,000, but is not necessarily limited thereto.
The compound represented by Chemical Formula 1 may be included at 0.01 to 30 wt %, 0.01 to 20 wt %, 0.01 to 10 wt %, 0.05 to 20 wt %, 0.1 to 20 wt %, 0.1 to 15 wt %, 0.1 to 10 wt %, or 1 to 10 wt % with respect to the total weight of the electrolyte solution additive for a secondary battery, but is not necessarily limited thereto.
The polymerization initiator may be used for forming a polymer by polymerizing the monomer or the oligomer, and a common polymerization initiator known in the art may be used without limitation. For example, a photopolymerization initiator or a thermal polymerization initiator may be used depending on a polymerization method, and specifically, for example, the photopolymerization initiator may include at least one or more selected from the group consisting of 2-hydroxy-2-methylpropiophenone (HMPP), 1-hydroxy-cyclohexylphenyl-ketone, benzophenone, 2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methyl-1-propanone, oxy-phenylacetic acid 2-[2-oxo-2-phenyl-acetoxy-ethoxy]-ethyl ester, oxy-phenyl-acetic 2-[2-hydroxyethoxy]-ethyl ester, α-dimethoxy-α-phenylacetophenone, 2-benzyl-2-(dimethylamino) -1-[4-(4-morpholinyl)phenyl]-1-butanone, 2-methyl-1-[4-(methylthio)phenyl]-2-(4-morpholinyl)-1-propanone, diphenyl (2,4,6-trimethylbenzoyl)-phosphine oxide, bis(2,4,6-trimethyl benzoyl)-phenyl phosphine oxide, bis(eta-5-2,4-cyclopentediene-1-yl), bis[2,6-difluoro-3-(1H-pyrrole-1-yl)phenyl]titanium, 4-isobutylphenyl-4′-methylphenyliodonium hexafluorophosphate, and methyl benzoylformate, and the thermal polymerization initiator may include at least one or more selected from the group consisting of benzoyl peroxide, acetyl peroxide, dilauryl peroxide, di-tert-butylperoxide, t-butyl peroxy-2-ethyl-hexanoate, cumyl hydroperoxide, hydrogen peroxide, 2,2′-azobis(2-cyanobutane), 2,2′-azobis(methylbutyronitrile), 2,2′-azobis(iso-butyronitrile) (AIBN), and 2,2′-azobisdimethyl-valeronitrile (AMVN), as a representative example.
The solvent is not particularly limited as long as it is an electrolyte solution solvent commonly used in secondary batteries, and for example, ethers, esters (such as acetates and propionates), amides, linear carbonates or cyclic carbonates, nitriles (such as acetonitrile and SN), and the like may be used alone or in combination or two or more.
The ester compound may include methyl acetate, ethyl acetate, n-propyl acetate, dimethyl acetate, methyl propionate, ethyl propionate, y-butyrolactone, decanolide, valerolactone, mevalonolactone, caprolactone, methyl formate, and the like.
The linear carbonate compound may include, for example, diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), methylpropyl carbonate (MPC), ethylpropyl carbonate (EPC), ethylmethyl carbonate (EMC), or a combination thereof, and the cyclic carbonate compound may include, for example, ethylene carbonate (EC), propylenecarbonate (PC), butylene carbonate (BC), vinylethylene carbonate (VEC), or a combination thereof.
Another embodiment provides an electrolyte solution for a secondary battery including the electrolyte solution additive for a secondary battery.
The electrolyte solution for a secondary battery may further include other additives known in the art, inorganic particles, and the like for increasing efficiency and decreasing resistance of a secondary battery.
For example, an oxalatophosphate-based additive, an oxalatoborate-based compound, a fluorine-substituted carbonate-based compound, a vinylidene carbonate-based compound, or a sulfinyl group-containing compound may be included as other additives. Otherwise, for example, lithium tetrafluoro(oxalato)phosphate (LiTFOP), lithium difluorobis(oxalato)phosphate (LiDFOP), lithium difluorooxalatoborate (LiDFOB), lithium bisoxalatoborate (LiB(C2O4)2, LiBOB), fluoroethylene carbonate(FEC), vinylene carbonate (VC), vinylethylene carbonate (VEC), divinyl sulfone, ethylene sulfite, propylene sulfite, diallyl sulfonate, ethane sultone, propane sultone (PS), butane sultone, ethene sultone, butene sultone, or propene sultone (PRS) may be included. In one embodiment, the compound or an oligomer including the compound as a monomer may be further reacted with other additives in an electrolyte solution.
The oxalatoborate-based compound may be a compound represented by the following Chemical Formula 3 or lithium bisoxalatoborate (LiB (C2O4)2, LiBOB):
wherein R21 an R22 are independently of each other halogen or haloC1-10 alkyl. A specific example of the oxalatoborate-based additive may include LiB(C2O4)F2 (lithiumdifluorooxalatoborate, LiDFOB), LiB (C2O4)2 (lithiumoxalatoborate, LiBOB), or the like.
The oxalatophosphate-based additive may be a compound represented by the following Chemical Formula 4 or lithium difluorobis(oxalato)phosphate (LiDFOP).
wherein R23 to R26 are independently of each other halogen or haloC1-10 alkyl. A specific example of the oxalatophosphate-based additive may include lithium tetrafluoro(oxalato)phosphate (LiTFOP), lithium difluoro bis(oxalato)phosphate (LiDFOP), or the like.
The fluorine-substituted carbonate-based compound may be fluoroethylene carbonate (FEC), difluoroethylene carbonate (DFEC), fluorodimethyl carbonate (FDMC), fluoroethylmethyl carbonate (FEMC), or a combination thereof.
The vinylidene carbonate-based compound may be vinylene carbonate (VC), vinyl ethylene carbonate (VEC), or a mixture thereof.
The sulfinyl group (S═O)-containing compound may be sulfone, sulfite, sulfonate, or sultone (cyclic sulfonate), and these may be used alone or in combination. Specifically, the sulfone may be represented by the following Chemical Formula 5, and may be divinyl sulfone. The sulfite may be represented by the following Chemical Formula 6, and may be ethylene sulfite or propylene sulfite. The sulfonate may be represented by following Chemical Formula 7, and may be diallyl sulfonate. In addition, a non-limiting example of sultone may include ethane sultone, propane sultone, butane sultone, ethene sultone, butene sultone, propene sultone, and the like.
wherein R27 and R28 are independently of each other hydrogen, halogen, C1-10 alkyl, C2-10 alkenyl, haloC1-10 alkyl, or haloC2-10 alkenyl.
As the inorganic particles, a single compound selected from the group consisting of BaTiO3, Pb(Zr,Ti)O3 (PZT), Pb1-aLaaZr1-bTibO3 (PLZT, wherein 0<a<1, 0<b<1), Pb (Mg1/3Nb2/3) O3-PbTiO3 (PMN-PT), halfnia (HfO2), SrTiO3, SnO2, CeO2, MgO, NiO, CaO, ZnO, ZrO2, Y2O3, Al2O3, TiO2, SiC, and a mixed body thereof, or a mixture of at least two or more thereof, lithium phosphate (Li3PO4), lithium titanium phosphate ((LicTid(PO4)3, 0<d<2, 0<d<3), lithium aluminum titanium phosphate (Lia1AlbiTic1 (PO4)3, 0<a1<2, 0<b1<1, 0<c1<3), (LiAlTiP)a2Ob2-based glass (0<a2<4, 0<b2<13) such as 14Li2O -9Al2O3-38TiO2 -39P2O5, lithium lanthanum titanate (Lia3Lab3TiO3, 0<a3<2, 0<b3<3), lithium germanium thiophosphate (Lia4Geb4Pc2Sd, 0<a4<4, 0<b4<1, 0<c2<1, 0<d<5) such as Li3.25Ge0.25P0.75S4, lithium nitride (Lia5Nb5, 0<a5<4, 0<b5<2) such as Li3N, SiS2-based glass (Lia6Sib6Sc3, 0<a6<3, 0<b6<2, 0<c3<4) such as L3PO4-Li2SSiS2, P2S5-based glass (Liaa6Sib6Sc3, 0<a6<3, 0<b6<2, 0<c3<4) such as LiI-Li2S-P2S5, or mixtures thereof, and the like may be used.
In one embodiment, the additive or the inorganic particles may be included at 0.1 wt % to 20 wt % with respect to the total weight of the electrolyte solution, but is not necessarily limited thereto.
The electrolyte solution may be formed by polymerizing the compound according to a common method known in the art. For example, a composition including the compound as an additive may be prepared by performing in-situ polymerization, coating polymerization, or the like. The composition for a secondary battery provided in one embodiment has excellent high-temperature stability and ion conductivity, so that it may be efficiently used in a secondary battery.
The compound according to one embodiment included in the additive is formed on the surface of an electrode to prevent a direct contact between the electrode and an electrolyte solution, so that a side reaction between the electrode and the electrolyte solution at a high temperature may be suppressed, and an electrode life may be improved due to the suppression of cracks of SEI by the shrinkage and expansion of the electrode during charging and discharging. That is, since the compound according to one embodiment may form thermally stable SEI on the surface of an electrode, a battery adopting the electrolyte solution according to one embodiment may have excellent storage characteristics and excellent thermal stability.
Another embodiment provides a protective film of an electrode including the compound or the electrolyte solution additive for a secondary battery including the same. Therefore, the use of the compound according to one embodiment is not necessarily limited only to the additive added to an electrolyte solution, the compound may be also used for forming a protective film in a secondary battery, and the protective film may be formed on the surface of the electrode or an electrode current collector to be used for suppressing the further decomposition of the electrolyte solution or improving a battery life. For example, it may be used as a layer for protecting a dendrite, and the layer may be a gel-polymer film. Thus, the cycle characteristics of a secondary battery electrode may be improved to improve the performance and the life of a battery.
Another embodiment provides a secondary battery including the electrolyte solution for a secondary battery.
A negative electrode included in the secondary battery includes a negative electrode current collector and a negative electrode active material layer formed on the negative electrode current collector, and the negative electrode active material layer includes a negative electrode active material. The negative electrode active material is not particularly limited as long as it is commonly used in the art. For example, it may be a silicon-based negative electrode active material or carbon-based negative electrode active material. Specifically, it may include graphite such as natural graphite, artificial graphite, and expanded graphite, crystalline carbon such as graphene, fullerene soot, carbon nanotubes, and carbon fiber, and amorphous carbon such as soft carbon (low temperature baked carbon), hard carbon, coke, mesocarbon microbeads (MCMB) baked at 1500° C. or lower, and mesophase pitch-based carbon fiber (MPCF). Otherwise, it may include a material selected from Si, SiOx (0<x<2), Si-Z alloy (wherein Z is an alkali metal, an alkaline earth metal, a Group 13 element, a Group 14 element, a Group 15 element, a Group 16 element, a transition metal, a rare earth element, or a combination thereof, and Si is excluded from Z), and a combination thereof. Element Z may be selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, La, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Tc, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Ge, P, As, Sb, Bi, S, Se, Te, Po, and combinations thereof. In addition, the silicon-based negative electrode active material such as Si, SiOx, and Si-Z alloy may substantially include crystalline (including monocrystalline and polycrystalline), amorphous, or a mixed form thereof. In addition, the negative electrode may further include a compound commonly used as a negative electrode active material.
A positive electrode included in the secondary battery includes a positive electrode current collector and a positive electrode active material layer formed on the positive electrode current collector, and the positive electrode active material layer includes a positive electrode active material. The positive electrode active material is not particularly limited as long as it is commonly used in the art. For example, it may include a positive electrode active material capable of adsorbing or desorbing a lithium ion, and as the positive electrode active material, those commonly used in the art as a lithium-containing metal oxide may be used without limitation. For example, a composite metal oxide of a metal selected from cobalt, manganese, nickel, and a combination thereof with lithium may be used.
A specific example of the positive electrode active material may include a compound represented by any one of the following chemical formulae : LiaA1-bBbD2 (wherein 0.90≤≤a≤1.8, and 0≤b0.5); LiaE1-bBbO2-cDc (wherein 0.90≤a≤1.8 , 0≤b≤0.5, and 0c≤0.05); LiE2-bBbO4-cDc (wherein 0≤b≤0.5 and 0≤c≤0.05); LiaNi1-b-cCobBcDα(wherein 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<α≤2); LiaNi1-b-cCobBcO2-αF60 (wherein 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<α<2); LiaNi1-b-cCobBcO2-αF2 (wherein 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<α<2); LiaNi1-b-cMnbBcDα(wherein 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<α≤2); LiaNi1-b-cMnbBcO2-αFα(wherein 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<α<2); LiaNi1-b-cMnbBcO2-αF2 (wherein 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<α<2); LiaNibEcGdO2 (wherein 0.90≤a≤1.8, 0≤b≤0.9, 0≤c≤0.5, and 0.001≤d≤0.1); LiaNibCocMndGeO2 (wherein 0.90≤a≤1.9, 0≤b≤0.9, 0≤c≤0.5, 0≤≤0.5, and 0.001≤e≤0.1); LiaNiGbO2 (wherein 0.90≤a≤1.8 and 0.001≤b≤0.1); LiaCoGbO2 (wherein 0.90≤a≤1.8 and 0.001≤b≤0.1); LiaMnGbO2 (wherein 0.90≤a≤1.8 and 0.001≤b≤0.1); LiaMn2GbO4 (wherein 0.90≤a≤1.8 and 0.001≤b≤0.1); QO2; QS2; LiQS2; V2O5; LiV2O5; LiIO2; LiNiVO4, Li(3-f)J2(PO4)3 (O≤f≤2); Li(3-f)Fe2(PO4)3(0≤f≤2); and LiFePO4.
In the above Chemical Formulae, A is Ni, Co, Mn, or a combination thereof; B is Al, Ni, Co, Mn, Cr, Fe, Mg, Sr, V, a rare earth element, or a combination thereof; D is O, F, S, P, or a combination thereof; E is Co, Mn, or a combination thereof; F is F, S, P, or a combination thereof; G is Al, Cr, Mn, Fe, Mg, La, Ce, Sr, V, or a combination thereof; Q is Ti, Mo, Mn, or a combination thereof; I is Cr, V, Fe, Sc, Y, or a combination thereof; and J is V, Cr, Mn, Co, Ni, Cu, or a combination thereof. For example, it may be LiCoO2, LiMnxO2x (x=1, 2) , LiNi1-xMnxO2x (0x<1), LiNi1-x-yCoxMnyO2 (0≤x≤0.5, 0≤y≤0.5), FePO4, or the like.
The positive electrode or the negative electrode may be produced by dispersing an electrode active material, a binder, a conductive material, or a thickener in a solvent to prepare an electrode slurry composition, and applying the slurry composition on an electrode current collector. As a positive electrode current collector, aluminum, an aluminum alloy, or the like may be often used, and as a negative electrode current collector, copper, a copper alloy, or the like may be often used. The positive electrode current collector and the negative electrode current collector may be in the form of foil or mesh.
The secondary battery provided in one embodiment includes the electrolyte solution for a secondary battery, so that sufficient performance may be exerted even at a high temperature, and suppresses the production of volatile materials, so that an effect of suppressing a battery thickness increase may be obtained. In addition, low-resistance characteristics of an electrode are improved, and a battery life may be increased. The secondary battery according to one embodiment may be formed in other shapes such as cylindrical and pouch shapes, in addition to a prismatic shape. The secondary battery may be used for an application requiring high voltage, high power, and high-temperature operation, such as an electric vehicle, in addition to the conventional uses such as a mobile phone or a portable computer. In addition, the secondary battery may be combined with conventional internal combustion engines, fuel cells, supercapacitors, and the like to be also used in a hybrid vehicle and the like, and may be used in electric bicycles, machine tools, and other uses requiring high power, high voltage, and high-temperature operation.
Hereinafter, the examples and the experimental examples will be illustrated in detail. However, the examples and the experimental examples described later are only illustrative of a part of the present disclosure, and the present disclosure is not limited thereto.
Boron lithium hydride (0.5 g, 23.0 mmol) and 40 mL of tetrahydrofuran were added to a round bottom flask and then stirring was performed. 2-Propen-1-ol (6.7 g, 114.8 mmol) diluted with 10 mL of tetrahydrofuran was slowly added to a reaction solution, and the solution was heated to 80° C. and stirred for 3 hours. A solid produced after the reaction was complete was filtered, washed with tetrahydrofuran, and dried to obtain 4.6 g of compound a of Example 1 as a white solid sample (yield: 81%).
1H-NMR(500 MHz, DMSO-d): 5.90(4H, m), 5.18(4H, d), 5.02(4H, d), 3.94(8H, s)
In a mixed solution of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) at a weight ratio of 3:7, LiPF6 was dissolved at a concentration of 1.0 M, and 1 wt % of the compound according to Example 1 was added to prepare the electrolyte solution according to Example 2.
The electrolyte solution according to Example 2 was tested by the following method, for measuring a decomposition initiation voltage through linear sweep voltammetry analysis, and an electrolyte solution including no compound a of Example 1 was used as a reference electrolyte solution for comparison. Specifically, a platinum electrode was used as a working electrode, a lithium metal was used as a reference electrode and a counter electrode, and the measurement was performed at a scan speed of 0.1 mV/s in a voltage range of 3 V to 7 V. As a LSV measuring instrument, Multi-Channel Potentiostat (Ametek, Inc.) PMC-100 was used. The results are shown in
As a result, as shown in
The electrolyte solution according to Example 2 was tested by the following method, for measuring a current-voltage curve through cyclic voltammetry analysis. Specifically, graphite was used as a working electrode and lithium was used as a counter electrode and a reference electrode, CV measurement was performed for 3 cycles at a CV scan speed of 0.5 mV/s in a voltage range of 0 V to 3 V, and as a CV measuring instrument, Multi-Channel Potentiostat (Ametek, Inc.) PMC-100 was used. The results are shown in
As a result, as shown in
The present disclosure relates to a novel boron-containing compound and an electrolyte solution additive for a secondary battery including the same. The electrolyte solution for a secondary battery provided in one embodiment includes the novel boron-containing compound, thereby suppressing the decomposition of an electrolyte solution to improve the capacity and the life characteristics of a battery.
Hereinabove, though the present disclosure has been described in detail by the preferred examples and experimental examples, the scope of the present disclosure is not limited to specific examples, and should be construed by the appended claims. In addition, it should be understood by a person skilled in the art that many modifications and variations are possible without departing from the scope of the present disclosure.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2021-0183651 | Dec 2021 | KR | national |
This application is a division of U.S. patent application Ser. No. 18/086,122 filed on Dec. 21, 2022, which claims priority under 35 U.S.C. § 119 to Korean Patent Application No. 10-2021-0183651, filed on Dec. 21, 2021, in the Korean Intellectual Property Office, the disclosure of which is incorporated herein by reference in its entirety.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 18086122 | Dec 2022 | US |
| Child | 18502094 | US |
