The present invention relates generally to a device suited for the applications of ultrapure liquid analysis. More particularly, the present invention relates to an improved bottle cap and a bottle or a container cooperating with such bottle cap, which can readily remove air or air bubbles from an inside of the bottle or the container.
Recent enhancements in modern analytical instrumentation have improved the sensitivity of analysis. Trace elements are now measured at ppt or sub-ppt levels. These levels can be achieved if careful control of the analytical protocol is maintained. Contamination can result from anything that comes into contact with the sample, e.g., the laboratory environment, the air, and anything used during sample preparation.
The quality of water has a significant influence on instrumental analyses. Studies concerning ultra-trace analysis represent that blank optimization is only achievable when ultrapure water with sub-ppt level contamination for most of the elements is used. Contamination risks are greatly increased when the ultrapure water is stored. Results clearly indicate that the quality of high purity water degrades with storage time.
Some studies represent that if ultrapure water is left open to the atmosphere, an anion concentration of about 0.1 ppb can be detected within 1 hour, and an anion concentration of about 1 ppb can be detected after 8 hours of storage. Of course, there are differences in the concentration depending on the indoor environment.
Conventionally, after ultrapure water is sampled with a sample container, air bubbles may remain inside the container after closing a lid or a bottle cap. Even if it is thought that the air bubbles have been removed successfully, small amount of air bubbles still may remain on an interior sidewall of the container. It is desirable to use ultrapure water as soon as possible after collection, and not to store it. Where storage is unavoidable, the container preferably may be buried with ultrapure water and sealed in order to eliminate contamination from the atmosphere.
It has been reported that the air sealed within the sample container may be contaminated. Although there are several pollution factors in the trace analysis of ultrapure water, pollution from the environment (atmosphere) is also regarded as a problem. Therefore, there is a strong need in this technical field to provide an improved device for applications of ultrapure liquid analysis to cope with such problem.
It is one object of the invention to provide an improved device suited for the applications of ultrapure liquid analysis.
It is another object of the invention to provide an improved bottle cap and a bottle or a container cooperating with such bottle cap, which can readily remove or discharge residual air or bubbles from the inside of the bottle or the container.
One aspect of the present invention provides a bottle cap including a cap body comprising a cover plate and a cylinder part integral with the cover plate, and a stopper member protruding from an inner surface of the cover plate. The stopper member includes a sealing part supported by a support structure integral with the cover plate. An annular guiding plate protrudes from a sidewall surface of the cylinder part and is inclined toward the stopper member to engage with the sealing part.
According to some embodiments, the sealing part comprises a convex curved surface.
According to some embodiments, the annular guiding plate defines a central opening to be enclosed by an outer peripheral of the sealing part in a plan view.
According to some embodiments, the sealing part further comprises a central bulge portion, a peripheral bulge portion surrounding the central bulge, and an annular recessed region between the central bulge portion and the peripheral bulge portion.
According to some embodiments, an upper rim of the annular guiding plate is located at the annular recessed region in a plan view.
According to some embodiments, the peripheral bulge portion is located while overlapping an upper portion of the annular guiding plate in a plan view.
According to some embodiments, the support structure comprises a vertical portion integral with the cover plate and a horizontal portion coupled to the vertical portion.
According to some embodiments, the vertical portion comprises a plurality of rods.
According to some embodiments, the support structure further comprises a prop secured to the inner surface of the cover plate and surrounded by the plurality of rods.
According to some embodiments, the horizontal portion is secured to a lower surface of the prop.
According to some embodiments, the sealing part is secured to the horizontal portion and is opposite to the prop.
According to some embodiments, the sealing part and the prop are composed of an elastic material.
According to some embodiments, the annular guiding plate comprises at least one perforation communicating an inner space between the cover plate, the cylinder part, the stopper member, and the annular guiding plate with an outside of the bottle cap.
According to some embodiments, the cylinder part comprises a spiral female threaded portion situated under the annular guiding plate.
According to some embodiments, the bottle cap further comprises an elastic sealing film adhered to a lower surface of the annular guiding plate.
According to some embodiments, the bottle cap further comprises an annular fixing structure integral with the cap body and in proximity to the cylinder part.
According to some embodiments, the inner space is divided into a first space and a second space by the annular fixing structure, and wherein the annular fixing structure comprises at least one channel that communicates the first space with the second space.
Another aspect of the invention provides a bottle that cooperates with the above-described bottle cap.
According to some embodiments, the bottle comprises a bottle neck for the bottle cap to screw thereto.
According to some embodiments, the bottle neck comprises a spiral male threaded portion, and wherein the spiral male threaded portion is not continuous and comprises a slit in a vertical direction.
These and other objectives of the present invention will no doubt become obvious to those of ordinary skill in the art after reading the following detailed description of the preferred embodiment that is illustrated in the various figures and drawings.
In the following detailed description of the disclosure, reference is made to the accompanying drawings, which form a part hereof, and in which is shown, by way of illustration, specific embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention.
Other embodiments may be utilized and structural, logical, and electrical changes may be made without departing from the scope of the present invention. Therefore, the following detailed description is not to be considered as limiting, but the embodiments included herein are defined by the scope of the accompanying claims.
The semiconductor industry is advancing rapidly with an increased demand for more chips per wafer and narrower linewidths in the single digit nanometer range. In order to meet these challenges, monitoring and control of ultrapure liquid such as ultrapure water (UPW) preferably may be implemented to detect ionic impurities among other things that could negatively impact wafer yield. Ensuring that contaminant levels of ultrapure water used in semiconductor fabrication processes remain as low as possible is an important challenge.
Due to newly developed instrumentation, limits of detection reached by trace analysis are becoming lower and lower. Ultrapure water or highly purified water (HPW) is water that has been purified to uncommonly stringent specifications. Ultrapure water is a commonly used term in the semiconductor industry to emphasize the fact that the water is treated to the highest levels of purity for all contaminant types, including: organic and inorganic compounds; dissolved and particulate matter; volatile and non-volatile, reactive and inert; hydrophilic and hydrophobic; and dissolved gases.
For ultrapure water analysis, it is desirable to use ultrapure water as soon as possible after collection, and not to store it. Where storage is unavoidable, the sample container preferably may be buried with ultrapure water and sealed in order to eliminate contamination from the atmosphere. Since the air sealed within the sample container may be contaminated, it is desirable to remove the residual air or bubbles remained inside the sample container before the collected ultrapure water is stored or used. However, even if it is thought that the air or bubbles have been removed successfully, small amount of air or bubbles still may remain on the interior sidewall of the sample container. The conventional sample container is not able to readily remove the air or bubbles from inside the sample container after collection of the ultrapure water. The present invention addresses this issue.
The present invention pertains to a screw cap for closing a bottle or a container, which can readily remove or discharge residual air or bubbles from the inside of the bottle or the container. The improved screw cap has low profile, is cost-effective and easy to operate. The invention can be applied in the technical fields including, but not limited to, semiconductor manufacturing, water treatment, medical treatment, research and development, biotechnology, thermal power generation, nuclear power generation, or the like. The screw cap has a structure for removing bubbles inside the bottle without impairing the functionality of the sample container, and anyone can easily remove the bubbles remaining inside the container by operating the novel screw cap.
According to one embodiment, the cap body 10 may be made of high-density polyethylene or fluorine resins, but not limited thereto. According to one embodiment, the bottle 2 may be made of high-density polyethylene or fluorine resins, but not limited thereto. According to one embodiment, the cap body 10 and the bottle 2 may be made of the same material. According to one embodiment, the cap body 10 may be made of a material that is different from that of the bottle 2.
According to one embodiment, the bottle cap 1 further comprises a stopper member 13, which axially protrudes from an inner surface 11i of the cover plate 11 of the bottle cap 1 toward the mouth 210 of the bottle 2. According to one embodiment, the stopper member 13 comprises a sealing part 131, which may be mechanically supported by a support structure 132. According to one embodiment, the support structure 132 may be formed integrally with the cover plate 11.
According to one embodiment, the bottle cap 1 further comprises an annular guiding plate 14 that laterally protrudes inwardly from a sidewall surface 12s of the cylinder part 12. According to one embodiment, the annular guiding plate 14 is inclined toward the stopper member 13 to engage with the sealing part 131. When the bottle cap 1 is mounted on the bottle neck 21 of the bottle 2, the annular guiding plate 14 merely masks an annular, peripheral region of the mouth 210 of the bottle 2. According to one embodiment, the annular guiding plate 14 defines a central opening 140 to be sealed by the sealing part 131.
According to one embodiment, the sealing part 131 comprises a bottom surface 131b that can seal the central opening 140 defined by the annular guiding plate 14. According to one embodiment, the bottom surface 131b is a convex, curved surface, which facilitates the removal of air or bubbles after collection of pure liquid. According to one embodiment, the sealing part 131 further comprises a central bulge portion 131c, a peripheral bulge portion 131p surrounding the central bulge portion 131c, and an annular recessed region 131r between the central bulge portion 131c and the peripheral bulge portion 131p. The peripheral bulge portion 131p is formed integrally with the central bulge portion 131c and the central bulge portion 131c defines the bottom surface 131b.
According to some embodiments, an upper rim 14r of the annular guiding plate 14 rests against the annular recessed region 131r. In other words, the upper rim 14r of the annular guiding plate 14 is located at the annular recessed region 131r in a plan view where the bottle cap 1 is not screwed. And the bottle cap 1 may have a space between the upper rim 14r of the annular guiding plate 14 and the annular recessed region 131r, where the bottle cap 1 is not screwed. According to some embodiments, the peripheral bulge portion 131p leans against an upper portion 14a of the annular guiding plate 14. In other words, the peripheral bulge portion 131p is located while overlapping the upper portion 14a of the annular guiding plate 14 in a plan view, where the bottle cap is not screwed. And the bottle cap 1 may have a space between the peripheral bulge portion 131p and the upper portion 14a of the annular guiding plate 14, where the bottle cap 1 is not screwed.
According to one embodiment, the support structure 132 comprises a vertical portion 1321 that is formed integrally with the cover plate 11, and a horizontal portion 1322 coupled to the vertical portion 1321. According to one embodiment, the support structure 132 further comprises a resilient prop 1323 secured to the inner surface 11i of the cover plate 11. According to one embodiment, the horizontal portion 1322 is secured to a lower surface of the prop 1323. According to one embodiment, the sealing part 131 is secured to the horizontal portion 1322 and is opposite to the prop 1323.
According to one embodiment, the sealing part 131 and the prop 1323 may be composed of an elastic material including, but not limited to, low-density polyethylene. According to one embodiment, the vertical portion 1321 and the horizontal portion 1322 are composed of a material same as the cap body 10. For example, the vertical portion 1321 and the horizontal portion 1322 of the support structure 132 may be made of high-density polyethylene or fluorine resins, but not limited thereto.
Please also refer to
As illustrated in
According to one embodiment, the prop 1323 is secured to the inner surface 11i of the cover plate 11 and surrounded by the plurality of rods 1321r. According to some embodiments, the horizontal portion 1322 comprises at least one recess on its upper surface for engaging with the vertical portion 1321. For example, as illustrated in
Optionally, each of the four rods 1321r may comprise a trench or a slot 1321st provided on the surface and along a lengthwise direction of each of the four rods 1321r. As can be seen in
Referring back to
According to one embodiment, the bottle cap 1 may further comprise an annular fixing structure 15 that is formed integrally with the cap body 10. According to one embodiment, the annular fixing structure 15 may be disposed in proximity to the cylinder part 12.
Please also refer to
When the bottle cap 1 is screwed onto the bottle neck 21, the annular fixing structure 15 presses the annular guiding plate 14 to force the elastic sealing film 141 and the elastic sealing film 211 to close together such that the space between the annular guiding plate 14 and the upper end surface of the bottle neck 21 is sealed, which avoids leakage of the collected liquid from the inside of the bottle 2. The elastic sealing film 141 may only be used without the elastic sealing film 211, if leakage can be avoided effectively, for example.
In addition, the annular fixing structure 15 may comprise at least one channel 151 that facilitates the removal of the residual air from the inside of the bottle 2. For example, four channels 151 positioned at the bottom of the annular fixing structure 15 are illustrated in
Please refer to
According to one embodiment, the spiral male threaded portion 213 comprises at least one protrusion near its lower extremity to prevent the bottle cap 1 from not being closed properly or being closed too tightly due to individual differences of users. For example, a smaller protrusion 216a and a larger protrusion 216b may be provided near the lower extremity of the spiral male threaded portion 216.
Please refer to
According to one embodiment, the curved chamfer 218 provided around the upper end surface of the bottle neck 21 makes it easier to gather the bubbles in the central region AC. Further, by rounding (curving) the upper corner of the container mouth, it is possible to prevent air from staying and facilitate the outflow to the outside. According to one embodiment, the central region AC is designed to be as small as possible.
As illustrated in
It is advantageous to use the present invention because the bottle cap or screw cap has a structure for removing or discharging bubbles or residual air inside the sample bottle without impairing the functionality of the sample bottle, and anyone can easily remove the bubbles remained inside the sample bottle by operating the novel bottle cap or screw cap. By simply exerting suitable pressure on the bottle, the air bubbles can escape from the inside of the sample bottle. Additionally, the elasticity of the inner wall 311, which is lower than the outer wall 312, can reduce unnecessary force inside of the bottle 3 and relax the unnecessary force of several parts of the bottle cap 1. For instance, the several parts are the sealing part 131, the vertical portion 1321, the horizontal portion 1322, the resilient prop 1323 and the annular guiding plate 14, etc.
To sum up, the improved bottle cap has an improved structure with a function to remove air from the bottle and the cap. The structures of the bottle and the bottle cap make it difficult for air to stay and make the air or bubbles flow out easily. By closing the bottle cap, the airtightness is increased. The bottle cap can prevent the bottle from being damaged and the seal (packing) from prematurely degrading when the cap is opened. Also, it can be closed with the same tightening torque no matter who closes it. Further, the bottle cap has a structure that prevents water from accumulating inside the cap. It also has a function to prevent damage to the bottle or container due to expansion and contraction of liquid. The contamination effects that affect analysis results can be reduced and the reliability of analysis results can be improved.
Those skilled in the art will readily observe that numerous modifications and alterations of the device and method may be made while retaining the teachings of the invention. Accordingly, the above disclosure should be construed as limited only by the metes and bounds of the appended claims.
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Entry |
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Kuroki , “Influence of Impurities in Ultra-Pure Water on Ultratrace Analyses with Analytical Instruments”, The Japan Society for Analytical Chemistry; Bunseki Kagaku vol. 59,No. 2,pp. 85-93(2010), Apr. 15, 2010. |
Number | Date | Country | |
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20220063873 A1 | Mar 2022 | US |