Patent Application
20240200426
This disclosure relates to sequestering carbon dioxide in subsurface formations, particularly in negative geologic closures.
Carbon dioxide is the most commonly produced greenhouse gas. Carbon sequestration is the process of capturing and storing carbon dioxide. It is one method of reducing the amount of carbon dioxide in the atmosphere with the goal of reducing global climate change. In one approach, captured carbon dioxide is stored in underground geologic formations. The carbon dioxide can be pressurized until it becomes a liquid before being injected into porous rock formations in geologic basins.
This specification describes methods and systems for sequestering carbon dioxide in subsurface formations, particularly in negative geologic closures. After identifying a plurality of negative geologic closures in the subsurface formation, the dimensions of the plurality of negative geologic closures and the layers of subsurface formation in the vicinity the negative geologic closures are characterized. One of the negative geologic closures is selected based on the characterized dimensions and layers and an injection well is positioned in the selected negative geologic closure. After completion, the well is used to discharging a fluid comprising carbon dioxide through the injection well into the selected negative geologic closure. This approach can also include increasing the density of fluid containing carbon dioxide so that it is biased to naturally remaining in the negative geologic closure where it is discharged.
Upon injection into deep geological formations, such as depleted oil and gas fields and saline aquifers, carbon dioxide can be trapped through either physical or geochemical trapping mechanisms. Physical trapping mechanisms include static (structural and stratigraphic), hydrodynamic, and residual gas trapping. These mechanisms initially trap carbon dioxide upon injection as geochemical trapping mechanisms take considerable time to become effective. However, geochemical trapping results in more permanent and secure storage of carbon dioxide and is hence preferable to physical trapping. The two types of geochemical trapping are solubility and mineral trapping.
Solubility trapping involves carbon dioxide dissolving in the local brine and becoming trapped as an aqueous component. The aqueous carbon dioxide then reacts with water to form carbonic species. The concentration of each of the three carbonic species, H2CO3, HCO3− and CO32−, is dependent on the brine pH. H2CO3 is the primary species at low pH (˜4), HCO3− dominates at the near neutral (˜6), and CO32− species are prevalent at basic pH (˜9).
Negative geologic closures are portions of a subsurface formation where a layer which limits flow of fluids through the formation generally has a lower central region defined by higher edges. Negative geologic closures tend to collect fluids that have a higher density (e.g., brine) than other fluids (e.g., fresh water) in the formation. In contrast, positive geologic closures are portions of a subsurface formation where a layer which limits flow of fluids through the formation generally has a higher central region defined by lower edges. Positive geologic closures tend to collect fluids that have a lower density (e.g., oil and gas) than other fluids (e.g., water) in the formation.
In one aspect, methods of storing carbon dioxide in a subsurface formation include: identifying a plurality of negative geologic closures in the subsurface formation; characterizing dimensions of the plurality of negative geologic closures; characterizing layers of subsurface formation in the vicinity the negative geologic closures; selecting one of the negative geologic closures based on the characterized dimensions and layers; positioning an injection well in the selected negative geologic closure; and discharging a fluid comprising carbon dioxide through the injection well into the selected negative geologic closure. Embodiments of these methods can include one or more of the following features.
In some embodiments, the negative geologic closure includes multiple layers of the subsurface formation. In some cases, positioning the injection well in the selected negative geologic closure comprises positioning the injection well at the bottom layer of the negative geologic closure. Some methods also include repositioning the injection well in a higher layer after carbon dioxide saturation pressure is reached in a current layer.
In some embodiments, discharging the fluid comprising carbon dioxide comprises discharging a carbon dioxide—water mixture. In some cases, discharging the carbon dioxide—water mixture comprises discharging a carbon dioxide—brine mixture.
In some embodiments, discharging the fluid comprising carbon dioxide comprises discharging liquid carbon dioxide.
In some embodiments, discharging the fluid comprising carbon dioxide comprises injecting carbon dioxide at a pressure between 14.5 and 35,000 psi.
In some embodiments, identifying the plurality of negative geologic closures in the subsurface formation comprises identifying the plurality of negative geologic closures in the subsurface formation based at least in part on seismic data. In some cases, methods also include acquiring a seismic survey.
In some embodiments, selecting one of the negative geologic closures comprises selecting a negative geologic closure with a temperature between 50 and 75° C.
In some embodiments, selecting one of the negative geologic closures comprises selecting a negative geologic closure where formation pressure is between 2,000 and 10,000 psi. In some cases, selecting one of the negative geologic closures comprises selecting a negative geologic closure with a porosity of between 5 and 25% in the storage formations. In some cases, selecting one of the negative geologic closures comprises selecting a negative geologic closure with a permeability between 5-50 millidarcy in the storage formations.
Currently carbon capture and sequestration typically begins with removing carbon dioxide from a flue gas through pre-, post- or oxyfuel-combustion. Once the carbon dioxide has been captured it needs to be stored in a safe and permanent manner. Although carbon dioxide storage within depleted oil and gas fields or deep saline aquifers takes advantage of their large storage capacities and existing infrastructure, the need for long term carbon storage is anticipated to eventually exceed the storage provided by these resources. In addition, the reservoirs associated with conventional oil and gas traps formed by positive closures can also be used for carbon dioxide sequestration as the oil and gas are depleted (e.g., through enhanced oil or gas recovery operations).
The methods and systems described in this specification focus on negative geological closures. However, the exact placement of carbon dioxide or carbon dioxide-concentrated fluids in these structures is important to utilize their full storage potential.
This approach can provide one or more of the following advantages. This approach eliminates potential wellbore stability issues and associated carbon dioxide leakage from existing wells in and above the reservoir by using geologic structures from which oil and gas is typically not produced. By employing in-situ injection rather than discharging carbon dioxide at the top of a reservoir and allowing it to migrate downward, this approach decreases the migration distance for carbon dioxide from the injection site to its final repository. By utilizing negative geologic closures to hold densified carbon dioxide fluids, this approach avoids potential cap rocks or seal integrity issues that can occur due to buoyancy pressures that can occur with less dense fluids. By using closed container-type geometries in negative geologic closures, this approach can provide long-term trapping of carbon dioxide within salt-rich water allowing sufficient time for carbon mineralization in the formation.
In existing carbon dioxide sequestration projects (which generally involve positive closures), injection is typically performed near the top or somewhere in the middle of the reservoir. Since carbon dioxide is still buoyant under these circumstances, the gas tends to migrate upwards, where it gets trapped at the reservoir-seal interface and forms a plume (Arts et al., 2004). This approach may result in incomplete filling of the reservoir, as the detailed migration pathway and connectivity among reservoir interlayers are difficult to predict ahead of time. In contrast, the approach described in this specification uses a more controlled injection method in which the available storage space is systematically filled from the bottom up.
The details of one or more embodiments of the invention are set forth in the accompanying drawings and the description below. Other features, objects, and advantages of the invention will be apparent from the description and drawings, and from the claims.
Like reference symbols in the various drawings indicate like elements.
This specification describes methods and systems for sequestering carbon dioxide in subsurface formations, particularly in negative geologic closures. After identifying a plurality of negative geologic closures in the subsurface formation, the dimensions of the plurality of negative geologic closures and the layers of subsurface formation in the vicinity the negative geologic closures are characterized. One of the negative geologic closures is selected based on the characterized dimensions and layers and an injection well is positioned in the selected negative geologic closure. After completion, the well is used to discharging a fluid comprising carbon dioxide through the injection well into the selected negative geologic closure. This approach can also include increasing the density of fluid containing carbon dioxide so that it is biased to naturally remaining in the negative geologic closure where it is discharged.
Oil and gas tend to rise through permeable reservoir rock until further upward migration is blocked, for example, by the layer of impermeable cap rock 102. Seismic surveys are typically performed to attempt to identify locations where interaction between layers of the subsurface formation 100 are likely to trap oil and gas by limiting this upward migration (e.g., the anticline trap 107, where the layer of impermeable cap rock 102 has an upward convex configuration. However, the data from seismic surveys and other exploration activities can be used to identify potential negative geologic closures (e.g., negative geologic closure 109) and then, if necessary, more detailed investigations can be performed that focus on the potential negative geologic closures.
Seismic surveys use a seismic source 112 (for example, a seismic vibrator or an explosion, or an array of air guns in offshore settings) generates seismic waves that propagate in the earth. Although illustrated as a single component in
The velocity of these seismic waves depends properties, for example, density, porosity, and fluid content of the medium through which the seismic waves are traveling. Different geologic bodies or layers in the earth are distinguishable because the layers have different properties and, thus, different characteristic seismic velocities. For example, in the subsurface formation 100, the velocity of seismic waves traveling through the subsurface formation 100 will be different in the sandstone layer 104, the intermediate impermeable layer 106, and the sand layer 108. As the seismic body waves 114 contact interfaces between geologic bodies or layers that have different velocities, each interface reflects some of the energy of the seismic wave and refracts some of the energy of the seismic wave.
The seismic body waves 114 are received by a sensor or sensors 116. Although illustrated as a single component in
The seismic surface waves 115 travel more slowly than seismic body waves 114. Analysis of the time it takes seismic surface waves 115 to travel from source to sensor can provide information about near surface features.
A control center 122 can be operatively coupled to the seismic control truck 120 and other data acquisition and wellsite systems. The control center 122 may have computer facilities for receiving, storing, processing, and analyzing data from the seismic control truck 120 and other data acquisition and wellsite systems that provide additional information about the subsurface formation. For example, the control center 122 can receive data from a computer 119 associated with a well logging unit 121. The well logging unit 121 can be used to obtain detailed information about the different layers of the subsurface formation at specific locations.
Densified carbon dioxide brine is generated through dissolution of carbon dioxide in water, mixing of formation water with highly saline water, and/or mixing water with other available densifying additives, for example as gels and fines. The carbon dioxide dissolution results in a 2-3% density increase of brines, which is sufficient to trigger negative buoyancy and hence sinking (Tang et al, 2017). Densifying additives may include barite, hematite, calcium carbonate, siderite, gels, fines, or combinations thereof. Specific proportions of densifying additives are variable because they are subject to the starting ranges.
Although the wellbore 178 is illustrated as being raised through the subsurface formation 179, the wellbore and casing will typically remain in place with packers being used to isolate lower portions of the wellbore and new perforations being formed at the depth of desired injection. This approach of bottom-up carbon dioxide storage uses the full potential of space available in the negative closure 176 for carbon dioxide storage.
Typical ranges of parameters found in negative closures include: size of 10s to 100s of kilometers; thickness of 10s to 100s of meters; porosity between 3 and 26%; permeability of 0 to 110 mD; and temperature of 20 to 375° C. (assuming an average geothermal gradient of 25° C./km and considering depths from 0.8 to 15 km). These are typical ranges occurring in nature. Exact combinations of parameters are site-specific and subject to characterization. Any combinations of these ranges are expected to work. A few selected examples of naturally occurring negative geologic structures and their dimensions are listed in Table 1.
The identified negative geologic closures are then assessed for potential use in carbon dioxide storage with the dimensions and characteristics of these closures documented. The dimensions of the plurality of negative geologic closures are characterized (step 212), for example, with respect to depth, length, and number of layers. Similarly, the layers themselves are characterized (step 214), for example, with respect to porosity, permeability, temperature, pressure, and chemical composition of trapped fluids and formation). Both the layers of the identified negative closure and other nearby portions of the subsurface formation are typically characterized. Parameters including length, depth, and porosity can be used estimate potential storage volume of the identified negative closures. Parameters including temperature, pressure, and chemical composition of trapped fluids and formation can be used to assess the extent and timing of mineralization of the carbon dioxide.
After the potential negative closures are assessed, one or more of them are selected based on the characterized layers (step 216). Selecting a negative geologic closure with a temperature between 50 and 75° C. and where surrounding formation is between 2,000 and 10,000 psi because higher pressure enhances the CO2 solubility in formation water. Selecting a negative geologic closure with a porosity of between 5 and 25% can provide adequate storage volume. Higher porosity provides high storage volume. Selecting a negative geologic closure with a permeability between 5-50 millidarcy can adequate fluid flow to allow the filling-up accessible pore volumes with carbon dioxide-rich brine in the storage zones.
One or more injection wells are then positioned in the selected formation(s) (step 218). Positioning the well(s) will typically include drilling the well(s) to the bottom layer of the selected negative closure before casing the well and perforating the casing in the bottom layer. When there are multiple layers, the well can be repositioned in a higher layer after carbon dioxide saturation pressure is reached in a current layer. The saturation can be monitored, for example, by time lapse seismic surveying. To begin filling the next higher layer, the portion of the well below the new layer can be filled with cement or isolated using packers before the casing is perforated in the new layer.
After the well is installed, a fluid including carbon dioxide is discharged through the injection well into the selected negative geologic closure (step 220). The fluid can be a carbon dioxide—water mixture, dissolved carbon dioxide in water (e.g., sea water, high salinity water, brines, or combination of these), liquid carbon dioxide or a supercritical phase. The pressures used can range from 14.5 to 35,000 psi (e.g., 100 to 25,000 psi or 500-10,000 psi).
After injection, pressure in the well is allowed to drop to facilitate the permeation of carbon dioxide into and storage of carbon dioxide in the bottom negative closure.
Theoretical studies of carbon dioxide injection into geologic formations predict that, due to its lower density and immiscibility, carbon dioxide will initially float to the top of the reservoir. After a period of time, carbon dioxide dissolves into the brine, thus increasing the brine density causing the brine to descend under gravity (Pau et al., 2010, Weir et al., 1995). Upward filling of a geologic formation with buoyant carbon dioxide has been confirmed at the Sleipner carbon dioxide storage site in the North Sea, a pilot project which began in 1996 (Arts et al., 2004, Eiken et al., 2011).
Comparing these results with
A number of embodiments of these methods and systems have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of these methods and systems. Accordingly, other embodiments are within the scope of the following claims.
