Brake unit having a nonmetallic brake disc of ceramic and a hub of a different material

Abstract
The invention relates to a brake unit (1) having a brake disc (2) of ceramic and a hub (10, 10′) of a different material, which radially overlap one another with their mutually facing rims and are mechanically joined by a wreath-type rim of mounting bolts (15) that axially penetrate the overlapping rims. Provision is made according to the present invention for the mounting bolts (15) to be uniformly included in the transmission of torque. For this, entrainment bores (5, 5′) or entrainment slots provided in the brake disc (2) are plastically lined according to the present invention with a metal or plastic sleeve (20), or the disc material is formed specifically to certain areas in this region (34) as a plastically deformable C/C structure. The invention relates furthermore to a method for manufacturing a partially ceramized molded article, in particular a brake disc (2) having a C/C structure in the area of the entrainment bores (5, 5′) or entrainment slots. The method of the present invention is based on the fact that a boron doping can effectively prevent the C/C structure from being ceramized as the result of liquid siliconization. The invention relates furthermore to a completely non-metallic brake unit (40, 50) and to a method for its manufacture.
Description


[0001] The invention is directed to a brake unit having a nonmetallic brake disc of ceramic and a hub of metal according to the definition of the species in claim 1, as well as to a method for manufacturing brake units of this kind according to the definition of the species in claim 14. The invention is directed more particularly to a brake unit having a nonmetallic brake disc of fiber-reinforced ceramic and a hub of the same fiber matrix according to the definition of the species in claim 20, and to a method for manufacturing a brake unit of this kind according to the definition of the species in claim 21.


[0002] A brake unit of the species and a manufacturing method of the species are known, for example, from German 44 38 455 Cl and from German 44 38 456 Al. German 44 38 456 Al also describes a frictional unit, a frictional body, and a core body, the core body being able to have an extension prolongation with connection orifices in the manner of a nonmetallic hub. The frictional body is made of a C-C/SiC material, while the core body is constituted of a carbon fiber-reinforced carbon. The core body and the frictional body are joined by an interconnection layer essentially containing silicon carbide.


[0003] Brake units are also known, whose brake discs are constituted of carbon over their entire cross-section. Special measures are required in this case to adapt a toroidally shaped disc of this kind to the wheel hub. For this, provision has been made in known methods heretofore for a hat- or pot-shaped metal hub. This hub is mechanically coupled by its free rim to the brake disc. This mechanical coupling is achieved using a wreath-type rim of mounting bolts and corresponding entrainment bores or radial slots in the area of the inner rim or the inside of the brake disc, which produce a mechanically loadable form-locking between the brake disc and metal hub. Provision is usually made for six or eight mounting bolts. What is problematic here is the enormous difference between the expansion coefficient specific to the brake disc (about 3-5×10−6/K) and that specific to the metal hub (about 15-20×10−6/K). For that reason, one has to prevent the parts from sticking, as can occur due to the tension produced by this type of attachment. Rather, radial expansion must still be allowed between the two parts, in spite of the mechanical coupling. Therefore, a suitable play is intentionally permitted between the entrainment bores and the bolt in the radial direction, whereas a precise as possible fit with the bolt diameter is aspired to in the circumferential direction.


[0004] The predefined, hub-side position of the bolts, on the one hand, and the disc-side position of the entrainment bores, on the other hand, must, therefore, conform as precisely as possible. However, in spite of all efforts to achieve manufacturing precision, mathematical agreement can not be achieved with any kind of realistic cost outlay. Rather, in practice, one has to be prepared for the fact that it will never be possible to entirely avoid positional tolerances with respect to the bolts, on one hand, and the entrainment bores, on the other hand. As a result, merely two, at the most three, of all the provided bolts are load-bearing in response to mechanical stressing of the brake, whereas a play exists between the remaining bolts and the entrainment bores, preventing these bolts from bearing load.


[0005] Only after a plastic or wear-related deformation has taken place in the area of the bearing bolts, is it possible for the play existing in the area of the other bolts to be reduced, enabling these bolts to be load-bearing as well. When working with carbon discs, sufficient plasticity is given in the area of the entrainment bores, depending on the material used, so that in this case, at the latest following the first extreme mechanical stressing of the brakes, the initially sole three bearing bolts have pressed into the inside face of the corresponding entrainment bores, plastically deforming these bores, eliminating the play between the remaining bolts and their entrainment bores, thus rendering them load-bearing as well.


[0006] It is a different situation, however, when it comes to the rigid ceramic discs of the species. In this case, as far as the known and just described mechanical coupling between the brake disc and the metal hub is concerned, play may be eliminated for the nonbearing bolts, at most due to wear, or because of a plastic deformation of the bearing bolts; but this can take a very long time. A way to get around this, as described in the German 44 38 456 Al, is to revert to a nonmetallic hub, which would clearly lessen the differences with respect to the expansion coefficients. What is problematic, however, is securing the hub to the brake disc, due to the high mechanical and thermal stressing experienced during braking maneuvers.


[0007] The object of the invention, when working with the conditions of a rigid ceramic brake disc, is to improve the basic brake unit of the species in such a way that, when a hub of metal is used, in spite of an inflexible ceramic disc, all of the bolts provided will be able to participate virtually uniformly in the transmission of the braking torque occurring at the brake disc, even without the bolts experiencing any plastic or wear-induced deformations. It is, moreover, the object of the invention to delineate an additional method for attaching a nonmetallic hub, as well as to present a method for manufacturing brake units of this kind.


[0008] The object is achieved by a brake unit having the features of claim 1 or 20, and by a method having the features of claim 14 or 21.


[0009] Therefore, in the case of a brake unit of the present invention having a metal hub, it is the region of the brake disc that represents the inside face of the entrainment bore that is designed to be plastically deformable. This can be achieved, on the one hand, with the aid of a plastically deformable sleeve, or by using a plastic form of the normally rigid ceramic material. The effect of the plastic deformability is to compensate for the mentioned positional deviation of the bolts, on the one hand, and of the entrainment bore, on the other hand, in that the sleeve undergoes a deformation in response to mechanical stress, so that all bolts are load-bearing and undesired play no longer occurs.


[0010] Provision is made in the case of a brake unit of the present invention having a nonmetallic hub for the hub to be molded into an inner region of the ceramic brake disc and doped with boron.


[0011] Advantageous further refinements are revealed in the dependent claims. A soft metal sleeve can be used as a plastically deformable lining for the inside bore face. Sleeves of copper or aluminum, for example, are suitable. Instead of a metal sleeve, a sleeve of carbon fiber-reinforced plastic (CFK material) or carbon fiber-reinforced carbon (C/C material) can also be used. A nonmetallic CFK or C/C material of this kind is sufficiently plastically deformable. The sleeve is preferably slotted at one peripheral location over the entire length and fits with mechanical prestressing on the inside face of the bore or of the slot. The longitudinal slot makes the sleeve radially elastic, so that even under conditions of considerable temperature variations, accompanied by noticeable expansion or contraction, it fits with prestressing on the inner bore face.


[0012] The wall thickness of the sleeve is a function of the size of the brake disc or of the diameter of the bores. As a rule of thumb, one can assume that the wall thickness is {fraction (1/20)} of the bore diameter. In the case of motor vehicle brake discs having a bore diameter of, for example, 15 mm, the wall thickness is about 0.75 mm; in the case of railroad brake units having a bore diameter of, for example, 200 mm, the wall thickness is about 10 mm.


[0013] It is a feature of a further embodiment of the present invention that the area immediately along the inner face of the entrainment bores or of the entrainment slots contains boron and/or boron-containing compounds and/or boron-releasing compounds in a locally limited fashion, and is constituted in this area here of a non-ceramic C/C material, while the ceramic brake disc is constituted of C/C-SiC material. This embodiment is based on the realization that boron or boron-containing or boron-releasing compounds effectively prevent silicon carbide formation and ceramization during liquid siliconization. If the porous C/C preform, which is intended to undergo the liquid siliconization, is doped in certain regions with boron and/or boron compounds, then no ceramization takes place in this region. There is no “sleeve” as a separate structural element in this embodiment.


[0014] The same result is also achieved, however, when the entrainment bores or the entrainment slots are lined with a sleeve of carbon fiber-reinforced carbon, which contains boron and/or boron-containing compounds and/or boron-releasing compounds. At its periphery, the sleeve makes the transition to silicon carbide and thus forms a direct bond with the C/C-SiC brake disc.


[0015] In both cases, the bore obtained has an inner face of C/C material, which gradually changes over to ceramic. Depending on the size of the brake disc or of the diameter of the entrainment bores or the entrainment slots, the radial layer thickness of this C/C material structure is preferably about {fraction (1/20)} of the bore diameter, in the case of motor vehicle brake discs, for example, from about 0.7 to 2.0 mm, in particular about 1.0 mm. Within these ranges, the boron and/or the boron-containing compounds are present in a concentration of from 5 to 35% by weight. Besides boron itself, suitable compounds are boron carbide, boron nitride, boron tetrachloride and/or borides, in particular zirconium diboride, hafnium diboride, silicon tetraboride and/or titanium diboride, as well as boron-containing polymers, in particular polyborosilazanes.


[0016] In principle, there are two different ways to couple the hub to the brake disc. On the one hand, one can configure the entrainment bores or the entrainment slots in the area of the inner rim of the brake disc, and provide the hub with an outwardly projecting, flangetype rim that joins it to the inner rim of the brake disc. The coupling can also be achieved by configuring the entrainment bores in the inside area of the brake disc, and by joining the hub by its free end to the inner side of the brake disc.


[0017] A brake unit of the present invention that includes a ceramic brake disc and a nonmetallic hub is distinguished by a brake disc of fiber-reinforced ceramic, preferably a C/C-SiC brake disc and a hub of the same fiber matrix, preferably a C/C hub. The hub is doped with boron and molded over an outwardly-projecting, flange-type rim into the inner side of the brake disc. Thus, the hub is made of a material which is not as damage-prone as the ceramic material of the brake disc, is less brittle, and easier to machine. The material permits greater expansion. On the other hand, a rigid hub is restricted in its use. Thus, the present invention provides for the hub to be integrally formed in the brake disc. An attachment of this kind provides for a high load-bearing capacity, e.g., when it comes to braking maneuvers, since there is no longer a “rupture joint”, as is the case with the known interconnection layer.


[0018] The method of the present invention for producing molded articles from fiber-reinforced C/C-SiC composite ceramic is distinguished in that preforms are fabricated, which are doped with boron and/or with the mentioned boron compounds in those regions that are not designated for ceramization. The preforms can either be green compacts (thus preforms of CFK material) or the C/C bodies that result from pyrolysis of the green compacts.


[0019] Alternatively, one can also fabricate green compacts, which correspond to the particular intended partial areas, as separate preforms. The green compacts corresponding to the partial areas not designated for ceramization, or the C/C members resulting from pyrolysis thereof, are doped using boron and/or the mentioned boron compounds and are joined, at the latest prior to the siliconization, to form the desired molded articles.


[0020] The advantage of the first alternative is that doping the bore regions eliminates the need for the entrainment bores to be drilled prior to the liquid siliconization. Rather, the brake disc can be mechanically machined in a uniform fashion, with respect to the entrainment bores as well, subsequent to the ceramization.


[0021] The second alternative of the method of the present invention provides for the entrainment bores to be drilled, at the latest, before the liquid siliconization takes place. Boron-doped sleeves or solid bodies are then inserted into the bore. One derives the benefit in this case of being able to easily control the infiltration depth and boron doping.


[0022] The initial products are either green compacts (i.e., CFK bodies) or already pyrolyzed, non-ceramic C/C bodies, in any desired combination. Thus, CFK brake discs can be combined with CFK- or C/C-sleeves or solid bodies. One can also combine C/C brake discs with CFK- or C/C-sleeves or solid bodies. The sleeves or solid bodies can be doped both in the CFK phase as well as in the C/C phase.


[0023] During the liquid siliconization, only a small portion of the silicon penetrates into the rim area of the now pyrolyzed sleeve or of the solid body and thus leads to a direct bonding between the sleeve or solid body and brake disc. Due to the boron doping, the doped sleeve or the doped solid body is not siliconized, but rather remains as a non-ceramic C/C workpiece. If a solid body is used, it needs only to be subsequently provided with a bore. A solid body or a bolt is more easily fabricated than a sleeve, and is less sensitive to handling. One benefit of the method of the present invention is that partial areas of a molded article can be targeted for ceramization. The boron-doped partial areas remain as non-ceramic areas, and are able to be more easily reworked. They permit a greater expansion than the ceramized partial areas, are not damage-prone, and are less brittle.


[0024] The method of the present invention is, therefore, suited for manufacturing one-piece brake units of a brake disc and of a non-metallic hub when the brake disc is a C/C-SiC brake disc and the hub is a C/C hub. In this case, the brake disc and the hub are manufactured separately, for example, as green compacts, with the green compact to be machined into the hub being doped with boron. The two parts are then joined, pyrolyzed, and ceramized, i.e., siliconized. The hub escapes the ceramization process because of the boron doping and, thus, remains moldable as a C/C component, while the brake disc is ceramized, the silicon penetrating into the rim area of the hub and, in this manner, ensuring a direct bonding. The green compacts are preferably joined by premolding the brake disc directly on the flange-type rim of the hub.


[0025] Another possible method for manufacturing nonmetallic brake units provides for two preforms for the brake disc. This is particularly advantageous when working with ventilated brake discs which have two disc halves interconnected by crosspiece segments. The two disc halves and the hub are fabricated separately as green compacts and pyrolyzed into C/C molded articles. The two brake disc halves are then joined along a flange-type rim of the hub, and the resulting brake unit is siliconized. Since the hub is doped with boron, it is not ceramized. A small portion of the silicon penetrates, however, into the rim area of the hub and ensures direct bonding.


[0026] The boron doping can be undertaken using a plurality of methods. On the one hand, boron and/or the mentioned boron compounds can be worked into the green compact as fillers. On the other hand, the porous C/C molded articles can be partially saturated with boron and/or boron compounds, or coated along the pore walls. The boron or the boron compounds can be introduced out of the liquid phase or out of the gas phase under high pressure.






[0027] Exemplary embodiments of the present invention are described in greater detail in the following on the basis of the attached drawing, whose Figures show:


[0028]
FIG. 1 a first exemplary embodiment of a brake unit of the present invention including a nonmetallic brake disc and a metal hub;


[0029]
FIG. 2 another exemplary embodiment of a brake unit of the present invention including a nonmetallic brake disc and a metallic hub;


[0030]
FIG. 3 a longitudinal section through a entrainment bore in the brake disc shown in FIGS. 1 and 2, including a metal sleeve;


[0031]
FIGS. 4

a
-c schematic representations of developments of metal sleeves of the present invention, including various peripheral slots;


[0032]
FIGS. 5

a
-c schematic representations of individual method steps of the method of the present invention for manufacturing a bore lined with C/C material;


[0033]
FIGS. 6

a
-b schematic sectional views of a brake unit of the present invention including a C/C hub and a C/C-SiC brake disc prior (FIG. 6a) and subsequent to (FIG. 6b) the liquid siliconization;


[0034]
FIG. 7 a schematic sectional view of a brake unit of the present invention including a C/C hub and a C/C-SiC brake disc subsequent to the liquid siliconization;






[0035]
FIG. 1 illustrates a first exemplary embodiment of a brake unit 1 including a nonmetallic brake disc 2 and a metal hub 10. Brake disc 2 is ring-shaped and has a center opening. Metal hub 10 is hat-shaped and has a cylindrical area 11, which extends through the center opening of brake disc 2. Joined to free end 12 of this cylindrical area is an outwardly projecting, flange-type rim 13, which is provided with bores 14. Mounting bolts 15 extend through bores 14 and through corresponding bores 5 or radial slots (not visible here) in the area of inner rim 3 of brake disc 2.


[0036] FIGS. 2 illustrates another exemplary embodiment of a brake unit 1′ of the present invention, including a metal hub 10′. In this instance, it is a so-called “floating” mounting attachment. Here, cylindrical area 11′ of hub 10′ does not have any flange. Provision is made, instead, for a number of bores 14′ on its free end 12′. Mounting bolts 15 extend through these bores 14′ and through corresponding bores 5′ (not visible here), which in this case are provided on inner circumference 4 of brake disc 2.


[0037] The present invention provides for bores 5, 5′ to be plastically lined on inner circumference 4 or on inner rim 3 of brake disc 2. FIG. 3 shows a schematic section, not true-to-scale, through such a bore 5, which is lined with a metal sleeve 20. Metal sleeve 20 is made of copper having a wall thickness of about 1 mm. It is, as is evident from FIGS. 4a-c provided with a slot that runs overs its entire surface height. The slot can have a screw-thread configuration (slot 21 in FIG. 4a); however, it can also run exactly perpendicularly to the surface (slot 22 in FIG. 4b); it is likewise possible that it follows a zigzag path (slot 23 in FIG. 4c).


[0038] The sleeve shown in FIG. 3 can also be fabricated from a CFK or a C/C material. These materials exhibit greater expansion than ceramic. They are not damage-prone and are easier to machine. Corresponding slots 21, 22, 23 can likewise be applied.


[0039] When working with brake discs of C/C-SiC material, provision is made according to the present invention for the area directly adjacent to bores 5, 5′ to be able to be doped with boron or boron-containing or boron-releasing compounds. The method for producing C/C-SiC molded articles is generally known. Carbon fibers, fillers and pyrolyzable, liquid binding agents are homogenized and compressed into a green compact of CFK material, the binding agent hardening in the process. The green compact is pyrolyzed into a porous C/C molded article, the binding agent being converted into carbon. The C/C molded article is saturated with liquid silicon and ceramized under a vacuum, at high temperatures, the carbon being completely or partially converted into silicon carbide.


[0040] The green compact or the porous foreign body obtained following pyrolysis is brought into contact with the mentioned boron-containing substances, in those regions where the intention is to place bores 5, 5′. This is achieved, for example, by saturating the drilling areas with boron-containing substances and with solutions thereof. It is likewise possible that the boron-containing substances be deposited out of the gas phase under high pressure, in a spot-type application. Thus, the pores of the C/C body can be coated, for example. In this context, one can also employ known CVD processes, e.g., to deposit BN3 out of a mixture of BCl3/NH3/H2 at 1000-1400° C. or ZrB2 out of a mixture of ZrCl4/BCl3/H2 at 1000-1500° C.


[0041] Following the ceramization, these regions remain as uninfiltrated, porous C/C bodies, since the boron doping effectively prevents a ceramization. The undoped regions, however, are infiltrated with silicon and ceramized, SiC being partially or predominantly formed. Bores 5, 5′ are subsequently placed in these regions, since they—unlike the ceramized regions—are easier to machine. In this context, bores 5, 5′ have a smaller diameter than the doped regions, so that a rim area, which takes on the sleeve function, remains as a non-ceramized C/C region.


[0042]
FIGS. 5

a
through c schematically depict how, in accordance with another variant of the method of the present invention, one can produce a region that does not ceramize during liquid siliconization, in the area of bore 5, 5′ of brake disc 2. The intention in the exemplary embodiment is to produce a bore (5) having a diameter (a) and a lining having wall thickness (c) (compare FIG. 5c). Following fabrication of the green compact or subsequent to pyrolysis, region (c)-(a)-(c) can be doped, as mentioned, with boron or boron compounds. Following siliconization and ceramization, region (a) is then bored, because it has retained its C/C structure and is easier to machine.


[0043] Provision is preferably made, however, for a bore 31 having diameter (b) to be inserted into a preform 30 before (or after) pyrolysis. Diameter (b) of bore 31 is larger than diameter (a) of the later resulting entrainment bore 5. As proceeds from FIG. 5a, diameter (b) also includes thickness (c) for the later sleeve, as well as a narrow region (d) for the direct bonding effected by the siliconization. In this exemplary embodiment, preform (30) is a green compact; however, it can also be a C/C body.


[0044] A solid body 32, which is doped with boron or boron compounds, is inserted as a green compact into bore 31. The boron or the boron compounds are added as filler during fabrication of green compact (32) in concentrations of 5-35% by weight. The volumetric fiber component is about 30-60% by volume, preferably about 40% by volume. The mass ratio of graphite filler to boron compounds is 1:1 or less, the graphite being replaced by fibers.


[0045] After placement of solid body 32, if indicated, preform 30 undergoes pyrolysis and liquid siliconization. The result is shown schematically in FIG. 5b. At this point, brake disc 2 is ceramized, the silicon also having penetrated into a narrow wall area 33 of full body 32, and thus leading to a direct bonding between solid body 32 and brake disc 2. Solid body 32 itself has a C/C structure; it is pyrolyzed, but not ceramized.


[0046] Solid body 32 is now provided with bore 5 having diameter (a). In the process, a rim region 34 of solid body 32 remains, since it had been selected to be larger than bore 5.


[0047] This rim region 34 of solid body 32 now constitutes the lining or sleeve of bore 5 of brake disc 2.


[0048] In similar fashion, brake units 40, including a brake disc (41) and a nonmetallic hub (43), are also able to be manufactured when the intention is for brake disc (41) to be constituted of a C/C-SiC material and hub (43) of a C/C material (FIGS. 6a, 6b). For this, two green compacts are fabricated; namely brake-disc preform (41′) and hub preform (43′), which likewise has a cylindrical region 44′ and, on its free end 45′, a flange-type rim 46′ (compare FIG. 6a).


[0049] According to one preferred method, hub preform (43′) is first fabricated. Brake-disc preform (41′) is subsequently pressed around its rim 46′. In this manner, rim 46′ is molded into inner region 42′ of the brake disc. Hub preform 43′ is doped with boron in the described manner. The entire brake unit 40 then undergoes pyrolysis and liquid siliconization.


[0050] The result is schematically shown in FIG. 6b. Brake disc 41 is siliconized and ceramized. The silicon has penetrated into a narrow region 47 of rim 46 of hub 43, ensuring a secure, direct bonding between hub 43 and brake disc 41. Hub 43 itself is molded into inner region 42 of brake disc 41. It is not ceramized, but is constituted of a non-ceramic, C/C material, which can easily be reworked, e.g., provided with bores 48.


[0051]
FIG. 7 depicts a brake unit 50 having ventilated brake discs 51. Brake discs 51 are constituted by two interconnected preforms 52, 53, joined by crosspiece segments 54. In this case, the preforms for the brake disc halves and hub 43 are initially fabricated and pyrolyzed, the hub preform being doped with boron. Both preforms for the brake disc halves are subsequently joined above and below rim 46 of hub 43. The entire brake unit is then ceramized using liquid siliconization, the brake disc halves being permanently joined together along their crosspiece segments 54 by direct bonding. Hub 43 is not ceramized. However, silicon presses into rim 47 of hub 43 and thus ensures a permanent, direct bonding between hub 43 and brake disc 51.

Claims
  • 1. A brake unit (1) having a nonmetallic brake disc (2) of ceramic and a metallic hub (10, 10′), which radially overlap one another with their mutually facing rims and are mechanically joined by a wreath-type rim of mounting bolts (15) that axially penetrate the overlapping rims, in the area of its inner rim (3), the brake disc (2) having corresponding entrainment bores (5, 5′) or radial entrainment slots to receive the mounting bolts (15), wherein the entrainment bores (5, 5′) or entrainment slots are lined with a sleeve (20) of plastically deformable material, or the disc material is conceived to be plastically deformable to specific areas in this region.
  • 2. The brake unit as recited in claim 1, wherein the entrainment bores (5, 5′) or entrainment slots are lined with a soft metal sleeve (20), in particular a copper or aluminum sleeve.
  • 3. The brake unit as recited in claim 1, wherein the entrainment bores (5, 5′) or entrainment slots are lined with a sleeve of carbon fiber-reinforced plastic (CFK) or with carbon fiber-reinforced carbon (C/C).
  • 4. The brake unit as recited in claim 2 or 3, wherein the sleeve (20) is slotted at one peripheral location over the entire length and fits with mechanical prestressing on the inside face of the entrainment bore (5,5′) or of the entrainment slot.
  • 5. The brake unit as recited in claim 4, wherein the slot (21, 22, 23) runs along a surface line, a screw-thread line, or a zigzag line.
  • 6. The brake unit as recited in one of claims 2 through 5, wherein the sleeve (20) has a wall thickness of about {fraction (1/20)} of the diameter of the entrainment bore (5, 5′) or of the entrainment slot.
  • 7. The brake unit as recited in claim 1, wherein in constructing the brake disc (2) as a ceramic C/C-SiC brake disc, the area directly adjacent to the entrainment bores (5, 5′) or the entrainment slots contains boron and/or boron-containing compounds and/or boron-releasing compounds in a locally limited fashion, and is constituted in this area here of a non-ceramic C/C material.
  • 8. The brake unit as recited in claim 1, wherein in constructing the brake disc (2) as a ceramic C/C-SiC brake disc, the entrainment bores (5, 5′) or the entrainment slots are lined with a sleeve (34) of carbon fiber-reinforced carbon, which contains boron and/or boron-containing compounds and/or boron-releasing compounds and, at its periphery, the sleeve makes the transition to silicon carbide and thus forms a direct bond with the brake disc (2).
  • 9. The brake unit as recited in one of claims 7 or 8, wherein as boron-containing or boron-releasing compounds, provision is made for boron carbide, boron nitride, boron tetrachloride and/or borides, in particular ZrB2, HfB2, SiB4 and/or TiB2, as well as boron-containing polymers, in particular polyborosilazanes.
  • 10. The brake unit as recited in one of claims 7 through 9, wherein the boron and/or the boron-containing or the boron-releasing compounds are present in a concentration of from 5 to 35% by weight.
  • 11. The brake unit as recited in one of claims 7 through 10, wherein provision is made for the C/C material area or the sleeve (34) to have a radial layer thickness of about {fraction (1/20)} of the bore diameter.
  • 12. The brake unit as recited in one of the preceding claims, wherein the entrainment bores (5) or the entrainment slots are configured in the area of the inner rim (3) of the brake disc (2), and the hub (10, 10′) has an outwardly projecting, flange-type rim (12) that joins it to the inner rim (13) of the brake disc (2).
  • 13. The brake unit as recited in one of claims 1 through 11, wherein the entrainment bores (5′) are configured in the area of the inner side (4) of the brake disc (2), and the metal hub (10′) is joined by its free end (12′) to the inner side (4) of the brake disc (2).
  • 14. A method for manufacturing brake units as recited in claim 1, 7, or 8, wherein fibers, fiber bundles or felt pads of carbon, binding agents, and fillers are homogenized, compression-molded, and hardened; the resulting green compact (CFK molded article) is subsequently pyrolyzed; the porous C/C molded article formed in the process is infiltrated with liquid silicon and ceramized; wherein, to manufacture only partially ceramized molded articles (40, 50): wherein, to manufacture only partially ceramized brake discs: 1. the green compact or the porous molded article is doped, in those regions not designated for ceramization, with boron and/or boron-releasing compounds and/or boron-containing compounds; or 2. green compacts corresponding to the partial regions (2, 34) are fabricated as preforms (30, 32); to manufacture the green compacts (32) corresponding to the partial regions (34) not designated for ceramization, boron and/or boron-containing compounds and/or boron-releasing compounds being used as fillers, and prior to the pyrolysis, the green compacts being joined to form the desired brake disc; or the green compacts being pyrolyzed, the resultant porous molded articles being doped with boron and/or boron-containing and/or boron-releasing compounds and, prior to the ceramization, being joined to form the desired brake disc.
  • 15. The method as recited in claim 14, wherein as boron-containing and/or boron-releasing compounds, boron nitride, boron tetrachloride boron carbide, and/or borides, in particular ZrB2, HfB2, SiB4 and/or TiB2, as well as boron-containing polymers, in particular polyborosilazanes, are used.
  • 16. The method as recited in claim 14 or 15, wherein the boron and/or the boron compounds are added in a concentration of from 5 to 35% by weight.
  • 17. The method as recited in one of claims 14 through 16, wherein the boron and/or the boron compounds are supplied to the C/C molded article out of a liquid phase, or in the gas phase under high pressure.
  • 18. The method as recited in one of claims 14 through 16, wherein to produce brake units in accordance with claim 8, an undoped brake-disc preform (30) is provided with bores (31), whose diameter is greater than that of the desired entrainment bores (5, 5′) or entrainment slots; and preforms, in the form of sleeves or solid bodies (32), doped with boron and/or boron compounds, are subsequently inserted into the bores (31).
  • 19. The method as recited in one of claims 14 through 18, wherein each preform (30, 32, 41′, 43′) is either used as a CFK preform or as a C/C preform.
  • 20. A brake unit (40, 50) having a brake disc (41, 51) of a fiber-reinforced ceramic material and a hub (43) of the same fiber matrix, which is also the basis, in terms of material, of the fiber-reinforced ceramic material, wherein the brake disc (41, 51) and the hub (43) are joined together, forming a bond, the hub containing boron and/or boron-containing compounds and/or boron-releasing compounds, and the fiber matrix of the hub (43) changing over to the fiber matrix of the brake disc (41, 51) and, in the transition region, changing over to silicon carbide.
  • 21. A method for manufacturing a brake unit as recited in claim 20, wherein a hub preform doped with boron or boron compounds is joined to an undoped brake-disc preform.
  • 22. The method as recited in claim 21, wherein the boron-doped hub preform (43′) is initially fabricated as a CFK body, and subsequently, by compressing and hardening of non-boron-doped homogenate into a CFK brake-disc preform (41′) along the flange-type rim (46′) of the hub preform (43′), the green compact of the complete brake unit (40′) is produced directly.
  • 23. The method as recited in claim 21 or 22, wherein the hub preform (41′) and the brake-disc preform (43′) are fabricated as C/C molded articles, which are subsequently joined and ceramized.
Divisions (1)
Number Date Country
Parent 09153678 Sep 1998 US
Child 09793301 Feb 2001 US