Patent Application
20230002234
This disclosure relates to Janus nanomaterials such as Janus nanoparticles or Janus nanosheets.
Janus particles are types of nanoparticles with at least two surfaces having different respective physical properties. This surface arrangement of Janus nanoparticles allows two different types of chemistry to occur on the same particle. This surface configuration gives properties related to the asymmetric structure or asymmetric functionalization of the particles. The synthesis of Janus nanoparticles generally relies on selectively creating each side of a nanometer-sized particle with different chemical properties. Example syntheses of Janus nanoparticles include masking, self-assembly, and phase separation.
An aspect relates to a method of synthesizing Janus material, including forming a lamellar phase having water layers and organic layers, incorporating nanosheets into the lamellar phase, adding a functional agent into the lamellar phase, and attaching the functional agent to the nanosheets in the lamellar phase to form Janus nanosheets.
Another aspect relates to a method of synthesizing Janus material, including forming a lamellar phase having a surfactant (or a surfactant with a co-surfactant), water layers, and oil layers. The method includes incorporating hydrophilic nanosheets into the water layers, placing a functional agent into the oil layers, and allowing the functional agent to attach to one face of the hydrophilic nanosheets in the lamellar phase to form Janus nanosheets as Janus nanoparticles.
Yet another aspect relates to a method of synthesizing Janus material, including forming a lamellar phase having a surfactant (or a surfactant with a co-surfactant), water layers, and organic layers. The method includes incorporating graphene oxide (GO) nanosheets into the water layers and adding a functional agent into the organic layers. The method includes attaching the functional agent to the GO nanosheets at interfaces of the water layers and the organic layers to form Janus GO nanosheets which are Janus nanoparticles.
Yet another aspect relates to a nanoreactor including an interface between a water layer of a lamellar phase and an organic layer of the lamellar phase, the nanoreactor forming Janus graphene oxide (GO) nanosheets from GO nanosheets and functional agents.
The details of one or more implementations are set forth in the accompanying drawings and the description later. Other features and advantages will be apparent from the description and drawings, and from the claims.
Like reference numbers and designations in the various drawings indicate like elements.
In some implementations, a Janus nanoparticle may be formed by dividing a nanoparticle into two distinct parts, each of a different respective material or bearing different functional groups. For example, a Janus nanoparticle may have one-half of its surface composed of hydrophilic groups and the other half hydrophobic groups. This may impart properties related to the asymmetric structure or functionalization of the Janus nanoparticle. The synthesis of Janus nanoparticles may rely on selectively forming each side of a nanometer-sized particle with different chemical properties.
This disclosure relates to the high-throughput bulk synthesis (for example, greater than 1 kilogram per hour) of Janus nanosheets. Some aspects are directed to the high-throughput bulk synthesis of Janus graphene nanosheets or graphene oxide nanosheets. The “high-throughput” can mean a million Janus nanosheets produced in a batch time of one or two hours in a single vessel. Janus nanomaterials have beneficial properties but the production of Janus nanomaterials in large quantities (for example, at least one kilogram per hour) has proven difficult in the past. The availability of Janus nanomaterials at commercial-scale quantities could give applications of Janus nanomaterials in several industries. Therefore, present embodiments provide for the mass production of Janus nanomaterials.
Embodiments address application of Janus nanomaterials to extract residual oil after primary recovery and secondary recovery. Nanofluid flooding is an alternative tertiary oil-recovery technique to chemical flooding. Nanoparticle fluid flooding to enhance oil recovery in reservoirs is a substitute or compliment to chemical flooding. Nanoparticle solution flooding with low concentration, for example, 0.01 weight percent (wt %) or less, of nanoparticles is applicable from environmental and economic perspectives. However, the oil recovery factor (obtained by core flooding measurement) for flooding with solutions of homogeneous nanoparticles may be below 5% with 0.01 wt % nanoparticle loading in about 2 wt % saline environment. In contrast, a nanofluid of graphene-based Janus amphiphilic nanosheets could achieve efficiency in oil recovery factor (for example, oil recovery factor of approximately 15%) with an ultralow concentration of loading (for example, less than 0.01 wt % nanoparticle loading).
Present embodiments include Janus graphene nanosheets as a material for nanofluid enhanced-oil-recovery (EOR). To synthesize Janus nanosheets in nanometer size and micrometer size ranges, a selective mono-facial modification process may be implemented, as discussed later. Previous syntheses of Janus amphiphilic nanomaterials have been based on two-dimensional interfacial reactions and which have generally produced relatively small quantities of materials, typically at milligram scale in lab bench experiments. These past techniques have been unable to produce Janus graphene-nanosheets material economically for industrial application.
In response, embodiments of the present techniques employ a lyotropic liquid-crystal phase as a template to produce Janus graphene nanosheets. The liquid-crystal phase medium may include surfactant, water, and oil to generate layered oil-water interfaces with intervals in nanometers (nm) such as approximately 10 nm, which can amplify the interfacial area significantly by at least about a million times (for example, at about 106 order), in comparison to conventional bi-phase solution methods. Homogeneous graphene nanosheets can be incorporated into either the water layers or the oil layers in a controlled manner in the lamellar phase, and each single layer of the layered lamellar phase can serve as a nanoreactor for controllable chemical reactions at the interface. These embodiments can perform interfacial reactions and facilitate production of the Janus nanosheets in quantities more economical for industrial application. Embodiments give a first instance of producing Janus graphene nanosheets at gram levels and which are scaled to produce product at kilogram levels such as in room-temperature reactions.
Lamellar phase may refer generally to packing of polar-headed long chain nonpolar-tail molecules as sheets of bilayers separated by bulk polar liquid. A particular microstructure of interest for certain embodiments is the organic lyotropic liquid-crystal with periodically structural order. This microstructure may be the so-called lamellar (La) phase or smectic A mesophase, formed in solvents with a solvent or mixtures of surfactant and cosurfactant. The surfactant may be nonionic, anionic, or cationic. The lamellar phase may consist of stacks of periodic molecular bilayer-sheets separated by layers of solvents. By adding a solvent, such as either water or oil, the bilayer separation (for example, d-spacing or d, lamellar periodicity) in the lyotropic lamellar phases can be swollen from a nanometer to tens of nanometer. A graphic illustration of the lamellar phase is displayed in
A liquid crystalline mesophase may be called lyotropic if formed by dissolving an amphiphilic mesogen in a solvent under specified conditions of concentration, temperature, and pressure. In contrast to thermotropic liquid crystals, lyotropics liquid crystals have an additional degree of freedom in the concentration that enables them to induce a variety of different phases. As the concentration of amphiphilic molecules is increased, several different type of lyotropic liquid crystal structures occur in solution, and the lamellar phase may be formed. This lamellar phase is denoted by the symbol La and can be considered the lyotropic equivalent of a smectic A mesophase. The lamellar phase may consist of amphiphilic molecules arranged in bilayer sheers separated by layers of water. A mesophase may be a state of matter intermediate between liquid and solid. Gelatin is a common example of a partially-ordered structure in a mesophase.
In general, surfactants may be compounds that reduce the surface tension or interfacial tension between two liquids, between a gas and a liquid, or between a liquid and a solid. With respect to the surfactants, the term “nonionic” may mean not ionic, not anionic, or not cationic. For a detergent, nonionic may mean that the detergent does not dissociate into ions in aqueous solution. A nonionic surfactant may have covalently bonded oxygen-containing hydrophilic groups, which are bonded to hydrophobic parent structures. The water-solubility of the oxygen groups may be the result of hydrogen bonding. Hydrogen bonding generally decreases with increasing temperature, and the water solubility of nonionic surfactants therefore decreases with increasing temperature.
A representative section 112 of the lamellar phase 110 is given enlarged for clarity, and which shows the lamellar phase 110 including alternating oil layers 116 and water layers 118. The oil layers 116 may be characterized as oil phase layers 116. The water layers 118 may be characterized as water phase layers 118. Further, the multiple lyotropic liquid crystals are the surfactant molecules with the hydrophilic heads and hydrophobic tails. The surfactant molecules in the exploded view of the representative portion 112 are depicted each with a head and a tail. In implementations, the lamellar phase 110 is generally not a micelle or emulsion. The lamellar phase 110 may typically be a planar structure with surfactant hydrophilic heads contacting water 118 and surfactant hydrophobic tails contacting the organic phase (for example, oil 116) in the illustrated implementation.
The layers 116 may be an oil layer or an organic layer. The oil layers 116 may be more generally an organic layer having organic compounds (for example, chloroform) that are not oil but are hydrophobic. The oil layers 116 may include mineral oil, refined oil, crude oil, fractions of crude oil, diesel, synthetic oil, or vegetable oil. The fractions of crude oil can include organic compounds such as decane or dodecane. The water layers 118 may be more generally an aqueous layer or hydrophilic layer. The water layers 118 may include ground water, treated water (for example, demineralized water), or formation water. The water layers 118 may include components other than water such as dissolved solids. The water layers 118 as an aqueous layer may include chemical components soluble in water.
In some instances, the oil layer 116 and water layer 118 may each be labeled as a lamellar layer. While the combination of the oil layer 116 and the water layer 118 (and with their interface) may instead be labeled as the lamellar layer, this combination is typically instead labeled as a lamellar unit 114 as depicted. The lamellar unit 114 may include the oil layer 116, the water layer 118, the oil-water interface, and the surfactant. While the
Embodiments innovatively employ the lamellae as template media to produce Janus nanosheets. The lamellar phase 110 can generate alternating interfaces of water and oil on the nanoscale range and, therefore, the many lamellar units 114 may each be utilized respectively as a nanoreactor for chemical reactions at the water-oil interfaces. The chemical reaction can be controllably-run occurring either at the water phase side or the oil phase side of the interface. Employing these nanoreactors may provide to selectively functionalize a selected side (surface) of graphene nanosheets, producing Janus nanosheets with one side hydrophilic and the other side hydrophobic.
In contrast to the conventional bi-phase system 102 having a single water-oil interface, the lamellar phase 110 gives many water-oil interfaces with each lamellar unit 114 being a respective lamellar nanoreactor. The lamellar phase 110 may have up to a million layer units 114 or more depending on the amount of surfactant and solution capacity.
In the bi-phase system, the majority of the chemical reagents stays in solution phase and only a small percentage (for example, less than 10 wt % of the chemical reagents) reaches the interface for chemical reactions. Conversely, in the lamellar phase 110, most or all of the chemical reagents are confined in thin layers of solvents (for example, oil 116 and water 118) near the interfaces, and thus the chemical reactions may be more effective (for example, incorporating greater than 90 wt % of the chemical reagents). The principle of the lamellar nanoreactor system is illustrated in
In the illustrated embodiment of
In general, a nanosheet may be a two-dimensional nanostructure with thickness in a scale ranging, for example, from 1 nm to 100 nm. Nanosheets can include silicon nanosheets and carbon nanosheets. A typical example of a nanosheet is graphene, for example, having a thickness of about 0.34 nm. The graphene nanosheet may be an allotrope (form) of carbon consisting of a single layer of carbon atoms arranged in a hexagonal lattice. Synthesis of the nanosheet may be a bottomup technique such as chemical vapor deposition (CVD) and also may be from chemical exfoliation of graphite powder. Graphene may be a structural element of other allotropes of carbon, such as graphite, diamond, charcoal, carbon nanotubes, and fullerenes. Graphene is a crystalline allotrope of carbon with two-dimensional (2D) properties. The carbon atoms may be packed densely in the atomic-scale hexagonal pattern. Thus, graphene is generally a material made of carbon atoms that are bonded together in a repeating pattern of hexagons or a honeycomb pattern. Graphene can be very thin (for example, about 0.34 nm) and thus graphene can be considered pseudo 2D. The single layers of carbon atoms provide the basis for other materials. For instance, graphite is formed by stacked graphene. Carbon nanotubes are made of rolled graphene.
Graphite oxide is a compound of carbon, oxygen, and hydrogen in variable ratios, obtained by treating graphite with oxidizers. The bulk material disperses in basic solutions to yield monomolecular sheets, known as graphene oxide by analogy to graphene the single-layer form of graphite. Graphene oxide (GO) may be a single-atomic layered material made by oxidation of graphite. Graphene oxide may be an oxidized form of graphene, laced with oxygen-containing groups. Graphene oxide may be synthesized by different techniques. The effectiveness of an oxidation to form GO may be evaluated by the carbon/oxygen ratios of the GO in certain instances. The surface of GO may be modified to change properties of the surface.
In the illustrated implementation of
In certain implementations, the functional agents 208 are silane-based chemical reagents. The depicted configuration exemplary of a head and tail of these functional agents 208 may mean a molecule with a reactive head and not indicative of the molecule being amphiphilic. In this implementation, the molecule overall is hydrophobic. The functional agents 208 may be coupling agents (for example, silane coupling agents) having a functional group to be attached or grafted onto the GO nanosheets 204 such as onto on side surface of the GO nanosheets 204.
As mentioned, in the lamellar phase 110, the functional agents 208 as chemical reagents may generally be confined in thin layers of solvents (for example, oil layer 116 or water layer 118) near the interfaces. To do the surface functionalization of the GO nanosheets 204, the chemical reagents may be added as a water-soluble reagent to the water layer 118 phase or added as an oil-soluble reagent to the oil 116 phase. Examples of hydrophobic reagents added to oil layer 116 are: (1) n-allyltriethoxysilane, alkyl═hexyl, octyl, decyl, docedyl, hexadecyl, octodecyl; and (2) perfluoroalkyl-1H,1H,2H,2H-triethoxysilane, alkyl=hexyl, decyl, octylphenyl. Examples of hydrophilic reagents added to water layer 118 are: (1) aminoalkyltriethoxysilane, alkyl=propyl; and (2) meraptoalkyltriethylsilane, alkyl=propyl.
The functional agent 208 is incorporated or attached 212 onto the GO nanosheets 204 to give Janus GO nanosheets 214, as indicate by reference numeral 216. The chemical reaction occurs at the interface of the water 118 and oil 116 layers. Therefore, as discussed, a single lamellar unit 114 including the combination of a water 118 and an oil 116 layer may be considered as one nanoreactor. Thus,
Therefore, the nanoscale reactor may include the interface between a water layer 118 of a lamellar phase 110 and an oil (or organic) layer 116 of the lamellar phase 110. The interface may be a region or volume at the location of where a water layer 118 meets an oil layer 116. The nanoreactor forms Janus GO nanosheets 214 from GO nanosheets 204 and functional agents 208. The functional agents 208 are attached to a surface of the GO nanosheets 204 in the nanoreactor encompassing the interface. The depiction 216 in
In contrast to graphene nanosheets which are generally hydrophobic, the GO nanosheets 204 are generally hydrophilic and thus inserted into the water layers 118 in the lamellar phase 110 for the further functionalization reaction. Chemical functional groups can be grafted onto the surface of the GO nanosheets 204 via the surface —OH groups of the GO nanosheets 204 from either the water layer 118 side or the oil layer 116 side. Hydrophobic graphene could be inserted into the oil layers 116 in the lamellar phase 110, but the inert surface of graphene is chemically stable and therefore resistant to further surface functionalization.
The type of surfactant(s) chosen may be EOR agents. In general for some implementations, the surfactants employed for the nanoreactors can also be used as EOR agents. In the application of Janus graphene oxide, the surfactants may be used in a diluted suspension of water (for example, seawater or brine) such as at less than 0.5 weight percent of surfactant. In such a concentration, the lamellar phase 110 nanoreactors may be dissolved, and both the surfactant molecules and the Janus GO nanosheets may be dissolved or suspended in the diluted solution, so that no post-synthesis purification or other treatment is needed for certain embodiments. Thus, a benefit may be that that after the synthesis of the Janus nanosheets 214, a post-synthesis purification or other treatments may be avoided. In other words, the collected Janus nanosheet 214 products and lamellar phase 110 reaction templates can be directly employed for EOR application.
Implementations include equipment, operating conditions, and production rate of a commercial system to produce these Janus nanosheets at industrial scale. In embodiments, the chemical reactions occur at ambient temperature and atmosphere pressure. The quantity of product in one batch reaction may depend on the volume of the reaction vessel. The scale can be amplified from lab scale in milliliters to intermediate scale at liters and industrial scale at tens or hundreds of liters. The Janus nanosheets may be collected with the lamellar phase in which the Janus nanosheets are formed. The lamellar phase having the Janus nanosheets may be discharged from the reaction vessel and collected for application(s).
An average recovery factor for a typical oilfield may be less than 50% which results in identified oil left behind despite an existing production infrastructure. To accelerate production and increase recovery factor, EOR schemes may be implemented. EOR is generally a process of increasing the amount of oil that can be recovered from an oil reservoir, typically by injecting a substance into an existing oil well to increase pressure and reduce the viscosity of the oil. EOR may the process of recovering oil not already extracted from an oil reservoir by primary or secondary recovery techniques. Primary or secondary recovery may rely on natural or enhanced pressures to force oil out of the ground. EOR methods may alter the chemical composition of the oil to facilitate extraction of the oil.
Decane was employed as the oil or oil layers in the Examples.
Surfactants employed in the Examples of the synthesis are commercially available. Moreover, in the Examples after the synthesis, no post-synthesis purification or other treatments was implemented. The Janus nanosheet products and the lamellar reaction templates can be directly applied for EOR application because the surfactants in the Examples are EOR agents and can give synergistic EOR effects.
For each lamellar system, the lamellar periodicity (d) may vary from several nanometers to several tens of nanometers by changing thickness of the organic (oil) layer or the water layer. This lamellar periodicity was determined in the Examples by small-angle x-ray scattering (SAXS) measurement. The lamellar phases 110 in the Examples were made in synthesis controlled with thicknesses of the water layer 118 at 5 nm to 10 nm and oil layer 116 at 2 nm to 15 nm, which are exemplary dimensions for the nanoreactor of the innovative chemical reaction disclosed here.
In synthesis in the Examples, the hydrophilic GO nanosheets were dispersed in water and this suspension utilized to build the lamellar system. Then, functionalization agents were placed into the oil phase, and the oil swelled the lamellar phase. Therefore, the GO nanosheets from the water layer side and the functionalization agents from the oil layer side could approach to meet at the water-oil interface for reactions (for example, hydrolysis) by modifying one side of the nanosheet. To make one side of the nanosheet hydrophobic, the silane coupling agents having hydrophobic functional groups are used for grafting hydrophobic functional groups onto graphene. Representative silane compounds include:
To confirm the formation of Janus nanoparticles, mono-facial modified graphene nanosheets with hydrophobic amino groups (—NH2) were coated on hydrophilic and hydrophobic silicon wafer surfaces, respectively. Thus, the amino groups on the hydrophobic face or side of the Janus GO nanosheets pointed away from the nanosheet on the hydrophilic substrate while the amino groups on the hydrophobic side of the Janus GO nanosheets are faced down to the substrate. Then, the Janus GO coated substrates were immersed into a dye solution of 1×10−4M of Rhodamine B isothiocyanate (RBITC). The RBITC molecules are fluorescent and can be covalently bonded to the —NH2 groups on GO. After washing the substrates with water, unbounded free dye molecules were likely removed, and those molecules bonded with —NH2 groups stayed on the GO surface. The fluorescence analysis is presented with respect to
As indicated in the fluorescence spectra of
The image 1012 is a hydrophobic container 1014 having the crude oil-seawater bi-phase system without the Janus GO sheets. The hydrophobic container 1016 has the same bi-phase system but with the Janus GO nanosheets. With the presence of the Janus GO nanosheets, the oil layer 1018 and the water layer 1020 are defined and not dispersed.
The image 1022 is a hydrophilic container 1024 having the oil and water layers 1028, 1030 without the Janus GO nanosheets. Such may be analogous to the container 1004 and bi-phase system in image 1002 but with container 1024 leaned to demonstrate effect on the interface between the oil layer 1028 and the water layer 1030. The hydrophilic container 1026 has the same bi-phase system but with the Janus GO nanosheets. The interface between the oil and water is generally unaffected by the leaning of the hydrophilic container 1026.
The properties of Janus GO nanosheets may have an effect on the water-oil interface. When injecting the Janus GO nanosheets suspension at ultralow concentration of less than 0.01 wt % into a water-oil mixture, the interfacial tension at the water-oil interface can be altered.
Embodiments provide an innovative technique for synthesizing Janus GO nanosheets in relatively large quantities. Such quantities can be greater than a million nanosheets in a single batch in a vessel. The technique may be at industrial scale and for a wide range of applications of Janus GO nanosheets in various industries. The Janus GO nanosheets can alter interfacial properties of water-oil interfaces. The Janus GO nanosheets have application in a nanoagent solution for EOR in oil and gas recovery applications.
Embodiments employ lyotropic liquid crystal phase as a template for Janus nanoparticle synthesis and with efficiency of interfacial reactions by a million times (at 106 order) compared with current conventional bi-phase reactions. Such promotes and facilitate bulk Janus nanosheets production feasible for industrial applications. The innovative nanoreactor utilizes a lyotropic liquid crystal phase as template media for chemical reactions at water-oil interfaces. A chemical reaction route is implemented to fabricate Janus graphene nanosheets in bulk quantities. The structural and property characterizations of the synthesized graphene or GO nanomaterials may be evaluated. Functionalized graphene or GO nanosheets may be designed and characterized. Microfluidic imaging of functionalized GO nanosheets may be performed for EOR applications.
At block 1102, the method includes providing or forming a lamellar phase having water layers and organic layers. The water layers may be characterized as water phase layers. Likewise, the organic layers may be characterized as organic phase layers. Moreover, in particular embodiments, the organic layers are oil layers. In certain embodiments, the lamellar phase is placed or formed in the vessel in which the synthesis (for example, batch synthesis) is to occur.
Further, the lamellar phase may include a surfactant. The surfactant may be a nonionic surfactant, a cationic surfactant, or an anionic surfactant. The lamellar phase may include a mixture of the surfactant and a cosurfactant. In certain implementations, hydrophilic heads of the surfactant contact the water layers and hydrophobic tails of the surfactant contact the organic layers. A cosurfactant may be a chemical utilized with a surfactant to improve performance or enhance effectiveness of the surfactant. A cosurfactant may be defined as a surfactant that acts in addition to another surfactant and thus further reduces the surface tension of a liquid. A cosurfactant may be employed to increase the oil-solubilizing capacity of a microemulsion surfactant system. An example of such a cosurfactant is a long-chain (at least 5 carbons) alcohol.
A surfactant may organize at a liquid-liquid boundary which can lead to an organized interface and liquid-crystal phases. To achieve ultralow interfacial tension (for example, less than 0.01 millinewton per meter) for EOR applications, a cosurfactant may be added to disturb the organized liquid-liquid interface.
In some implementations, the surfactant is an EOR agent for flooding or chemical injection, or both. Therefore, the Janus nanomaterial synthesized in the lamellar phase in method 1100 generally need not be separated from the lamellar phase for application in EOR such as nanoflooding. In other words, the lamellar phase having the formed Janus nanoparticles (nanosheets) after synthesis may be collected and utilized in nanoflooding EOR. In some examples, the collection may involve discharging of the lamellar phase with the Janus nanoparticles from the vessel to a storage vessel.
As discussed earlier, a lamellar unit (nanoreactor) of the lamellar phase may include a water layer and an organic layer. Lamellar units (for example, at least 100,000 in the lamellar phase) may each include a respective water layer and respective oil layer, and where each lamellar unit may be a nanoreactor.
At block 1104, the method include adding or incorporating nanosheets into the lamellar phase. The nanosheets may be hydrophilic nanosheets such as GO nanosheets, and where the nanosheets are incorporated into the water layers. In examples, the nanosheets are placed into the lamellar layer, and the hydrophilic nanosheets position, migrate, or flow into the water layers because of the affinity of the hydrophilic nanosheets for the water layers. The nanosheets may be hydrophobic nanosheets such as graphene nanosheets, and where the nanosheets are incorporated into the organic layers.
In some implementations, the forming (block 1102) of the lamellar phase is contemporaneous with incorporating the nanosheets into the lamellar phase. For example, the forming of the lamellar phase and the incorporating of the nanosheets (for example, hydrophilic) includes forming a water suspension of the nanosheets in water and building the lamellar phase with the water suspension. Thus, as the lamellar phase forms, the nanosheets are simultaneously incorporated into the water layers in the lamellar phase.
At block 1106, the method includes adding a functional agent to the lamellar phase. For example, the method may include placing the functional agent into the organic layers or oil layers. The functional agents may be placed into the lamellar phase, and the functional agents migrate into the organic layers because of the affinity of the hydrophobic functional agents for the organic layers. In particular implementations, the functional agent is a silane coupling agent having a functional group. The functional agent may be silane-based chemical reagents. The functional agent may include silane compounds having one or more functional groups.
At block 1108, the method includes forming the Janus nanosheets. In particular, the method includes attaching the functional agent to the nanosheets in the lamellar phase to form the Janus nanosheets. The method may include allowing the functional agent to attach to the nanosheets in the lamellar phase to form Janus nanosheets as Janus nanoparticles. In one implementation, the nanosheets are hydrophilic GO nanosheets and the Janus nanoparticles formed are Janus GO nanosheets.
The method may include attaching the functional agent to the nanosheets at interfaces of the water layers and the organic layers to form the Janus nanosheets. The Janus nanosheets may be Janus graphene nanosheets or Janus GO nanosheets that may be characterized as Janus nanomaterial or Janus nanoparticles. In certain embodiments, the functional agent is hydrophobic molecules, and where allowing the functional agent to attach to the nanosheets as hydrophilic nanosheets involves the functional agent attaching onto a surface of a hydrophilic nanosheet converting that surface to hydrophobic.
In general, nanoreactors may be a form of chemical reactor that are particular in disciplines of nanotechnology. Nanoreactors may maintain a working nanofoundry that manufacture products on a nanoscale. A nanoreactor may carry out chemical reactions in a limited space whose size does not exceed 100 nm in at least one dimension and is physically limited by the dimensions of ordered structure elements.
In the lamellar phase, a nanoreactor that forms Janus nanosheets may include the interface between a water layer of a lamellar phase and an organic layer (for example, oil layer) of the lamellar phase. The lamellar phase may include a surfactant such as a nonionic surfactant, anionic surfactant, or cationic surfactant. The lamellar phase may have at least 100,000 lamellar units. Thus, the lamellar phase may have at least 100,000 nanoreactors. In operation, GO nanosheets may be received into the water layer of the nanoreactor for migration to the interface. A functional agent may be received into the organic layer of the nanoreactor for migration to the interface and to be attached to one side of the GO nanosheets to form the Janus GO nanosheets. The functional agent may be a silane-based chemical reagent. In some implementations, the formed Janus GO nanosheets are not separated from the lamellar phase or nanoreactor. The lamellar phase having the Janus GO nanosheets may be applied as an EOR agent for chemical injection or flooding of a geological formation in tertiary recovery.
Oil production may be separated into at least three phases: primary, secondary, and tertiary. Tertiary recovery may also be known as EOR. Primary oil recovery is generally limited to hydrocarbons that naturally rise to the surface or recovered via artificial lift devices such as pumps. Secondary recovery employs water and gas injection, displacing the oil to the surface. Primary and secondary recovery of production can leave, for example, up to 75% of the oil in the well. A way to further increase oil production is through tertiary recovery or EOR. Although typically more expensive to employ on a field, EOR can increase production from a well, for example, up to 75% recovery. Again, EOR may be labeled as tertiary recovery and can be the extraction of crude oil from an oil field that generally cannot be extracted otherwise. For example, EOR may extract 30% to 60% or more of reservoir oil compared to 20% to 40% recovery of reservoir oil employing primary and secondary recovery. The EOR may involve thermal recovery (for example, steam flooding or fire flooding), gas injection (for example, carbon dioxide), or chemical injection (for example, polymers or surfactants). More advanced speculative EOR techniques are sometimes called quaternary recovery. In EOR, physical and chemical properties of the rock may be changed to enhance the recovery of hydrocarbon. The properties of the reservoir fluid system which are affected by EOR may be chemical, biochemical, density, miscibility, interfacial tension (IFT), surface tension (ST), viscosity and thermal. Secondary recovery may involve water injection or waterflooding and in which EOR may be performed thereafter. EOR or tertiary recovery may involve flooding or waterflooding which may include chemical flooding, polymer flooding, surfactant flooding, nanoflooding such as nanofluid flooding or nano material (nanoparticle) flooding, or any combinations thereof. Embodiments herein are Janus graphene nanosheets as a material for EOR involving nanoflooding such as nanofluid (nanoparticle) flooding.
At block 1202, the method includes receiving Janus nanosheets at the well site. The Janus nanosheets may be Janus GO nanosheets that are Janus nanoparticles. The Janus nanosheets may be received in a lamellar phase in which the Janus nanosheets were formed. The lamellar phase may include a surfactant that is an EOR agent employed in surfactant flooding and compatible with nanofluid flooding. The Janus nanosheets (and lamellar phase) may be received into a surface vessel at the well site or received via a vessel on a vehicle to the well site.
At block 1204, the method includes introducing the Janus nanoparticles into the geological formation. The method may include applying the Janus nanosheets through the wellbore into the geological formation. The wellbore may be of a producing well or an injection well. The Janus nanosheets (or lamellar phase having the Janus nanosheets) may be injected in a fluid (for example, water) through the wellbore into the geological formation to contact hydrocarbon or hydrocabon-bearing fluid in the geological formation. The Janus nanosheets in the fluid may be pumped through the wellbore into the geological formation.
At block 1206, the method includes performing EOR through the geological formation with the Janus nanosheets. The EOR may be nanoflooding. The Janus nanosheets are generally Janus nanoparticles. The method includes contacting hydrocarbon (for example, crude oil) or hydrocarbon-bearing fluid in the geological formation with the Janus nanosheets.
In summary, an embodiment is a method of EOR including receiving Janus nanoparticles that are Janus GO nanosheets, injecting the Janus nanoparticles through a wellbore into a geological formation to contact hydrocarbon in the geological formation, and performing nanoflooding through the geological formation with the Janus nanoparticles.
A number of implementations have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the disclosure.
This application claims the benefit of priority to U.S. Provisional Patent Application Ser. No. 62/819,080, filed Mar. 15, 2019, the contents of which are hereby incorporated by reference.
| Number | Date | Country | |
|---|---|---|---|
| 62819080 | Mar 2019 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16818632 | Mar 2020 | US |
| Child | 17940367 | US |
