1. Field of the Invention
Various embodiments of the present invention described herein generally relate to solar cells; particularly solar cells with reduced-area bus bars.
2. Description of Related Art
In basic design, a solar cell is composed of a material such as a semiconductor substrate that absorbs energy from photons to generate electricity through the photovoltaic effect. When photons of light penetrate into the substrate, the energy is absorbed and an electron previously in a bound state is freed. The released electron and the previously occupied hole are known as charge carriers.
The substrate is generally doped with p-type and n-type impurities to create an electrical field inside the solar cell at a p-n junction. In order to use the free charge carriers to generate electricity, the electrons and holes are separated by the electrical field at a p-n junction. The free electrons are then be collected by the electrical contacts on the n-type layer and the holes are collected by electrical contacts on the p-type layer. The charge carriers that do not recombine are then available to power a load.
Solar cells of this type are commonly connected together in groups to produce a solar module. A typical approach involves providing one or more bus bars on the p-type and n-type surfaces of a first solar cell to collect current from the first cell's contacts. The first cell's p-type bus bar can then be connected a second solar cell's n-type bus bar using an interconnecting medium, such as a metallic ribbon soldered to the appropriate bus bars. As a result, the first and second solar cells are connected in series and—using the same approach for all cells in the module—charge carriers from each cell are collectively made available to power a load.
However, typical solar cell bus bars are formed from expensive conductive materials, such as silver, nickel, or Titanium/Pd/Ag. As cost and performance are major factors in the viability of solar cells as widely used energy producing devices, there is a need in the art for an improved bus bar for a solar cell that reduces the usage of expensive conducting materials while enabling high levels of electrical and mechanical performance.
Various embodiments of the present invention are directed to a solar cell having a front surface and a back surface. In various embodiments, the solar cell comprises: a semiconductor wafer; one or more contacts positioned on at least one of the front surface and back surface of the solar cell, the contacts being in electrical communication with the solar cell; and at least one bus bar disposed on the at least one of the front surface and back surface in electrical communication with the one or more contacts and configured for collecting current from the one or more contacts. According to various embodiments, the bus bar is oriented along a generally longitudinal axis and the width of the bus bar varies at points along the longitudinal axis. In addition, in various embodiments, the bus bar defines: a first portion having a first width; a second portion positioned adjacent the first portion, the second portion having a second width that is less than the first width; a third portion positioned adjacent the first portion opposite the second portion, the third portion having a third width that is less than the first width; and a fourth portion positioned adjacent the third portion, the fourth portion having a fourth width that is greater than the third width.
In addition, various embodiments of the present invention are directed to a solar cell having a front surface and a back surface, the solar cell comprising: a semiconductor wafer; a plurality of contacts positioned on at least one of the front surface and back surface of the solar cell in a spaced-apart relationship, the contacts being in electrical communication with the solar cell; and at least one bus bar disposed on the at least one of the front surface and back surface in electrical communication with the one or more contacts and configured for collecting current from the one or more contacts. According to various embodiments, the bus bar is oriented along a generally longitudinal axis and comprises a plurality of bus bar segments disposed in a spaced-apart relationship along the longitudinal axis.
Reference will now be made to the accompanying drawings, which are not necessarily drawn to scale, and wherein:
The present invention now will be described more fully hereinafter with reference to the accompanying drawings, in which embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art Like numbers refer to like elements throughout.
As used herein, embodiments in which a first element is described to be “overlying,” “over,” or “above” a second element may generally be taken to signify that the first element is closer to the primary illuminated surface or primary illumination source. For example, if a first element is said to be overlying a second element, the first element may be closer to the primary illumination source. Similarly, embodiments in which a first element is described to be “underlying,” “under,” and “below” a second element may generally be taken to signify that the first element is further from the primary illumination source. For example, if a first element is said to be underlying a second element, the first element may be further from the sun. It should be noted that, in various embodiments, forms of secondary illumination, such as light returning to the device from a reflective surface located behind or beyond the device after the light originating from a primary illumination source has passed through or around the device, may be considered separate from the primary illumination source.
Various embodiments of the present invention are directed to a solar cell having an improved bus bar. Generally, solar cell bus bars function to collect current from a plurality of contacts on the front or back surface of a cell. On a surface that includes a plurality of contact lines (e.g., a contact grid), one or more continuous, linear bus bars are frequently provided. Typically, the width of the bus bar is dictated by the requirement that it not only provide a conductive medium for collecting current from the contacts, but that it also provide a solderable surface to which an interconnecting ribbon may be soldered. In various embodiments, the ribbon may be formed, for example, from metallic copper and may be coated with tin (or another solderable material). The ribbon will also generally have a width sufficient to provide a relatively low series resistance in order to effectively carry current from one solar cell to another. To connect a pair of solar cells in series, the ribbon may be soldered along the length of the bus bar.
In order to ensure the reliability of the solar module, the inventors have recognized that the soldered connection between ribbon and the bus bar should have a high pull strength to ensure the ribbon is not disconnected from the bus bar (e.g., by inadvertent picking of the ribbon during manufacturing or use). However, the inventors have also recognized that is desirable to provide a bus bar formed from reduced amounts of conductive material (e.g., reduced silver paste) in order to minimize the cost of an associated solar cell. According to various embodiments described herein, the inventors have devised a reduced-area bus bar having a width that varies at various points along its longitudinal axis. In particular, the inventors have recognized that the larger width portions of the reduced-area bus bar provide sufficient pull strength when a ribbon is soldered along the bus bar, while the smaller width portions of the reduced-area bus bar enable a reduction in the material required to form the bus bar.
As described in greater detail below, various embodiments of the reduced-area bus bar described herein provide reduced cost solar cell without sacrificing significant cell performance or reliability. Exemplary embodiments will now be described in greater detail below.
According to various embodiments, the solar cell 5 may be formed of a semiconductor substrate. The substrate may be composed of silicon (Si), germanium (Ge) or silicon-germanium (SiGe) or other semiconductive material, or may be formed from a combination of such materials. In the case of monocrystalline substrates, the semiconductor substrate may be grown from a melt using Float Zone (FZ) or Czochralski (Cz) techniques. The resulting mono-crystalline boule may then be sawn into wafers to form the substrates. In other embodiments, the substrate can be multi-crystalline, which may be less expensive than monocrystalline substrates.
The front 8 and back 9 surfaces of the substrate may define pyramidal structures created by their treatment with a solution of potassium hydroxide (KOH) and isopropyl alcohol (IPA) during an anisotropic etching process. In various embodiments, the presence of these structures increases the amount of light entering the solar cell 5 by reducing the amount of light that is lost by reflection from the front surface 8. The pyramidal structures on the back surface 9 may be fully or partially destroyed during formation of a back contact by alloying aluminum with silicon.
In the illustrated embodiment of
In certain embodiments, a front surface layer may be formed by introducing dopant into the front surface of the substrate, for example by diffusion, ion implantation, or the like. The dopant may be of an n-type conductivity or p-type conductivity. In embodiments where the conductivity type of the front surface layer is the same as the base layer, the front surface layer may act as a front surface field layer. In other embodiments where the conductivity type of the front surface layer is opposite the conductivity type of the base layer, the front surface layer may act as an emitter layer. According to certain embodiments, the front surface layer may either be a substantially uniform layer or a selective front surface layer. In the illustrated embodiment of
In the embodiment of
As shown in
The solar cell 5 also includes front contacts 30, which may be formed from conductive materials such as silver (Ag). Generally, for silicon and other substrates, silver may be used to form front contacts on a surface of the substrate when the front surface layer is doped n-type. To decrease recombination where the metal directly contacts silicon and limit the proportion of metal covering the surface of the substrate, the front contacts 30 may be configured as point or line contacts (sometimes called “local contacts”). In particular, the front contacts 30 may be formed by screen-printing the silver on the front surface of the antireflection layer 45. As described in greater detail below, the front contacts 30 may be in electrical communication with bus bars to facilitate electrical connections to the front surface of the solar cell 5.
In addition, for the front contacts 30, silver may be selected because of its high electrical conductivity to limit shadowing effects that can lower solar cell efficiency. In embodiments comprising a selective front surface layer, the front contacts 30 may also be aligned with the heavily doped regions 15 of the selective front surface layer. In accordance with certain embodiments, the front passivation layer 40 and the antireflection layer 45 may be disposed on the front surface of the doped regions 15, 20 of the selective front surface layer prior to forming the front contacts 30. In this case, the front contacts 30 may physically penetrate the front passivation layer 40 and the antireflection layer 45 to make contact with the underlying regions of the selective front surface layer.
According to certain embodiments, the back contact 35 may be formed on the back surface 9 of the substrate using screen-printed pastes. The paste used to form the back contact 35 may be an aluminum paste, for example an aluminum paste chosen to have high cohesion after firing. In some embodiments, the screen-printed paste may be applied to cover nearly the entire back surface 9 of the substrate, for example the paste may not be printed over a narrow border near the edges of the wafer approximately 1 mm wide. In accordance with certain embodiments, firing of the screen-printed paste may form the back contact 35 and back surface layer 50. In some embodiments, the back contact 35 may physically penetrate an optional rear passivation layer during firing. In other embodiments, local back contacts may be formed through one or more holes or vias through a rear passivation layer, and the remainder of the back contact 35 may not penetrate or consume the rear passivation layer, for example when the paste used to form the back contact 35 is fritless.
As noted above, due to the firing of the back contact 35, a back surface layer 50, such as an aluminum-doped p+ silicon layer, is formed by liquid phase epitaxial regrowth in the region between the base layer 10 and the back contact 35. In the illustrated embodiment, the back contact 35 may make electrical contact with the back surface layer 50. The back contact 35 may be composed at least partially of an aluminum-silicon eutectic composition. In embodiments where the conductivity type of the back surface layer 50 is opposite the conductivity type of the base layer 10, for example where the base layer is doped to be n-type and where the back surface layer 50 comprises a sufficient amount of aluminum to be doped p-type, a p-n junction 60 may be formed at the interface between the base layer 10 and the back surface layer 50. According to these embodiments, the back surface layer 50, such as the aluminum-doped p+ silicon layer, may act as an emitter layer. Furthermore, the method may reduce the possibility of the back contact 35 shunting the p-n junction because the aluminum of the back contact 35 is the source of the p-type dopant for forming the back surface layer 50, which in turn forms the p-n junction 60 at the interface of the base layer 10 and the back surface layer 50.
The back contact 35 may also serve as a reflective back layer for the solar cell 5. Having a reflective back layer provides a reflective surface to return incident light reaching the back to the substrate where it can generate free charge carriers. The thickness of the back contact 35 may be from 5 to 50 micrometers in thickness. The back layer may, in some embodiments, provide a measure of reflectivity.
As will be appreciated from the description herein, the back junction solar cell 5 shown in
In the illustrated embodiment, front contacts 30 are in electrical communication with three reduced-area bus bars 100, each of which is oriented longitudinally (e.g., perpendicular to the front contacts 30) and extends along the length of the wafer. As an example, in one embodiment, the length of the wafer may be approximately 153 mm. In particular, as will be appreciated from
According to various embodiments, the bus bars 100 may be formed from an electrically conductive material, such as silver, disposed on the front surface 8 of the wafer. For example, in order to remain in electrical communication with the front contacts 30, various portions of the conductive material forming the bus bars 100 may be disposed over portions of the front contacts 30 on the cell's front surface 8. In this way, the bus bars 100 are able to collect current (i.e., free charge carriers) from the front contacts 30.
As noted above, each of the bus bars 100 is also configured for being soldered to an interconnecting ribbon. In particular, in a solar module, the ribbon may be soldered to bus bars on opposite terminals of adjacent solar cells in order to connect the adjacent cells in series. In order to reduce material usage while providing a solderable connection to the ribbon of sufficient pull strength, each bus bar 100 is configured such that its width generally varies between a first larger width and second smaller width at various points along the respective bus bar's longitudinal axis 105. As described in greater detail below, the wider portions of each bus bar 100 provide regions of high pull strength when the ribbon is soldered to the bus bar 100, while the narrower portions of the bus bar 100 reduce overall material usage in forming the bus bar 100.
As will be appreciated from the description herein, the dimension of the diamond-patterned bus bar 100 may vary according to various embodiments. For example, in one embodiment, the fourth portion 104 may have a width that is greater than the second and third portions 102, 103, but less than the first portion 101. Likewise, the first portion 101 may have a width that is greater than the second and third portions 102, 103, but less than the fourth portion 104.
In addition, various embodiment of the bus bar 100 may be dimensioned such that the diamond-shaped pattern defined by the bus bar 100 repeats more or less frequently along the length of the bus bar 100. For example, in various embodiments, the spacing between first portion 101 and fourth portion 104 may be relatively short (e.g., 0.05% of the length of the wafer). In other embodiments, the spacing between the first portion 101 and the fourth portion 404 may be relatively long (e.g., 50% of the length of the wafer).
According to various embodiments, the bus bar 100 is configured such that an interconnecting ribbon (e.g., a metallic copper ribbon coated with tin) may be soldered along the length of the bus bar 100. In such embodiments, the portions of the ribbon soldered to the wider portions 101, 104 of the bus bar 100 will have a strong connection to the bus bar 100 (e.g., as compared to the strength of the ribbon's connection to the narrower portions of the bus bar 100). As has been recognized by the inventors, this is attributable to the larger width W1 of the bus bar's portions 101, 104. For example, testing of certain bus bar embodiments having the profile shown in
In addition to the high pull strength, the profile of the bus bar 100 also enables a reduction in material usage due to the narrower portions 102, 103 of the bus bar 100. For example, in the illustrated embodiment, the bus bar 100 can be formed from 50% less silver paste than a linear bus bar having the width W1. This reduction in material usage has a number of advantages. First, in certain embodiments, reducing the usage of expensive bus bar material (e.g., silver) reduces the overall cost of the solar cell 5 as the cell's bus bars can be formed from less material without sacrificing high levels of electrical and mechanical performance. This can be particularly advantageous for solar cells utilizing exceptionally high cost materials to form bus bars (e.g., specially formulated low temperature Ag pastes). Second, the ability to reduce the amount of material needed to form individual bus bars can also enable improvements in electrical and mechanical cell performance. For example, in certain embodiments, reducing the material required to form a single bus bar may enable additional bus bars to be formed on the surface a solar cell without increasing the overall cost of the cell (e.g., two bus bars 100 might be formed using the same amount of material necessary to form a single linear bus bar). In such embodiments, the additional bus bars can reduce fill factor losses and improve the overall performance of the cell without leading to increased costs.
As will be appreciated from the description herein, the bus bar 100 described above may be used on the surfaces of various solar cells and in various configurations. For example, any number of bus bars 100 may be provided on the top surface 8 of the solar cell 5 (e.g., one, two, three, four, etc. bus bars 100 provided on the top surface 8 in a manner analogous to that shown in
According to various embodiments, other bus bars having varying widths are contemplated as being within the scope of the present invention. For example,
In addition, various embodiment of the bus bars 200, 300, 400, 500 may be dimensioned such that the patterns defined by the bus bars repeat more or less frequently along the length of the bus bars. For example, in various embodiments, the spacing between the first portions 201, 301, 401, 501 and fourth portions 204, 304, 404, 504—respectively—may be relatively short (e.g., 0.05% of the length of the wafer). In other embodiments, the spacing between the first portions 201, 301, 401, 501 and fourth portions 204, 304, 404, 504—respectively—may be relatively long (e.g., 50% of the length of the wafer).
In addition, various embodiments of the bus bars 600, 700, 800, 900, 1000 may be dimensioned such that the spacing between the segments defined by the bus bars may differ. For example, in various embodiments, the spacing between the bus bar segments 601, 701, 801, 901, 1001—respectively—may be relatively short (e.g., 0.05% of the length of the wafer). In other embodiments, the spacing between the bus bar segments 601, 701, 801, 901, 1001—respectively—may be relatively long (e.g., 50% of the length of the wafer).
As will be appreciated from the description herein, the bus bars 200, 300, 400, 500, 600, 700, 800, 900, and 1000 described above may be used on the surfaces of various solar cells and in various configurations (e.g., such that any appropriate number of bus bars may be provided on the front and/or back surfaces of the cell). According to various embodiments, the bus bars 200, 300, 400, 500, 600, 700, 800, 900, and 1000 are each configured such that an interconnecting ribbon (e.g., a metallic copper ribbon coated with tin) may be soldered along the length of each respective bus bar. In such embodiments, the portions of the ribbon soldered to the wider portions (201, 301, 401, 501, 601, 701, 801, 901, 1001) of the bus bars will have a strong connection to each bus bar (e.g., as compared to the strength of the ribbon's connection to the narrower, or spaced, portions of the bus bars). As each of the bus bars 200, 300, 400, 500, 600, 700, 800, 900, and 1000 vary in width (or have segments spaced from one another), a strong connection between the ribbon and the bus bar 100 may be achieved while also reducing material usage in the bus bars (e.g., the volume of silver used to form each bus bar). In this way, the bus bars 200, 300, 400, 500, 600, 700, 800, 900, and 1000 also enable a reduction in the overall cost of their associated solar cells without sacrificing high levels of electrical and mechanical performance.
Many modifications and other embodiments of the inventions set forth herein will come to mind to one skilled in the art to which these inventions pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the inventions are not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.