This application is the U.S. national phase of International Application No. PCT/IB2013/054816 filed Jun. 12, 2013 which designated the U.S. and claims priority to EP Patent Application No. 12172306.8 filed Jun. 15, 2012, the entire contents of each of which are hereby incorporated by reference.
The invention lies in the field of flexible tubes or pouches formed using plastic films. It relates more specifically to the flexible tubes or pouches of which the ends are butt-welded.
Many flexible tubes are made by welding the ends of a film containing at least one layer of plastic.
The butt welding of flexible films in order to form tubular packaging bodies is described in patent applications WO 2007/113781 and WO 2007/113782. Butt welding is advantageous in many cases, since this welding configuration makes it possible to improve the esthetics of the packagings owing to a decoration over the entire circumference of the tubular bodies. Butt welding also makes it possible to limit the interactions between the packaged product and the packaging since the possible migrations through the edge of the flexible film are very greatly reduced. By virtue of butt welding, the use of novel multilayer structures becomes possible. The multilayer packagings thus obtained have a greater delamination resistance.
The strength of the packaging at the butt-welded zone is often lower than the strength of the flexible film. This reduction in strength is even more critical with multilayer films that comprise non-butt welding layers. In order to overcome these difficulties, patent applications WO 2007/113781 and WO 2007/113782 propose the addition of a thin reinforcing strip at the butt weld.
Patent application EP 0 177 470 describes the use of a reinforcing strip welded to the inside of the tube and that joins the butt-welded ends of the film. It proposes a wide strip containing a thick aluminum foil that gives the plastic tube deformation behavior similar to that of an aluminum tube (no spring-back). This strip is at least equal to 10% of the circumference of the tube and mainly modifies the behavior of the tube (the rigidity) in the direction of the axis of the packaging. A tube produced according to patent application EP 0 177 470 has the major drawback that the packaged product is in contact with the aluminum layer of the reinforcing strip. The direct aluminum-product contact is generally avoided in the packaging field and mainly for liquid or pasty products packaged in tubes.
However, after tests and use of the flexible tubes manufactured according to the method described in patents WO 2007/113781, WO 2007/113782 and EP 0 177 470 it is observed that the repetitive deformation of the packaging in order to extract the product may create a fracture of the weld zone 6 and reveal the defect illustrated in
In the summary of the invention the following terms and abbreviations are used:
The invention consists in adding to the butt weld a reinforcing element that has the effect of making the weld zone non-deformable perpendicular to the welded ends without substantially modifying the flexibility of the weld zone in the tangential direction to the welded ends.
According to the invention, the reinforcing element added to the butt weld is invisible and imperceptible. It is invisible because it is located on the inside of the packaging. It is imperceptible because its small size does not significantly modify the flexibility of the packaging.
According to the invention, the reinforcing element added to the butt weld is made of plastic.
According to the invention, the weld zone is rendered non-deformable locally and in the direction perpendicular to the welded ends owing to the addition, inside of the packaging, of a reinforcing element which cannot be deformed under the action of the fingers in the direction perpendicular to the axis of the reinforcing element, and can be easily deformed in the direction of the reinforcing element.
Surprisingly, it has been found that a reinforcing element of very small size makes it possible to overcome the problem of brittleness of the weld zone. It has been found that the cross section of the reinforcing element defined by its width l and its height h depends on the thickness e of the packaging film and must comply with the following conditions:
Outside of these limits, it is found that the effect of the reinforcing element for protecting the weld is insufficient or, conversely, that the flexural rigidity of the reinforcing element along the main axis is too great and substantially modifies the flexibility of the packaging.
The invention consists of a tubular packaging formed from a butt-welded flexible film and comprising, at the weld, an invisible and imperceptible reinforcing element that joins the welded ends and prevents any stressing of the weld zone perpendicular to the welded ends.
More specifically, the invention consists of a tubular packaging body formed from a flexible film having a thickness e, the ends of which are butt-welded and covered by a plastic reinforcing element positioned on the inner surface of said tubular body and having a cross section defined by a width l and a height h, said tubular body being characterized in that all of the following conditions must be met:
Preferably, the height h of the reinforcing element is at most equal to two times the thickness e of the film.
More preferably, the following conditions must also be met:
More preferably still, the height h of the reinforcing element is 1.2 times equal to the thickness e of the film.
Preferably, l is between 1 and 3 mm.
The film may be a single-layer or multilayer film.
The invention is particularly advantageous when the multilayer film comprises layers which are not welded together or are only partially welded together such as for example layers of aluminum, EVOH, PA, PET, BOPP, paper, or cellulose-based products.
The invention is particularly advantageous when the layer that forms the outer surface of the packaging is not welded together or is only partially welded together. This is the case for example for multilayer films having, as outer surface, layers of PET, BOPP, paper, PA.
According to a first variant of the invention, the reinforcing element added to the inside of the packaging also substantially improves the impermeability properties of the weld zone such as for example the impermeability to oxygen, to aromas, to steam or else to solvents. Depending on the impermeability properties desired, the reinforcing element may be multilayer and/or contain oxygen absorbers.
The reinforcing element may comprise layers consisting of polyolefins, such as for example PE, PP and/or layers consisting of barrier polymers such as for example EVOH.
The oxygen absorbers may be, for example, organic polymers that operate via oxidation of iron, of ascorbic acid or of a polyamide catalyzed by cobalt; these products are standard on the market. These elements react with oxygen in order to limit the migration of the oxygen molecules to the inside of the packaging.
According to a second variant of the invention, the reinforcing element contains additives that make it possible to combat counterfeiting. These additives of microscopic or nanoscopic size do not modify the mechanical properties of the reinforcing element.
These additives are, for example, metal salts or else derivatives of crosslinked melamine particles or powders of micrometer or nanometer size. These additives, added in a very small amount to the plastic, are generally sold in the form of compounds or masterbatches and may be easily integrated into the process for manufacturing the reinforcing element 7. These products are sold for example by the companies Microtrace, Polysecure or Phoenix Plastics.
The first process for producing the tubular packaging body according to the invention consists in forming the reinforcing element together with the butt weld of the flexible film. In one preferred embodiment, a bead of plastic is extruded and deposited in the melt state on the ends of the flexible film; the thermal energy contained in the bead is used to weld the bead to the flexible film and to at least partially weld the ends of the flexible film to one another; and finally the bead is shaped by a suitable tool in order to form the reinforcing element according to the dimensions defined in the invention.
A second process consists in welding a previously manufactured plastic reinforcing element to the ends of the flexible film. The welding of the reinforcing element to the face of the flexible film that forms the inner wall of the packaging is carried out together with the butt welding of the flexible film. In one preferred embodiment, the bead is preheated before the welding operation.
In one variant of the invention, the process is advantageously coupled with a beveled cutting of the ends of the flexible film in order to facilitate the butt welding. The beveled cutting of the welded ends of the flexible film makes it possible to increase the contact area and the pressurization of the weld zone. According to one preferred embodiment of the invention, a cutting angle of 45° with respect to the surface of the film is used.
The invention will be better understood with the aid of the description of embodiments of these and the following figures in which:
The invention consists of a novel butt welding configuration for a flexible film that consists in adding to the inside of the packaging a plastic reinforcing element of small size that joins the welded ends of the flexible film; said reinforcing element having the effect of preventing any deformation of the weld zone perpendicular to the welded ends; and said reinforcing element having a geometry such that the flexibility of the weld zone in the direction tangential to the welded ends is not substantially modified.
The reinforcing element has the effect of preventing the modification of the radius of curvature of the packaging at the butt-welded zone.
It should be noted that in EP 0 177 470, the ratio (l·e)/h2 is not between 1 and 10. Indeed, generally, the diameter of packaging tubes for example for toothpaste or cosmetics lies between 28 and 50 mm. A calculation of the minimum and maximum ratio for reasonable combinations that can be achieved in EP 0 177 470 is described in detail below:
Theoretical Strip:
Theoretical Film:
The reasonable combinations A and B are the following:
A) Strip having a maximum height h of 300 μm and film having a maximum thickness e of 140 μm,
B) Strip having a minimum height h of 60 μm and film having a minimum thickness e of 25 μm.
Thus, the maximum ratio (l·e)/h2 for combination A is equal to (15 700×140)/3002=24.4 and the minimum ratio (l·e)/h2 for combination B is equal to (8790×25)/602=61.0.
These calculations of the ratio (l·e)/h2 for tubes as described in EP 0 177 470 demonstrate that the ratio (l·e)/h2 is not between 1 and 10.
As is illustrated in
The effect of the reinforcing element 7 on the strength of the weld is illustrated in
The multilayer film illustrated in
It is often advantageous to use the reinforcing element 7 in order to jointly improve the strength of the weld and its impermeability properties. The use of a reinforcing element that is a multilayer reinforcing element and/or that contains oxygen absorbers makes it possible to also improve the impermeability of the weld zone to oxygen for example. The combination of an aluminum layer in the flexible film with a reinforcing element that is a multilayer reinforcing element or that contains oxygen absorbers makes it possible to manufacture packagings having very high impermeability. A multilayer reinforcing element will advantageously comprise a thin layer of EVOH or another barrier polymer.
The reinforcing element 7 is advantageously used for jointly improving the strength of the weld and protection of the packaging against counterfeiting. The reinforcing element 7 may contain additives in the form of nanoparticles such as metal salts or oxides or else multilayer microadditives for which the combinations of layers and colors may give more than 37 million unique codes.
Several processes for making the packaging according to the invention may be envisaged.
A first process consists in extruding a bead of plastic and depositing it in the melt state on the ends of the flexible film. The heat contained in the bead is used to weld the bead to the layer 5 of the flexible film, and to at least partially butt weld the ends of the flexible film. The bead is then shaped using a tool of suitable geometry in order to form the reinforcing element, the cross section of which corresponds to the dimensions defined in the invention. During the extrusion, the geometry of the bead is cylindrical; said cylindrical bead is deposited in the melt state on the ends of the flexible film; a portion of the heat contained in the cylindrical bead is transferred to the flexible film at the ends; said bead is shaped and pressed against the surface of the flexible film in order to form the reinforcing element 7, the cross section of which corresponds to the description given in the invention; the profiled element, and also the weld zone 6, are cooled.
The deposition of the bead in the melt state is carried out by virtue of a relative movement between the extrusion device and the flexible film. Preferably, the extrusion device is fixed and the packaging moves at constant speed with respect to said extrusion device. The shaping operation of the reinforcing element is carried out by pressure of the bead in a shaping tool. In a first example, the shaping tool is fixed with respect to the bead and the flexible film. The bead in the melt state is pressed against the shaping tool that comprises a groove, the cross section of which corresponds to the cross section of the reinforcing element. Preferably, the shaping tool is maintained at a temperature below that of the bead, which has the effect of cooling the reinforcing element at the same time or immediately after its formation. In a second example, the shaping tool moves together with the bead in the melt state in order to prevent friction during the shaping operation of the reinforcing element. The shaping tool may be a wheel comprising a groove on its periphery, the cross section of which corresponds to the cross section of the reinforcing element. The tangential speed of the wheel at the interface with the flexible film is equal to the rate of travel of the flexible film. In one preferred embodiment, the wheel is rotated by the movement of the flexible film.
A second process for producing the weld is based on the extrusion of a bead, the cross section of which is close to the cross section of the reinforcing element, then in shaping the final geometry of the reinforcing element according to the first process.
A third process for producing the weld is based on the use of a previously manufactured reinforcing element 7, then in the joining thereof to the abutted ends of the flexible film 2. One preferred embodiment of the third process consists in welding the reinforcing element 7 to the flexible film 2 at the same time as the operation for butt welding the ends of the flexible film 2.
Here are some examples of the packaging structure and of the geometry of reinforcing elements produced according to the invention:
Description of the Multilayer Film of the First Example:
Description of the Reinforcing Element of the First Example:
Description of the Multilayer Film of the Second Example:
Description of the Reinforcing Element of the Second Example:
Description of the Multilayer Film of the Third Example:
Description of the Reinforcing Element of the Third Example:
Description of the Multilayer Film of the Fourth Example:
Description of the Reinforcing Element of the Fourth Example:
Description of the Multilayer Film of the Fifth Example:
Description of the Reinforcing Element of the fifth Example:
Description of the Single-Layer Film of the Sixth Example:
Description of the Reinforcing Element of the Sixth Example:
Description of the Multilayer Film of the Seventh Example:
Description of the Reinforcing Element of the Seventh Example:
The invention is particularly advantageous since it makes it possible to produce packagings by butt welding films that combine welding layers and layers which are not butt welded. The invention makes it possible to butt join the ends of a film of which the ends are partially welded.
The invention makes it possible to obtain welded packagings with a very high strength at the weld zone. The packagings obtained may be printed over their entire surface without a break in the printing in the weld zone. The invention makes it possible to obtain packagings of great strength and improved esthetics.
The invention is particularly advantageous for producing packaging tubes. The invention also has numerous advantages for the production of flexible packaging pouches.
The description of the invention has been given with flexible films comprising three layers. In this description, the thin adhesive layers that are essential for the cohesion of the multilayer film have been deliberately excluded from the description so as not to complicate the summary of the invention. It is also obvious for a person skilled in the art that the invention is not limited to flexible films comprising one to three layers; the number of layers not being a limiting factor of the invention.
Number | Date | Country | Kind |
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12172306.8 | Jun 2012 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/IB2013/054816 | 6/12/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2013/186723 | 12/19/2013 | WO | A |
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0 177 470 | Apr 1986 | EP |
2 511 089 | Oct 2012 | EP |
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Number | Date | Country | |
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20150132517 A1 | May 2015 | US |