Button cell having winding electrode and method for the production thereof

Information

  • Patent Grant
  • 10804506
  • Patent Number
    10,804,506
  • Date Filed
    Wednesday, February 15, 2017
    7 years ago
  • Date Issued
    Tuesday, October 13, 2020
    4 years ago
Abstract
A button cell includes a housing consisting of two metal housing halves, an electrode separator assembly in the form of a preferably spiral-shaped winding inside the housing, and metal conductors which electrically connect the electrodes of the assembly to the housing halves, wherein at least one of the conductors is connected to the respective housing half by welding.
Description
TECHNICAL FIELD

This disclosure relates to button cells having a housing consisting of two metal housing halves that contains a wound electrode separator assembly, and to a method for its production.


BACKGROUND

Button cells conventionally comprise a housing consisting of two housing halves: a cell cup and a cell top. These may, for example, be produced as stamped parts from nickel-plated deep-drawn sheet metal. Usually, the cell cup is positively poled and the housing top negatively poled. The housing may contain a very wide variety of electrochemical systems, for example, zinc/MnO2, primary and secondary lithium systems, or secondary systems such as nickel/cadmium or nickel/metal hydride.


The liquid-tight closure of button cells is conventionally carried out by crimping the edge of the cell cup over the edge of the cell top, in combination with a plastic ring which is arranged between the cell cup and the cell top and is used simultaneously as a sealing element and for electrical insulation of the cell cup and the cell top. Such button cells are described, for example, in DE 31 13 309.


As an alternative, however, it is also possible to manufacture button cells in which the cell cup and the cell top are held together in the axial direction exclusively by a force-fit connection, and which correspondingly do not have a crimped cup edge. Such button cells and a method for their production are described in unpublished German patent application 10 2009 017 514.8. Regardless of the various advantages which such button cells without crimping may present, they nevertheless cannot withstand such high stresses in the axial direction as comparable button cells with a crimped cup edge, especially as regards axial mechanical loads which originate from inside the button cell. For example, the electrodes of rechargeable lithium ion systems are constantly subjected to volume changes during charging and discharging processes. In button cells without crimping, the axial forces occurring in this case can naturally cause leaks more easily compared with button cells with crimping.


A solution to this problem may be found in unpublished German patent applications 10 2009 030 359.6 and 10 2009 008 859.8. Inter alia, references may be found therein to button cells comprising a housing having a plane bottom region and a plane top region parallel thereto, an assembly consisting of flat electrode layers and separator layers in the form of a preferably spiral-shaped electrode winding being arranged in the housing such that the end sides of the winding face in the direction of the plane bottom region and the plane top region. The electrode layers of the winding are thus oriented essentially orthogonally to the plane bottom and top regions of the housing. As a result of this, radial forces such as occur during the aforementioned charging and discharging processes of lithium ion systems can in principle be absorbed better than in the case of conventional lithium ion button cells, in which electrode layers are arranged stacked in parallel alignment with the plane bottom and top regions.


Windings consisting of flat electrode layers and separator layers can be produced quite straightforwardly using known methods (see, for example, DE 36 38 793) by the electrodes being applied, in particular laminated, particularly in the form of strips, flat onto a separator provided as an endless band. The assembly consisting of the electrodes and separators is generally wound on a so-called “winding mandrel.” After the winding has been removed from the winding mandrel, an axial cavity is left at the center of the winding, the effect of which is that the winding may possibly expand into this cavity. This, however, can sometimes lead to problems in the electrical contact of the electrodes with the metal housing halves.


It could therefore be helpful to provide a button cell in which the aforementioned problems do not occur, or only occur to a greatly reduced extent.


SUMMARY

I provide a button cell including two metal housing halves separated from one another by an electrically insulating seal forming a housing having a plane bottom region and a plane top region parallel thereto, an electrode separator assembly including at least one positive electrode and at least one negative electrode inside the housing, the assembly provided in the form of a winding, end sides of which face in a direction of the plane bottom region and the plane top region, and metal conductors electrically connected to the at least one positive electrode and the at least one negative electrode, respectively, to one of the housing halves, wherein at least one of the conductors is connected to the respective housing half by welding wherein weld beads and/or weld spots pass through the housing.


I also provide a method of producing button cells including (a) providing a first and a second metal housing half, (b) placing an electrode separator assembly including a positive electrode and a negative electrode in one of the housing halves, wherein a metal conductor is bonded to at least one of the electrodes, (c) assembling the two housing halves, and, subsequently, (d) laser welding at least one of the conductors to the inner side of one of the metal housing halves.


I further provide a button cell including two metal housing components separated from one another by an electrically insulating seal forming a housing having a substantially planar bottom region and a substantially planar top region substantially parallel thereto, an electrode separator assembly including at least one positive electrode and at least one negative electrode inside the housing, the assembly provided as a winding, end sides of which face in a direction of the substantially planar bottom region and the substantially planar top region such that layers of the winding are oriented essentially orthogonally to the substantially planar bottom region and substantially planar top region, and metal conductors electrically connected to the at least one positive electrode and the at least one negative electrode and, respectively, to one of the housing components, wherein the button cell has a height-to-diameter ratio less than one, at least one of the conductors is a metal foil and at least one subsection of the at least one conductor bears flat on an inner side of the housing components in the substantially planar bottom or top region of the housing and the at least one conductor connects to the housing in this region by one or more spot-shaped and/or linear welded connections.


I yet further provide a method of producing the button cell, including (a) providing a first and a second metal housing component, (b) placing the electrode separator assembly including the positive electrode and the negative electrode in one of the housing components, the metal conductor being bonded to at least one of the electrodes, (c) assembling the two housing components, optionally with a separate step of sealing the housing, and (d) welding at least one of the conductors to the inner side of one of the metal housing components, wherein step (d) is carried out after step (c).





BRIEF DESCRIPTION OF THE DRAWINGS


FIGS. 1A and 1B schematically show a cross section of a preferred example of a button cell 100.



FIGS. 2A to 2C schematically show selected assembly steps of the button cell of FIGS. 1A and 1B.



FIGS. 3A and 3B schematically show selected views of windings of the button cell.



FIGS. 4A and 4B schematically show two different welds.



FIG. 5 shows microphotographs of a weld from top and cross-sectional views.





DETAILED DESCRIPTION

My button cell always comprises two metal housing halves separated from one another by an electrically insulating seal and forming a housing having a plane bottom region and a plane top region parallel thereto. As mentioned in the introduction, the two housing halves are generally a so-called “housing cup” and a “housing top.” In particular, nickel-plated steel or sheet metal are preferred as the material for the housing halves. Trimetals, in particular, are furthermore suitable as the metallic material, for example, ones comprising the sequence nickel, steel (or stainless steel) and copper (in which case the nickel layer preferably forms the outer side of the button cell housing and the copper layer preferably forms the inner side).


As the seal, it is, for example, possible to use an injection-molded seal or a film seal. The latter are described, for example, in DE 196 47 593.


At least one positive electrode and at least one negative electrode are arranged inside the housing, specifically each in the form of flat electrode layers. The electrodes are preferably connected to one another by at least one flat separator. The electrodes are preferably laminated or adhesively bonded onto this separator. The electrodes and the separator generally each have a thickness only in the μm range. A porous plastic film is generally used as the separator.


This assembly is provided in the form of a winding, particularly in the form of a spiral-shaped winding, in the housing of a button cell, the winding being arranged such that its end sides face in the direction of the plane bottom region and the plane top region of the housing. Full reference is hereby made to the description of such windings, and button cells comprising such windings, in unpublished German patent applications DE 10 2009 030 359.6 and DE 10 2009 008 859.8 already mentioned above. All the preferred forms described in those applications are also intended to apply for the button cell described here and the electrode winding described here.


Besides the housing halves and the electrode separator assembly, my button cell always also comprises metal conductors which electrically connect the at least one positive electrode and/or the at least one negative electrode respectively to one of the housing halves. The conductor or conductors connected to the at least one positive electrode preferably consist of aluminum. The conductors connected to the at least one negative electrode preferably consist of nickel or copper.


On the electrode side, the conductors are preferably connected to current collectors. The latter are generally metal foils or meshes conventionally coated on both sides with active electrode material. These current collectors preferably consist of aluminum on the side of the positive electrode, and preferably nickel or copper on the side of the negative electrode. The foils or meshes have, in particular, thicknesses of 1 μm to 100 μm. The connecting of the conductors to the current collectors is preferably carried out by welding.


Particularly in respect of preferred forms of the electrode separator assembly arranged in my button cell, reference is made to DE 10 2009 030 359.6 and DE 10 2009 008 859.8. These disclose in particular preferred layer sequences and layer thicknesses for electrodes and separators, for example, an assembly comprising the layer sequence:

    • negative electrode/separator/positive electrode/separator or
    • positive electrode/separator/negative electrode/separator.


Assemblies comprising the layer sequences:

    • negative electrode/separator/positive electrode/separator/negative electrode or
    • positive electrode/separator/negative electrode/separator/positive electrode may also be preferred. In these, the assembly therefore comprises more than one positive electrode and/or more than one negative electrode.


Particularly preferably, at least one of the electrodes of a button cell is a lithium intercalation electrode. The button cell is preferably a lithium ion battery, in particular a secondary lithium ion battery.


My button cell is distinguished particularly in that at least one of the conductors is welded to the respective housing half, preferably both the conductor connected to the at least one positive electrode and the conductor connected to the at least one negative electrode.


As has already been mentioned in the introduction, particularly in the case of lithium ion button cells the electrodes are subject to volume changes during a charging-discharging cycle, as a result of which contact problems may arise between the conductors and the housing halves. Such contact problems no longer apply when the conductors are welded to the respective housing halves.


Particularly preferably, the conductor or conductors are welded onto the inner side of the housing in the plane bottom region or the plane top region, respectively, of the housing. For this purpose, according to conventional methods the welding process must be carried out before the housing is assembled, which is very difficult to achieve in terms of production technology. Welded connections have therefore been regarded as highly disadvantageous for bonding the conductors to the inner side of the housing halves. By virtue of my method as described in more detail below, however, a solution can be provided which also has great advantages in terms of production technology.


By the welding, the at least one positive electrode and/or the at least one negative electrode are thus connected by one or more conductors directly to the plane bottom region or to the plane top region of the housing of a button cell, the housing top generally being poled negatively and the housing cup positively.


The button cell is preferably a conventional button cell having a circular plane bottom region and a circular plane top region. In some cases, the button cell may nevertheless have an oval configuration. It is, however, important that the ratio of height to diameter is preferably always less than 1. Particularly preferably, it is 0.1 to 0.9, in particular 0.15 to 0.7. The height is in this case intended to mean the shortest distance between the plane bottom region and the plane top region parallel thereto. The diameter means the maximum distance between two points on the lateral region of the button cell.


Preferably, the conductors of a button cell are flat conductors, in particular metal foils, particularly preferably rectangular, strip- or band-shaped metal foils. The foils preferably have thicknesses of 5 μm to 100 μm.


The conductors are preferably separate components bonded, in particular welded, to the electrodes, in particular to the current collectors in the electrodes. As an alternative, however, the conductors may also be uncoated sections of a current collector (sections which are free of active electrode material), in particular the uncoated ends of such a current collector. By bending these uncoated sections, in particular these uncoated ends, for example, through 90°, these ends can be connected to the bottom or top region of a button cell. There, the connecting is preferably carried out by welding.


Preferably, at least one subsection of the conductor or conductors bears flat on the inner side of the housing half or halves in the bottom and/or top region of the housing, in particular when the conductors are flat conductors such as foils. Such conductors may form a flat layer between the inner side of the housing halves and an end side of the electrode winding, and therefore a large-area electrical contact with the housing.


Since in principle both positive and negative electrodes may be exposed on the end sides of the electrode winding, however, it is necessary to avoid a short circuit between the electrodes. Particularly preferably, my button cell therefore comprises at least one separate insulating means which prevents direct electrical contact between the end sides of the winding and the conductors, in particular a subsection of the conductor or conductors which bears flat on the inner side of the housing halves. Such an insulating means may, for example, be a film, for example, a plastic adhesive film, by which the side of the conductor or conductors remote from the inner side of the button cell housing is covered.


The electrode winding of a button cell may be produced by known methods, for example, the method described in DE 36 38 793, according to which electrodes and separators are wound on a winding mandrel. After the winding has been removed from the winding mandrel, there may be an axial cavity at the center of the winding, preferably an essentially cylindrical axial cavity. In the housing of my button cell, such a cavity is delimited laterally by the winding and on the end sides by the bottom or top region of the housing, respectively, or at least by a subregion thereof. Particularly preferably, the at least one conductor is welded to one housing half or the housing halves in one of these subregions.


The axial cavity may optionally contain a winding core, which can prevent the winding from expanding uncontrolledly into the cavity.


The button cell is in particular a button cell without crimping, as is described in DE 10 2009 017 514.8 already mentioned in the introduction. Accordingly, there is preferably an exclusively force-fit connection between the housing halves. The button cell thus does not have a crimped cup edge, as is always the case with known button cells. The button cell is closed without crimping. The content of DE 10 2009 017 514.8 is also fully incorporated herein by reference. All the preferred forms described in that application are also intended to apply for the button cell described here and its housing.


As already mentioned above, welding of conductors to the inner side of button cell housings is very elaborate in terms of production technology. I overcome this problem with my method of producing button cells, which always comprises at least the following steps:

    • (a) providing a first and a second metal housing half (preferably a cell cup, and a cell top),
    • (b) placing an electrode separator assembly comprising a positive electrode and a negative electrode in one of the housing halves (preferably into the cell top), a metal conductor being bonded to at least one of the electrodes (preferably to all the electrodes),
    • (c) assembling the two housing halves (preferably by inserting the cell top into the cell cup), optionally with the provision of separate steps for sealing the housing (for example, fitting a seal) and
    • (d) welding at least one of the conductors to the inner side of one of the metal housing halves.


The components used in the method, such as the housing halves, the conductors and the electrode separator assembly, have already been described above. Reference is hereby made to the corresponding remarks.


The method is distinguished in particular in that step (d) is carried out after step (c). This means that the at least one conductor is welded to the inner side of the housing when the housing is closed. The welding must correspondingly be carried out from the outside through the housing wall of one or both housing halves.


Accordingly, I provide button cells which have weld beads and/or weld spots that pass through the housing, in particular starting from its outer side.


Particularly preferably, the conductor or conductors and the button cell housing are connected to one another by one or more spot-like and/or linear welded connections.


Welding the conductors and the housing is preferably carried out by a laser. Its operating parameters must be adapted as accurately as possible to the thickness of the housing. The power may, for example, be modulated by varying the pulse frequency. Lastly, the laser should merely ensure welding of the housing and conductors while other components such as the electrode winding should as far as possible not be damaged.


Suitable lasers are, for example, commercially available fiber lasers, i.e., solid-state lasers, in which the doped core of a glass fiber forms the active medium. The most common dopant for the laser-active fiber core is erbium. For high-power applications as in the present case, however, ytterbium and neodymium are more preferred.


Irrespective of the fact that such lasers can be adapted very finely to the respective housing thickness and conductor dimension, it is nevertheless possible that in certain cases the intensity of the laser will be selected to be too strong and the laser will penetrate through the housing wall and the conductor. For this reason, welding the conductors to the housing is particularly preferably carried out in the subregion of the bottom or top region, which delimits the axial cavity at the center of the winding on the end side. If a laser beam penetrates through the housing in this region, the winding cannot be damaged. Instead, the laser beam will be absorbed by the housing half lying opposite or by a winding core optionally arranged inside the cavity.


If possible, the conductors to be welded should bear as flatly as possible on the inner side of the housing. This may, for example, be ensured by fixing the conductors flat by an adhesive tape onto or at the end sides of an electrode winding, before the latter is inserted into the housing.


The aforementioned advantages, and further advantages thereof, are in particular also revealed by the description which now follows of the drawings. In this context, the individual features may be implemented separately or in combination with one another. The examples described merely serve for explanation and better understanding, and are in no way to be interpreted as restrictive.


Button cell 100 comprises two metal housing halves: a metal cup part 101 and a metal top part 102. With a seal 103 lying between them, the two parts are connected together in a leaktight fashion. Together, they form a housing having a plane bottom region 104 and a plane top region 105 parallel thereto. In the functional state, these two plane regions 104 and 105 form the poles of the button cell 100, from which current can be drawn by a load. The cell top 102 is inserted into the cell cup 101 so that the lateral surface regions of the cell top and the cell cup overlap, the internal radius of the cell cup 101 in the overlap region 106 being essentially constant in the direction of the rim 107. The edge of the cell 101 is thus not crimped. The button cell 100 is therefore an uncrimped button cell.


An assembly 108 of strip-shaped electrodes and strip-shaped separators is arranged inside the electrode. The assembly 108 is provided in the form of a spiral-shaped winding, the end sides of which face in the direction of the plane bottom region 104 and the plane top region 105 parallel thereto. The assembly is wound on the winding core 109 at the center of the button cell 100. The winding core is a hollow plastic cylinder, which partially fills an axial cavity at the center of the winding. The cavity itself is delimited laterally by the winding and upward and downward by corresponding circular sections of the plane cup and top regions of the button cell housing. Metal foils 110 and 111, which act as conductors and are connected to the electrodes, bear flat on these regions. These conductors are shielded from the end sides of the winding by the insulating elements 112 and 113. The latter are thin plastic films. The wall thickness of the housing in the region of the plane bottom or top region is generally between 30 μm and 400 μm. The thickness of the metal foils 110 and 111 acting as conductors generally lies between 5 μm and 100 μm.


Welding of the metal foils 110 and 111, acting as conductors, to the respective housing half, which is preferably done by the schematically represented laser 114, is preferably carried out in that subregion of the bottom region or of the top region of the button cell housing which delimits the axial cavity at the center of the winding on the end side. This creates a weld bead 115 which passes fully through the housing of the button cell 100 from the outside inward, and by which the internally lying metal foils 110 and 111 acting as conductors are firmly connected to the inner side of the housing. This can be seen clearly in the detail enlargement (FIG. 1B).



FIG. 2A to FIG. 2C represent some important steps in the production of an electrode winding, which is suitable in particular for button cells (for example, as represented in FIGS. 1A and 1B). Thus, FIG. 2A shows segmented collector foils 201 and 202 coated with active electrode material, to which conductor strips 203 and 204 offset at an angle of 90° are attached by welding. The conductor 204 on the anode side consists of nickel or copper, and the conductor 203 on the cathode side of aluminum. The conductors 203 and 204 are respectively applied in a material-free region (205, 206) of the collector foils 201 and 202. Elsewhere, they are coated with active material on both sides. The connection between the collector foils 201 and 202 and the conductors may, for example, be produced by welding in the region 211.



FIG. 2B and FIG. 2C represent the way in which the rear sides of the conductors 203 and 204 are adhesively bonded using an insulating tape 207 and 208 (for example, made of KAPTON or polypropylene) (Step 2). This insulating tape is subsequently intended to function as an insulating element, which is meant to prevent direct electrical contact between the conductors 203 and 204 and the end sides of the electrode winding which is to be produced. The conductors 203 and 204 are fixed on the front in a further step (Step 3) with further adhesive strips 209 and 210. The region 211 is bonded over in this case.


The conductor position in a winding of electrode foils obtained according to FIG. 2A to FIG. 2C can be seen clearly in FIG. 3A. Two different perspective representations of the same winding are shown (left and right). The conductor 301 (which corresponds to the conductor 204 in FIGS. 2A and 2C) and the conductor 302 (which corresponds to the conductor 203 in FIGS. 2A and 2B) are themselves aligned axially at a 90° angle to the winding direction and by folding down by 90° bear flat on the end sides 303 and 304 of the electrode winding. The insulating elements 305 and 306 (which correspond to the insulating tapes 207 and 208 in FIGS. 2B and 2C) prevent direct electrical contact between the conductors 301 and 302 and the end sides 303 and 304 of the electrode winding represented. The outer side of the winding is protected by the insulating film 307. Ideally, the conductors 301 and 302 overlap with the openings of the axial cavity 308 on the end sides, so that welding to the button cell housing can be carried out in this region. This can be seen clearly in FIG. 3B, as can the winding core 309 which fills the axial cavity 308.



FIGS. 4A and 4B show possible welding variants. For example, it is possible to configure the weld bead as a minus sign 401 or a plus sign 402 (see the respective enlarged representations on the right) so as to indicate the polarity of the respective housing half at the same time. The plus sign 402 is preferably applied on the lower side 404 of a button cell, and the minus sign on the upper side 403.



FIG. 5 shows an enlarged representation of a cross section through a housing half 500 of a button cell. The stainless steel cup wall 501, the aluminum conductor 502 bearing flat underneath and an insulating tape 503 of KAPTON film arranged below can be seen. The weld beads 504 and 505, which extend from the outer side of the housing inward as far as the insulating tape 503 of KAPTON film can be seen clearly. The top left image is a plan view of the cutaway plane bottom region of the housing half 500. The housing half 500 and the conductor 502 have been welded using an ytterbium-doped fiber laser of the YLR-400-AC type (manufacturing company IPG Photonics Corporation, USA). The intensity of the laser was in this case adjusted so that the insulating tape 503 was not penetrated.

Claims
  • 1. A rechargeable button cell comprising: a housing including metal housing halves separated from one another by an electrically insulating injection-molded seal or film seal, one of the housing halves including a planar bottom region and another housing half including a planar top region substantially parallel to the planar bottom region, the housing having a height-to-diameter ratio of less than one;an electrode separator assembly comprising a positive electrode and a negative electrode disposed inside the housing, wherein the electrode separator assembly is in the form of a winding, end sides of the winding respectively facing in directions of the planar bottom region and the planar top region such that layers of the electrode separator assembly are oriented essentially orthogonally to the planar bottom region and the planar top region of the housing, the winding having a substantially centrally located axis and an open cavity extending along the axis interiorly of the winding, the open cavity having axially spaced opposite ends, the planar top and bottom regions of the housing each having a subregion, each subregion disposed both radially and axially adjacent one of the ends of the open cavity, the positive electrode and the negative electrode each including a current collector in the form of a metal foil or a metal mesh coated on both sides with active electrode material, and each of the current collectors comprises an uncoated section;two metal foils functioning as conductors and electrically connecting the positive and the negative electrode to the housing halves, wherein both metal foils bear flat on an inner surface of the planar bottom region or the planar top region, one of the metal foils is attached by a weld to one of the uncoated sections and one of the planar bottom and top regions, another one of the metal foils is attached by a weld to another one of the uncoated sections and to another one of the planar bottom and top regions; andat least one insulator disposed to prevent direct electrical contact between one of the metal foil conductors and an adjacent one of the end sides of the electrode separator assembly,wherein the button cell is configured as a secondary lithium ion cell, and the open cavity includes no winding core.
  • 2. The button cell according to claim 1, further comprising an insulating tape adhesively bonded to a side of the one of the metal foil conductors.
  • 3. The button cell according to claim 1, wherein the metal foil connected to the planar bottom region is connected to the bottom region by one or more spot-shaped and/or linear welded connections.
  • 4. The button cell according to claim 3, wherein the welded connection is disposed at the subregion of the planar bottom region.
  • 5. The button cell according to claim 3, wherein the welded connection is disposed at the subregion of the planar top region.
  • 6. The button cell according to claim 1, wherein the metal foil connected to the planar top region is connected to the top region by one or more spot-shaped and/or linear welded connections.
  • 7. The button cell according to claim 1, wherein the metal foil connected to the planar bottom region is aligned axially at a 90° angle to the winding direction and folded down by 90° to bear flat on an end side of the winding.
  • 8. The button cell according to claim 7, wherein the metal foil connected to the planar top region is aligned axially at a 90° angle to the winding direction and folded down by 90° to bear flat on an end side of the winding.
  • 9. The button cell according to claim 1, wherein an outer side of the winding is protected by an insulating film.
  • 10. The rechargeable button cell according to claim 1, wherein the housing halves are a first and a second housing half,the second housing half comprises an edge defining an opening,the first housing half is inserted into the second housing half so that lateral surface regions of the two housing halves overlap, andthe edge of the second housing half is not crimped over an edge of the first housing half to provide liquid-tight closure of the cell.
  • 11. A rechargeable button cell comprising: a housing including metal housing halves separated from one another by an electrically insulating injection-molded seal or film seal, one of the housing halves including a planar bottom region and another housing half including a planar top region substantially parallel to the planar bottom region, the housing having a height-to-diameter ratio of less than one;an electrode separator assembly comprising a positive electrode and a negative electrode disposed inside the housing, wherein the electrode separator assembly is in the form of a winding, end sides of the winding respectively facing in directions of the planar bottom region and the planar top region such that layers of the electrode separator assembly are oriented essentially orthogonally to the planar bottom region and the planar top region of the housing, the winding having a substantially centrally located axis and an open cavity extending along the axis interiorly of the winding, the open cavity having axially spaced opposite ends, the planar top and bottom regions of the housing each having a subregion, each subregion disposed both radially and axially adjacent one of the ends of the open cavity, the positive electrode and the negative electrode each including a current collector in the form of a metal foil or a metal mesh coated on both sides with active electrode material, and each of the current collectors comprises an uncoated section;two metal foils functioning as conductors and electrically connecting the positive and the negative electrode to the housing halves, wherein both metal foils bear flat on an inner surface of the planar bottom region or the planar top region, one of the metal foils is attached by a weld to one of the uncoated sections and one of the planar bottom and top regions, another one of the metal foils is attached by a weld to another one of the uncoated sections and to another one of the planar bottom and top regions; andat least one insulator disposed to prevent direct electrical contact between one of the metal foil conductors and an adjacent one of the end sides of the electrode separator assembly, wherein the button cell is configured as a secondary lithium ion cell, and the open cavity is defined at an outer lateral extent thereof by an inner region of the winding, the open cavity being laterally unobstructed by a winding core; andthe metal foils have a thickness of 5 μm to 100 82 m.
  • 12. The button cell according to claim 11, further comprising an insulating tape adhesively bonded to a side of the one of the metal foil conductors.
  • 13. The button cell according to claim 11, wherein the metal foil connected to the planar bottom region is connected to the bottom region by one or more spot-shaped and/or linear welded connections.
  • 14. The button cell according to claim 13, wherein the welded connection is disposed at the subregion of the planar bottom region.
  • 15. The button cell according to claim 13, wherein the welded connection is disposed at the subregion of the planar top region.
  • 16. The button cell according to claim 11, wherein the metal foil connected to the planar top region is connected to the top region by one or more spot-shaped and/or linear welded connections.
  • 17. The button cell according to claim 11, wherein the metal foil connected to the planar bottom region is aligned axially at a 90° angle to the winding direction and folded down by 90° to bear flat on an end side of the winding.
  • 18. The button cell according to claim 11, wherein the metal foil connected to the planar top region is aligned axially at a 90° angle to the winding direction and folded down by 90° to bear flat on an end side of the winding.
  • 19. The button cell according to claim 11, wherein an outer side of the winding is protected by an insulating film.
  • 20. The rechargeable button cell according to claim 11, wherein the housing halves are a first and a second housing half,the second housing half comprises an edge defining an opening,the first housing half is inserted into the second housing half so that lateral surface regions of the two housing halves overlap, andthe edge of the second housing half is not crimped over an edge of the first housing half to provide liquid-tight closure of the cell.
Priority Claims (2)
Number Date Country Kind
10 2009 030 359 Jun 2009 DE national
10 2009 060 800 Dec 2009 DE national
RELATED APPLICATIONS

This is a divisional application of U.S. application Ser. No. 13/378,117 filed Dec. 14, 2011, which is a § 371 of International Application No. PCT/EP2010/058637, with an international filing date of Jun. 18, 2010 (WO 2010/146154 A2, published Dec. 23, 2010), which is based on German Patent Application Nos. 10 2009 030 359.6, filed Jun. 18, 2009, and 10 2009 060 800.1, filed Dec. 31, 2009, the subject matter of which is incorporated by reference.

US Referenced Citations (155)
Number Name Date Kind
3069489 Carmichael et al. Dec 1962 A
3748182 Brown Jul 1973 A
3827916 Fagan, Jr. Aug 1974 A
3960599 Reynier et al. Jun 1976 A
4053687 Coibion et al. Oct 1977 A
4091181 Merritt, Jr. May 1978 A
4220695 Ishida et al. Sep 1980 A
4224387 Nakayama Sep 1980 A
4262064 Nagle Apr 1981 A
4321316 Kuehl Mar 1982 A
4487819 Koga Dec 1984 A
4520085 Wyser May 1985 A
4539271 Crabtree Sep 1985 A
4554226 Simonton Nov 1985 A
4664989 Johnson May 1987 A
4927719 Ashihara et al. May 1990 A
5128219 Kohler et al. Jul 1992 A
5273842 Yamahira et al. Dec 1993 A
5356736 Kita et al. Oct 1994 A
5378560 Tomiyama Jan 1995 A
5432027 Tuttle et al. Jul 1995 A
5470357 Schmutz et al. Nov 1995 A
5567538 Oltman et al. Oct 1996 A
5603737 Marincic et al. Feb 1997 A
5626988 Daniel-Ivad et al. May 1997 A
5631104 Zhong et al. May 1997 A
5639569 Köhler et al. Jun 1997 A
5698340 Xue et al. Dec 1997 A
5792574 Mitate et al. Aug 1998 A
5912091 Daio et al. Jun 1999 A
5964902 Mao et al. Oct 1999 A
6042625 Daio et al. Mar 2000 A
6045944 Okada et al. Apr 2000 A
6066184 Brenner May 2000 A
6143440 Volz et al. Nov 2000 A
6221524 Andrew et al. Apr 2001 B1
6245452 Oltman Jun 2001 B1
6265100 Saaski et al. Jul 2001 B1
6277522 Omaru et al. Aug 2001 B1
6277752 Chen Aug 2001 B1
6287719 Bailey Sep 2001 B1
6312848 Kilb et al. Nov 2001 B1
6443999 Cantave et al. Sep 2002 B1
6468691 Malay et al. Oct 2002 B1
6495293 Arai et al. Dec 2002 B1
6516266 Shoji Feb 2003 B2
6682853 Kimijima et al. Jan 2004 B2
6723466 Oogami et al. Apr 2004 B2
6884541 Enomoto et al. Apr 2005 B2
6896994 Urairi et al. May 2005 B2
6964690 Goda et al. Nov 2005 B2
7108941 Hayashi et al. Sep 2006 B2
7195840 Kaun Mar 2007 B2
7276092 Holl et al. Oct 2007 B2
7341802 Ota et al. Mar 2008 B1
7432014 Konishiike et al. Oct 2008 B2
7455929 Dopp et al. Nov 2008 B2
7488553 Tsukamoto et al. Feb 2009 B2
7566515 Suzuki et al. Jul 2009 B2
7582387 Howard et al. Sep 2009 B2
7641992 Howard et al. Jan 2010 B2
7642013 Howard et al. Jan 2010 B2
7662509 Howard et al. Feb 2010 B2
7745041 Kozuki et al. Jun 2010 B2
7794869 Howard et al. Sep 2010 B2
7803481 Howard et al. Sep 2010 B2
7858236 Howard et al. Dec 2010 B2
7883790 Howard et al. Feb 2011 B2
7931980 Kwak et al. Apr 2011 B2
7951476 Kim May 2011 B2
7981541 Sato et al. Jul 2011 B2
8021775 Kaun Sep 2011 B2
8048570 Visco et al. Nov 2011 B2
8236441 Gardner et al. Aug 2012 B2
8435658 Yamashita et al. May 2013 B2
8465860 Pozin et al. Jun 2013 B2
8703327 Kim et al. Apr 2014 B2
9077022 Howard et al. Jul 2015 B2
9899640 Yabushita et al. Feb 2018 B2
20010009737 Lane Jul 2001 A1
20010016282 Kilb et al. Aug 2001 A1
20010053617 Shoji Dec 2001 A1
20020004171 Kimijima et al. Jan 2002 A1
20020034680 Inoue et al. Mar 2002 A1
20020106559 Takahashi et al. Aug 2002 A1
20020146621 Yageta et al. Oct 2002 A1
20020192559 Yoshimura et al. Dec 2002 A1
20030003370 Arai et al. Jan 2003 A1
20030013007 Kaun Jan 2003 A1
20030035993 Enomoto et al. Feb 2003 A1
20030068557 Kumashiro et al. Apr 2003 A1
20030077505 Goda et al. Apr 2003 A1
20030138693 Suzuki et al. Jul 2003 A1
20030162088 Nakanishi et al. Aug 2003 A1
20030175589 Kaminaka et al. Sep 2003 A1
20030193317 Shimamura et al. Oct 2003 A1
20040029004 Miyaki Feb 2004 A1
20040048151 Hayashi et al. Mar 2004 A1
20040048160 Omaru Mar 2004 A1
20040081895 Adachi et al. Apr 2004 A1
20040110061 Haug et al. Jun 2004 A1
20040115521 Cho Jun 2004 A1
20040185338 Holl et al. Sep 2004 A1
20040202933 Yamaki et al. Oct 2004 A1
20050042506 Tomimoto et al. Feb 2005 A1
20050058904 Kano et al. Mar 2005 A1
20050064283 Anderson et al. Mar 2005 A1
20050074667 Yang Apr 2005 A1
20050142440 Yamaki et al. Jun 2005 A1
20050171383 Arai et al. Aug 2005 A1
20050181276 Miyaki Aug 2005 A1
20050233212 Kaun Oct 2005 A1
20050271938 Suzuki et al. Dec 2005 A1
20050277021 Kozuki et al. Dec 2005 A1
20060051662 Kwak et al. Mar 2006 A1
20060093871 Howard et al. May 2006 A1
20060093872 Howard et al. May 2006 A1
20060093894 Scott et al. May 2006 A1
20060093918 Howard et al. May 2006 A1
20060093923 Howard et al. May 2006 A1
20060124973 Arai et al. Jun 2006 A1
20060183020 Davidson et al. Aug 2006 A1
20060228629 Christian et al. Oct 2006 A1
20070037058 Visco et al. Feb 2007 A1
20070122698 Mitchell et al. May 2007 A1
20070172728 Yamashita et al. Jul 2007 A1
20070200101 Asao et al. Aug 2007 A1
20080003500 Issaev et al. Jan 2008 A1
20080003503 Kawakami et al. Jan 2008 A1
20080050652 Hirose et al. Feb 2008 A1
20080240480 Pinnell et al. Oct 2008 A1
20080241645 Pinnell et al. Oct 2008 A1
20080248384 Yabushita et al. Oct 2008 A1
20080318126 Ishii Dec 2008 A1
20090123840 Shirane et al. May 2009 A1
20090186263 Pozin et al. Jul 2009 A1
20090208849 Pozin et al. Aug 2009 A1
20090286158 Howard et al. Nov 2009 A1
20090325062 Brenner et al. Dec 2009 A1
20100009245 Howard et al. Jan 2010 A1
20100015528 Howard et al. Jan 2010 A1
20100076523 Howard et al. Mar 2010 A1
20100196756 Wakita et al. Aug 2010 A1
20100227217 Fujikawa et al. Sep 2010 A1
20100247984 Yamashita et al. Sep 2010 A1
20100266893 Martin et al. Oct 2010 A1
20110091753 Wang et al. Apr 2011 A1
20110133699 Howard et al. Jun 2011 A1
20110200871 Pytlik et al. Aug 2011 A1
20120015224 Pytlik et al. Jan 2012 A1
20120028110 Brenner Feb 2012 A1
20120058386 Wyser et al. Mar 2012 A1
20120100406 Gaugler Apr 2012 A1
20130130066 Pytlik et al. May 2013 A1
20130216881 Gaugler Aug 2013 A1
Foreign Referenced Citations (113)
Number Date Country
1184338 Jun 1998 CN
1224934 Aug 1999 CN
2502410 Jul 2002 CN
1490891 Apr 2004 CN
2632871 Aug 2004 CN
1630126 Jun 2005 CN
1744347 Mar 2006 CN
2847540 Dec 2006 CN
2874790 Feb 2007 CN
1960040 May 2007 CN
101120462 Feb 2008 CN
101202357 Jun 2008 CN
101217188 Jul 2008 CN
101286572 Oct 2008 CN
101517820 Aug 2009 CN
201440429 Apr 2010 CN
1 471 758 May 1969 DE
31 13 309 Oct 1982 DE
36 38 793 May 1988 DE
196 47 593 May 1998 DE
697 00 312 Feb 2000 DE
69700312 Feb 2000 DE
198 57 638 Jun 2000 DE
10313830 Oct 2007 DE
10 2009 008 859 Aug 2010 DE
10 2009 017 514 Oct 2010 DE
0202857 Nov 1986 EP
0 202 857 Jul 1991 EP
1137091 Sep 2001 EP
1205985 May 2002 EP
1315220 May 2003 EP
1318561 Jun 2003 EP
1 339 115 Aug 2003 EP
1 372 209 Dec 2003 EP
1 808 916 Jul 2007 EP
1873846 Jan 2008 EP
1886364 Feb 2008 EP
1 968 134 Sep 2008 EP
1968134 Sep 2008 EP
1088271 Oct 1967 GB
2 110 464 Jun 1983 GB
58-10375 Jan 1983 JP
S5842167 Mar 1983 JP
58-154178 Sep 1983 JP
59-78460 May 1984 JP
60-148058 Aug 1985 JP
S62-113358 May 1987 JP
62-139265 Jun 1987 JP
62-272472 Nov 1987 JP
63-285878 Nov 1988 JP
1-307176 Dec 1989 JP
H01309254 Dec 1989 JP
2-56871 Feb 1990 JP
2-60072 Feb 1990 JP
H03-225748 Oct 1991 JP
4-249073 Sep 1992 JP
5-121056 May 1993 JP
6-96750 Apr 1994 JP
7-153467 Jun 1995 JP
7-153488 Jun 1995 JP
8-293299 Nov 1996 JP
11-40189 Feb 1999 JP
11-135101 May 1999 JP
H11176414 Jul 1999 JP
2937456 Aug 1999 JP
H11245066 Sep 1999 JP
11-345626 Dec 1999 JP
11-354150 Dec 1999 JP
2000-77040 Mar 2000 JP
2000082486 Mar 2000 JP
2000-164259 Jun 2000 JP
2000156218 Jun 2000 JP
2000331717 Nov 2000 JP
2002-042744 Feb 2002 JP
2002-100408 Apr 2002 JP
2002-134073 May 2002 JP
2002-134096 May 2002 JP
2002-164076 Jun 2002 JP
2002-289257 Oct 2002 JP
2002-289259 Oct 2002 JP
2002-289260 Oct 2002 JP
2002-298803 Oct 2002 JP
2002-324584 Nov 2002 JP
2002-352789 Dec 2002 JP
2003-31266 Jan 2003 JP
2003-077543 Mar 2003 JP
2003-123830 Apr 2003 JP
2003217562 Jul 2003 JP
2003-249201 Sep 2003 JP
2004-139800 May 2004 JP
2004-158318 Jun 2004 JP
2004-362968 Dec 2004 JP
2006-040596 Feb 2006 JP
3902330 Apr 2007 JP
2007-200683 Aug 2007 JP
2007-220601 Aug 2007 JP
2007207535 Aug 2007 JP
2007-294111 Nov 2007 JP
2007294111 Nov 2007 JP
2008-047303 Feb 2008 JP
2008103109 May 2008 JP
2008198552 Aug 2008 JP
2008-251192 Oct 2008 JP
2008-262825 Oct 2008 JP
2008-262825 Oct 2008 JP
2008-262826 Oct 2008 JP
2008-262827 Oct 2008 JP
2009-199761 Sep 2009 JP
20030087316 Nov 2003 KR
WO 2008109025 Sep 2008 WO
WO 2008117215 Oct 2008 WO
WO 2008118478 Oct 2008 WO
2010089152 Aug 2010 WO
Non-Patent Literature Citations (60)
Entry
The English language machine translation of Higuchi et al. JP 2008-262825 in pdf format (Year: 2008).
Linden, D., et al., “Handbook of Batteries,” 2002, Third Edition, The McGraw-Hill Companies, Inc., Sections 11.4, 11.4.1, 14.1, 14.5.2, 14.8 and 14.8.2, and Figs. 11.2, 11.5, 14.38, 34.13, 35.30 and 35.32.
Official Action dated Mar. 27, 2014 of related U.S. Appl. No. 13/146,669.
Official Action dated Sep. 2, 2014 of related U.S. Appl. No. 13/146,669.
“Button cell”, Electropedia, International Electrotechnical Commission, Apr. 2004.
Official Action dated May 28, 2019, of counterpart U.S. Appl. No. 15/699,435.
Guoshun, Zhang et al. “Application of Auto Laser Welding in Rechargeable Battery Manufacturing,” Chinese Journal of Lasers, vol. 35, No. 11, Nov. 2008.
Qu, Guoqiang, “Initial Analysis on the Working Principle of Through the Partition Welding,” Feb. 1989.
Yi, Si-ping et al. “Laser Auto-Welding for Lithium Battery Tab,” Chinese Journal of Power Sources, vol. 29, No. 2, pp. 80-81, Feb. 2005.
“Complaint for Patent Infringement” of U.S. Pat. No. 9,153,835; U.S. Pat. No. 9,496,581; and U.S. Pat. No. 9,799,913 against Amazon.com, Inc., Feb. 24, 2020.
“Complaint for Patent Infringement” of U.S. Pat. No. 9,153,835; U.S. Pat. No. 9,496,581; U.S. Pat. No. 9,799,913; and U.S. Pat. No. 9,799,858 against Best Buy Co., Inc., Feb. 24, 2020.
“Complaint for Patent Infringement” of U.S. Pat. No. 9,153,835; U.S. Pat. No. 9,496,581; and U.S. Pat. No. 9,799,913 against Costco Wholesale Corporation, Feb. 24, 2020.
“Complaint for Patent Infringement” of U.S. Pat. No. 9,153,835; U.S. Pat. No. 9,496,581; U.S. Pat. No. 9,799,913; and U.S. Pat. No. 9,799,858 against Audio Partnership LLC and Audio Partnership PLC, Mar. 3, 2020.
“Complaint for Patent Infringement” of U.S. Pat. No. 9,153,835; U.S. Pat. No. 9,496,581; U.S. Pat. No. 9,799,913; and U.S. Pat. No. 9,799,858 against PEAG, LLC, Mar. 4, 2020.
Machine English translation of “Compact Battery” by Kobayashi Yoshikazu in JP 2007294111 (A)—Nov. 8, 2007 (Year: 2007).
“Notification of invalidation request acceptance” against Chinese Patent No. 201080036551.3, Jan. 2020.
“Annulment” against EP 2 394 324 B1, Jan. 22, 2020.
“Complaint for Patent Infringement” of U.S. Pat. No. 9,153,835; U.S. Pat. No. 9,496,581; and U.S. Pat. No. 9,799,913 against Samsung Electronics America, Inc., Feb. 5, 2020.
U.S. Appl. No. 16/812,482, filed Mar. 9, 2020.
U.S. Appl. No. 16/813,776, filed Mar. 10, 2020.
U.S. Appl. No. 16/810,976, filed Mar. 6, 2020.
U.S. Appl. No. 16/810,998, filed Mar. 6, 2020.
U.S. Appl. No. 16/792,420, filed Feb. 17, 2020.
U.S. Appl. No. 16/796,977, filed Feb. 21, 2020.
U.S. Appl. No. 16/798,509, filed Feb. 24, 2020.
“Notice of acceptance of request for invalidation” against Chinese patent application No. 201080007121.9, dated Jun. 17, 2020
InvenTek Corp., “Our Technology,” Dec. 6, 2004, https://web.archive.org/web/20041206230046/http://inventekcorp.com/page3.html.
InvenTek Corporation, “Powerful Design: Technology,” Nov. 22, 2007, https://web.archive.org/web/20071122010915/http://inventekcorp.com/technology.html.
InvenTek Corporation, “Powerful Design: Partners,” Nov. 22, 2007, https://web.archive.org/web/20071122011734/http://inventekcorp.com/partners.html.
Saft Specialty Battery Group, “Premium lithium battery LM 17130,” Doc. No. 31089-2-0908, Sep. 2008.
Saft, “Premium lithium battery LM 22150,” DOC N° 32040-2-0313, Mar. 2013.
Saft Specialty Battery Group, “Premium lithium battery LO 34 SX,” Doc N° 31099-2-0411, Apr. 2011.
Saft Specialty Battery Group, “Rechargeable lithium-ion battery VL 34480,” Doc. N° 54054-2-0607, Jun. 2007.
Saft, “Saft lithium batteries: Selector guide,” Doc. N° 54083-2-0320, Mar. 2020.
Saft, “Saft lithium batteries: Selector guide,” Doc. N° 54083-2-0613, Jun. 2013.
Saft Specialty Battery Group, “Saft lithium-ion rechargeable batteries for transportable power applications,” Doc. N° 54047-2-0706, Jul. 2006.
Ultralife Corporation, “UB0006,” https://www.ultralifecorporation.com/ECommerce/product/ub0006/type-ba-5367-33v-limno2, retrieved Jul. 15, 2020.
Ultralife Batteries, Inc., “UBOOO6: BA-5367/U” https://web.archive.org/web/20061109153052/http://www.ultralifebatteries.com/datasheet.php?ID=U80006#top, Nov. 9, 2006.
Ultralife Batteries, Inc., “BA-5367/U Technical Datasheet,” Aug. 4, 2006.
Ultralife Corporation, “BA-5367/U Technical Datasheet,” Aug. 27, 2015.
Ultralife Batteries, Inc., “Product Summary Guide: Technical Datasheet,” Sep. 27, 2006.
Ultralife Batteries, Inc., “Ultralife: Lithium-Manganese Dioxide Primary and Lithium Ion Rechargeable Batteries,” Dec. 13, 2004.
Ultralife Corporation, “Lithium Carbon Mono-fluoride / Manganese Dioxide Hybrid Application Guide,” Apr. 2, 2014.
Defendants' P.R. 3-3 Invalidity Contentions, Jul. 10, 2020.
Petition for Inter Partes Review of U.S. Pat. No. 9,799,858, Jul. 7, 2020.
Petition for Inter Partes Review of U.S. Pat. No. 9,153,835, Jul. 7, 2020.
Petition for Inter Partes Review of U.S. Pat. No. 9,496,581, Jul. 7, 2020.
Petition for Inter Partes Review of U.S. Pat. No. 9,799,913, Jul. 7, 2020.
Exhibit 1 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 2 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 3 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 4 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 5 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 6 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 7 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 8 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 9 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 10 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Exhibit 11 of Defendant's Invalidity Contentions, Jul. 10, 2020.
Jul. 10, 2020 Statement of Thomas Kaun.
Related Publications (1)
Number Date Country
20170187008 A1 Jun 2017 US
Divisions (1)
Number Date Country
Parent 13378117 US
Child 15433654 US