Patent Application
20080015123
As used herein, approximating language may be applied to modify any quantitative representation that may vary, without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as “about” and “substantially,” may not be limited to the precise value specified, in some cases.
As used herein, wires, cables, or similar lengthy conductors will be referred to as “cable,” “wiring,” “strand,” or “strands” interchangeably; and the tube, duct, pipe section, or conduit, including the dies and fittings thereon, will be termed “conduit” or “conduit pipe.”
As used herein, the term “cable-pulling composition” maybe used interchangebly with “cable-lubricating composition,” referring to a composition for use lubricating/coating a cable, allowing the cable to go through a conduit with reduced resistance, e.g., at least 20% less force, compared to an uncoated cable.
The term “an effective amount,” as used herein, means an amount of the coating composition sufficient to pull a cable strand through a conduit with reduced resistance or pulling force than would be required without such a composition.
The cable-pulling compositions of the invention can be in the form of a gel; a grease; an oil; a solid stick, wand, or block; a spray, distributed as a pump or an aerosol; a paint; or a powder. In one embodiment, the composition is applied as a stick, a wand, or a block, in an apparatus that allows the block of the coating composition to be pulverized, thus distributing a coating onto the cable.
The cable-pulling compositions may comprise ingredients generally used in products of this type (a gel, a spray paint, etc.), well known to those skilled in the art, provided that they do not interfere with the boron nitride as the cable pulling key ingredient described herein.
Active Cable Pulling Ingredient—Boron nitride: Boron nitrides (BN), which can be used in the cable pulling composition of the invention, are commercially available from a number of sources, including, but not limited to, BN materials from GE Advanced Materials, Sintec Keramik, Kawasaki Chemicals, and St. Gobain Ceramics.
The BN for use in the composition of the invention can be in one of the following forms, or mixtures thereof, including amorphous boron nitride (referred to herein as a-BN); boron nitride of the hexagonal system, having a laminated structure of hexagonal-shaped meshed layers (referred to herein as h-BN); or a turbostratic boron nitride, having randomly oriented layers (referred to herein as t-BN). In one embodiment, the BN is in the turbostratic form, hexagonal form, or mixtures thereof.
In one embodiment, the BN particles have a primary average particle size of less than 100 μm. In a second embodiment, less than 50 μm. In a third embodiment, in the range of 10 to 30 μm. In a fourth embodiment, having an average particle size of less than 20 μm. In yet another embodiment, the boron nitride powder particles have a primary average particle size of less than 250 μm.
In one embodiment, the BN particles consist essentially of hBN platelets having an aspect ratio of from about 10 to about 300. In another embodiment, the BN particles have an oxygen content from 0.2 to 2.5 wt %. In another embodiment, the hBN particles have a graphitization index of less than 7.
In one embodiment, the composition is in the form of a block consisting essentially of boron nitride with the block of boron nitride having a density ranging from 0.20 to 1.500 g/cm3, and an O2 concentration ranging from 0.2 to 1.3 wt. %,
In one embodiment, the BN is surface-treated (“coated”) to further impart lubricating characteristics to the ingredient. Examples of surface coating materials for the boron nitride powder include, but are not limited to, isohexadecane, liquid paraffin, non-ionic surfactants, dimethylpolysiloxane (or dimethicone), a mixture of completely methylated, linear siloxane polymers which have been terminally blocked with trimethylsiloxy units, a silazane compound possessing perfluoroalkyl groups, a zirconate coupling agent, a zirconium aluminate coupling agent, an aluminate coupling agent, and mixtures thereof.
Cable Pulling Compositions. The active BN cable-pulling composition is applied onto cable in various forms, including, but not limited to, a boron nitride-containing paint, grease, stick, wand, or block, cream, and powder.
In embodiments such as a paint, a grease, a cream, etc., the boron nitride cable-pulling material is mixed with a binder or carrier material, e.g., a water-soluble binder, aqueous emulsion, paraffin, a liquid silicone, oil, etc. There is no special limitation to the binder material usable in the cable pulling composition, so long as it does not interfere with the cable pulling ability of the BN agglomerate and has the retaining properties and binding abilities necessary for the agglomerate. Examples of the binder materials include, but are not limited to, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycol, etc. In one embodiment, other binder materials are also used in combination with alcohol binders, e.g., carboxymethyl cellulose, hydroxy propyl cellulose, methylethyl cellulose, and lignosulfonates. In yet another embodiment, additional inorganic binders, such as sodium silicate or other silicates, may also be used in very small amounts, e.g., less than 5 wt. %. The combination and percentages of the binders is not critical, but the amounts and combinations should not be so large as to interfere with the cable-pulling ability of the boron nitride, as noted above.
The total amount of boron nitride in the finished cable-pulling formulation may be varied within wide parameters, but should be such an amount for the composition to have a coating layer of boron nitride on at least 20% of the cable surface, to allow the cable to go through the conduit with reduced resistance, e.g., at least 20% less force, compared to the uncoated cable. This amount is a cable-pulling effective amount. Without this amount, cables are found to bind and are very difficult to pull through the conduit. In one embodiment, the cable-pulling effective amount is the amount sufficient to allow the cable to be pulled through the conduit with at least 10% reduced force, compared to the force required for an uncoated cable (i.e., 90% of the required force for an uncoated cable). In a second embodiment, a sufficient amount of cable-pulling formulation is applied for the cable to be pulled through the conduit with at least 50% reduced force, compared to the force required for an uncoated cable. In a third embodiment, a sufficient amount of cable-pulling formulation is applied for the cable to be pulled through the conduit with at least 90% reduced force.
In one embodiment, the composition is applied onto the cable leaving a coating of boron nitride powder of a thickness of 2 to 500 μm on the coated surface of the cable. In yet another embodiment, the coating layer containing boron nitride on coated cable has a thickness of 10 to 100 μm.
Generally, in one embodiment, the cable-pulling effective amount is in the range of 0.1 to 99.9 wt. %, based on the total weight of the cable-pulling formulation. In one embodiment, the amount is 2 to 95 wt. %. In a second embodiment, the amount ranges from 2 to 75 wt. %. In a third embodiment, from 5 to 50 wt. %. In a fourth embodiment, this amount is less than 15 wt. %. In a fifth embodiment, this amount ranges from 5 to 30 wt. %.
In addition to the boron nitride component as the principal cable-pulling ingredient, at least one binder/carrier component may be included, depending on the form of the application. The composition can also contain a variety of additives known in the art, including, but not limited to, agitants, dyes, colorants, preserving agents, surfactants, or corrosion inhibitors.
In one embodiment, the cable pulling composition is in the form of a boron nitride liquid, e.g., a BN paint with high lubricity as well as good adherence to the cable surface, resulting in a dried composition of BN. In one embodiment, the boron nitride cable-pulling composition is in the form of a BN paint containing 50 to 100 parts by weight of BN; 25 to 75 parts by weight of an acrylic, such as vinyl acrylic; and 100 to 200 parts by weight of a volatile liquid, such as an alcohol.
The BN cable-pulling composition can be applied in a liquid form directly to the cable surface using a conventional liquid application technique, such as washing, brushing, painting, spraying, or the like. In one embodiment, the cable pulling comprising BN is applied using an apparatus as disclosed in U.S. Pat. No. 4,569,420, wherein a nozzle, on a nozzle head secured to the leading end of the cable, is provided, so that while the cable is pulled through the conduit, the BN cable-pulling composition is sprayed onto the interior walls of the conduit, ahead of the leading end of the cable being pulled. In yet another embodiment, the composition is applied onto the cable using an apparatus as disclosed in U.S. Pat. No. 4,296,837, with a split ring carrying a plurality of nozzles for dispensing the BN cable-pulling composition onto the cable being pulled through the conduit.
Cable pulling compositions in a form similar to BN paints are commercially available and can be obtained from a number of sources, including GE Advanced Materials of Strongsville, Ohio.
In one embodiment, the cable-pulling composition is in the form of a wand, a stick, or a block. In one embodiment, the solid block contains 5 to 40 wt. % boron nitride, optional lubricants, such as molybdenum disulfide of 0 to 50 wt. %, PTFE of 0 to 50 wt. %, calcium carbonate of 5 to 50 wt. %, and/or optional minerals, such as mica, sericite, and talc in 0 to 30 wt %. In another embodiment, wherein the block consists essentially of boron nitride or boron nitride in combination with electrically-insulating lubricants such as PTFE, the cable-pulling composition is electrically insulating upon application to the cable, allowing the power to the circuit to be turned on after application, without the additional waiting time normally required to allow an electrically-conductive composition to dry.
In yet another embodiment, the cable-pulling composition employs BN as the primary solid component, with a block comprising 0 to 99.9 wt. % of h-BN and 0 to 99 wt. % of t-BN. In one embodiment, the block is formed using the following process: a mixture of high oxygen t-BN and optional carbon additive is first cold pressed via a known method, such as uniaxial pressing, filter pressing, or isostatic pressing, and is then heated to a temperature of 1500-2300° C. for 1 to 40 hrs., forming a block of sintered BN, having a density ranging from 0.20 to 1.50 g/cm3.
In yet another embodiment, the cable-pulling block employs synthetic wax, paraffin, or an organophosphate, such as triphenyl phosphate, as a carrier. The BN cable-pulling component is added to the melted liquid carrier. Then, the mixture thus formed is poured into molds, where the mixture is allowed to cool and the carrier is allowed to solidify. The molds can produce a bar or other desired shape.
In one embodiment, the cable-pulling block employs synthetic or natural wax, paraffin, or an organophosphate, such as triphenyl phosaphate, as a carrier. The BN component is dry blended with the carrier component using a v-blender. The dry mixture is then charged into a mold, heated to 250° F., and pressed at a pressure of between 250 and 1500 psig, cooled to room temperature, and de-moulded to form a bar or other desired shape.
In one embodiment, the cable-pulling composition is in the form of a grease or oil, which can be applied onto the cable surface via junction boxes at various intervals for additional lubrication of the cable.
In one embodiment, the cable-pulling composition is a grease, containing 1- to 30 wt. % of the boron nitride active ingredient in a carrier of a mineral or synthetic oil. The grease composition in one embodiment further comprises at least one of a mineral thickener such as acetylene black, talc, clay, or silica in an amount of 2 to 30 wt. %. In another embodiment, the grease composition further comprises ingredients such as lithium soap, polyurea, sodium soap, calcium soap, aluminum soap, aluminum-complex soap, calcium complex soap, calcium sulfonates, lithium complex soap, bentonite, graphite/carbon, PTFE, indianthrene dye, polyethylene, or phthalocyanine dye in an amount of 1 to 30 wt %.
In one embodiment, a cable-pulling grease, containing boron nitride, is applied onto the cable surface using an apparatus as disclosed in U.S. Patent Publication No. 2004/0035642, wherein a plastic device is used to dispense the composition onto a strand of cable, while the cable is being pulled through a conduit. This plastic device has embedded channels that carry the cable-pulling composition under pressure from an inlet to outlets, at which points the lubricant is dispensed. In another embodiment, the BN-containing cable pulling grease is injected into the conduit through fittings, as disclosed in U.S. Pat. No. 3,565,213.
In one embodiment, wherein the cable pulling composition is in an oil form, an apparatus as disclosed in JP Patent Publication No. 07-0878640 is used in conjunction with compressed air to blow the composition onto the cable, thus distributing the composition and facilitating the cable pulling process.
The invention is further illustrated by the following non-limiting examples:
A mixture comprising 29.4 wt. % h-BN powder with an oxygen content of 0.3 wt % (grade AC6004 from GE Advanced Materials), 68.6 wt. % of t-BN with an oxygen content of 15 wt % (also from GE Advanced Materials), and 2 wt. % of carbon black (grade N991 from Cancarb) is homogenously blended together. The blend is pressed in a uniaxial press, forming a plurality of blocks. The blocks are then sintered for 10-30 hours at 1800-2300° C., forming low-density BN blocks with density ranging from 0.20 to 1.50 g/cm3, and with a fired O2 concentration of <1.0 wt %.
In this example, the BN block fabricated in Example 1 is employed in the apparatus 50, as illustrated in
In the figure, a boron nitride stick or block (not shown) is confined in the space behind rollers 1. As a cable is pulled through the apparatus in the direction of A-A′, the BN block is pulverized via the roller assembly, thus forming a coating on most, if not all, of the cable surface being pulled through. The apparatus 50 is provided with a plurality of flat blades 4, which function to contain the pulverized BN material confined within the roller assembly. A plurality of brushes 2, provided at the entry and exit of the apparatus, help with the distribution of the cable pulling composition onto the cable surface. In one embodiment, only one single (circular brush is provided) at either the entry or exit of the apparatus for the distribution of the composition onto the cable surface. Assembly pin 3 holds the apparatus housing parts in place during assembly/disassembly to replace the boron nitride stick.
As best seen in
In this example, the rollers of Example 2 are removed, allowing the cable-pulling block to be pressed directly against the cable being pulled through the conduit. The cable, in this example, has a roughened surface texture jacket, thus directly abrading the BN block, and causing BN powder to be deposited directly onto the cable/wire jacket.
It should be noted that the cable-pulling composition for use with the cable lubricating/lubricant dispensing apparatus illustrated in the Figures does not need to be in the form of a block, a stick or a wand. In one embodiment, boron nitride powder is dispensed into the hollow space of
Although not illustrated in any of the drawings, in one embodiment, a cable pulling mechanism is provided for use in conjunction with the lubricating apparatus. The mechanism engages the lubricating apparatus by intermittently applying pressure on the apparatus and/or gripping the cable and pulling the cable through the lubricating apparatus. In yet another embodiment, a cable supplying mechanism is provided. The cable supplying means comprises a supply of cable, and a motor operable to cause spooling-out the cable the supply at a predetermined rate of speed in response to the movement of the cable through the conduit. In one embodiment, the cable pulling mechanism comprises a plurality of members for alternately gripping, pulling and releasing the cable, effectively allowing the cable to be pulled through the apparatus/conduit as it is being lubricated.
This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to make and use the invention. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims, if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.
All citations referred herein are expressly incorporated herein by reference.
This application claims the benefits of U.S. 60/807550 filed Jul. 17, 2006, which patent application is fully incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 60807550 | Jul 2006 | US |
