The present invention is directed generally to communications cables, and more specifically to cables with highly expanded foam of a uniform, small, and closed cell nature.
It has been taught by Yuto and Suzuki (U.S. Pat. Nos. 4,547,328 and 4,683,166) that the addition of at least 20% by weight of a 55% or greater die swell ratio (DSR) plastic to a polymer blend produces certain advantages in the making of coaxial cable. Specifically, the addition of the 55% or greater DSR polymer increases the elasticity of the melted polymer, allowing better control over the process whereby wire is coated with a foamed insulation. The teachings indicate that advantages are obtained from a high degree of foaming (expansion ratio) and a cell structure of the foamed polymer that is 50 microns or less. Small cell structures at high expansion ratios are desirable for the properties of low electrical loss (attenuation), low material usage and improved mechanical strength. It is understood by those skilled in the art that the prior art had to restrict the 55% or greater DSR material to no less than 20% of the total mixture in order to maintain aforementioned desirable cell structure, high expansion ratio, and stress crack resistance. However, in order to enhance dimensional stability and mechanical strength of the cable, the foamed insulation layer was coated with an unfoamed solid polymer layer or skin. It is known that such a layer adds complexity to the manufacturing process and increases the cost of initial capital and ongoing material usage. Additionally, the high DSR materials themselves are electrically disadvantaged, and thus adversely affect the electrical purity (dissipation factor) of the cable.
The present invention provides electrical communications elements, such as wires and cables, having a superior combination of low dissipation factor, and high thermally accelerated stress crack resistance in either solid or preferably, foamed states. This novel combination of properties achieves the following unique and advantageous characteristics concurrently in the same structure:
According to the present invention, an electrical communications element is provided that comprises a conductor and a surrounding foamed plastic insulation. The foamed plastic insulation comprises no more than 20% by weight of a polymer having an ultra-high die swell ratio greater than 55%. Preferably, the ultra-high die swell polymer is blended with one or more electrically and/or environmentally superior additional polymer compositions to achieve desirable mechanical, electrical, thermal, lifetime properties and cost advantages that heretofore have physically not been able to exist simultaneously in the same embodiment. More particularly, the additional polymer compositions have a high thermally accelerated stability as defined by an oxidative induction time (OIT) of greater than 15 minutes at 200° C. according to ASTM method 4568. More desirably, the additional polymer composition has an oxidative induction time of greater than 20 minutes.
Preferably, the additional polymer composition has a dissipation factor lower than that of the ultra high die swell ratio polymer and less than 75 micro radians, and more desirably less than 50 micro radians.
The insulation provided by the present invention has a thermally accelerated stress crack resistance of greater than 100 hours at 100° C. while coiled at a stress level of 1 times the insulation outside diameter without exhibiting radial or longitudinal cracks.
In one preferred aspect, the foamed plastic insulation comprises about 15% by weight of an olefin polymer having a die swell ratio with a value greater than 55%. In a further preferred aspect, the foamed plastic insulation comprises no more than 20% by weight of a low density polyethylene having a die swell ratio greater than 55% and at least one additional polyolefin composition having a high thermally accelerated stability defined by an oxidative induction time (OIT) of greater than 15 minutes at 200° C. according to ASTM method 4568. Preferably, the least one additional polyolefin composition has a dissipation factor lower than that of the high die swell ratio low density polyethylene and less than 75 micro radians.
The insulated electrical communications element of the present invention can be embodied in various kinds of structures used for electrical communications, such as coaxial cables, drop cables or twisted pair cables.
In a further embodiment, the present invention provides an electrical communications cable comprising a conductor and a surrounding foamed plastic insulation. The foamed plastic insulation comprises a blend of a first polyolefin having an ultra high die swell ratio with a value greater than 55% present in an amount no more than 20% by weight and at least one additional polyolefin having a high thermally accelerated stability as defined by an oxidative induction time (OIT) of greater than 15 minutes at 200° C. according to ASTM method 4568. Preferably the at least one additional polyolefin has a dissipation factor lower than the ultra high die swell ratio polyolefin and less than 75 micro radians. The additional polyolefin may suitably be a highly stabilized polyolefin including phenolic antioxidants or phenolic antioxidant-phosphite blends as well as a hindered amine light stabilizer.
Some of the features and advantages of the invention having been described, others will become apparent from the detailed description which follows, and from the accompanying drawings, in which:
The present invention now will be described more fully hereinafter with reference to the accompanying drawings, in which some, but not all embodiments of the invention are shown. Indeed, the invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
Closely surrounding the core 11 is a continuous tubular smooth-walled sheath 15. In the preferred embodiment illustrated, the tubular sheath 15 is made from an aluminum strip that has been formed into a tubular configuration with the opposing side edges of the strip butted together, and with the butted edges continuously joined by a continuous longitudinal weld, indicated at 16. The welding may be carried out generally as described in U.S. Pat. Nos. 4,472,595 and 5,926,949 which are incorporated herein by reference. While production of the sheath 14 by longitudinal welding has been illustrated as preferred, persons skilled in the art will recognize that other methods for producing a mechanically and electrically continuous thin walled tubular bimetallic sheath could also be employed. Preferably, the inner surface of the tubular sheath 15 is continuously bonded throughout its length and throughout its circumferential extent to the outer surface of the foam dielectric 14 by a thin layer of adhesive 17. A preferred class of adhesive for this purpose is a random copolymer of ethylene and acrylic acid (EAA) or EAA blended with compatible other polymers. The outer surface of the sheath 15 is surrounded by a protective jacket 18. Suitable compositions for the outer protective jacket 18 include thermoplastic coating materials such as polyethylene, polyvinyl chloride, polyurethane and rubbers. In the embodiment illustrated, the protective jacket 18 is preferably bonded to the outer surface of the sheath 15 by an adhesive layer 19 to thereby increase the bending properties of the coaxial cable. Preferably, the adhesive layer 19 is a thin layer of adhesive, such as the EAA copolymer or blends described above. Although an adhesive layer 19 is illustrated in the drawing, the protective jacket 18 can also be directly bonded to the outer surface of the sheath 15.
Referring now to
Referring now to
According to the present invention, the insulated electrical communications element is produced by extruding a foamable polymer composition around a conductor and causing the composition to foam and expand. The foaming process can use chemical and/or mechanical blowing agents, such as nitrogen, conventional in the wire and cable industry for producing foam insulation. The polymer composition comprises no more than 20% by weight of a polymer having an ultra-high die swell ratio greater than 55%. The presence of the ultra-high die swell polymer provides excellent foaming properties for the insulation. Preferably, the polymer composition includes at least one additional polymer that is selected for its superior electrical and/or environmental stability characteristics. Polymers suitable for use in the present invention may be selected from any of a number of commercially available polymer compositions conventionally used in the wire and cable industry, including polyolefins such as polypropylene and low, medium and high density polyethylene. Particularly preferred for use as the ultra-high die swell ratio component is low density polyethylene, preferably a polyethylene with a density within the range of about 0.915 g/cm3 to about 0.930 g/cm3. The additional polymer component is preferably a medium and/or high density polyethylene. Preferably, this additional polymer has a high thermally accelerated stability as defined by an oxidative induction time (OIT) of greater than 15 minutes at 200° C. according to ASTM method 4568.
The ability of a strained polymeric molecular chain to store energy will impact the amount of swell that takes place following the affects of temperature and work. A polymer such as low density polyethylene (LDPE) with longer chains and side branching will store more energy and recover at a higher rate after processing than that of similar molecular weight LDPE with shorter chains and less side branching. The measurement of the recovery can be determined by the die swell ratio (DSR), which can be determined by the following relation:
DSR(%)=[(ds−do)/do×100]
Where ds is an outer diameter of the extruded material and do is an inner diameter of an orifice provided in an extrusion plastometer defined in ASTM D1238. ds and do may be obtained during measurement of melt index (MI) by an extrusion plastometer. The diameter of the orifice is measured at room temperature, usually before heating of the device. The resultant diameter of the extrudate is measured after it is allowed to cool to room temperature. Typical settings for the ASTM D1238 test, utilizing low density polyethylene, are a temperature of 190° C. and a 2160 gram load.
It is theorized that molecular weight distribution (Mw/Mn) also plays an important role in the identification of high die swell properties. In the scope of this investigation it was shown the LDPE compounds having a MWD of eight (8) or higher yielded significantly higher die swell and melt elasticity—desirous for the formation of low density foamed dielectric insulation of communications elements. While these properties are more inherent to those LDPE resins manufactured using an autoclave reaction process, LDPE resins produced by certain tubular or other reactor products may yield similar performance. Polydispersity or ER value as defined by Equistar Chemicals is also an indicator of the melt elasticity of the polyethylene product. The procedure for measurement of ER value is described in an article by R. Shroff, et al. entitled “New Measures of Polydispersity from Rheological Data on Polymer Melts”, J. Applied Polymer Science, Vol. 57, pp. 1605-1626 (1995) and in U.S. Pat. No. 5,534,472, both of which are incorporated herein by reference. As shown in table 1, high die swell materials correlate with increased ER values and better foaming results.
In the course of this experimentation, a list of primary polyethylene compounds (HDPE) and secondary high die swell low-density polyethylene compounds were evaluated for electrical performance in terms of the electrical dissipation factor of a molded 75-mil (0.075 inch) specimen. This parameter is also interchangeably referred to as a material's Loss Tangent. An HP/Agilent 4342A Model Q Meter was used to measure the dissipation factor and dielectric constant at a frequency of 1 megahertz (MHz). Typically this measurement is stated in units of micro-radians or a value times 10−6 radians.
The LDPE component is specified to be “neat”; that is, having little or no antioxidants, UV stabilizers, slip, or antiblocking additives. LDPE resins containing high levels of stabilizers or process aids will not meet the electrical criteria and heat aging properties established for optimal attenuation properties. In this respect, the HDPE component of the foam dielectric blend contains, minimally, the environmental stabilizers and antioxidants required to provide long term thermally accelerated stability and thermally accelerated stress crack resistance of the HDPE/LDPE foam blend. It is important to note that while stabilizers are required for lifetime performance, the addition of such stabilizers will typically negatively impact electrical attenuation. To accomplish the desired environmental stabilization with optimal attenuation properties, a preferred system consists of a primary high-performance phenolic antioxidant such as Irganox 1010 or 1076 (Ciba Chemicals) and a secondary Phosphite co-stabilizer such as Irgafos 168 (Ciba Chemicals). The combination of the primary and secondary antioxidants provides a synergistic effect and impacts the long-term thermally accelerated stability of the foam product. Furthermore, the stabilizer system preferably includes a third multifunctional long-term stabilizer belonging to the family of hindered amine light stabilizers (HALS), which provides additional long term environmental stability and weathering (UV) protection. Given the levels required for effective UV stabilization, it was theorized that the additional HALS loading would have a negative impact on the dissipation factor (hence attenuation) of HDPE used in the manufacture of coaxial cables. Test results as shown in Table 2 demonstrate that the dissipation factors of HDPE compounds containing the various blends of primary and secondary antioxidants and HALS do not follow this predicted theory.
The blend of antioxidants and HALS used in this particular development is described as follows:
Commercial blends such as Irganox B215 (Ciba) are attainable which can also provide the correct ratio of primary and secondary antioxidants. It should be evident that other blends of similar components from alternate manufacturers in various other concentrations will also serve to describe the state of material.
The thermally accelerated stress crack resistance of a 0.180-inch diameter foam coaxial member having a 0.0403-inch copper clad steel center conductor was tested per the prescribed test method of wrapping the foamed core about a mandrel that has a diameter of one times the diameter of the element under test. This places the test specimen in a predetermined stress level that is proportionate to its diameter. As shown in
The graph of
These discoveries and their subsequent experimental practice teach us that the desirous combinations of high stress crack resistance, low attenuation (dissipation factor and density), low cost (density), and stable, small and closed cell foamed extrusion can be achieved on a consistent and repeatable basis, owing to the novel combinations of the aforementioned materials.
Many modifications and other embodiments of the inventions set forth herein will come to mind to one skilled in the art to which these inventions pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the inventions are not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Number | Name | Date | Kind |
---|---|---|---|
4547328 | Yuto et al. | Oct 1985 | A |
4683166 | Yuto et al. | Jul 1987 | A |
5254188 | Blew | Oct 1993 | A |
5346926 | Sakamoto et al. | Sep 1994 | A |
5959245 | Moe et al. | Sep 1999 | A |
6137058 | Moe et al. | Oct 2000 | A |
6201189 | Carlson et al. | Mar 2001 | B1 |
6265667 | Stipes et al. | Jul 2001 | B1 |
6492596 | Higashikubo et al. | Dec 2002 | B1 |
Number | Date | Country |
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2 013 960 | Aug 1979 | GB |
Number | Date | Country | |
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20040222009 A1 | Nov 2004 | US |