This invention relates to electrical power generation, and in particular to a power generator comprising a fuel cell and a capacitor.
Fuel cells generate electricity from an electrochemical reaction between a hydrogen-containing fuel and an oxidant. One type of fuel cell is a proton-exchange-membrane (PEM) fuel cell, which uses a proton conductive membrane such as NAFION® to separate the fuel and oxidant reactants. Other known fuel cells include solid oxide fuel cells (SOFC), alkaline fuel cells and direct methanol fuel cells (DMFC). Such fuel cells can be stacked together to provide a greater voltage, than can be generated by a single fuel cell.
Because fuel cells generate electricity electrochemically rather than by combustion, pollutants found in combustion products can be avoided, and fuel cells are perceived to be an environmentally friendlier alternative to combustion engines. Applications for fuel cells include stationary and portable power generators, and vehicular powerplants.
Especially in vehicular applications, the load on the fuel cell stack can vary dramatically over an operating cycle. Efforts have been made to develop efficient “load-following” fuel cell systems, which can quickly increase or decrease electrical output to match the load changes demanded by the application. However, load following tends to impose stresses on the fuel cell system, thereby increasing wear and tear on the fuel cell system components and decreasing system operating life.
One approach to reducing the stress on fuel cell systems used in variable load applications is to couple the fuel cell stack in parallel to an energy storage device, such as an electrochemical battery to produce a “hybrid” power system. In such an arrangement, the battery acts like a buffer for the fuel cell stack, supplying electricity in times of high demand, thereby reducing the peaks in electrical demand on the fuel cell system: when demand is low, the fuel cell stack can recharge the battery. Therefore, the load varations imposed on the fuel cell stack are smoothed and system operating life can be extended.
There are challenges with implementing a battery hybrid fuel cell system as shown in
There is thus a need to provide an effective fuel cell system that can supply power to highly variable loads in a way that does not unduly stress the fuel cell stack and reduce its operating life.
According to one aspect of the invention, there is provided a method of operating an electrical power generator comprising at least one fuel cell and at least one capacitor electrically coupled together in parallel. The method comprises: monitoring a current drawn by a load; monitoring a voltage across the capacitor, and operating the fuel cell to generate an electrical output within a target output range when either the monitored current or voltage are within a respective selected current and voltage range, the fuel cell output supplying the load and/or recharging the capacitor. The capacitor is configured to discharge stored electrical energy to the load when the load exceeds the target output range. Operating the generator using such a method enables the fuel cell to operate within an efficient range that reduces stress on the fuel cell, thereby prolonging the life of the fuel cell.
The fuel cell output can be adjusted by adjusting the rate of oxidant transmitted to the fuel cell. The rate of transmitted oxidant is within a range that corresponds to the target output range of the fuel cell.
When the monitored current is below the current range and the monitored voltage is within the voltage range, the load is below the target output range of the fuel cell and the capacitor requires recharging. In such case, the recharging rate of the capacitor can be reduced by reducing the fuel cell output. This prolongs fuel cell power generation and reduces the frequency of starting and stopping the fuel cell, thereby reducing stress on the fuel cell.
Particularly, the fuel cell output can be reduced to a lower limit of the target output range to reduce the recharging rate of the capacitor to a minimum. When the monitored voltage reaches an upper limit of the voltage range, the fuel cell operation is stopped. The upper limit of the voltage range can be selected to correspond to a fully charged capacitor. Stopping fuel cell operation can comprise reducing the fuel cell output to zero as the monitored voltage approaches the upper limit of the voltage range. To further prolong fuel cell power generation, the fuel cell output rate is can be further reduced as the monitored voltage approaches the upper limit of the voltage range. Alternatively, stopping fuel cell operation can comprise directing the fuel cell output from recharging the capacitor to heating the fuel cell when the fuel cell output has not reached zero after the monitored voltage reaches the upper limit of the voltage range.
When the monitored current is above the current range, fuel cell output can be increased to an upper limit of the target output range.
Additionally, the temperature of the fuel cell can be monitored, and the fuel cell can be operated to generate an electrical output within the target output range when the monitored temperature falls below a selected setpoint. This operation keeps the fuel cell sufficiently warm so that the fuel cell can be quickly started. Starting the fuel cell to generate electrical output can comprise transmitting fuel and oxidant to the fuel cell using power supplied by the capacitor. Once the fuel cell is generating sufficient power, fuel and oxidant transmission can be powered by the fuel cell.
In accordance with another aspect of the invention, a computer readable memory is provided having recorded statements and instructions for execution by a programmable device to carry out the above method of operating an electrical power generator.
In accordance with another aspect of the invention, there is an electrical power generator comprising: at least one fuel cell; at least one capacitor electrically coupled to the fuel cell in parallel; a current sensor for monitoring a current drawn by a load; a voltage sensor for monitoring a voltage across the capacitor; and a controller communicative with the current sensor and voltage sensor, and programmed with the above method of operating the generator.
Referring to
The generator 3 operates to supply load-following power from the capacitor bank 10 or the fuel cell stack 7, or both, as circumstances dictate. The generator 3 executes an operating strategy that operates the fuel cell stack 7 within parameters that reduces stress on the fuel cell stack 7, thereby increasing the stack's operating life. The operating strategy includes defining a stack operating range which minimizes the stress on the stack 7, then using the capacitor bank 10 to supplement the stack output by providing power when a load on the generator 3 exceeds the stack operating range. When the load drops to within or below the stack operating range, the operating strategy includes conducting some of the stack output to recharge the capacitor bank 10, and to shut down the stack 7 if necessary, i.e. when the load is below the stack operating range and the capacitor bank 10 is fully charged. Another aspect of the operating strategy is to reduce the frequency at which the stack 7 is started up and shut down, as such cycling tends to impose stress on the stack 7. Therefore, when the load falls below the stack operating range for an extended period of time, the generator 3 will reduce the recharging, rate of the capacitor bank 10 in order to extend the period of time that the stack remains on, i.e. continues to generate electricity. This strategy is particularly effective when the load is highly variable, and tends to reduce the frequency which the stack 7 starts up and shuts down.
The generator 3 also includes “balance of plant components 16 for controlling the supply of oxidant and fuel to the fuel cell stack, controlling and conditioning the supply of electricity generated by the stack 7, cooling and humidifying the stack 7, and removing excess water, unreacted fuel and air and contaminants from the stack 7. Such balance of plant components 16 include at least a cooling system fan 106, a radiator 108, and an air compressor 112.
Referring to
A first contactor 26 is provided on the positive conductor 28 between the stack 7 and the voltage converter 8 and serves to electrically couple and uncouple the stack 7 from the power circuit 4. A stack voltage sensor 21 is connected to the power circuit 4 between the stack 7 and the first contactor 26 and measures stack voltage. A stack current sensor 23 is connected to the positive conductor 28 between the first contactor 26 and voltage converter 8 and measures stack current.
The balance of plant components 16 are electrically coupled to the power circuit 4 by a component circuit 15 which is located on the power circuit 4 between the capacitor bank 10 and the load 11. A second contactor 27 is provided on the component circuit 15 to couple or uncouple the balance of plant components 16 from the power circuit 4. A controller assembly 18 for controlling operation of the capacitor hybrid fuel cell generator 3 is electrically coupled to the power circuit 4 by a controller circuit 17, which is located on the power circuit 4 between the capacitor bank 10 and the component circuit 15. A key switch contactor 17a is provided on the controller circuit 17 to couple or uncouple the controller assembly 18 from the power circuit 4. So configured, the balance of plant components 16 and the controller assembly 18 can be powered by electricity supplied by the ultra capacitor bank 10.
A power circuit switch 30 is provided on the positive conductor 28 between the component circuit 15 and the load 11 to couple and uncouple the power circuit from the load 11.
A capacitor voltage sensor 22 is positioned across the capacitor bank 10 to measure the voltage of the power circuit 4 at the capacitor bank 10. A power circuit current sensor 24 is positioned at the positive conductor 28 to measure the current of the power circuit 4, and when the contactor 26 is opened, the current of the capacitor bank 10.
A heater circuit 41 is provided to heat the coolant of the cooling system, and thereby heat the stack 7. The heater circuit 41 is in parallel with the fuel cell stack 7 between the stack 7 and the first contactor 26. The heating circuit includes at least one heater component 42 and a coolant temperature sensor 25 (shown in
Referring to
Referring to
The capacitor hybrid fuel cell generator 3 can include a key switch (not shown) that opens and closes a key switch contactor 17a. The key switch contactor 17a is closed when the key switch is set to an “On” position, and is open when the key switch is set to an “Off” position. The generator 3 is ready to operate as long as fuel is available to the fuel cells, and the key switch contactor 17a is closed. When ready to operate, the generator 3 can start up the fuel cell stack 7 as required, and as described in detail below under the heading “start up procedure”.
Operating Strategy
The controller 120 is programmed with a target output range to correspond with the most efficient operating output range of the stack 7. The controller 120 effects operation of the stack 7 within the stack's target output range through operational control of balance of plant components 16 and through operational control of the voltage converter 8. Feedback on the operational state of the generator 3, including data on the target output range reaches the controller 120 by way of data from the system sensors 22, 24, and the stack current sensor 23. In alternate embodiments of the present invention, direct feedback from the balance of plant components 16 and/or from the voltage converter 8 may be used instead of or in addition to data from the system sensors.
Operating the stack 7 to generate a generally steady state output within the target output range ensures that stresses on the stack 7 are minimized, thereby increasing the operating life of the stack 7. However, it is within the scope of the invention for the target output range to be based on other parameters as desired by the operator.
The controller 120 instructs the stack 7 to generate a power output to supply the load 11 and/or to charge the capacitor bank 10 up to a maximum output corresponding to the upper limit of the target output range. When the load 11 is above the target output range of the stack 7, additional electricity is discharged by the capacitor bank 10 to meet the load 11. When the load 11 is within the target output range, some of the electricity generated by the stack 7 can be used to recharge the capacitor bank 10 if recharging is required. In this way, the capacitor bank 10 functions as an energy storage device, at times storing energy, and at times supplying energy.
When the load 11 continues to be more than the target output range of stack 7, the controller 120 instructs the balance of plant components 16 to increase the air flow to the stack 7 to increase the level of power generated up to the upper limit of the target output range, and the controller 120 instructs the voltage converter 8 to ramp up accordingly.
When the load 11 falls below the target output range of the stack 7 and the capacitor bank 10 requires recharging, the controller 120 reduces the stack output to the lower limit of the stack output range, and the stack output not needed to supply the load is used to recharge the capacitor bank 10. This procedure is defined as a “first ramp down phase”, and involves the controller signalling the balance of plant components 16 to ramp down the air flow at a first rampdown rate to a level corresponding to the minimum level of the target output range of the stack 7, and the controller 120 signals the voltage converter 8 to ramp down accordingly.
When the capacitor bank 10 is recharged past a certain threshold represented by a capacitor voltage setpoint, a second rampdown phase is initiated wherein a second rampdown rate is effected that is lower than the first rampdown rate. That is, the controller 120 signals the balance of plant components 16 to ramp down power generation at the second rampdown rate. This slows down the recharge rate of the capacitor bank 10, thereby allowing the fuel cell stack 7 to continuing operating, and reducing the frequency at which the stack 7 has to shut down and start up. Such repeated shut downs and start ups increase the stress on the fuel cell stack 7 and reduces the stack's operating life.
Shutdown Strategy
When the voltage of the capacitor bank 10 nears full capacity, i.e. the capacitors are nearly fully charged, the controller 120 signals the balance of plant components 16 to stop the air flow to the stack 7, thereby completing the shut down of the stack 7.
Shutting down of the stack 7 does not immediately terminate power generation in the stack 7, as is well known for fuel cell generators. A stack bleed down procedure has typically been applied to absorb the residual power so generated. Residual oxidant reacts with residual fuel or recirculating fuel to generate power. A power sink or energy storage device can be advantageously applied to absorb the generated power, as can a resistor to convert the power into heat.
In the present embodiment, the stack 7 is shut down before the capacitors are fully charged. In this way, the capacitors retain some energy storage capability when the stack 7 is shut down, and absorb the residual power. When the capacitor bank 10 is fully charged, the controller 120 opens the first contactor 26 to prevent overcharging of the capacitors, and closes the fourth contactor 43 to divert the remaining residual power to the heater component 42.
Safety Check Procedure
In an alternate embodiment, the generator 3 does not have a key switch contactor 17a, and is always in the ready slate.
Demand Check Procedure
Once the generator 3 is in the ready state 200, the controller 120 is programmed to check for power demand, and when a power demand is sensed, to initiate a startup procedure in a demand check procedure 203, the controller 120 monitors the system sensor 22, 24, 25 for current, voltage and temperature date respectively, and starts the stack 7 when the current, voltage or temperature conditions require that power be added to the generator 3.
Power is demanded from the stack 7 when the load 11 exceeds a certain current level; when the capacitor bank 10 needs recharging indicated by a certain voltage level; or when the temperature of the slack 7 drops below a certain temperature level. The levels at which the current, voltage or temperature conditions trigger startup of the stack 7 are programmed as setpoints in the controller 120.
Referring to
When the generator 3 is in ready state 200, the heater circuit 41 is not normally active; however, when the controller receives a temperature signal from the coolant temperature sensor 25 that is below a low temperature setpoint, the controller starts up the fuel cell stack 7 and closes the fourth contactor 43, and the first contactor 26. In this way the generated energy from the fuel cell stack 7 is provided to the heater circuit 41 to heat the coolant and thereby the fuel cell stack 7. When the coolant temperature sensor 24 reports a continued coolant temperature at a second temperature setpoint that is higher than the first temperature setpoint, the controller shuts down the stack 7 by initiating a shutdown procedure, described in detail under the heading ‘shutdown procedure’. Typically, running the stack 7 for 30 seconds is sufficient to heat the stack 7 to the second temperature setpoint in this way, the generator 3 prevents the fuel cell stack 7 from freezing.
For a generator 3 intended for use in environments where the ambient temperature never approaches freezing, the heating circuit 41 and the heater components 41 may be removed or bypassed.
Startup Procedure
Referring to
Specifically, in the first phase 204 the controller actions are represented by process block 206 in which the Controller 120 closes the second contactor 27 to close the component circuit 15 thereby supplying power to balance of plant components 16. The startup procedure continues as represented by process block 208 in which the controller 120 signals an air compressor relay (not shown) to close, thereby readying the air compressor 112 for operation.
In the second phase 205, the controller actions are represented by process block 210 in which the controller 120 activates a fuel circulation pump (not shown) and related components to deliver fuel to the stack 7, and by process block 212, in which the controller activates the air compressor 112 to supply oxidant in air to the stack 7; and by process block 214 in which the controller 120 activates a coolant pump (not shown) to supply coolant to the stack 7.
When the actions represented by process block 214 are complete, the startup procedure 221 is complete, as represented by block 220. The startup procedure 221 takes 3 to 5 seconds to complete. Contactor 26 is closed, and the stack 7 enters into a run state wherein electricity is generated.
Run Check Procedure
Referring to
When the generator 3 is in the run state 220, the controller 120 is operative to adjust the operation of the balance of plant components 16 and the operation of the voltage converter 8.
Blocks 222 through 225 represent a run check sub-procedure that the controller 120 continually applies to determine whether power generation is required or not. When power generation is not required for a selected length of time, the run procedure 219 ends, and the shutdown procedure as represented by block 228 starts.
In detail, as represented by decision block 222, the controller 120 monitors the power circuit current sensor 24 to ascertain whether the current draw has dropped below a first current setpoint as stored in controller memory; and the controller 120 monitors the capacitor bank voltage sensor 22 to ascertain whether the capacitor voltage has risen above a first voltage setpoint as stored in controller memory. When not, power generation continues and the controller continues to monitor the sensors.
When both the first current setpoint and the first voltage setpoint are surpassed, the controller 120 starts an internal timer, as represented by process block 223, and then as represented by decision block 224, the controller monitors the power circuit current sensor 24 to ascertain whether the current draw has risen above a second current setpoint; and monitors the capacitor bank voltage sensor 22 to ascertain whether the capacitor voltage has dropped below a second voltage setpoint. When either second setpoint is surpassed, power generation continues, and the controller resets the internal timer as represented by process block 225. The controller continues to monitor the system sensors 22, 24 as represented by decision block 222.
In this way, when the load 11 returns to within the target output range of the stack 7 or when the capacitor bank 10 needs recharging, power generation by the stack continues.
When neither the current nor the voltage reach their respective first setpoints, the controller refers to the internal timer to check whether the setpoint has been surpassed by a length of time, as represented by decision block 226, and when that length of time has not been surpassed, the controller continues to monitor the system sensors 22, 24 as represented by decision block 224. When that length of time has been surpassed, the controller 120 initiates the shutdown procedure as represented by block 228.
Shutdown Procedure
The shutdown procedure 230 is initiated when the voltage of the capacitor bank 10 rises above a shutdown voltage setpoint, and the current drops below a shutdown current setpoint. When these two conditions occur, the controller 120 shuts down the fuel cell stack 7, and bleeds down residual generated power. In this way, the shutdown procedure 230 returns the generator 3 to the ready state 200.
Referring to
When the capacitor hybrid fuel cell generator 3 is in the shutdown state 228, the controller 120 is operative to shut down the operation of the balance of plant components 16 and the operation of the voltage converter 8. As represented by process block 230, the controller signals the balance of plant components 16 to terminate air flow to the stack 7 to end power generation. As represented by process block 232 the residual generated power is conducted to the capacitor bank 10. In decision block 234, the controller 120 monitors the stack voltage sensor 21 and when the sensed voltage is less than the voltage of a fully charged capacitor, the controller does nothing to allow the residual power to continue conducting to the capacitor bank 10. When the sensed voltage is equal to the voltage of a fully charged capacitor, the controller 120 opens the first contactor 26, and closes the fourth contactor 43, as represented by process block 236. In this way, the residual generated power is diverted from the capacitor bank 10 to the heater circuit 41 where it is converted to heat within the coolant of the generator's cooling system. As represented by decision block 238, the controller continually monitors the stack current sensor 23 to determine when the residual power generation has ended. When residual power generation has ended, the controller 120 opens the fourth contactor 43 to disconnect the heater circuit 41 from the stack 7 and the controller shuts down the fuel circulation pump (not shown) to save energy, as represented by process block 240. Next, as represented by process block 242, the controller 120 opens the second contactor 27 to unpower the balance of plant components 16. On completion of this shutdown procedure 230, the generator 3 returns to the ready state 200.
In an altercate embodiment, the power circuit current sensor 24 is eliminated, and only the capacitor bank voltage sensor 22 is used to provide information to the controller 120 to determine whether to start or increase power generation of the fuel cell stack 7. In this embodiment, a current value can still be used to provide for efficient start up of the fuel cell stack 7 by calculating the power circuit current from the capacitor voltage using the formula:
I=dVc/dt×F
Where:
I is the current in Amps
d denotes ‘delta’
Vc is the voltage across the double-layer capacitors in Volts
t is time
F is the capacitance of the double layer capacitor(s) in Farads
In another alternative embodiment, the preferred voltage in process block 226 is substantially reduced when the controller 120 senses a low fuel signal from a pressure transducer (not shown) on a fuel supply to the fuel cell stack 7. In this way, shutdown is initiated at a lower voltage level than normal; and equipment powered by the capacitor hybrid fuel cell generator 3 and coupled to receive a voltage value from the controller 120, receives a voltage value equivalent to a trigger voltage for an interrupt device, such as a lift interrupt on a lift truck, and therefore activates the interrupt device. When such equipment is provided with a voltage gauge, as is often incorporated to show the equipment operator that a battery installed to power the equipment requires charging, the received lowered voltage value from the generator 3 informs the operator that the fuel supply for the generator 3 requires fuel. An additional benefit of providing a lowered voltage to such equipment is that the equipment operates sluggishly, thereby simulating the sluggish operation associated with a battery that requires charging. The preferred voltage reduction is 6.3 Volts for a nominal 36-Volt power system to mimic the voltage drop of a 36-Volt battery system that requires charging of the battery.
In yet another alternative embodiment, the capacitor hybrid fuel cell generator 3 can further reduce the adverse effects of load following by the controller inputting the voltage value of the double-layer capacitor bank 10 and filtering the voltage value to eliminate outlier values and otherwise smooth and average the voltage values inputted over a time period, the time period preferably being 5 seconds, however another time period may be used without detracting from the invention in the preferred embodiment of the invention, the controller continually samples the voltage of the capacitor bank voltage sensor 22 in 20, 20 and 10 millisecond (ms) intervals, filters the voltages values received, and outputs a control signal to the fuel cell stack 7 and the voltage converter 8 every 50 ms, however, another sampling rate and/or control signal rate may be used without detracting from the invention. In this way, the lifetime of the fuel cells, and therefore the lifetime of the capacitor hybrid fuel cell generator 3, is improved, and due to the high cost of fuel cells, the cost of the capacitor hybrid fuel cell generator 3 over time is reduced.
It is to be understood that even though various embodiments and advantages of the present invention have been set forth in the foregoing description, the above disclosure is illustrative only, and changes may be made in detail, and yet remain within the broad principles of the invention. Therefore, the present invention is to be limited only by the claims appended to the patent.
Number | Date | Country | Kind |
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2,5232,640 | Oct 2005 | CA | national |
2,537,728 | Feb 2006 | CA | national |
This application is a continuation-in-part of U.S. application Ser. No. 11/360,486 “Fuel Cell Fluid Dissipater” to Robin et al., filed on Feb. 24, 2006: U.S. application Ser. No. 11/251,792 “Fluid Management System” to Mulvenna et al., filed on Oct. 18, 2005; and U.S. application Ser. No. 11/436,594 “Fuel Cell Power Pack” to Mulvenna et al., filed on May 18, 2006, which are all incorporated herein by reference in their entirety and for all teachings, disclosures and purposes.
Number | Date | Country | |
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Parent | 11360486 | Feb 2006 | US |
Child | 11476083 | Jun 2006 | US |
Parent | 11251792 | Oct 2005 | US |
Child | 11360486 | Feb 2006 | US |
Parent | 11436594 | May 2006 | US |
Child | 11476083 | Jun 2006 | US |