The present invention is related to outside-in capillary membrane filters for water treatment.
Filters for water treatment with capillary ultra- or micro-filtration membranes having the smallest pores at its outside diameter (so called “outside-in capillary membranes”) are filtering the raw water by imposing a lower pressure at the inside diameter (“lumen”) side. The permeate flows from the outside diameter towards the lumen but the dirt accumulates at the outside perimeter and is removed by air scrub and/or back pulse. This requires a good contact between the air bubbles and the capillary membrane. Other points of concern are to avoid entrapment of the entrained dirt and to have a design that can be constructed in an economic way. Different module designs to cope with these requirements have been proposed already.
In U.S. Pat. No. 5,248,424, a capillary membrane module is described that consists of a layer of membranes potted at both ends in a header that serves as a permeate collector. The membranes can move freely and form a configuration in the form of an arc above a horizontal plane through both headers. A disadvantage of this configuration is that the horizontal layer of membranes easily accumulates suspended solids.
U.S. Pat. No. 5,783,083 describes a capillary membrane/hollow fiber membrane module where both fiber ends are potted in a header of which at least one serves as permeate collector. The fibers form a vertical cylindrical skein. The fiber length is 0.1% to 5% longer as the fixed distance between both headers, to allow the fibers to make a certain displacement. Rinsing is done by blowing air between the fibers. To assure that the fibers are at a well defined distance from each other in the header, the ends of the fibers are fixated on a flexible support and wound spirally before being potted in a tube. The potting of the fibers in both headers is almost identical, with the exception that in case only one header is used as permeate collector, the lumen of the fibers is only open at one end. This configuration has the risk to entrap dirt in the upper header that hinders the free passage and circulation of the air and raw water at the top of the module.
To avoid entrapment of dirt patent WO 02/22244 describes a vertical skein of capillary membranes that is only potted in one header at the bottom side. The lumen side of the ends of the capillary membranes at the top side are only closed by potting material. The capillary membranes are loose so that there is no obstruction at the top to entrap dirt present from the raw water. Injection of air in the header at the bottom cleans the outer surfaces of the capillary membranes (air scrub).
The objective of EP 0931582 is to make a highly integrated hollow fiber membrane module by potting the ends of a planar layer of fibers into an aperture of a tube. At least at one side the lumen of the fiber ends remains open so that the tube serves as permeate collector. Potting is done by providing a weir at the periphery of the aperture of the collector and filling the weir with a potting material, for instance polyurethane. Each layer is potted in a separate header.
Several of the module designs discussed above have a planar layer of capillary membranes or hollow fibers, who are normally made in a continuous process. EP 0931582 describes a technique to produce such a layer by making a knitted fabric of hollow fibers. In U.S. Pat. No. 5,716,689, the membranes are put side by side and an adhesive strip is pushed on the membranes on a fixed distance. Then the membranes are cut adjacent to these strips and these strips are assembled into a hollow fiber carpet by bringing the strips at each end of the membrane together to form a loop of hollow fibers.
The present invention aims to provide a novel filtration module design based on planar vertical layers of capillary membranes that can be cleaned easily by air scrub and that is less susceptible to entrapment of dirt.
The present invention concerns a filtration device for removing particles from a liquid, said filtration device comprising a collector header arranged to collect and remove permeate and a plurality of planar membrane assemblies having an upper side and a lower side. Said lower side is operatively linked to said collector header. Said planar membrane assemblies each comprise a plurality of outside-in micro- or ultrafiltration capillary membranes, each capillary membrane extending from said lower side to said upper side of said planar membrane assembly. Said plurality of capillary membranes form a plane. The capillary membranes of each planar membrane assembly are (operatively) linked to an individual upper header. The upper headers of each planar membrane assembly and the disposition of the planar membrane assemblies at the lower side are arranged to allow a flow of air bubbles, crude water and particles to pass from said lower side to said upper side. The filtration device of the invention reduces particle build-up at said upper side.
The capillary membranes of a planar membrane assembly are arranged side by side. As a result, the plurality of capillary membranes forming a plane means that the capillary membranes of a planar membrane assembly form a single row. Hence, the capillary membranes of a planar membrane assembly are arranged in a single row. Each planar membrane assembly hence consists of a single row of capillary membranes.
The collector header is formed of a single collector chamber. The capillary membranes of said plurality of planar membrane assemblies are linked together at the lower side to said collector header (linked to said collector chamber).
The filtration device comprises an individual upper header for each planar membrane assembly. Hence, all single rows of capillary membranes (all planar membrane assemblies) are linked together to the collector header at the lower side, but each single row of capillary membrane (each planar membrane assembly) is linked to an individual upper header. The capillary membranes of a planar membrane assembly are linked at the upper side to an individual upper header. The planar membrane assemblies may be linked to the corresponding upper header either operatively or purely mechanically.
In a particular embodiment, the capillary membranes are closed at the upper side of the planar membrane assembly. In an alternative embodiment, the capillary membranes are kept open at the upper side and each upper header is arranged to collect and remove permeate.
In a specific embodiment of the present invention, the filtration device comprises an air supply arranged to provide air bubbles between the planar membrane assemblies. The air supply is preferably arranged over the complete length thereof. The air supply is integrated with or placed just above the collector header. The air supply is preferably provided between all planar membrane assemblies.
Preferably, in the filtration device according to the present invention, the upper headers of each planar membrane assembly are fixed at a predetermined distance from each other.
The capillary membranes can have an outer diameter between 0.4 and 5 mm. The filtration device according to the invention preferably comprises between 2 and 50, preferably between 2 and 20, and advantageously between 3 and 8 planar membrane assemblies.
Capillary membranes suitable for carrying out the invention are disclosed in WO2006/053406. The invention is however not limited to the use of these specific capillary membranes.
The capillary membranes are hanging side by side to form a planar vertical layer. As a result, a planar vertical layer comprises capillary membranes arranged in a single row. In the present invention, each single row of capillary membranes is to be regarded as a planar membrane assembly.
At one side—the bottom side—several such planar layers are potted together in one header, parallel to each other. The membrane ends remain open here so that the permeate is collected and evacuated from the membranes of all layers together. At the other side—the top side—each planar layer (each single row) of capillary membranes has an individual upper header. Here the header may also act as a collector or the ends may be closed. The gap that remains between two adjacent upper headers allows the raw water and the air bubbles to pass easily.
The present invention relates to a submerged filtration module made out of outside-in capillary membranes. Filtration is done by imposing a lower pressure to the lumen side of the capillary membranes.
The functioning is best explained by means of the drawings. On
An essential novelty of the invention presented here is that at the upper end of the capillary membranes the different planar layers of membranes are potted in individual headers (4). The capillary membrane upper ends (14) can be closed by potting material (12) as shown on
In a typical application as membrane bioreactors (MBR), course air bubbling is applied to keep the raw water, outside the capillaries, moving and to prevent that particles sink to the bottom of the membrane bioreactor tank. This air is blown below the modules and cleans the outer surface of the capillary membranes by scrubbing effect. Optionally additional air can be supplied by blowing air through openings (11) of an air supply tube (10) placed between the planar layers of capillaries just above the lower collector (3). The number of air supply tubes placed can vary from zero to one between every planar layer as shown on
The novel collector design presented here comprises different planar layers of capillary membranes. A method to make such planar layers in a cheap way is presented in what follows. A machine to make this is schematically represented in
Number | Date | Country | Kind |
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06117912.3 | Jul 2006 | EP | regional |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP07/57276 | 7/13/2007 | WO | 00 | 1/22/2009 |