Capped component and method for forming

Information

  • Patent Grant
  • 8460797
  • Patent Number
    8,460,797
  • Date Filed
    Thursday, December 10, 2009
    14 years ago
  • Date Issued
    Tuesday, June 11, 2013
    10 years ago
Abstract
A method of manufacturing a component comprised of a substrate layer and a cap layer. In one exemplary embodiment, multiple co-extruded wood composite components may be formed simultaneously. In another exemplary embodiment, a component may have a substrate layer comprised of cellulosic material. The cap layer may also include cellulosic filler and at least one streaker. The resulting component may serve a variety of different uses. For example, the component may be used in railing systems such as for decks, porches, fences, stairs, or other suitable applications.
Description
BACKGROUND AND SUMMARY OF THE INVENTION

Exemplary embodiments of the present invention relate generally to a method of manufacturing a component having a cap layer. More specifically, some exemplary embodiments relate to a method of manufacturing a cellulosic composite component having a substrate and a cap layer.


A problem with the use of wood materials in structural applications is the lack of durability and the degradation in appearance when exposed to the environment. In the example of exposed railing systems, such as those commonly found about the perimeter of residential decks, rain can infiltrate the tops of posts and the other exposed surfaces of the wood components, which may eventually cause rot and the loss of a pleasing aesthetic appearance. Traditional wood surface treatments, such as paint or lacquers, have limited life and require routine maintenance, which can result in significant expense over time. Additionally, wood railing systems, for example, are typically custom-built on-site, thereby requiring significant amounts of labor to custom-cut and install individual components. Consequently, there is a need for materials that are weather resistant and can be formed into structural components, such as exterior rail systems as an example.


Exemplary embodiments of the present invention may address some or all of these deficiencies by employing composite materials to make a component. An exemplary component of the present invention may be comprised of a cap layer that is placed over a composite substrate. This combination of a cap layer and composite substrate may provide multiple advantages. In particular, this combination enables the use of a relatively low cost, composite material as a substrate that provides desired structural characteristics for the component, even though the composite material may not have desirable aesthetic characteristics. An exemplary embodiment of the cap layer may include streaker and cellulosic filler. The cap layer may be applied on the composite substrate to provide an attractive and protective finish for the component. Furthermore, the cap layer may reduce manufacturing costs by not requiring a streaker to be applied throughout the entire substrate. As a result of such benefits, an exemplary embodiment of the component may be resistant to weathering and may be used for railing, siding, or other similar or suitable indoor or outdoor products.


In one exemplary embodiment, the cap layer may include a blend of polyvinyl chloride (PVC) and acrylic and may exhibit an improved resistance to degradation, which may be caused by UV light exposure or other environmental factors. In another exemplary embodiment, a component may be made from a plastic material comprising acrylic-styrene-acrylonitrile (ASA), which may also exhibit an improved resistance to degradation, such as may be caused by environmental factors. In yet another exemplary embodiment, the cap layer may be a polyolefin-based material that has enhanced resistance to degradation and scratching. In still another exemplary embodiment, the cap layer may include a cellulosic material and/or a streaker material.


An example of a method for forming such aforementioned components may include providing an extrusion system having at least one extruder and at least one die system. The method may also include providing a substrate material and a cap layer material. Exemplary embodiments of the method may include extruding the substrate material and co-extruding the cap layer material onto at least a portion of the substrate material. In certain exemplary embodiments, the method may further include forming a flow from the substrate material and cap layer material, and forcing the flow through the die system to form at least one component. Furthermore, in some exemplary embodiments, multiple components may be simultaneously produced from the same tooling.


In addition to the novel features and advantages mentioned above, other features and advantages will be readily apparent from the following descriptions of the drawings and exemplary embodiments.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a cross-sectional view of an exemplary embodiment of a rail of the present invention.



FIG. 2 is a cross-sectional view of an exemplary embodiment of a post cover of the present invention.



FIG. 3 is a perspective view of an example of a railing system that may utilize components made by an exemplary embodiment of the present invention.



FIG. 4 is a perspective view of an example of a component made according to an exemplary embodiment of the present invention.



FIG. 5 is a perspective view of an example of a component made according to an exemplary embodiment of the present invention.



FIG. 6 is an example of an extrusion system that may be used to make a component of one exemplary embodiment of the present invention.



FIG. 7 is a cross-sectional view of one exemplary embodiment of a co-extrusion system that may be used when practicing an exemplary embodiment of the present invention.



FIG. 8 is an example of an extrusion system that may be used to make a component of one exemplary embodiment of the present invention.



FIG. 9 is a front elevation of an exemplary embodiment of a die system that may be used when practicing an exemplary embodiment of the present invention.



FIG. 10 is a front elevation of an exemplary embodiment of a die system that may be used when practicing an exemplary embodiment of the present invention.





DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENT(S)


FIG. 1 illustrates an example of a component of the present invention. In this example, a handrail 10 is comprised of a composite substrate 12 and a cap layer 14. The handrail 10 may, for example, be useful for a deck railing system or other similar or suitable types of railing.


Another exemplary component of the present invention is illustrated in FIG. 2. FIG. 2 shows an exemplary post cover 20 that also comprises a composite substrate 22 and a cap layer 24. Such a cover may be installed, for example, over an existing wood post to provide an aesthetically pleasing appearance as well as to provide protection from exposure to the elements.



FIG. 3 shows an example of a railing system that may utilize the components shown in FIGS. 1 and 2. In particular, rail 25 and rail 27 may be connected to post cover 20 at a variety of horizontal and vertical angles, such as for deck and stair applications. Post covers 20 may be installed over pre-installed posts from which they derive structural rigidity and strength. Nevertheless, it should be recognized that the railing may utilize a post without the benefit of the post cover components. It should be noted that in this exemplary embodiment, any or all of the components may be fabricated as described above to provide a durable, weather-resistant, and aesthetically pleasing railing system.


Exemplary embodiments of the present invention may also be useful for making other types of railing components including, but not limited to, spindles, squash blocks, support rails, and posts. Nevertheless, while exemplary embodiments of the present invention may be particularly useful for making railing components, it should be recognized that they may also be useful for manufacturing other types of indoor and outdoor components. Examples of components that can be made with the present invention include, but are not limited to, fence components, furniture components, cabinet components, storage device components, lawn edging components, flower box components, floor components, baseboards, roof components, wall covering components, building siding components, basement floor components, basement wall covering components, interior and exterior decorative house molding components, crown molding components, chair rail components, picture frame components, porch deck components, deck railing components, window molding components, window components, window frames, door components, door frames, door moldings, posts, boards (e.g., 5/4-inch boards, 2 inch×6 inch boards, and other desired sizes of boards), and other suitable indoor and outdoor items. Furthermore, it should be recognized that the component may be solid or hollow.


In exemplary embodiments of the present invention, the substrate may be comprised of a composite that has a high cellulosic content. For instance, one exemplary embodiment of the composite is comprised of cellulosic material in the amount of at least about 30% by weight, more preferably about 30% to about 70% by weight (e.g., about 60% by weight), and even more preferably about 40% to about 60% by weight. A plastic material may be included in an amount of about 0.01% to about 70% by weight, more preferably about 30% to about 70% by weight, and still more preferably about 30% to about 60% by weight (e.g., about 40% by weight). For another example, the composite may be comprised of cellulosic material in an amount of about 55% by weight and a plastic material in an amount of about 30% to about 45% by weight. In yet another exemplary embodiment, the composite may be comprised of cellulosic material in the amount of about 50% by weight and a plastic material in an amount of about 50% by weight. In some exemplary embodiments, cellulosic material may be provided in an amount less than 50% by weight of the composite, and plastic material may be provided in an amount more than 50% by weight of the composite.


A high cellulosic content enables the cost-effective production of a substrate that has desirable structural characteristics. For example, the high cellulosic content promotes the desired durability, rigidity, flexibility, and other structural characteristics for a variety of types of components. For instance, the high cellulosic content enables the cost-effective production of railing components that exceed load-testing requirements.


The cellulosic material may be virgin or recycled. Examples of cellulosic material include sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, flax, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagasse, plant fibers, bamboo fiber, palm fiber, kenaf, and other similar or suitable materials. Any of the wood examples may be hard or soft wood or variations thereof. Furthermore, any desired mesh size of the cellulosic material can be used. With regard to cellulosic material, an exemplary range of mesh size is about 10 to about 100 mesh, more preferably about 20 mesh to about 80 mesh depending on the desired characteristics of the composite. However, some exemplary embodiments may use other cellulosic materials of other sizes.


The cellulosic material may be dried to a desired moisture content prior to or during the formation of the substrate. For example, the cellulosic material may be dried to about 0.5% to about 3% moisture content by weight, more preferably to about 1% to about 2% moisture content by weight. However, it should be recognized that the cellulosic material may have a moisture content less than about 0.5% by weight or greater than about 3% by weight and still be within the scope of the present invention.


The plastic material may be comprised of virgin or recycled materials that may improve the characteristics of the reinforced composite and/or enhance the manufacture or moldability thereof. In addition, the plastic material may be foamable or foamed. In one exemplary embodiment of the present invention, the plastic material may be a PVC or polyethylene (PE) material, which enables the production of a component having structural characteristics suitable for railing or other applications. The PVC or PE material may, for example, be made by mixing PVC or PE resin with, optionally, at least one stabilizer, at least one lubricant, at least one process aid, and other optional ingredients (e.g., acrylic modifier, inorganic filler, and other suitable additives). Optionally, another plastic resin may also be included in the composite such as, but not limited to, acrylonitrile butadiene styrene (i.e., ABS) resin. An example of a mixer is a high intensity mixer such as those made by Littleford Day Inc. or Henschel Mixers America Inc. As an example, the mechanically induced friction may heat the ingredients to a temperature between about 200° F. and about 230° F. After mixing, the ingredients may be cooled to ambient temperature. Alternatively, the ingredients of the PVC or PE material may be mixed together during the formation of the substrate. Although PVC or PE may be preferred for some embodiments, it should be recognized that other plastics may be used in other exemplary embodiments of the present invention.


With reference to a plastic material that may comprise PVC or PE resin, one exemplary embodiment may include PVC or PE resin in an amount of about 20% to about 45% by weight of the composite, more preferably about 25% to about 40% by weight of the composite, and still more preferably about 27% to about 37% by weight of the composite. An exemplary embodiment of the plastic material may further include stabilizer(s) in an amount of about 1 to about 10 parts, more preferably about 2 to about 4 parts, per 100 parts of resin. In an example, lubricant(s) may be present in an amount of about 1 to about 40 parts, more preferably about 5 to about 35 parts, per 100 parts of resin. In one exemplary embodiment, lubricant(s) may be included in an amount of about 0.01% to about 10% by weight of the composite. Also, process aid(s) may be included in an exemplary embodiment in an amount of about 0.5 to about 8 parts, more preferably about 0.7 to about 3 parts, per 100 parts of resin. Optionally, in an exemplary embodiment, acrylic modifier(s) (e.g., impact modifiers) may be present in an amount of about 1 to about 10 parts, more preferably about 4 to about 8 parts, per 100 parts of resin. As a further option in an embodiment, inorganic filler(s) may be added in an amount of up to about 150 parts, more preferably about 2 to about 60 parts, per 100 parts of resin. In one example, inorganic filler(s) may be included in an amount of about 0.01% to 20% by weight of the composite, more preferably about 1% to about 20% by weight of the composite, and still more preferably about 5% to about 15% by weight of the composite. In addition, another plastic resin (e.g., ABS resin or any other similar or suitable resin) may be included in an exemplary embodiment in an amount up to about 50% by weight of the composite, more preferably about 5-10% by weight of the composite.


Stabilizer(s) may be employed to limit or prevent the breakdown of the plastic material during molding. Examples of stabilizers include tin stabilizers, lead and metal soaps such as barium, cadmium, and zinc, and other similar or suitable materials.


Internal or external lubricant(s) may aid in the molding process. Lubricants may be added to the plastic material to assist the reinforced composite through an extruder, compounder, or other molding machine, and to help facilitate mold release. Examples of lubricants include zinc stearate, calcium stearate, esters, amide wax, paraffin wax, ethylene bis-stearamide, and other similar or suitable materials.


Process aid(s) may aid in the fusion of the compound. Examples of process aids include acrylic process aids and other similar or suitable materials for improving the fusion of the compound. R&H K-120N and R&H K-175 are examples of acrylic process aids that are available from Rohm & Haas.


Acrylic modifier(s) may improve the physical characteristics of the compound. One example of an impact modifier is Arkema P530. Another example of an acrylic modifier is R&H K-400, which is available from Rohm & Haas. Although R&H K-400 is a high molecular weight acrylic modifier that is specifically designed for PVC or PE foam applications, the inventors have discovered that it may also improve the physical characteristics of the substrate of the present invention, which has a high cellulosic content and may not include any foaming or blowing agents.


Inorganic filler(s) may be used to increase the bulk density of the reinforced composite. The use of inorganic filler may also improve the ability to process the reinforced composite, thereby allowing for higher rates of manufacture (e.g., extrusion). Inorganic filler may also allow the reinforced composite to be molded into articles having reduced moisture sensitivity and reduced flame and smoke spread. Examples of inorganic fillers include talc, calcium carbonate, kaolin clay, magnesium oxide, titanium dioxide, silica, mica, barium sulfate, wollastanite, acrylics, and other similar or suitable materials.


Other optional ingredients that may be included in the PVC or PE material include, but are not limited to, polymers, plastics, thermoplastics, rubber, cross-linking agents, accelerators, inhibitors, enhancers, blowing agents/foaming agents, fillers, compatibilizers, thermosetting materials, pigments, weathering additives, and other similar or suitable materials.


Blowing agent(s) may be used to reduce the cost (e.g., by reducing the amount of polymer used in the composite) and weight of the composite material. A blowing agent may be an endothermic or exothermic blowing agent. An example of a chemical endothermic blowing agent is Hydrocerol BIH (i.e., sodium bicarbonate/citric acid), which is available from Clariant Corp., whereas an example of a chemical exothermic foaming agent is azodicarbonamide, which is available from Uniroyal Chemical Co.


The use of thermosetting materials may, for example, reduce moisture absorption and increase the strength of products manufactured from the reinforced composite material. Examples of thermosetting materials include polyurethanes (e.g., isocyanates), phenolic resins, unsaturated polyesters, epoxy resins, and other similar or suitable materials. Combinations of the aforementioned materials are also examples of thermosetting materials.


Pigments may be used to give the composite a desired color (e.g., white, cedar, gray, and redwood). Examples of pigments include titanium dioxide, iron oxide, and other similar or suitable colorant additives.


Titanium dioxide is also an example of a weathering additive. Other similar or suitable weathering additives include, but are not limited to, other ultraviolet absorbers. Examples of other ultraviolet absorbers include organic chemical agents such as benzophenone and benzotriazole types.


The substrate may not provide the desired aesthetic characteristics. As a result, exemplary embodiments of the present invention may provide a cap layer on the substrate. In an exemplary embodiment, the cap layer may be comprised of PVC, PE, or another similar or suitable material. The use of a cap layer may enable lower cost, less attractive, yet structurally desirable materials that may have a high cellulosic content to be used as the base substrate. For instance, the cap layer may be applied on the substrate to provide an attractive and protective finish for the component. For example, the cap layer may be provided in any desired color (e.g., to match the appearance of a deck or building exterior), and it may have a smooth outer surface or a pattern or texture formed on its outer surface.


One exemplary embodiment of a cap layer may be made from a plastic material, which may, for example, be comprised of a blend of two or more polymers. In particular, any number of polymers may be used to obtain a blend having desirable weathering characteristics. For instance, examples of a blend include, but are not limited to, PVC compounds, PE compounds, PVC/acrylic alloys, other acrylic alloys, and other similar or suitable alloys, compounds, and mixtures having desirable weathering, aesthetic, degradation, and/or durability characteristics. In other exemplary embodiments, a suitable composite may be used as a cap layer. An example of a composite may be comprised of PVC, PE, polypropylene, or any other similar or suitable plastic.


In one exemplary embodiment, a PVC/acrylic alloy may be particularly useful for making a cap layer having desirable resistance to scratching and/or to degradation such as may be caused by UV light or other environmental factors. For example, the plastic material may include polyvinyl chloride in an amount between about 10% by weight and about 90% by weight and acrylic in an amount between about 10% by weight and about 90% by weight. In another exemplary embodiment, the plastic material may include polyvinyl chloride in an amount between about 20% by weight and about 80% by weight and acrylic in an amount between about 20% by weight and about 80% by weight. In still another exemplary embodiment, the plastic material may include polyvinyl chloride in an amount between about 40% by weight and about 60% by weight and acrylic in an amount between about 40% by weight and about 60% by weight. In yet another exemplary embodiment, the plastic material may include polyvinyl chloride in an amount of about 50% by weight and acrylic in an amount of about 50% by weight.


In another exemplary embodiment, a PE compound or mixture may be useful for making a cap layer having desirable resistance to scratching and/or to degradation such as may be caused by UV light or other environmental factors. For example, the PE compound or mixture may include polyethylene in an amount between about 20% by weight and about 70% by weight. In still another exemplary embodiment, the PE compound or mixture may include polyethylene in an amount between about 20% and about 40% by weight.


In some other exemplary embodiments of the present invention, a cap layer may be made from a plastic material that is comprised of an acrylic-styrene-acrylonitrile (i.e., ASA) material or compound. In some exemplary embodiments, the plastic material may be comprised of ASA in an amount of 100% by weight. In other exemplary embodiments, the plastic material may be comprised of a major proportion of ASA. An example of an ASA compound is Luran S, which is available from BASF Corporation of Florham Park, N.J. An ASA compound may also provide desirable weathering characteristics for some exemplary components of the present invention.


Another example of a cap layer may be a composite that has more desirable aesthetic characteristics. An exemplary embodiment of a composite may or may not be a blend of two or more polymers. Furthermore, as previously mentioned, an example of a composite may be comprised of PVC, PE, or any other similar or suitable plastic.


An exemplary embodiment of a composite cap layer preferably includes cellulosic filler, which may facilitate a desired wood-like appearance. In one example, the cellulosic filler may be included in a cap material in an amount in the range from about 20% to about 70% by weight, more preferably in an amount in the range from about 35% to about 55% by weight, and still more preferably in an amount of about 40% to about 45% by weight. In one example, the cap material may be comprised of cellulosic filler in amount of about 43% by weight.


In addition to the amount of cellulosic filler, the roughness of a cap layer may be controlled by selecting the desired size of cellulosic filler. A rough cap may facilitate a desired wood-like appearance. In some exemplary embodiments of the present invention, 40 mesh or 60 mesh cellulosic filler may be used. However, in other exemplary embodiments, smaller or larger sizes of cellulosic filler may be used. By decreasing the size of the cellulosic filler, the roughness of a resulting cap layer may be reduced. On the other hand, by increasing the size of cellulosic filler, a cap layer may be made rougher. Unless expressly claimed otherwise, it is not intended to limit the cellulosic filler to any particular mesh size.


Any suitable cellulosic filler may be used. Examples of cellulosic fillers include sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagass, plant fibers, bamboo fiber, palm fiber, kenaf, flax, and other similar or suitable materials. In addition, it should be recognized that virgin or recycled cellulosic filler may be used.


In order to further enhance the appearance of the cap layer, streaker(s) may be used. By using streaker(s) in a cap layer, it limits the amount of streaker(s) needed as the streaker(s) are not dispersed throughout the entire cross-section of the component. A streaker refers to a color additive that has a different, preferably higher, melt index than the base plastic material used in a cap layer or a color additive that has some other distinguishing characteristic that facilitates streaking when mixed with the base plastic material used in a cap layer (e.g., a desired degree of immiscibility when mixed with the base plastic material). Examples of streakers include, but are not limited to, PVC, ABS, and polycarbonate (i.e., PC) pellets or any other suitable plastic pellet that includes a desired pigment. Examples of streakers are available from companies such as Americhem and Penn Color. Streaker(s) may be included in a cap layer in any desired amount and form. For example, in some exemplary embodiments, streaker(s) may be included in the cap layer in an amount in the range from about 0.01% to about 20% by weight, more preferably in an amount in the range from about 0.01% to about 10% by weight, and still more preferably in an amount of about 2% to about 8% by weight. A desired streaking effect may be achieved by selecting the desired amount(s), color(s), and melt index(es) of streaker(s).


In addition to cellulosic filler and optional streaker(s), the cap layer may be comprised of any desired base plastic material. For instance, in one exemplary embodiment of the present invention, a base plastic material may provide a solid or base color (e.g., brown, tan, gray, or any other desired base color), and streaker(s) may be used in addition to the solid or base color to obtain a variegated appearance. Nevertheless, it is not intended to limit the present invention to any particular base plastic material, unless expressly claimed otherwise. As previously mentioned, examples of base plastic material may include, but are not limited to, PVC material, PE material, PVC compounds, PE compounds, PVC/acrylic alloys, other acrylic alloys, acrylic-styrene-acrylonitrile (i.e., ASA), ASA compounds, and other similar or suitable alloys, compounds, and plastics.


An exemplary cap layer of the present invention may also include other ingredients as described above in reference to the plastic material of the substrate, such as other plastics, cross-linking agents, blowing agents, foaming agents, foam modifiers, lubricants, stabilizers, accelerators, inhibitors, enhancers, compatibilizers, thermosetting materials, weathering additives, rubber, colorants, process aids, and inorganic fillers. These materials may be used individually, or in combination, to improve the characteristics of the plastic material and/or enhance the manufacture or moldability thereof.


In view of the foregoing, one example of a cap layer may be PE composite. This example of a cellulosic composite material may include at least one cellulosic filler in an amount of about 20% to about 70% by weight, more preferably about 30% to about 60% by weight, still more preferably about 35% to about 55% by weight, and even more preferably about 40% to about 45% by weight. The composite may also include polyethylene resin in an amount of about 20% to about 70% by weight, more preferably about 25% to about 40% by weight, still more preferably about 25% to about 35% by weight, and even more preferably about 30% to about 35% by weight. The composite may also include talc or another suitable inorganic filler in an amount of about 0.01% to about 20% by weight (e.g., about 1% to about 20% by weight), more preferably about 5% to about 15% by weight, and still more preferably about 10% to about 15% by weight. In addition, the composite may include lubricant in an amount of about 5% to about 10% by weight and more preferably about 6% to about 9% by weight. Streaker(s) may also be included in the composite in an amount of about 0.01°/o to about 20% by weight, more preferably in an amount in the range from about 0.01% to about 10% by weight, and still more preferably in an amount of about 2% to about 8% by weight. The combination of cellulosic filler and streaker(s) may facilitate a desired variegated appearance that simulates natural wood.



FIGS. 1 and 2 show examples in which the cap layer 14 covers the entire exterior surface of the profile. If desired, a cap layer 14 may also be applied on an interior surface of the profile. It should also be recognized that a cap layer 14 may only cover a limited portion of the interior or exterior surface of the substrate 12 in certain embodiments of the present invention. FIGS. 4 and 5 show examples in which a cap layer 14 only covers a portion of the substrate 12. For example, the cap layer 14 may only cover a portion of the substrate 12 that is intended to be visible during the intended use of a component, which may further help reduce the cost of the component. The cap layer 14 may have different thicknesses, depending upon the component design and intended use. In some exemplary embodiments, the cap layer 14 may have a thickness of approximately 50 mils to about 100 mils.


An exemplary component of the present invention may be manufactured using suitable manufacturing techniques. For example, the substrate and the cap layer may be co-extruded. Alternatively, the cap layer may be applied on the substrate (or vice versa) in a sequential extrusion process. Other molding techniques including, but not limited to, injection molding and compression molding may be used to manufacture a component of the present invention. In addition, it should be recognized that the layers may be formed separately and then joined then in a subsequent process, such as with the use of adhesives or other suitable bonding materials. In other examples, a component may be made using one or more manufacturing methods including, but not limited to: extrusion, co-extrusion, compression molding, and other similar or suitable manufacturing methods.



FIG. 6 is an example of an extrusion system that may be used to make a component of one exemplary embodiment of the present invention. The ingredients of one wood composite material may be physically mixed or blended by any conventional mixing device or industrial blender 30. The composition may then be placed into a feed hopper 32. Feed hoppers such as gravity feed or force feed mechanisms (having a crammer) may be used. After the materials are mixed and transferred to the hopper 32, they may be delivered to a heated extruder 34 where they are processed at a suitable speed and temperature. Several well-known extruders may be used in the exemplary embodiments of the present invention. For example, a twin screw extruder by Cincinnati Milacron (CM80-HP) may be used. In the extruder 34, the materials may be blended and heated and then forced into a die system 36. The die system 36 can be made up of one or more plates. The die system 36 allows the starting materials to bond and form a shaped product. The extruded material 38 may then, for example, be cooled in a cooling chamber 40 and, in one exemplary embodiment, be later secured to a cap layer and cut to a required size.


In another exemplary embodiment, a cap layer may be simultaneously processed in a system similar to the one described above, and the melt flows from each of the extruders can be joined in the same die system to form the desired profile. A cross-sectional view of one example of such a co-extrusion system is shown in FIG. 7. In FIG. 7, a co-extrusion apparatus 42 may include at least one extruder 44 which is adapted to prepare a first wood composite material 45 for extrusion through a cross-head die 49 which forms a profile 43 and urges it along longitudinal direction 46. As shown in this example, the co-extrusion apparatus may include two extruders 44 for providing the first wood composite material 45 to the cross-head die 49. At least one other layer of cap material such as layer 47 may be added through the use of at least one additional extruder such as extruder 48. Layer 45 and layer 47 are formed by the forming die 49 into the desired final shape 43, e.g., a hollow or solid cross-section. In this example, a cross-sectional view of a hollow profile 43 is shown. The hollow profile 43 is comprised of an inner substrate layer 45 and a cap layer 47 that are intimately bonded. Although not shown, it should be recognized that a tie layer may be extruded between layers 45 and 47, if desired or necessary. In some exemplary embodiments, resin compatibility may be sufficient to secure substrate layer 45 to cap layer 47.



FIG. 8 shows another example of an extrusion system that may be used to form a component of one exemplary embodiment of the present invention. This exemplary embodiment may improve manufacturing efficiency by simultaneously producing multiple components and overcoming the extrusion cooling limitations of a substantially similar single component that is produced at a substantially same rate. A main extruder 50 may receive a first material where it is processed at a suitable speed and temperature. The main extruder 50 may heat and blend the material and force it to a junction 52. The junction 52 may split the heated material flow into multiple flows, such as, a first flow and a second flow. The first flow may travel through a first branch 54 of the junction 52, and the second flow may travel through a second branch 56 of the junction 52. The junction 52 may include as many branches as desired, to enable the system to form as many simultaneous extruded components as desired.


A second extruder 58 may receive a second material where it is processed at a suitable speed and temperature. The second extruder 58 may force the second material through a bracket or portion 60 to the first branch 54 and second branch 56 to co-extrude the second material with the first material. Any number of additional extruders may be used to apply as many layers as desired. In one exemplary embodiment, the first material may be a substrate layer, and the second material may be a cap layer. The cap layer may be applied to any suitable side or sides of the substrate layer or may be applied to all of the sides of the substrate layer. The first flow may pass through the first branch 54 to a first die system 62. The second flow may pass through the second branch 56 to a second die system 64. The first and second die systems, 62 and 64 respectively, may have any size and shape desired. The first and second flows may exit the die systems as first extruded component 66 and second extruded component 68. The extruded components may optionally be passed on to a cooling system or systems. Such an extrusion system may allow multiple components to be formed simultaneously. For example, a four-branch junction could form four different shaped components simultaneously. Each component may have a substrate layer and a cap layer. FIGS. 9 and 10 illustrate examples of die systems that may be used in exemplary embodiments of the present invention. FIG. 9 shows an example of a die system 70 adapted to interlock a substrate layer and a cap layer, whereas FIG. 10 shows an example of a die system 80 adapted to form a cap layer on a top surface of a substrate layer.


EXAMPLES

One example of a composite that is suitable for a substrate comprises ingredients in the following amounts:















PARTS PER 100 PARTS



INGREDIENT
OF RESIN
WEIGHT PERCENT

















wood flour
150
55.1


PVC resin
100
36.8


lubricant
7.5
2.8


acrylic modifier
6
2.2


calcium carbonate
5
1.8


tin stabilizer
2.5
0.9


process aid
1
0.4









Another example of a composite that is suitable for a substrate comprises ingredients in the following amounts:















PARTS PER 100 PARTS



INGREDIENT
OF RESIN
WEIGHT PERCENT

















wood flour
183
60


PVC resin
100
32.8


lubricant
7.5
2.5


acrylic modifier
6
2


calcium carbonate
5
1.6


tin stabilizer
2.5
0.8


process aid
1
0.3









A third example of a composite that is suitable for a substrate comprises ingredients in the following amounts:















PARTS PER 100 PARTS



INGREDIENT
OF RESIN
WEIGHT PERCENT

















wood flour
146.6
50.0


PVC resin
100
34.1


ABS resin
18.4
6.3


thermal stabilizer
3.75
1.3


lubricant
10
3.4


impact modifier
6.0
2.1


process aid
1
0.3


calcium carbonate
7.5
2.6









A fourth example of a composite that is suitable for a substrate comprises ingredients in the following amounts:















PARTS PER 100 PARTS



INGREDIENT
OF RESIN
WEIGHT PERCENT

















wood flour
179.3
55.0


PVC resin
100
30.7


ABS resin
18.4
5.7


thermal stabilizer
3.75
1.2


lubricant
10
3.1


impact modifier
6.0
1.8


process aid
1
0.3


calcium carbonate
7.5
2.3









A fifth example of a composite that is suitable for a substrate comprises ingredients in the following amounts:















PARTS PER 100 PARTS



INGREDIENT
OF RESIN
WEIGHT PERCENT

















wood flour
220
60.0


PVC resin
100
27.3


ABS resin
18.4
5.0


thermal stabilizer
3.75
1.0


lubricant
10
2.7


impact modifier
6.0
1.6


process aid
1
0.3


calcium carbonate
7.5
2.1









A sixth example of a composite that is suitable for a substrate comprises ingredients in the following amounts:


















PARTS PER 100 PARTS




INGREDIENT
OF RESIN
WEIGHT PERCENT




















wood flour
333.35
50.0



PE resin
100
15.0



lubricant
35
5.3



talc
98.3
14.8



Recycled PE
100
15.0










A first example of a composite that is suitable for a cap layer comprises ingredients in the following amounts:


















PARTS PER 100 PARTS




INGREDIENT
OF RESIN
WEIGHT PERCENT




















wood flour
133
43.2



PE
100
32.5



lubricant
24.9
8.1



Talc
38.2
12.4



Colorant
11.5
3.8










A second example of a composite that is suitable for a cap layer comprises ingredients in the following amounts:


















PARTS PER 100 PARTS




INGREDIENT
OF RESIN
WEIGHT PERCENT




















wood flour
133
42.5



PE
100
31.9



lubricant
24.9
8.0



Talc
38.2
12.2



Colorant
16.9
5.3










Any embodiment of the present invention may include any of the optional or preferred features of the other embodiments of the present invention. The exemplary embodiments herein disclosed are not intended to be exhaustive or to unnecessarily limit the scope of the invention. The exemplary embodiments were chosen and described in order to explain the principles of the present invention so that others skilled in the art may practice the invention. Having shown and described exemplary embodiments of the present invention, those skilled in the art will realize that many variations and modifications may be made to affect the described invention. Many of those variations and modifications will provide the same result and fall within the spirit of the claimed invention. It is the intention, therefore, to limit the invention only as indicated by the scope of the claims.

Claims
  • 1. A coextruded component comprising: a substrate layer comprising: (a) cellulosic material in an amount between about 30% by weight to about 70% by weight of said substrate material; and(b) polyethylene material in an amount between about 30% by weight to about 70% by weight of said substrate material, said polyethylene material comprising polyethylene resin; anda cap layer secured to said substrate layer, said cap layer comprising: (a) cellulosic material in an amount between about 20% by weight and about 70% by weight of said cap layer;(b) polyethylene resin in an amount between about 20% by weight and about 70% by weight of said cap layer; and(c) at least one streaker in a total amount between about 0.01% by weight and about 20% by weight of said cap layer.
  • 2. The coextruded component of claim 1 wherein the coextruded component is a deck board.
  • 3. The coextruded component of claim 1 wherein the coextruded component is a hollow deck rail.
  • 4. The coextruded component of claim 1 wherein: said substrate layer comprises: (a) said cellulosic material in an amount between about 40% by weight to about 60% by weight of said substrate material; and(b) said polyethylene material in an amount between about 30% by weight to about 60% by weight of said substrate material; andsaid cap layer comprises: (a) said cellulosic material in an amount between about 35% by weight and about 55% by weight of said cap layer;(b) said polyethylene resin in an amount between about 25% by weight and about 40% by weight of said cap layer; and(c) said at least one streaker in a total amount between about 0.01% by weight and about 10% by weight of said cap layer.
  • 5. The coextruded component of claim 4 wherein said substrate and/or cap layer further comprises at least one inorganic filler in a total amount between about 1% by weight and about 20% by weight of said layer.
  • 6. The coextruded component of claim 4 wherein said substrate and/or cap layer further comprises at least one inorganic filler in a total amount between about 5% by weight and about 15% by weight of said layer.
  • 7. The coextruded component of claim 6 wherein said at least one inorganic filler comprises talc.
  • 8. The coextruded component of claim 1 wherein: said substrate layer comprises: (a) said cellulosic material in an amount of about 55% by weight of said substrate material; and(b) said polyethylene material in an amount of about 30% to about 45% by weight of said substrate material; andsaid cap layer comprises: (a) said cellulosic material in an amount between about 40% by weight and about 45% by weight of said cap layer;(b) said polyethylene resin in an amount between about 25% by weight and about 35% by weight of said cap layer; and(c) said at least one streaker in a total amount between about 2% by weight and about 8% by weight of said cap layer.
  • 9. The coextruded component of claim 8 wherein said substrate and/or cap layer further comprises at least one inorganic filler in a total amount between about 1% by weight and about 20% by weight of said layer.
  • 10. The coextruded component of claim 8 wherein said substrate and/or cap layer further comprises at least one inorganic filler in a total amount between about 5% by weight and about 15% by weight of said layer.
  • 11. The coextruded component of claim 10 wherein said at least one inorganic filler comprises talc.
  • 12. A coextruded deck board comprising: a substrate layer comprising: (a) cellulosic material in an amount between about 40% by weight to about 60% by weight of said substrate material; and(b) polyethylene material in an amount between about 30% by weight to about 60% by weight of said substrate material, said polyethylene material comprising polyethylene resin; anda cap layer secured to said substrate layer, said cap layer comprising: (a) cellulosic material in an amount between about 40% by weight and about 45% by weight of said cap layer;(b) polyethylene resin in an amount between about 30% by weight and about 35% by weight of said cap layer; and(c) at least one streaker in a total amount between about 0.01% by weight and about 10% by weight of said cap layer.
  • 13. The coextruded deck board of claim 12 wherein said substrate and/or cap layer further comprises at least one inorganic filler in a total amount between about 5% by weight and about 15% by weight of said layer.
  • 14. The coextruded deck board of claim 13 wherein: said at least one streaker is in a total amount between about 2% by weight and about 8% by weight; andsaid at least one inorganic filler is in a total amount between about 10% by weight and about 15% by weight of said cap layer.
  • 15. A method of forming a cellulosic composite component, said method comprising: providing an extrusion system comprising: a plurality of extruders; andat least one die system;providing a substrate material to a first extruder of said extruders, said substrate material comprising: (a) cellulosic material in an amount between about 30% by weight to about 70% by weight of said substrate material; and(b) polyethylene material in an amount between about 30% by weight to about 70% by weight of said substrate material, said polyethylene material comprising polyethylene resin; andproviding a cap layer material to a second extruder of said extruders, said cap layer material comprising: (a) cellulosic material in an amount between about 20% by weight and about 70% by weight of said cap layer;(b) polyethylene resin in an amount between about 20% by weight and about 70% by weight of said cap layer; and(c) at least one streaker in a total amount between about 0.01% by weight and about 20% by weight of said cap layer;extruding said substrate material;co-extruding said cap layer material onto at least a portion of said substrate material;forming a flow of said substrate material and said cap layer material; andforcing said flow through said at least one die system to form at least one component.
  • 16. The method of claim 15 wherein said component is hollow deck rail.
  • 17. The method of claim 15 wherein said component is a deck board.
  • 18. The method of claim 15 wherein said extrusion system comprises a junction associated with said extruders and a plurality of branches associated with said junction, said method further comprising: extruding said substrate material through said junction and said plurality of branches;co-extruding said cap layer material onto at least a portion of said substrate material forming a plurality of flows from said substrate material and said cap layer material; andforcing said flows respectively through a plurality of die systems to simultaneously form a plurality of components.
  • 19. The method of claim 15 wherein said cap layer material substantially covers an entire exterior surface of said substrate material of said component.
  • 20. The method of claim 15 wherein: said substrate layer comprises: (a) said cellulosic material in an amount between about 40% by weight to about 60% by weight of said substrate material; and(b) said polyethylene material in an amount between about 30% by weight to about 60% by weight of said substrate material; andsaid cap layer comprises: (a) said cellulosic material in an amount between about 40% by weight and about 45% by weight of said cap layer;(b) said polyethylene resin in an amount between about 30% by weight and about 35% by weight of said cap layer;(c) said at least one streaker in a total amount between about 0.01% by weight and about 10% by weight of said cap layer; and(d) at least one inorganic filler in a total amount between about 5% by weight and about 15% by weight of said cap layer.
Parent Case Info

This application is a continuation of U.S. patent application Ser. No. 11/935,217, filed Nov. 5, 2007, which is hereby incorporated by reference in its entirety. This application is also a continuation-in-part of U.S. application Ser. No. 11/967,434, filed Dec. 31, 2007, which claims priority to U.S. Provisional Application No. 60/882,869, filed Dec. 29, 2006, each of which is hereby incorporated by reference in its entirety.

US Referenced Citations (395)
Number Name Date Kind
2072687 Robinson Mar 1937 A
2153316 Sherrard et al. Apr 1939 A
2156160 Olson et al. Apr 1939 A
2188396 Semon Jan 1940 A
2306274 Meiler Dec 1942 A
2316283 Piperoux et al. Apr 1943 A
2451558 Schlosser Oct 1948 A
2489373 Gilman Nov 1949 A
2519442 Delorme et al. Aug 1950 A
2535373 Shearer et al. Dec 1950 A
2558378 Petry Jun 1951 A
2634534 Brown Apr 1953 A
2635976 Meiler et al. Apr 1953 A
2680102 Becher Jun 1954 A
2759837 Roberts Aug 1956 A
2789903 Lukman et al. Apr 1957 A
2935763 Newman et al. May 1960 A
2976164 Glab Mar 1961 A
3287480 Wechsler et al. Nov 1966 A
3308218 Wiegand et al. Mar 1967 A
3309444 Schueler Mar 1967 A
3492388 Inglin-Knuse Jan 1970 A
3493527 Schueler Feb 1970 A
3533906 Reiniger Oct 1970 A
3562373 Logrippo Feb 1971 A
3645939 Gaylord Feb 1972 A
3671615 Price Jun 1972 A
3769380 Wiley Oct 1973 A
3852387 Bortnick et al. Dec 1974 A
3864201 Susuki et al. Feb 1975 A
3867493 Seki Feb 1975 A
3878143 Baumann et al. Apr 1975 A
3879505 Boutillier et al. Apr 1975 A
3888810 Shinomura Jun 1975 A
3899559 Johnanson et al. Aug 1975 A
3908902 Collins et al. Sep 1975 A
3922328 Johnson Nov 1975 A
3931384 Forquer et al. Jan 1976 A
3943079 Hamed Mar 1976 A
3954555 Kole et al. May 1976 A
3956541 Pringle May 1976 A
3956555 McKean May 1976 A
3969459 Fremont et al. Jul 1976 A
4005035 Deaver Jan 1977 A
4005162 Bucking Jan 1977 A
4012348 Chelland et al. Mar 1977 A
4016232 Pringle Apr 1977 A
4016233 Pringle Apr 1977 A
4018722 Baker Apr 1977 A
4029831 Daunheimer Jun 1977 A
4045603 Smith Aug 1977 A
4048101 Nakamachi et al. Sep 1977 A
4056591 Goettler et al. Nov 1977 A
4058580 Flanders Nov 1977 A
4071479 Broyde et al. Jan 1978 A
4071494 Gaylord Jan 1978 A
4081582 Butterworth et al. Mar 1978 A
4091153 Holman May 1978 A
4097648 Pringle Jun 1978 A
4101050 Buckler et al. Jul 1978 A
4102106 Golder et al. Jul 1978 A
4107110 Lachowicz et al. Aug 1978 A
4115497 Halmo et al. Sep 1978 A
4129132 Butterworth et al. Dec 1978 A
4133930 Wright et al. Jan 1979 A
4145389 Smith Mar 1979 A
4157415 Lindenberg Jun 1979 A
4168251 Schinzel et al. Sep 1979 A
4178411 Cole et al. Dec 1979 A
4181764 Totten Jan 1980 A
4187352 Klobbie Feb 1980 A
4191798 Schumacher et al. Mar 1980 A
4192839 Hayashi et al. Mar 1980 A
4198363 Noel Apr 1980 A
4203876 Dereppe et al. May 1980 A
4228116 Colombo et al. Oct 1980 A
4239679 Rolls et al. Dec 1980 A
4241125 Canning et al. Dec 1980 A
4241133 Lund et al. Dec 1980 A
4244903 Schnause Jan 1981 A
4248743 Goettler Feb 1981 A
4248820 Haataja Feb 1981 A
4250222 Mavel et al. Feb 1981 A
4263184 Leo et al. Apr 1981 A
4263196 Schumacher et al. Apr 1981 A
4272577 Lyng Jun 1981 A
4273688 Porzel et al. Jun 1981 A
4277428 Luck et al. Jul 1981 A
4290988 Nopper et al. Sep 1981 A
4297408 Stead et al. Oct 1981 A
4303019 Haataja et al. Dec 1981 A
4305901 Prince et al. Dec 1981 A
4317765 Gaylord Mar 1982 A
4323625 Coran et al. Apr 1982 A
4351873 Davis Sep 1982 A
4376144 Goettler Mar 1983 A
4382108 Carroll et al. May 1983 A
4382758 Nopper et al. May 1983 A
4393020 Li et al. Jul 1983 A
4414267 Coran et al. Nov 1983 A
4420351 Lussi et al. Dec 1983 A
4430468 Schumacher Feb 1984 A
4440708 Haataja et al. Apr 1984 A
4480061 Coughlin et al. Oct 1984 A
4481701 Hewitt Nov 1984 A
4491553 Yamada et al. Jan 1985 A
4503115 Hemels et al. Mar 1985 A
4505869 Nishibori Mar 1985 A
4506037 Suzuki et al. Mar 1985 A
4508595 Gasland Apr 1985 A
4518552 Matsuo et al. May 1985 A
4562218 Fornadel et al. Dec 1985 A
4594372 Natov et al. Jun 1986 A
4597928 Terentiev et al. Jul 1986 A
4610900 Nishibori Sep 1986 A
4645631 Hegenstaller et al. Feb 1987 A
4659754 Edwards et al. Apr 1987 A
4663225 Farley et al. May 1987 A
4686251 Ostermann et al. Aug 1987 A
4687793 Motegi et al. Aug 1987 A
4708623 Aoki et al. Nov 1987 A
4717742 Beshay Jan 1988 A
4734236 Davis Mar 1988 A
4737532 Fujita et al. Apr 1988 A
4744930 Twist et al. May 1988 A
4746688 Bistak et al. May 1988 A
4769109 Tellvik et al. Sep 1988 A
4769274 Tellvik et al. Sep 1988 A
4783493 Motegi et al. Nov 1988 A
4789604 van der Hoeven Dec 1988 A
4790966 Sandberg et al. Dec 1988 A
4791020 Kokta Dec 1988 A
4800214 Waki et al. Jan 1989 A
4801495 van der Hoeven Jan 1989 A
4818590 Prince et al. Apr 1989 A
4818604 Tock Apr 1989 A
4820749 Beshay Apr 1989 A
4833194 Kuan et al. May 1989 A
4844766 Held Jul 1989 A
4851458 Hopperdietzel Jul 1989 A
4865788 Davis Sep 1989 A
4889673 Takimoto Dec 1989 A
4894192 Warych Jan 1990 A
4915764 Miani Apr 1990 A
4927572 van der Hoeven May 1990 A
4927579 Moore May 1990 A
4935182 Ehner et al. Jun 1990 A
4960548 Ikeda et al. Oct 1990 A
4968463 Levasseur Nov 1990 A
4973440 Tamura et al. Nov 1990 A
4978489 Radvan et al. Dec 1990 A
4988478 Held Jan 1991 A
5002713 Palardy et al. Mar 1991 A
5008310 Beshay Apr 1991 A
5009586 Pallmann Apr 1991 A
5049334 Bach Sep 1991 A
5055247 Ueda et al. Oct 1991 A
5057167 Gersbeck Oct 1991 A
5064592 Ueda et al. Nov 1991 A
5075057 Hoedl Dec 1991 A
5075359 Castagna et al. Dec 1991 A
5078937 Eela Jan 1992 A
5082605 Brooks et al. Jan 1992 A
5087400 Theuveny Feb 1992 A
5088910 Goforth et al. Feb 1992 A
5091436 Frisch et al. Feb 1992 A
5096046 Goforth et al. Mar 1992 A
5096406 Brooks et al. Mar 1992 A
5110663 Nishiyama et al. May 1992 A
5110843 Bries et al. May 1992 A
5120776 Raj et al. Jun 1992 A
5145891 Yasukawa et al. Sep 1992 A
5151238 Earl et al. Sep 1992 A
5153241 Beshay Oct 1992 A
5160784 Shmidt et al. Nov 1992 A
5165941 Hawley Nov 1992 A
5194461 Bergquist et al. Mar 1993 A
5218807 Fulford Jun 1993 A
5219634 Aufderhaar Jun 1993 A
5234652 Woodhams et al. Aug 1993 A
5258232 Summers et al. Nov 1993 A
5272000 Chenoweth et al. Dec 1993 A
5276082 Forry et al. Jan 1994 A
5284710 Hartley et al. Feb 1994 A
5288772 Hon Feb 1994 A
5302634 Mushovic Apr 1994 A
5318737 Trabert et al. Jun 1994 A
5356697 Jonas Oct 1994 A
5369147 Mushovic Nov 1994 A
5387381 Saloom Feb 1995 A
5393536 Brandt et al. Feb 1995 A
5406768 Giuseppe et al. Apr 1995 A
5413745 Andersson May 1995 A
5422170 Iwata et al. Jun 1995 A
5423933 Horian Jun 1995 A
5435954 Wold Jul 1995 A
5441801 Deaner et al. Aug 1995 A
5443887 Nakao Aug 1995 A
5458834 Faber et al. Oct 1995 A
5474722 Woodhams Dec 1995 A
5480602 Nagaich Jan 1996 A
5486553 Deaner et al. Jan 1996 A
5497594 Giuseppe et al. Mar 1996 A
5505900 Suwanda et al. Apr 1996 A
5516472 Laver May 1996 A
5518677 Deaner et al. May 1996 A
5532065 Gubitz et al. Jul 1996 A
5537789 Minke et al. Jul 1996 A
5538777 Pauley et al. Jul 1996 A
5539027 Deaner et al. Jul 1996 A
5574094 Malucelli et al. Nov 1996 A
5576374 Betso et al. Nov 1996 A
5585155 Heikkila et al. Dec 1996 A
5593625 Riebel et al. Jan 1997 A
5616350 Wissmann et al. Apr 1997 A
5624616 Brooks Apr 1997 A
5695874 Deaner et al. Dec 1997 A
5711349 Wissmann Jan 1998 A
5725939 Nishibori Mar 1998 A
5735092 Clayton et al. Apr 1998 A
5744210 Hofmann et al. Apr 1998 A
5759680 Brooks et al. Jun 1998 A
5773138 Seethamraju et al. Jun 1998 A
5776841 Bondoc et al. Jul 1998 A
5783125 Bastone et al. Jul 1998 A
5795641 Pauley et al. Aug 1998 A
5807514 Grinshpun et al. Sep 1998 A
5827462 Brandt et al. Oct 1998 A
5827607 Deaner et al. Oct 1998 A
5836128 Groh et al. Nov 1998 A
5847016 Cope Dec 1998 A
5851469 Muller et al. Dec 1998 A
5858522 Turk et al. Jan 1999 A
5863064 Rheinlander et al. Jan 1999 A
5863480 Suwanda Jan 1999 A
5866054 Dorchester et al. Feb 1999 A
5866264 Zehner et al. Feb 1999 A
5869138 Nishibori Feb 1999 A
5869176 Dorchester et al. Feb 1999 A
5882564 Puppin Mar 1999 A
5910358 Thoen et al. Jun 1999 A
5932334 Deaner et al. Aug 1999 A
5948505 Puppin Sep 1999 A
5948524 Seethamraju et al. Sep 1999 A
5951927 Cope Sep 1999 A
5965075 Pauley et al. Oct 1999 A
5981067 Seethamraju et al. Nov 1999 A
5985429 Plummer et al. Nov 1999 A
6004652 Clark Dec 1999 A
6004668 Deaner et al. Dec 1999 A
6007656 Heikkila et al. Dec 1999 A
6011091 Zehner Jan 2000 A
6015611 Deaner et al. Jan 2000 A
6015612 Deaner et al. Jan 2000 A
6035588 Zehner et al. Mar 2000 A
6044604 Clayton et al. Apr 2000 A
6054207 Finley Apr 2000 A
6066367 Nishibori May 2000 A
6066680 Cope May 2000 A
6083601 Prince et al. Jul 2000 A
6103791 Zehner Aug 2000 A
6106944 Heikkila et al. Aug 2000 A
6114008 Eby et al. Sep 2000 A
6117924 Brandt Sep 2000 A
6122877 Hendrickson et al. Sep 2000 A
6131355 Groh et al. Oct 2000 A
6133348 Kolla et al. Oct 2000 A
6153293 Dahl et al. Nov 2000 A
6161353 Negola et al. Dec 2000 A
6180211 Held Jan 2001 B1
6180257 Brandt et al. Jan 2001 B1
6207729 Medoff et al. Mar 2001 B1
6210616 Suwanda Apr 2001 B1
6210792 Seethamraju et al. Apr 2001 B1
6248813 Zehner Jun 2001 B1
6265037 Godavarti et al. Jul 2001 B1
6272808 Groh et al. Aug 2001 B1
6280667 Koenig et al. Aug 2001 B1
6284098 Jacobsen Sep 2001 B1
6295777 Hunter et al. Oct 2001 B1
6295778 Burt Oct 2001 B1
6337138 Zehner et al. Jan 2002 B1
6341458 Burt Jan 2002 B1
6342172 Finley Jan 2002 B1
6344268 Stucky et al. Feb 2002 B1
6344504 Zehner et al. Feb 2002 B1
6346160 Puppin Feb 2002 B1
6357197 Serino et al. Mar 2002 B1
6358585 Wolff Mar 2002 B1
6360508 Pelfrey et al. Mar 2002 B1
6362252 Prutkin Mar 2002 B1
6409952 Hacker et al. Jun 2002 B1
6423257 Stobart et al. Jul 2002 B1
6448307 Medoff et al. Sep 2002 B1
6453630 Buhrts et al. Sep 2002 B1
6464913 Korney, Jr. Oct 2002 B1
6498205 Zehner Dec 2002 B1
6511757 Brandt et al. Jan 2003 B1
6531010 Puppin Mar 2003 B2
6569540 Preston et al. May 2003 B1
6578368 Brandt et al. Jun 2003 B1
6579605 Zehner Jun 2003 B2
6590004 Zehner Jul 2003 B1
6605245 Dubelsten et al. Aug 2003 B1
6617376 Korney, Jr. Sep 2003 B2
6632863 Hutchison et al. Oct 2003 B2
6637213 Hutchison et al. Oct 2003 B2
6641384 Bosler et al. Nov 2003 B2
6662515 Buhrts et al. Dec 2003 B2
6680090 Godavarti et al. Jan 2004 B2
6682789 Godavarti et al. Jan 2004 B2
6682814 Hendrickson et al. Jan 2004 B2
6685858 Korney, Jr. Feb 2004 B2
6708504 Brandt et al. Mar 2004 B2
6716522 Matsumoto et al. Apr 2004 B2
6752941 Hills Jun 2004 B2
6773255 Benz et al. Aug 2004 B2
6780359 Zehner et al. Aug 2004 B1
6784216 Zehner et al. Aug 2004 B1
6784230 Patterson et al. Aug 2004 B1
6793474 Gröeblacher et al. Sep 2004 B2
6844049 Amin-Javaheri Jan 2005 B2
6863972 Burger et al. Mar 2005 B2
6939496 Maine et al. Sep 2005 B2
6958185 Zehner Oct 2005 B1
6971211 Zehner Dec 2005 B1
6984676 Brandt Jan 2006 B1
7017352 Hutchison et al. Mar 2006 B2
7030179 Patterson et al. Apr 2006 B2
7037865 Kimberly May 2006 B1
7186457 Zehner et al. Mar 2007 B1
7378462 Hughes et al. May 2008 B1
7445840 Moriya et al. Nov 2008 B2
7743567 Buhrts Jun 2010 B1
20010019749 Godavarti et al. Sep 2001 A1
20010051242 Godavarti et al. Dec 2001 A1
20010051243 Godavarti et al. Dec 2001 A1
20020015820 Puppin Feb 2002 A1
20020038684 Puppin Apr 2002 A1
20020040557 Felton Apr 2002 A1
20020066248 Buhrts et al. Jun 2002 A1
20020090471 Burger et al. Jul 2002 A1
20020092256 Hendrickson et al. Jul 2002 A1
20020106498 Deaner et al. Aug 2002 A1
20020143083 Korney, Jr. Oct 2002 A1
20020161072 Jacoby et al. Oct 2002 A1
20020166327 Brandt et al. Nov 2002 A1
20020174663 Hutchison et al. Nov 2002 A1
20020192401 Matsumoto et al. Dec 2002 A1
20020192431 Edgman Dec 2002 A1
20030021915 Rohatgi et al. Jan 2003 A1
20030025233 Korney, Jr. Feb 2003 A1
20030050378 Blanchard et al. Mar 2003 A1
20030087994 Frechette May 2003 A1
20030087996 Hutchison et al. May 2003 A1
20030096094 Hayduke May 2003 A1
20030154662 Bruchu et al. Aug 2003 A1
20030176538 Wu et al. Sep 2003 A1
20030229160 Williams et al. Dec 2003 A1
20040026021 Groh et al. Feb 2004 A1
20040038002 Franco et al. Feb 2004 A1
20040048055 Branca Mar 2004 A1
20040071964 Nesbitt Apr 2004 A1
20040142157 Melkonian Jul 2004 A1
20040147625 Dostal et al. Jul 2004 A1
20040148965 Hutchison et al. Aug 2004 A1
20040191494 Nesbitt Sep 2004 A1
20040192794 Patterson et al. Sep 2004 A1
20040219357 Van Dijk et al. Nov 2004 A1
20040220299 Drabeck, Jr. et al. Nov 2004 A1
20050009960 Ton-That et al. Jan 2005 A1
20050013984 Dijk et al. Jan 2005 A1
20050067729 Laver et al. Mar 2005 A1
20050154094 Maeda et al. Jul 2005 A1
20050163969 Brown Jul 2005 A1
20050171246 Maine et al. Aug 2005 A1
20050192382 Maine et al. Sep 2005 A1
20050266222 Clark et al. Dec 2005 A1
20050271872 Dolinar Dec 2005 A1
20050271889 Dolinar Dec 2005 A1
20060010883 Hutchison et al. Jan 2006 A1
20060010884 Hutchison et al. Jan 2006 A1
20060012066 Hutchison et al. Jan 2006 A1
20060012071 Groh et al. Jan 2006 A1
20060022372 Matuana et al. Feb 2006 A1
20060057348 Maine et al. Mar 2006 A1
20060068053 Brandt et al. Mar 2006 A1
20060068215 Dolinar Mar 2006 A2
20060269738 Kimberly Nov 2006 A1
20070052124 Park et al. Mar 2007 A1
20070235705 Burger et al. Oct 2007 A1
20070296112 Brandt et al. Dec 2007 A1
20080093763 Mancosh et al. Apr 2008 A1
20080197523 Heigel et al. Aug 2008 A1
20090264560 Warnes et al. Oct 2009 A1
Foreign Referenced Citations (49)
Number Date Country
2153659 Feb 1999 CA
580130 Sep 1976 CH
343-95 Mar 1995 CL
3037-99 Dec 1999 CL
2042176 Apr 1971 DE
3801574 Aug 1989 DE
4033849 Apr 1991 DE
4221070 Dec 1993 DE
140148 Jun 1979 DK
0269470 Jan 1988 EP
0586211 Mar 1994 EP
0586212 Mar 1994 EP
0586213 Mar 1994 EP
0668142 Aug 1995 EP
0747419 Dec 1996 EP
2270311 Dec 1975 FR
2365017 Apr 1978 FR
2445885 Aug 1980 FR
2564374 Nov 1985 FR
1298823 Dec 1972 GB
1443194 Jul 1976 GB
2036148 Jun 1980 GB
2104903 Mar 1983 GB
2171953 Sep 1986 GB
2186655 Aug 1987 GB
57-190035 Nov 1982 JP
2000-17245 Jan 2000 JP
2000-109589 Apr 2000 JP
2002-86544 Mar 2002 JP
2002-113768 Apr 2002 JP
2002-137333 May 2002 JP
2002-144489 May 2002 JP
9008020 Jul 1990 WO
9513179 May 1995 WO
9911444 Mar 1999 WO
0011282 Mar 2000 WO
0034017 Jun 2000 WO
0039207 Jul 2000 WO
0166873 Sep 2001 WO
02057692 Jul 2002 WO
02079317 Oct 2002 WO
02103113 Dec 2002 WO
03091642 Nov 2003 WO
2004083541 Sep 2004 WO
2004083541 Nov 2004 WO
2004102092 Nov 2004 WO
2006041508 Apr 2006 WO
2006071517 Jul 2006 WO
2007085836 Aug 2007 WO
Non-Patent Literature Citations (61)
Entry
ASTM, Standard Terminology Relating to Wood-Base Fiber and Particle Panel Material, 1995 Annual Book of ASTM Standards, vol. 04.10, Oct. 1986, pp. 214-216.
Bendtsen et al., Chapter 4: Mechanical Properties of Wood, USDA Ag. Hdbk. #72, Wood Handbook: Wood as an Engineering Material, Madison, WI, pp. 4-2 to 4-44 (1987).
Bibliography of Solid Phase Extrusion, pp. 187-195.
Brzoskowski et al., Air-Lubricated Die for Extrusion of Rubber Compounds, Rubber Chemistry and Technology, vol. 60, p. 945-956 (1987).
Campbell et al., The Reinforcement of Thermoplastic Elastomers With Santoweb® Fibre, Short Fibre Reinforced Thermoplastics, pp. 14/1-14/10.
Collier et al., High Strength Extrudates by Melt Transformation Coextrusion, ANTEC, 1987, pp. 497-502.
Collier et al., Streamlined Dies and Profile Extrusion, ANTEC, 1987, pp. 203-206.
Company News, Plastics Industry News, May 1994, pp. 70-71.
Dalvag et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part II. Filling with Processing Aids and Coupling Agents, 1985, vol. 11, pp. 9-38.
Doroudiani et al., Structure and Mechanical Properties Study of Foamed Wood Fiber/Polyethylene Composites, ANTEC, 1997, pp. 2046-2050.
EIN Engineering Inc., Making Wood From Waste Wood and Waste Plastic Using EIN Technology, EIN Plastic & Wood Recycling System Catalog, 1999, 16 pages.
EIN Engineering Inc., Wood-like Material Superior to Real Wood, 5 pages.
English et al., Wastewood-Derived Fillers for Plastics, The Fourth International Conference on Woodfiber-Plastic Composites, 1997, pp. 309-324.
Fiberloc Polymer Composites, B.F. Goodrich, Geon Vinyl Division, section 1, pp. 2-15 (1986).
Fill Thermoplastics with Wood, Modern Plastics, May 1974, pp. 54-55.
Fillers for Thermoplastics: Beyond Resin Stretching, Modern Plastics International, Oct. 1976, pp. 12-15.
From Sweden: Extruded Interior Trim Made of PVC and Wood Fluor, Plastic Building Construction, vol. 9 No. 5, 1986, pp. 5-6.
Forest Products Laboratory, Wood Handbook: Wood as an Engineering Material, Agriculture Handbook 72, United States Department of Agriculture Forest Service, 1974, 2 pages.
Gatenholm et al., The Effect of Chemical Composition of Interphase on Dispersion of Cellulose Fibers in Polymers. I. PVC-Coated Cellulose in Polystyrene, Journal of Applied Polymer Science, vol. 49, 1993, pp. 197-208.
Henrici-Olive et al., Integral/Structural Polymer Foams: Technology, Properties and Applications, Springer Verlag, pp. 111-122 (1986).
Klason et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part 1. Filling without Processing Aids or Coupling Agents, Polymeric Materials, 1984, vol. 10, pp. 159-187.
Kokta et al., Composites of Poly(Vinyl Chloride) and Wood Fibers. Part II: Effect of Chemical Treatment, Polymer Composites, Apr. 1990, pp. 84-89.
Kokta et al., Composites of Polyvinyl Chloride—Wood Fibers. I. Effect of Isocyanate as a Bonding Agent, Polym.—Plast. Technol. Eng., 1990, 29(1&2), pp. 87-118.
Kokta et al., Composites of Polyvinyl Chloride—Wood Fibers. III: Effect of Silane as Coupling Agent, Journal of Vinyl Technology, Sep. 1990, pp. 146-153.
Kokta et al., “Use of Grafted Wood Fibers in Thermoplastic Composites v. Polystyrene”, Centre de recherche en pâtes et papiers, Université du Québec à Trois-Rivières, Canada (1986).
Kokta et al., Use of Wood Fibers in Thermoplastic Composites, Polymer Composites, Oct. 1983, pp. 229-232.
Kowalska et al., Modification of Recyclates of Polyethylene and Poly(Vinyl Chloride) with Scrap Paper Cellulose Fibres, Polymer Recycling, vol. 6, Nos. 2/3, 2001, pp. 109-118.
Lightsey, Organic Fillers for Thermoplastics, Polymer Science and Technology, vol. 17, Aug. 1981, pp. 193-211.
Maldas et al., Composites of Polyvinyl Chloride—Wood Fibers: IV. Effect of the Nature of Fibers, Journal of Vinyl Technology, Jun. 1989, pp. 90-98.
Maldas et al., Improving Adhesion of Wood Fiber with Polystyrene by the Chemical Treatment of Fiber with a Coupling Agent and the Influence on the Mechanical Properties of Composites, Journal of Adhesion Science Technology, vol. 3 No. 7, pp. 529-539 (1989).
Maloney, Modern Particleboard & Dry-Process Fiberboard Manufacturing, Miller Freeman Publications, 1977, 6 pages.
Myers et al., “Wood flour and polypropylene or high-density polyethylene composites: influence of maleated polypropylene concentration and extrusion temperature on properties”, Forest Products Society, Wood Fiber/Polymer Composites: Fundamental Concepts, Processes, and Material Options, Madison, WI, pp. 49-56 (1993).
Myers et al., Bibliography: Composites from Plastics and Wood-Based Fillers, USDA Forest Products Laboratory, Madison, WI, pp. 1-27 odds (1991).
Myers et al., Effects of Composition and Polypropylene Melt Flow on Polypropylene—Waste Newspaper Composites, ANTEC, 1992, pp. 602-604.
Panshin et al., Forest Products, Wood Flour, Chapter 11, 1950, pp. 232-239.
Pornnimit et al., Extrusion of Self-Reinforced Polyethylene, Advances in Polymer Technology, vol. 11, No. 2, pp. 92-98 (1992).
Raj et al., The Influence of Coupling Agents on Mechanical Properties of Composites Containing Cellulose Fillers, Marcel Dekker, Inc., 1990, pp. 339-353.
Raj et al., Use of Wood Fiber as Filler in Common Thermoplastics: Studies on Mechanical Properties, Science and Engineering of Composite Materials, vol. 1 No. 3, 1989, pp. 85-98.
Raj et al., Use of Wood Fibers in Thermoplastics. VII. The Effect of Coupling Agents in Polyethylene—Wood Fiber Composites, Journal of Applied Polymer Science, vol. 37, pp. 1089-1103 (1989).
Redbook, For Resin Producers, Formulators, and Compounders, Plastics Compounding, 1992/93, 2 pages.
Reineke, Wood Flour, U.S. Department of Agriculture Forest Service, U.S. Forest Service Research Note FPL-0113, Jan. 1966, 7 pages.
Resin Stretching: Accent on Performance, Modern Plastic International, Jan. 1974, pp. 58-60.
Robson et al., A Comparison of Wood and Plant Fiber Properties, Proceedings: Woodfiber-Plastic Composites, 1995, pp. 41-46.
Rogalski et al., Poly(Vinyl-Chloride) Wood Fiber Composites, ANTEC, 1987, pp. 1436-1441.
Royal Group Technologies, Inc., New Composite Building Material Adds the Right Mix of Beauty and Brawn to Upscale Homes, www.royalgrouptech.com, printed Aug. 18, 2005, 3 pages.
Schneider et al., Biofibers as Reinforcing Fillers in Thermoplastic Composites, ANTEC, 1994, pp. 6 pages.
Schut, Compatibilizing Mixed Post-Consumer Plastics, Plastics Formulating & Compounding, Mar./Apr. 1997, pp. 43.
Simonsen et al., Wood-Fiber Reinforcement of Styrene-Maleic Anhydride Copolymers, J. Appl. Polm. Sci. 68, No. 10, Jun. 6, 1998, pp. 1567-1573.
Sonwood Outline, Sonesson Plast AB, Apr. 1975.
Sonwood: a new PVC wood-flour alloy for Extrusions and other Plastic Processing Techniques, Sonesson Plast AB, Malmo, Sweden (1975).
Stark et al., Effect of Particle Size on Properties of Wood-Flour Reinforced Polypropylene Composites, The Fourth International Conference on Woodfiber-Plastic Composites, 1997, pp. 134-143.
Stark et al., Photostabilization of Wood Flour Filled Hdpe Composites, ANTEC, May 5-9, 2002, pp. 2209-2013.
Stark, Wood Fiber Derived From Scrap Pallets Used in Polypropylene Composites, Forest Products Journal, vol. 49, No. 6, Jun. 1999, pp. 39-46.
Suchsland et al., Fiberboard Manufacturing Practices in the United States, Agriculture Handbook No. 640, United States Department of Agriculture Forest Service, 1986, 4 pages.
Thomas et al., Wood Fibers for Reinforcing Fillers for Polyolefins, ANTEC, 1984, pp. 687-689.
Wood Filled PVC, Plastics Industry News, Jul. 1996, p. 6.
Woodhams et al., Wood Fibers for Reinforcing Fillers for Polyolefins, Polymer Engineering and Science, Oct. 1984, pp. 1166-1171.
Yam et al., Composites from Compounding Wood Fibers With Recycled High Density Polyethylene, Polymer Engineering and Science, mid-Jun. 1990, pp. 693-699, vol. 30, No. 11.
Yuskova et al., Interaction of Components in Poly(Vinyl Chloride) Filled in Polymerization, Makroniol Chem., Macromol. Symp. 29, 315-320 (1989).
Zadorecki et al., Future Prospects for Wood Cellulose as Reinforcement in Organic Polymer Composites, Polymer Composites, Apr. 1989, pp. 69-77.
W.L. Gore & Associates, Inc. V. Garlock, Inc., 721 F.2d 1540, 1553, 220 USPQ 303, 312-13 (Fed. Cir. 1983), cert denied, 469 U.S. 851 (1984), 18 pages.
Provisional Applications (1)
Number Date Country
60882869 Dec 2006 US
Continuations (1)
Number Date Country
Parent 11935217 Nov 2007 US
Child 11967434 US
Continuation in Parts (1)
Number Date Country
Parent 11967434 Dec 2007 US
Child 12635532 US