Exemplary embodiments of the present invention relate generally to a method of manufacturing a component having a cap layer. More specifically, some exemplary embodiments relate to a method of manufacturing a cellulosic composite component having a substrate and a cap layer.
A problem with the use of wood materials in structural applications is the lack of durability and the degradation in appearance when exposed to the environment. In the example of exposed railing systems, such as those commonly found about the perimeter of residential decks, rain can infiltrate the tops of posts and the other exposed surfaces of the wood components, which may eventually cause rot and the loss of a pleasing aesthetic appearance. Traditional wood surface treatments, such as paint or lacquers, have limited life and require routine maintenance, which can result in significant expense over time. Additionally, wood railing systems, for example, are typically custom-built on-site, thereby requiring significant amounts of labor to custom-cut and install individual components. Consequently, there is a need for materials that are weather resistant and can be formed into structural components, such as exterior rail systems as an example.
Exemplary embodiments of the present invention may address some or all of these deficiencies by employing composite materials to make a component. An exemplary component of the present invention may be comprised of a cap layer that is placed over a composite substrate. This combination of a cap layer and composite substrate may provide multiple advantages. In particular, this combination enables the use of a relatively low cost, composite material as a substrate that provides desired structural characteristics for the component, even though the composite material may not have desirable aesthetic characteristics. An exemplary embodiment of the cap layer may include streaker and cellulosic filler. The cap layer may be applied on the composite substrate to provide an attractive and protective finish for the component. Furthermore, the cap layer may reduce manufacturing costs by not requiring a streaker to be applied throughout the entire substrate. As a result of such benefits, an exemplary embodiment of the component may be resistant to weathering and may be used for railing, siding, or other similar or suitable indoor or outdoor products.
In one exemplary embodiment, the cap layer may include a blend of polyvinyl chloride (PVC) and acrylic and may exhibit an improved resistance to degradation, which may be caused by UV light exposure or other environmental factors. In another exemplary embodiment, a component may be made from a plastic material comprising acrylic-styrene-acrylonitrile (ASA), which may also exhibit an improved resistance to degradation, such as may be caused by environmental factors. In yet another exemplary embodiment, the cap layer may be a polyolefin-based material that has enhanced resistance to degradation and scratching. In still another exemplary embodiment, the cap layer may include a cellulosic material and/or a streaker material.
An example of a method for forming such aforementioned components may include providing an extrusion system having at least one extruder and at least one die system. The method may also include providing a substrate material and a cap layer material. Exemplary embodiments of the method may include extruding the substrate material and co-extruding the cap layer material onto at least a portion of the substrate material. In certain exemplary embodiments, the method may further include forming a flow from the substrate material and cap layer material, and forcing the flow through the die system to form at least one component. Furthermore, in some exemplary embodiments, multiple components may be simultaneously produced from the same tooling.
In addition to the novel features and advantages mentioned above, other features and advantages will be readily apparent from the following descriptions of the drawings and exemplary embodiments.
Another exemplary component of the present invention is illustrated in
Exemplary embodiments of the present invention may also be useful for making other types of railing components including, but not limited to, spindles, squash blocks, support rails, and posts. Nevertheless, while exemplary embodiments of the present invention may be particularly useful for making railing components, it should be recognized that they may also be useful for manufacturing other types of indoor and outdoor components. Examples of components that can be made with the present invention include, but are not limited to, fence components, furniture components, cabinet components, storage device components, lawn edging components, flower box components, floor components, baseboards, roof components, wall covering components, building siding components, basement floor components, basement wall covering components, interior and exterior decorative house molding components, crown molding components, chair rail components, picture frame components, porch deck components, deck railing components, window molding components, window components, window frames, door components, door frames, door moldings, posts, boards (e.g., 5/4-inch boards, 2 inch×6 inch boards, and other desired sizes of boards), and other suitable indoor and outdoor items. Furthermore, it should be recognized that the component may be solid or hollow.
In exemplary embodiments of the present invention, the substrate may be comprised of a composite that has a high cellulosic content. For instance, one exemplary embodiment of the composite is comprised of cellulosic material in the amount of at least about 30% by weight, more preferably about 30% to about 70% by weight (e.g., about 60% by weight), and even more preferably about 40% to about 60% by weight. A plastic material may be included in an amount of about 0.01% to about 70% by weight, more preferably about 30% to about 70% by weight, and still more preferably about 30% to about 60% by weight (e.g., about 40% by weight). For another example, the composite may be comprised of cellulosic material in an amount of about 55% by weight and a plastic material in an amount of about 30% to about 45% by weight. In yet another exemplary embodiment, the composite may be comprised of cellulosic material in the amount of about 50% by weight and a plastic material in an amount of about 50% by weight. In some exemplary embodiments, cellulosic material may be provided in an amount less than 50% by weight of the composite, and plastic material may be provided in an amount more than 50% by weight of the composite.
A high cellulosic content enables the cost-effective production of a substrate that has desirable structural characteristics. For example, the high cellulosic content promotes the desired durability, rigidity, flexibility, and other structural characteristics for a variety of types of components. For instance, the high cellulosic content enables the cost-effective production of railing components that exceed load-testing requirements.
The cellulosic material may be virgin or recycled. Examples of cellulosic material include sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, flax, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagasse, plant fibers, bamboo fiber, palm fiber, kenaf, and other similar or suitable materials. Any of the wood examples may be hard or soft wood or variations thereof. Furthermore, any desired mesh size of the cellulosic material can be used. With regard to cellulosic material, an exemplary range of mesh size is about 10 to about 100 mesh, more preferably about 20 mesh to about 80 mesh depending on the desired characteristics of the composite. However, some exemplary embodiments may use other cellulosic materials of other sizes.
The cellulosic material may be dried to a desired moisture content prior to or during the formation of the substrate. For example, the cellulosic material may be dried to about 0.5% to about 3% moisture content by weight, more preferably to about 1% to about 2% moisture content by weight. However, it should be recognized that the cellulosic material may have a moisture content less than about 0.5% by weight or greater than about 3% by weight and still be within the scope of the present invention.
The plastic material may be comprised of virgin or recycled materials that may improve the characteristics of the reinforced composite and/or enhance the manufacture or moldability thereof. In addition, the plastic material may be foamable or foamed. In one exemplary embodiment of the present invention, the plastic material may be a PVC or polyethylene (PE) material, which enables the production of a component having structural characteristics suitable for railing or other applications. The PVC or PE material may, for example, be made by mixing PVC or PE resin with, optionally, at least one stabilizer, at least one lubricant, at least one process aid, and other optional ingredients (e.g., acrylic modifier, inorganic filler, and other suitable additives). Optionally, another plastic resin may also be included in the composite such as, but not limited to, acrylonitrile butadiene styrene (i.e., ABS) resin. An example of a mixer is a high intensity mixer such as those made by Littleford Day Inc. or Henschel Mixers America Inc. As an example, the mechanically induced friction may heat the ingredients to a temperature between about 200° F. and about 230° F. After mixing, the ingredients may be cooled to ambient temperature. Alternatively, the ingredients of the PVC or PE material may be mixed together during the formation of the substrate. Although PVC or PE may be preferred for some embodiments, it should be recognized that other plastics may be used in other exemplary embodiments of the present invention.
With reference to a plastic material that may comprise PVC or PE resin, one exemplary embodiment may include PVC or PE resin in an amount of about 20% to about 45% by weight of the composite, more preferably about 25% to about 40% by weight of the composite, and still more preferably about 27% to about 37% by weight of the composite. An exemplary embodiment of the plastic material may further include stabilizer(s) in an amount of about 1 to about 10 parts, more preferably about 2 to about 4 parts, per 100 parts of resin. In an example, lubricant(s) may be present in an amount of about 1 to about 40 parts, more preferably about 5 to about 35 parts, per 100 parts of resin. In one exemplary embodiment, lubricant(s) may be included in an amount of about 0.01% to about 10% by weight of the composite. Also, process aid(s) may be included in an exemplary embodiment in an amount of about 0.5 to about 8 parts, more preferably about 0.7 to about 3 parts, per 100 parts of resin. Optionally, in an exemplary embodiment, acrylic modifier(s) (e.g., impact modifiers) may be present in an amount of about 1 to about 10 parts, more preferably about 4 to about 8 parts, per 100 parts of resin. As a further option in an embodiment, inorganic filler(s) may be added in an amount of up to about 150 parts, more preferably about 2 to about 60 parts, per 100 parts of resin. In one example, inorganic filler(s) may be included in an amount of about 0.01% to 20% by weight of the composite, more preferably about 1% to about 20% by weight of the composite, and still more preferably about 5% to about 15% by weight of the composite. In addition, another plastic resin (e.g., ABS resin or any other similar or suitable resin) may be included in an exemplary embodiment in an amount up to about 50% by weight of the composite, more preferably about 5-10% by weight of the composite.
Stabilizer(s) may be employed to limit or prevent the breakdown of the plastic material during molding. Examples of stabilizers include tin stabilizers, lead and metal soaps such as barium, cadmium, and zinc, and other similar or suitable materials.
Internal or external lubricant(s) may aid in the molding process. Lubricants may be added to the plastic material to assist the reinforced composite through an extruder, compounder, or other molding machine, and to help facilitate mold release. Examples of lubricants include zinc stearate, calcium stearate, esters, amide wax, paraffin wax, ethylene bis-stearamide, and other similar or suitable materials.
Process aid(s) may aid in the fusion of the compound. Examples of process aids include acrylic process aids and other similar or suitable materials for improving the fusion of the compound. R&H K-120N and R&H K-175 are examples of acrylic process aids that are available from Rohm & Haas.
Acrylic modifier(s) may improve the physical characteristics of the compound. One example of an impact modifier is Arkema P530. Another example of an acrylic modifier is R&H K-400, which is available from Rohm & Haas. Although R&H K-400 is a high molecular weight acrylic modifier that is specifically designed for PVC or PE foam applications, the inventors have discovered that it may also improve the physical characteristics of the substrate of the present invention, which has a high cellulosic content and may not include any foaming or blowing agents.
Inorganic filler(s) may be used to increase the bulk density of the reinforced composite. The use of inorganic filler may also improve the ability to process the reinforced composite, thereby allowing for higher rates of manufacture (e.g., extrusion). Inorganic filler may also allow the reinforced composite to be molded into articles having reduced moisture sensitivity and reduced flame and smoke spread. Examples of inorganic fillers include talc, calcium carbonate, kaolin clay, magnesium oxide, titanium dioxide, silica, mica, barium sulfate, wollastanite, acrylics, and other similar or suitable materials.
Other optional ingredients that may be included in the PVC or PE material include, but are not limited to, polymers, plastics, thermoplastics, rubber, cross-linking agents, accelerators, inhibitors, enhancers, blowing agents/foaming agents, fillers, compatibilizers, thermosetting materials, pigments, weathering additives, and other similar or suitable materials.
Blowing agent(s) may be used to reduce the cost (e.g., by reducing the amount of polymer used in the composite) and weight of the composite material. A blowing agent may be an endothermic or exothermic blowing agent. An example of a chemical endothermic blowing agent is Hydrocerol BIH (i.e., sodium bicarbonate/citric acid), which is available from Clariant Corp., whereas an example of a chemical exothermic foaming agent is azodicarbonamide, which is available from Uniroyal Chemical Co.
The use of thermosetting materials may, for example, reduce moisture absorption and increase the strength of products manufactured from the reinforced composite material. Examples of thermosetting materials include polyurethanes (e.g., isocyanates), phenolic resins, unsaturated polyesters, epoxy resins, and other similar or suitable materials. Combinations of the aforementioned materials are also examples of thermosetting materials.
Pigments may be used to give the composite a desired color (e.g., white, cedar, gray, and redwood). Examples of pigments include titanium dioxide, iron oxide, and other similar or suitable colorant additives.
Titanium dioxide is also an example of a weathering additive. Other similar or suitable weathering additives include, but are not limited to, other ultraviolet absorbers. Examples of other ultraviolet absorbers include organic chemical agents such as benzophenone and benzotriazole types.
The substrate may not provide the desired aesthetic characteristics. As a result, exemplary embodiments of the present invention may provide a cap layer on the substrate. In an exemplary embodiment, the cap layer may be comprised of PVC, PE, or another similar or suitable material. The use of a cap layer may enable lower cost, less attractive, yet structurally desirable materials that may have a high cellulosic content to be used as the base substrate. For instance, the cap layer may be applied on the substrate to provide an attractive and protective finish for the component. For example, the cap layer may be provided in any desired color (e.g., to match the appearance of a deck or building exterior), and it may have a smooth outer surface or a pattern or texture formed on its outer surface.
One exemplary embodiment of a cap layer may be made from a plastic material, which may, for example, be comprised of a blend of two or more polymers. In particular, any number of polymers may be used to obtain a blend having desirable weathering characteristics. For instance, examples of a blend include, but are not limited to, PVC compounds, PE compounds, PVC/acrylic alloys, other acrylic alloys, and other similar or suitable alloys, compounds, and mixtures having desirable weathering, aesthetic, degradation, and/or durability characteristics. In other exemplary embodiments, a suitable composite may be used as a cap layer. An example of a composite may be comprised of PVC, PE, polypropylene, or any other similar or suitable plastic.
In one exemplary embodiment, a PVC/acrylic alloy may be particularly useful for making a cap layer having desirable resistance to scratching and/or to degradation such as may be caused by UV light or other environmental factors. For example, the plastic material may include polyvinyl chloride in an amount between about 10% by weight and about 90% by weight and acrylic in an amount between about 10% by weight and about 90% by weight. In another exemplary embodiment, the plastic material may include polyvinyl chloride in an amount between about 20% by weight and about 80% by weight and acrylic in an amount between about 20% by weight and about 80% by weight. In still another exemplary embodiment, the plastic material may include polyvinyl chloride in an amount between about 40% by weight and about 60% by weight and acrylic in an amount between about 40% by weight and about 60% by weight. In yet another exemplary embodiment, the plastic material may include polyvinyl chloride in an amount of about 50% by weight and acrylic in an amount of about 50% by weight.
In another exemplary embodiment, a PE compound or mixture may be useful for making a cap layer having desirable resistance to scratching and/or to degradation such as may be caused by UV light or other environmental factors. For example, the PE compound or mixture may include polyethylene in an amount between about 20% by weight and about 70% by weight. In still another exemplary embodiment, the PE compound or mixture may include polyethylene in an amount between about 20% and about 40% by weight.
In some other exemplary embodiments of the present invention, a cap layer may be made from a plastic material that is comprised of an acrylic-styrene-acrylonitrile (i.e., ASA) material or compound. In some exemplary embodiments, the plastic material may be comprised of ASA in an amount of 100% by weight. In other exemplary embodiments, the plastic material may be comprised of a major proportion of ASA. An example of an ASA compound is Luran S, which is available from BASF Corporation of Florham Park, N.J. An ASA compound may also provide desirable weathering characteristics for some exemplary components of the present invention.
Another example of a cap layer may be a composite that has more desirable aesthetic characteristics. An exemplary embodiment of a composite may or may not be a blend of two or more polymers. Furthermore, as previously mentioned, an example of a composite may be comprised of PVC, PE, or any other similar or suitable plastic.
An exemplary embodiment of a composite cap layer preferably includes cellulosic filler, which may facilitate a desired wood-like appearance. In one example, the cellulosic filler may be included in a cap material in an amount in the range from about 20% to about 70% by weight, more preferably in an amount in the range from about 35% to about 55% by weight, and still more preferably in an amount of about 40% to about 45% by weight. In one example, the cap material may be comprised of cellulosic filler in amount of about 43% by weight.
In addition to the amount of cellulosic filler, the roughness of a cap layer may be controlled by selecting the desired size of cellulosic filler. A rough cap may facilitate a desired wood-like appearance. In some exemplary embodiments of the present invention, 40 mesh or 60 mesh cellulosic filler may be used. However, in other exemplary embodiments, smaller or larger sizes of cellulosic filler may be used. By decreasing the size of the cellulosic filler, the roughness of a resulting cap layer may be reduced. On the other hand, by increasing the size of cellulosic filler, a cap layer may be made rougher. Unless expressly claimed otherwise, it is not intended to limit the cellulosic filler to any particular mesh size.
Any suitable cellulosic filler may be used. Examples of cellulosic fillers include sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagass, plant fibers, bamboo fiber, palm fiber, kenaf, flax, and other similar or suitable materials. In addition, it should be recognized that virgin or recycled cellulosic filler may be used.
In order to further enhance the appearance of the cap layer, streaker(s) may be used. By using streaker(s) in a cap layer, it limits the amount of streaker(s) needed as the streaker(s) are not dispersed throughout the entire cross-section of the component. A streaker refers to a color additive that has a different, preferably higher, melt index than the base plastic material used in a cap layer or a color additive that has some other distinguishing characteristic that facilitates streaking when mixed with the base plastic material used in a cap layer (e.g., a desired degree of immiscibility when mixed with the base plastic material). Examples of streakers include, but are not limited to, PVC, ABS, and polycarbonate (i.e., PC) pellets or any other suitable plastic pellet that includes a desired pigment. Examples of streakers are available from companies such as Americhem and Penn Color. Streaker(s) may be included in a cap layer in any desired amount and form. For example, in some exemplary embodiments, streaker(s) may be included in the cap layer in an amount in the range from about 0.01% to about 20% by weight, more preferably in an amount in the range from about 0.01% to about 10% by weight, and still more preferably in an amount of about 2% to about 8% by weight. A desired streaking effect may be achieved by selecting the desired amount(s), color(s), and melt index(es) of streaker(s).
In addition to cellulosic filler and optional streaker(s), the cap layer may be comprised of any desired base plastic material. For instance, in one exemplary embodiment of the present invention, a base plastic material may provide a solid or base color (e.g., brown, tan, gray, or any other desired base color), and streaker(s) may be used in addition to the solid or base color to obtain a variegated appearance. Nevertheless, it is not intended to limit the present invention to any particular base plastic material, unless expressly claimed otherwise. As previously mentioned, examples of base plastic material may include, but are not limited to, PVC material, PE material, PVC compounds, PE compounds, PVC/acrylic alloys, other acrylic alloys, acrylic-styrene-acrylonitrile (i.e., ASA), ASA compounds, and other similar or suitable alloys, compounds, and plastics.
An exemplary cap layer of the present invention may also include other ingredients as described above in reference to the plastic material of the substrate, such as other plastics, cross-linking agents, blowing agents, foaming agents, foam modifiers, lubricants, stabilizers, accelerators, inhibitors, enhancers, compatibilizers, thermosetting materials, weathering additives, rubber, colorants, process aids, and inorganic fillers. These materials may be used individually, or in combination, to improve the characteristics of the plastic material and/or enhance the manufacture or moldability thereof.
In view of the foregoing, one example of a cap layer may be PE composite. This example of a cellulosic composite material may include at least one cellulosic filler in an amount of about 20% to about 70% by weight, more preferably about 30% to about 60% by weight, still more preferably about 35% to about 55% by weight, and even more preferably about 40% to about 45% by weight. The composite may also include polyethylene resin in an amount of about 20% to about 70% by weight, more preferably about 25% to about 40% by weight, still more preferably about 25% to about 35% by weight, and even more preferably about 30% to about 35% by weight. The composite may also include talc or another suitable inorganic filler in an amount of about 0.01% to about 20% by weight (e.g., about 1% to about 20% by weight), more preferably about 5% to about 15% by weight, and still more preferably about 10% to about 15% by weight. In addition, the composite may include lubricant in an amount of about 5% to about 10% by weight and more preferably about 6% to about 9% by weight. Streaker(s) may also be included in the composite in an amount of about 0.01°/o to about 20% by weight, more preferably in an amount in the range from about 0.01% to about 10% by weight, and still more preferably in an amount of about 2% to about 8% by weight. The combination of cellulosic filler and streaker(s) may facilitate a desired variegated appearance that simulates natural wood.
An exemplary component of the present invention may be manufactured using suitable manufacturing techniques. For example, the substrate and the cap layer may be co-extruded. Alternatively, the cap layer may be applied on the substrate (or vice versa) in a sequential extrusion process. Other molding techniques including, but not limited to, injection molding and compression molding may be used to manufacture a component of the present invention. In addition, it should be recognized that the layers may be formed separately and then joined then in a subsequent process, such as with the use of adhesives or other suitable bonding materials. In other examples, a component may be made using one or more manufacturing methods including, but not limited to: extrusion, co-extrusion, compression molding, and other similar or suitable manufacturing methods.
In another exemplary embodiment, a cap layer may be simultaneously processed in a system similar to the one described above, and the melt flows from each of the extruders can be joined in the same die system to form the desired profile. A cross-sectional view of one example of such a co-extrusion system is shown in
A second extruder 58 may receive a second material where it is processed at a suitable speed and temperature. The second extruder 58 may force the second material through a bracket or portion 60 to the first branch 54 and second branch 56 to co-extrude the second material with the first material. Any number of additional extruders may be used to apply as many layers as desired. In one exemplary embodiment, the first material may be a substrate layer, and the second material may be a cap layer. The cap layer may be applied to any suitable side or sides of the substrate layer or may be applied to all of the sides of the substrate layer. The first flow may pass through the first branch 54 to a first die system 62. The second flow may pass through the second branch 56 to a second die system 64. The first and second die systems, 62 and 64 respectively, may have any size and shape desired. The first and second flows may exit the die systems as first extruded component 66 and second extruded component 68. The extruded components may optionally be passed on to a cooling system or systems. Such an extrusion system may allow multiple components to be formed simultaneously. For example, a four-branch junction could form four different shaped components simultaneously. Each component may have a substrate layer and a cap layer.
One example of a composite that is suitable for a substrate comprises ingredients in the following amounts:
Another example of a composite that is suitable for a substrate comprises ingredients in the following amounts:
A third example of a composite that is suitable for a substrate comprises ingredients in the following amounts:
A fourth example of a composite that is suitable for a substrate comprises ingredients in the following amounts:
A fifth example of a composite that is suitable for a substrate comprises ingredients in the following amounts:
A sixth example of a composite that is suitable for a substrate comprises ingredients in the following amounts:
A first example of a composite that is suitable for a cap layer comprises ingredients in the following amounts:
A second example of a composite that is suitable for a cap layer comprises ingredients in the following amounts:
Any embodiment of the present invention may include any of the optional or preferred features of the other embodiments of the present invention. The exemplary embodiments herein disclosed are not intended to be exhaustive or to unnecessarily limit the scope of the invention. The exemplary embodiments were chosen and described in order to explain the principles of the present invention so that others skilled in the art may practice the invention. Having shown and described exemplary embodiments of the present invention, those skilled in the art will realize that many variations and modifications may be made to affect the described invention. Many of those variations and modifications will provide the same result and fall within the spirit of the claimed invention. It is the intention, therefore, to limit the invention only as indicated by the scope of the claims.
This application is a continuation of U.S. patent application Ser. No. 11/935,217, filed Nov. 5, 2007, which is hereby incorporated by reference in its entirety. This application is also a continuation-in-part of U.S. application Ser. No. 11/967,434, filed Dec. 31, 2007, which claims priority to U.S. Provisional Application No. 60/882,869, filed Dec. 29, 2006, each of which is hereby incorporated by reference in its entirety.
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Number | Date | Country | |
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Parent | 11967434 | Dec 2007 | US |
Child | 12635532 | US |