Patent Grant
9499888
The present invention relates to wear resistant compositions, and more particularly to carbide pellets containing relatively small amounts of metallic binder for use in various applications such as hard facing materials and bulk composite materials.
Carbide pellets may generally be used for wear resistant applications, such as composite materials for forming bits, for example drill bits for earth-boring drills, or as hard facing compositions, for example, hard facing compositions for rock bits or as a plasma tungsten arc coating compositions. When used in hard facing applications, the carbide pellets are generally cemented or sintered tungsten carbide pellets.
U.S. Pat. No. 4,944,774 to Keshavan et al. discloses cemented tungsten carbide used in hard facing materials. The cemented tungsten carbide comprises small particles of tungsten carbide bonded together with cobalt in amounts ranging from 6 to 8 weight percent. The cemented tungsten carbide is made by mixing tungsten carbide, organic wax, and cobalt powders; pressing the mixed powders to form a green compact; and sintering the composite at temperatures near the melting point of cobalt. The resulting dense cemented carbide can then be comminuted to form particles of cemented tungsten carbide for use in hard facing applications. Other hard facing compositions are disclosed in U.S. Pat. Nos. 3,800,891; RE37,127; 6,248,149; 6,659,206; and 6,782,958.
Pan and tube granulation processes have conventionally been used to make carbide pellets containing relatively large amounts of metallic binder, e.g., 6 weight percent cobalt. In these techniques, tungsten carbide powder and cobalt powder are milled with wax in an organic solution for several hours, then the milled powder is dried in a vacuum dryer.
In the pan granulation process, the powder is fed continuously to the top of a rotating disk pelletizer to form green pellets. The disk pelletizer typically rotates at approximately 15 revolutions per minute at an angle of 50° to 75° relative to the horizontal plane. Agglomeration occurs by particle coalescence as the pelletizer rotates. The larger agglomerates rotate to the outer pan rim and are readily discharged from the pan.
In the tube granulation process, the milled and dried powder is fed into a tube or drum pelletizer at one end to form green pellets. The drum pelletizer rotates at approximately 15 revolutions per minute to cause agglomeration by particle coalescence. The agglomerates are continuously discharged at the other end of the tube.
In both the pan and tube granulation processes, the agglomerated green pellets may be sized. Undersized pellets may be recycled, and oversized pellets may be crushed and recycled, by feeding the pellets back to the granulator with the powders. The properly sized green pellets are then sintered, and may be broken into individual pellets if necessary.
While pan and tube granulation processes have effectively been used to make carbide pellets with relatively large amounts of metallic binder, attempts to make carbide pellets containing less than 3 weight percent cobalt by such processes have been unsuccessful. The present invention provides an improved process for forming carbide pellets having a metallic binder, such as cobalt, in an amount less than 3 weight percent.
An aspect of the present invention is to provide substantially spherical sintered carbide pellets comprising carbide and from 0.5 to 2.5 weight percent of a metallic binder.
This and other aspects of the present invention will be more apparent from the following description.
The present invention provides a method of making carbide pellets with relatively small amounts of metallic binder. The sintered carbide pellets may be produced according to the process illustrated in
The milled powders are fed to a press where they are pressed to form a green compact or billet. Any suitable type of press may be used, such as a uniaxial press applying a pressure of from about 2,000 to about 10,000 psi.
The formed green compact or billet is comminuted, e.g., crushed, to form loose, faceted granules comprising the carbide and metallic binder particles. For example, the green compact may be fed to a Stokes granulator to form the granules. A Stokes granulator is a machine that forces the material through a screen to produce granules. The granules have faceted shapes with sharp edges and may typically range in size from about ASTM 200 mesh (74 microns) to about ASTM 10 mesh (1,885 microns), for example, from about ASTM 40 mesh (381 microns) to about ASTM 16 mesh (1,130 microns). A sample of faceted granules produced by the comminuting step of
The faceted granules are then shaped to remove the sharp edges and to form rounded or substantially spherical green pellets containing the carbide and metallic binder. The shaping step may include subjecting the granules to a tumbling process, e.g., in a mill drum, followed by a screening process to obtain uniform pellet size. The rounded green pellets may typically range in size from about ASTM 40 mesh (381 microns) to about ASTM 16 mesh (1,130 microns), for example, about ASTM 20 mesh (860 microns). A sample of rounded and substantially spherical pellets produced by the shaping step of
The green pellets are then sintered rather than being sent directly to a press to form parts. The final step involves sintering the green pellets to form dense rounded or substantially spherical sintered carbide pellets, wherein each pellet contains less than 3 weight percent metallic binder based on the weight of the sintered pellet. The sintering temperature may typically range from about 1,380° C. to about 1,480° C., for example, about 1,450° C. Alternatively, vacuum sintering at a temperature of about 1,900° C. may be used, followed by hot isostatic pressing in an inert atmosphere such as Ar, e.g., at 1,500 psi and 1,900° C., or at 30,000 psi and 1,500° C. The rounded sintered pellets may typically range in size from about ASTM 40 mesh (381 microns) to about ASTM-10 mesh (1,885 microns), for example, about ASTM 20 mesh (860 microns). A sample of rounded sintered pellets produced by the sintering step of
In an embodiment of the invention, the metallic binder may be present in amounts ranging from zero or 0.01 to about 2.9 weight percent based on the total weight of the mixture. For example, the metallic binder may comprise from about 0.5 to about 2.5 weight percent based on the total weight of the mixture. In one embodiment, the metallic binder is present in an amount of about 2 weight percent. The amount of carbide added in the mixture typically ranges from about 97.1 to about 99.99 or 100 weight percent based on the total amount of the mixture. For example, the carbide may comprise from about 97.5 to about 99.5 weight percent based on the total weight of the mixture. In one embodiment, the carbide is present in amount of about 98 weight percent. The sintered carbide pellets produced in accordance with the method of the present invention comprise hard carbide particles and metallic binder in similar amounts as described above. Due to the relatively low amount of metallic binder in the sintered carbide pellets, their hardness is increased over sintered carbide pellets having higher amounts of metallic binder for a given grain size of the hard carbide particles.
The carbide may be selected from tungsten carbide (WC), di-tungsten carbide (W2C), titanium carbide (TiC), tantalum carbide (TaC), chromium carbide (Cr3C2) and vanadium carbide (VC). Borides such as titanium diboride (TiB2) may optionally be added to the carbide(s) or used alone. For example, the carbide may comprise WC with up to 10 weight percent W2C. Also, Cr3C2 in an amount up to 2 weight percent and/or VC in an amount up to 0.5 weight percent may be added to WC. Other optional elements may be added, such as Ni, Ti, Ta and Nb in amounts up to 0.5 weight percent. The carbide may be provided in the form of powder having an average particle size of from about 0.5 to about 10 microns, typically from about 2 to about 4 microns.
The metallic binder may be selected from cobalt, iron, nickel, steel and mixtures thereof. The metallic binder may be provided in the form of powder having an average particle size of from about 0.5 to about 100 microns, typically from about 35 to about 45 microns.
The carbide pellets of the invention may be used in any of the several wear resistant applications which involve surface modification. These include hard facing, plasma tungsten arc and high velocity oxy fuel coating applications. For example, the carbide pellets may be applied as hard facing materials and cutting surfaces to workpieces including tools, such as hand and power shovels, cutting tools, hammers, agricultural tools, drill bits and the like. The carbide pellets may also be used in matrix powders for fixed cutter oil and gas bits. The carbide pellets provide improved mechanical properties, including improved wear resistance compared to currently available carbide pellets containing greater amounts of metallic binder, for example cobalt, while maintaining the required strength and toughness required for longer life of the tools to which the hard facing materials are applied.
In accordance with an embodiment of the present invention, the sintered carbide pellets of the invention may be used in a hard facing rod 10 in which the pellets are contained in a hard facing tube 12 schematically shown in
The hard facing may be applied to various substrates by melting an end of the rod on the surface of the substrate which is to be coated. The steel tube or rod melts as it is welded to the surface and provides the matrix for the carbide particles. The thickness of the hard facing layer on surface of substrate may range from about 0.0625 to about 0.5 inch. A hard facing method which may be used in applying a hard facing composition comprising the sintered tungsten carbide pellets in accordance with the teachings of the invention is disclosed in U.S. Pat. No. 5,250,355 to Newman et al. which is incorporated herein by reference.
The sintered carbide pellets of the invention may be used to form a composite material for use not only as a hard facing on the body and/or cutting elements, but also to form portions or all of the body and cutting elements, and as bulk composite materials. The sintered carbide pellets of the invention may also be used in matrix powders for fixed cutter oil and gas bits, plasma tungsten arc (PTA) powders, and high velocity oxy fuel (HVOF) powders.
The following example is intended to illustrate various aspects of the present invention, and is not intended to limit the scope of the invention.
Sintered carbide pellets comprising tungsten carbide particles and 2 weight percent cobalt metallic binder were made. Tungsten carbide powder having an average particle size of about 5 microns was mixed in an amount of 98 weight percent with 2 weight percent cobalt powder having an average particle size of about 1 micron. Paraffin was mixed with the powder in an amount of 2 weight percent of the powder mixture in a ball mill for about 12 hours. The mixture was pressed in a uniaxial press at a pressure of 3 tons per square inch to form a green compact. The green compact was comminuted by forcing the green compact through a Stokes granulator screen which crushed the green compact to form faceted granules having an average particle size of about 1,130 microns.
The faceted granules were then shaped into generally spherical green pellets by tumbling the granules in a mill drum at a speed of about 50 to 120 revolutions per minute for about 60 minutes to round off the sharp edges.
The green granulated spherical pellets were loaded in loose form into a ceramic boat and into a sinter hip furnace at about 1,450° C. with a ramp up, hold, and cool down procedure as follows: ramp from room temperature to 400° C. at a ramp rate of 0.5 to 3 degrees per minute; hold for 1 hour at 400° C.; ramp from 400° C. to 1,400° C. at 6 degrees per minute; hold at 1,400 degrees for 30 minutes; and cool down by turning off the power to the furnace to allow cooling at the natural cooling rate of the furnace. During this time, the cobalt melted to help bind or cement adjacent carbide particles together within each pellet. The resultant cemented tungsten carbide pellets were then processed in a roll crusher to break up any of the pellets that became stuck together during the sintering process. The resultant sintered carbide pellets ranged in size from about 200 mesh (74 microns) to about −80 mesh (178 microns), and had an average particle size of about 125 microns.
A portion of the resultant carbide pellets were then introduced into a hard facing tube, and applied as a hard facing composition to a steel substrate using conventional hard facing application techniques. The hard facing tube was made of a steel sheath, with an inner diameter of 0.156 inch, an outer diameter of 0.18 inch, a thickness of 0.024 inch, and a length of 28 inches.
Whereas particular embodiments of this invention have been described above for purposes of illustration, it will be evident to those skilled in the art that numerous variations of the details of the present invention may be made without departing from the invention as defined in the appended claims.
This application is a divisional application of U.S. patent application Ser. No. 12/827,860, filed Jun. 30, 2010, now U.S. Pat. No. 8,834,786, which is incorporated herein by reference.
| Number | Name | Date | Kind |
|---|---|---|---|
| 3149411 | Smiley et al. | Sep 1964 | A |
| 3515540 | Meadows | Jun 1970 | A |
| 3800891 | White et al. | Apr 1974 | A |
| 4173685 | Weatherly | Nov 1979 | A |
| 4177324 | Brown et al. | Dec 1979 | A |
| 4451508 | Brown | May 1984 | A |
| 4526618 | Keshavan et al. | Jul 1985 | A |
| 4689077 | Chevigne et al. | Aug 1987 | A |
| 4744943 | Timm | May 1988 | A |
| 4944774 | Keshavan et al. | Jul 1990 | A |
| 4945073 | Dubensky et al. | Jul 1990 | A |
| 5045277 | Penkunas | Sep 1991 | A |
| 5102452 | Taskinen et al. | Apr 1992 | A |
| 5250355 | Newman et al. | Oct 1993 | A |
| 5256608 | Dubensky et al. | Oct 1993 | A |
| 5334561 | Matsui et al. | Aug 1994 | A |
| 5563107 | Dubensky et al. | Oct 1996 | A |
| 5612264 | Nilsson et al. | Mar 1997 | A |
| 5663512 | Schader et al. | Sep 1997 | A |
| 5681783 | Nilsson et al. | Oct 1997 | A |
| 5791422 | Liang et al. | Aug 1998 | A |
| RE37127 | Schader et al. | Apr 2001 | E |
| 6248149 | Massey et al. | Jun 2001 | B1 |
| 6659206 | Liang et al. | Dec 2003 | B2 |
| 6782958 | Liang et al. | Aug 2004 | B2 |
| 7510034 | Curry et al. | Mar 2009 | B2 |
| 7784381 | Ladi et al. | Aug 2010 | B2 |
| 8292985 | Curry et al. | Oct 2012 | B2 |
| 8322466 | Bird | Dec 2012 | B2 |
| 20070079992 | Curry et al. | Apr 2007 | A1 |
| 20080127776 | Persson et al. | Jun 2008 | A1 |
| 20080127781 | Ladi et al. | Jun 2008 | A1 |
| 20090260482 | Curry et al. | Oct 2009 | A1 |
| 20100101866 | Bird | Apr 2010 | A1 |
| 20110195834 | Banerjee et al. | Aug 2011 | A1 |
| Number | Date | Country |
|---|---|---|
| 1433868 | Aug 2003 | CN |
| 2084612 | Apr 1982 | GB |
| 0131075 | May 2001 | WO |
| 2007124523 | Nov 2007 | WO |
| Entry |
|---|
| Aug. 29, 2014—Office—Action. |
| Kennametal Inc., “Engineered Product Solutions”, sales brochure, 2006, published in U.S. |
| Number | Date | Country | |
|---|---|---|---|
| 20140345423 A1 | Nov 2014 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12827860 | Jun 2010 | US |
| Child | 14458918 | US |
