The present disclosure relates to an apparatus and a method of carbon capture. More particularly, the present disclosure relates to an enhanced carbon dioxide capture element that may be used with such an apparatus and method.
Carbon dioxide is estimated to comprise 76% of all greenhouse gasses. Unless CO2 levels are managed, its atmospheric heat-trapping characteristics are expected to cause a catastrophic 2.5° C.-4.5° C. (4.5° F. to 8° F.) rise in temperature by the year 2100. Anthropogenic carbon dioxide emission is the main contributor to the observed ˜110 ppm rise in CO2 concentration from pre-industrial levels (NOAA, 2013).
Supplementing the transition away from fossil fuels to low-carbon energy sources with carbon capture and storage (CCS) is a potential approach for the mitigation of CO2 emissions. CCS uses a combination of technologies to capture CO2 and transport it to a safe and permanent storage location. Various industrial-scale CO2 capture technologies have been developed or are in research. For example, industrial-scale direct-air carbon dioxide capture plants move large volumes of ambient air through scrubber mechanisms that adsorb CO2 which can then be sequestered in underground formations. In some cases, large-scale carbon capture devices are coupled with facilities such as fossil fuel power plants to capture CO2 from the gases emitted by combustion. Such centralized systems are not suitable for directly capturing CO2 emitted by individuals, or groups of individuals.
Various carbon capture apparatuses and processes have been proposed, including U.S. Patent Application Publication 20210370230, which describes a method for enhancing a sorbent membrane for carbon dioxide capture; U.S. Patent Application Publication 20210340078, which describes electrolysis and carbon dioxide capture in a suitable solvent; U.S. Patent Application Publication 20210260527, which describes a substrate with a carbon dioxide capture coating composition that may comprise a coating material and a photosynthetic organism; U.S. Patent Application Publication 20210060483, which describes a hollow membrane unit having an inner conduit composed of a vapor membrane, and an outer conduit having an inside surface circumscribing the inner conduit forming a lumen; U.S. Patent Application Publication 20200129930, which describes a carbon dioxide capture unit that has a layer comprising solid porous material; U.S. Patent Application Publication 20130098246, which describes a polymer membrane used in carbon dioxide capture equipment for capturing carbon dioxide from the exhaust gas of a boiler; and U.S. Patent Application Publication 20160074831, which describes compositions of various sorbents based on aerogels of various silanes and their use as sorbent for carbon dioxide, all of which are incorporated herein by reference.
Known CO2 capture techniques do not address the need to capture CO2 where it is generated by individuals, families, and coworkers, in offices, homes, and neighborhoods. CCS technologies currently under development focus on emissions from large point sources such as coal or natural gas-fired power plants and cement industries. Indoor, residential, and hyper-local CO2 capture has not been seriously considered.
Described are a system, apparatus, method, and means for carbon capture using a treated substrate. According to an embodiment, a carbon capture apparatus includes a fabric substrate adapted to absorb an atmospheric gas at ambient temperature in a housing containing the fabric substrate. The carbon capture apparatus may also include an air handler providing a flow of air to the capture apparatus to increase the kinetics of carbon dioxide capture. For example, the air handler may include one or more fans or other air flow-controlling means that provide a substantially fixed rate of airflow to the substrate.
According to another embodiment, an atmospheric gas processing system and apparatus include a degassing chamber designed to receive the fabric substrate. In an embodiment, the degassing chamber includes a temperature control causing the received fabric substrate to be at a second temperature substantially greater than ambient temperature at which the atmospheric gas desorbs from the fabric substrate. The desorbed gas may be captured and used for industrial or agricultural purposes, e.g., to create fertilizer. Alternatively, the desorbed gas flows through an aqueous sequestration apparatus connected to the degassing chamber. The sequestration apparatus includes a liquid absorbent, wherein the atmospheric gas desorbed from the fabric substrate dissolves in the absorbent. A slurry-forming apparatus may be in fluid communication with the sequestration apparatus to receive the liquid absorbent. A material that reacts with the desorbed gas may be provided as a slurry mixed with liquid absorbent. The reactive material may include a mineral substrate, wherein the liquid absorbent is mixed with the mineral substrate to form a slurry, and wherein the atmospheric gas absorbed in the liquid absorbent reacts with the mineral substrate to form a solid over time.
In such an atmospheric gas processing system and apparatus, according to an embodiment, the atmospheric gas is carbon dioxide.
In such an atmospheric gas processing system and apparatus, according to an embodiment, the fabric substrate is first treated with a carbon sequestering agent. The sequestering agent may be a chemical that reversibly binds carbon dioxide. The fabric substrate may be a high surface area material.
In such an atmospheric gas processing system and apparatus, according to an embodiment, the carbon sequestering agent may be a sorbent selected from one or more of metal hydroxides such as sodium hydroxide or calcium hydroxide. According to another embodiment, the carbon sequestering agent may be an amine-functionalized silica. According to another embodiment, the carbon sequestering agent is a monomeric or polymeric amine such as monoethanolamine (MEA) or diethanolamine (DEA), a silylated amine such as 3-aminopropyltriethoxysilane, poly (L-lysine), or a combination thereof. According to a preferred embodiment, the carbon sequestering agent is polyethyleneimine (PEI).
In such a carbon capture apparatus, the fabric may be made of a polyester fabric, a polyethylene fabric, a polypropylene fabric, a polyolefin fabric, a cotton fabric, a polyethylene silica aerogel composite fabric, a cellulosic aerogel, a ceramic wool, or a combination of two or more of the foregoing.
In such an apparatus, according to an embodiment, the fabric substrate is made of cotton or may be comprised mostly of cotton, or nearly entirely of cotton. According to another embodiment, the fabric comprises polyester or cotton, or a combination thereof.
In such an apparatus, according to an embodiment, the fabric substrate has a specific surface area from approximately 0.5 m2/g to approximately 200 m2/g, as measured, for example, by BET/nitrogen surface area measurement. According to one embodiment, the specific surface area of the fabric substrate is greater than 1 m2/g.
According to an embodiment, the fabric substrate is configured in an arrangement in the housing to facilitate contact between ambient air flowing through the apparatus and the substrate. For example, the fabric substrate may be in one or more configurations: pleated, folded, rolled, or stacked. Such compact arrangements may increase the surface area of the fabric substrate so as to optimize the usable inside volume of the housing of the apparatus.
In such an apparatus, according to an embodiment, the fabric substrate is folded into specific patterns such as Miura Ori folds.
According to one embodiment, the fabric substrate is disposed on rolls that facilitate transporting the substrate through an air stream including carbon dioxide. The rolls may be motorized to transport fabric through the apparatus to facilitate contact between the air and reactive moieties on the substrate.
According to an embodiment, such an apparatus is configured to be deployed indoors and has a compact profile suitable for use in a residence and is adapted to be replaceable. In one embodiment, the housing holding the substrate can be conveniently removed to a carbon capture facility and replaced with a new housing including a new substrate. According to one embodiment, the housing includes wheels to facilitate the movement of the housing. According to another embodiment, the housing is fixed, for example, by being attached to a heating, ventilating, or air conditioning (HVAC) system and the fabric substrate is removable from the housing for transportation to a carbon processing and desorption facility.
The above-provided aspects and/or other aspects of the disclosure will be more apparent based on the detailed exemplary embodiments of the disclosure with reference to the accompanying drawings, in which:
Exemplary embodiments of the disclosure will now be described below by reference to the attached Figures. The described exemplary embodiments are intended to assist the understanding of the invention and are not intended to limit the scope of the invention in any way. Like reference numerals refer to like elements throughout.
According to one embodiment, one or more air-directing devices 11, for example, fans, are provided at or in the CO2 capture unit 20 to increase the rate of airflow to the substrates. This may increase the amount of CO2 captured per unit of time by increasing the amount of ambient airflow to inner facing surfaces of the substrates 21 and to substrates positioned as inside rows. The air-directing device 11 may be a part of an air conditioner system 10, such as the air handler of an HVAC system. The CO2 capture unit 20 is integrated with or provided adjacent to an HVAC system or outlet/inlet so that the CO2 capture unit 20, while provided as a passive airflow system, is provided with forced air through the parallel sheets of substrate 21 inside the CO2 capture unit 20. Thus, inefficiencies due to the local depletion of CO2 may be mitigated and an increased rate of CO2 capture overall may be provided by the CO2 capture unit 20 without the need for additional fans for the CO2 capture unit 20 itself. According to another embodiment, CO2 capture unit 20 is a passive capture system relying on natural air flows to expose the substrates 21 to ambient CO2. This may save energy and prolong the useful life of the substrate.
Substrates 21 may be formed by a fabric including one or more sorbents that reversibly sequester CO2. According to embodiments of the disclosure high-efficiency sorbents that have a low to moderate cost are provided on substrate 21. Sorbents for direct air capture (DAC) can be solid or liquid and can be based on physisorption or chemisorption. Adsorbents or absorbents include activated carbon, silica, alumina, mesoporous carbon, zeolites, metal-organic frameworks (MOFs), microporous carbon, polymers, metal hydroxides such as Na or Ca hydroxides, and the like. According to some embodiments, sorbents include monomeric and polymeric amines such as monoethanolamine (MEA) or diethanolamine (DEA), silylated amines such as 3-aminopropyltriethoxysilane, poly (L-lysine), polyethyleneimine silane, polyethyleneimine (PEI), and the like. According to one embodiment, the carbon dioxide sequestering agent is a branched polyethyleneimine or polyethyleneimine silane with a molecular weight >5,000.
Amine-based sorbents on solid substrates may be preferred due to their lower energy penalty in regeneration compared to conventional aqueous amine scrubbing technology. According to one embodiment, polyethyleneimine may be preferred because it is easily synthesized, relatively inexpensive, and more thermostable relative to monomeric amines such as MEA or DEA. Desirable attributes for such adsorbents include high absorption rates, thermal stability, cyclic capacity, and low cost.
Illustrative embodiments of the disclosure using PEI are provided. Embodiments within the scope of the disclosure are not limited to PEI sorbents and include other moieties that react with gasses such as CO2 to releasably fix molecules of the gas and allow the gas to later be desorbed.
According to an embodiment, prior to being positioned in the CO2 capture unit 20, the substrates are treated with a CO2 adsorbing agent. As shown in
The substrate including PEI is then used to adsorb and desorb CO2. Steps 57, 59 and 61 in
According to an embodiment, the substrate 21 with housing 23 may be arranged in a folding pattern to enable greater capture capacities in smaller footprints. According to one embodiment, the substrate may be pressed so that a Miura Ori crease pattern is formed as a tessellation of the substrate. Such creasing of the substrates to form a Miura pattern would yield a substrate of a matrix of parallelograms, as shown in
As shown in
According to another embodiment, the released CO2 may then be bubbled into water in a water tank 36 to dissolve the CO2 in the water. The water may be combined with metal oxide-bearing minerals, such as basalt, a natural, abundant rock, and/or other minerals to form a slurry in a mixing tank 37. The CO2 reacts with the mineral, to form a solid, for example, by forming carbonates. The slurry may be transported to a regional facility 38 for permanent sequestration, for example, by injecting the slurry underground (˜800 meters). According to another embodiment, instead of forming a mineral slurry, the water including dissolved CO2 is injected into a rock formation containing metal oxide bearing minerals where reaction between the CO2 and the rock formation sequesters the CO2 by lithification.
Table 1, below, shows properties of preferred substrates 21.
Fabric substrate 21 may be made of a variety of materials having various characteristics relevant to embodiments of the disclosure. Such fabric substrates may include, but are not limited to:
As summarized in Table 2, below, fabric substrate materials may have a range of specific surface areas. The surface area of the CSAF material is approximately 236.01 m2/g, which is significantly greater than the other substrates tested. Ceramic wool material showed the second-highest surface area at ˜3.02 m2/g of the materials above-noted. Cotton has the third-highest surface area ˜1.28 m2/g, which is two orders of magnitude lower than CSAF. Polyester (˜0.09 m2/g) and nylon (0.08 m2/g) textiles had significantly lower surface areas. The Filtrete materials also showed a low surface area of ˜0.06-0.07 m2/g. The Brunauer-Emmett-Teller (BET) method was used for surface area measurements. The fabric substrate may also be formed from a cellulosic aerogel. Specific surface areas for aerogels derived from cellulose may be between about 10 m2/g and about 975 m2/g. According to embodiments of the disclosure, substrate 21 has a specific surface area of between about 0.05 m2/g to about 1000 m2/g, or a specific surface area of greater than 1 m2/g.
Samples of various substrate materials were treated with a PEI/isopropyl alcohol mixture and dried, as discussed above. The amounts of PEI bound to three such substrates varied. Table 3, below, summarizes the amounts of PEI bound to substrates of various types:
As shown in Table 3, much more PEI was taken up by CSAF than by cotton or other materials noted above.
Substrates made of different materials when tested demonstrated advantages and disadvantages relative to one another. According to one embodiment, CSAF, 3M Filterete, and cotton substrates were treated with a PEI/isopropyl alcohol solution, as described above. After drying, these substrates were tested using the apparatus shown in
CO2 capture was shown by all three substrates. Under ambient CO2 conditions, both CSAF (25 g-CO2/m2) and cotton (12 g-CO2/m2) showed significant CO2 capture, while 3M Filtrete 1000 showed lower capture (3 g-CO2/m2), as shown in
According to embodiments of the disclosure, in addition to selecting the material forming the substrate 21, the porosity of the substrate is selected to facilitate airflow through the substrate to enhance the absorption of CO2.
A surprising finding is the high ambient CO2 capture by cotton substrate, given the low loading of the PEI material on the cotton fabric during the substrate pre-treatment phase.
The ability for selected substrates 21 to absorb CO2 under ambient conditions is shown in
According to one embodiment, recyclability was demonstrated for regeneration of the substrates made of CSAF, 3M Filtrete, and cotton, as shown in
During the CO2 removal phase, the substrates are heated significantly, for example to about 85° C. to 100° C. In the recyclability testing shown in
While cotton has a much lower surface area (1.28 m2/g) relative to CSAF (236 m2/g) and a significantly lower PEI loading (3.64 g/m2) relative to CSAF (166 g/m2), surprisingly the efficiencies of ambient air capture, the ratio of CO2 capture under ambient to pure CO2 atmospheres, are comparable; 60% for cotton and 73% for CSAF after 24 hours. Moreover, cotton enables much more conservative use of PEI: 3.022 g CO2 per 1 g-PEI, compared to 0.205 g-CO2 per 1 g-PEI for CSAF. The conservation of the active capture agent PEI in conjunction with inexpensive and robust textile substrates would improve capture/cost ratios for cotton. The PEI-impregnated cotton fabric is a highly efficient sorbent capturing ˜3.1 mmol-CO2/g-substrate based on its capture capacity (˜250 mmol/m2) and weight (˜81 g/m2). In fact, this capacity is significantly higher (29%) than currently reported values of 1.7-2.4 mmol/g. In addition, cotton production, under some circumstances, is a carbon-negative process. Thus, according to some embodiments of the disclosure, a carbon dioxide capture unit 20 that includes substrates 21 including cotton has favorable carbon dioxide characteristics and with favorable properties in terms of the low expense and low carbon footprint of their production, and with good recyclability.
According to another embodiment, the fabric substrate 21 is formed partially or entirely from a cellulosic material such as a cellulosic aerogel. Cellulosic aerogels may be derived from biological sources including cotton, may generate fewer CO2 emissions when created compared with synthetic polymer materials, and may be biodegradable. According to one embodiment, fabric substrate 21 is formed from a cellulosic aerogel with a specific surface area between about 10 m2/g to about 1000 m2/g. The fabric substrate is treated with one or more sorbents, as discussed in the previous embodiments.
According to one embodiment, CO2 is captured where it is generated—in factories, homes, and neighborhoods. A three-stage CCS process is provided that is compatible with community-based initiatives for carbon management as shown in
Carbon capture efficiencies for the embodiment of the disclosure including CO2 capture at locations such as homes and offices using substrates 21 can be significant. It has been reported that the energy required for the desorption of CO2 is about 1740 MJ/MT-CO2. The production of 1 GJ energy from natural gas releases 55.82 kg-CO2. Thus, the desorption CO2 emissions of 1 MT captured would offset the net CO2 capture potential by about 97 kg-CO2 (9.7%). This number is expected to be reduced with the further implementation of clean energy alternatives.
According to one embodiment, substrate 21 is transported to the local facility by a vehicle, such as a side loader garbage truck. Emissions associated with transportation are an important consideration in the efficiency of CO2 capture. For example, a heavy-duty diesel vehicle (side loader garbage truck) that reaches 1500 homes/day emits 8 MTCO2/yr while idling (940 hr), and 42 MTCO2/yr while driving (14,000 km/yr; based on 52 weeks, 5 days/week, 7 hr/day). A truck used full-time to deliver capture units offsets the CO2 captured (˜16,100 MT) (1500*260*41.25 kg/cycle) in the communities it serves by only 50MT-CO2 or ˜0.3%.
For sequestration, the energy needed to inject concentrated CO2 into a geological formation (for displacing water in its pore space), is approximately 2 kJ/mol-CO2. This energy penalty correlates to 2.5 kg-CO2 released for the capture of 1 MT-CO2 (0.25% offset). With consideration of all given factors, the CO2 capture potential of embodiments within the scope of the disclosure is decreased by ˜10.3% resulting in a net CO2 capture potential of ˜1.89 MT-CO2/year.
While the invention has been particularly shown and described with reference to exemplary embodiments thereof, the invention is not limited to these embodiments. It will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the following claims. Therefore, the description should not be construed as limiting the scope of the invention.
This application claims priority under 35 U.S.C. § 119 to U.S. Provisional Pat. Appl. No. 63/339,775, filed May 9, 2022, the disclosure of which is incorporated herein by reference.
Number | Date | Country | |
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63339775 | May 2022 | US |