The invention is an anodal stabilization chamber which is the final process of a five step electrochemical procedure for the organic synthesis of carbon chain polymers and for tertiary nitrile products from coal fired furnace emissions. In the beginning process an intensive electrical surge is released at one second evenly spaced intervals by dispensing finite quantities of sodium into a water spray within a reaction chamber. The hydrolyzation produces a coulombic surge within the interstice of a heated CO2 molecules carrier gas flowing continuously through the reaction chamber. In the present application one pound (1 lb) of sodium is divided into 3600 finite 126 mg quantities to synthesize 6000 pounds of heated CO2 per hour into carbon chain products.
The electrical energy required in the synthesis procedure is obtained by the oxidation of reduced alkaline metals (Li, Na, K) and alkaline earth metals (Mg, Ca). These metals are hereinafter referred to as “electrolytic fuels”. The oxidation of 1 lb of Na by hydrolyzation shown in Eq. 1 produces 528 ampere-hours of electrical current.
The electrical energy in a reduced metal is stored as an electrochemical potential equivalence which is equal to its oxidative release after hydrolyzation. Hydration of 126 mg/sec of sodium produces an electrical current surge of 30 coulombs/sec.
126 mg Na+H—OH→NaOH+H++e−→30.00 coulombs Eq. 2
The 30 coulombs of Eq. 2 is released at one second (1 sec) evenly spaced intervals of peaked oscillative modular flow hereinafter referred to as a “coulombic surge”. The hydration of 126 mg of sodium also produces 2.72×1019 electrons (e−) and an equal number of much heavier companion protons (H+) which are released into the flowing heated CO2 carrier gas stream.
Sodium is chosen in the demonstration example presented because it is the least expensive of the alkaline metals which are to be used in the process and it is important to note; Sodium is 33 times more abundant in the earth's crust than the total sum of all fossil fuels (petroleum, coal, natural gas). Alkaline metal electrolytic fuels are also used in the battery circuits of domestic electric cars. The cost of hydroelectric generated sodium based electrolytic fuel is about $0.50/lb. Wind and solar generated sodium electrolytic fuels will cost about $1.00/lb. The availability of electrolytic fuels (Li, Na, K, Ca, Mg) are 129 times more plentiful in the earth's crust than carbon based fossil fuels (petroleum, coal, natural gas) as shown graphically in
The protons (H+) released in the hydrolyzation reaction of Eq. 2 are distributed within the thermally expanded interstices of the heated CO2 molecules of the carrier gas while the electrons (e−) simultaneously produced in Eq. 2 move freely within the gaseous diffuse mixture of diverse elements, NaOH, CO2, e−, H+ flowing through the reaction chamber. The NaOH component is removed in intermediate secondary reactions in the formation of sodium carbonate (Na2CO3.nH2O). The sodium carbonate (N2CO3) is inert and has no further effect within the reacting system and is removed as a precipitant.
The synthesis procedure presented begins as a coulombic surge generated by the hydration of finite 126 mg quantities of sodium at one second evenly spaced intervals. The hydration of the sodium occurs within a heated CO2 carrier gas flowing through a reaction chamber at 6000 lbs per hour. The hydrolyzation reaction produces 30 amperes per second releasing 2.72×1019 electrons (e−) and an equal number of companion protons (H+) as indicated in Eq. 2. The diffuse mixture of hydrolyzation reaction components is carried out of the reaction chamber by heated CO2 carrier gas and passes into a steel cylinder that is flanged at both ends and has an evenly spaced plurality of finned protrusions longitudinally lining its inner surface. The steel chamber is called a “tuyere” and the finned protrusions are called “strakes”. The negative electron charges (e−) of Eq. 2 are produced within the heated CO2 carrier gas and are electrostatically absorbed on the strakes lining the internal surface of the tuyere. The electrons electrostatically absorbed on the tuyere strakes are transferred by electrical conduction into a dielectric capacitor circuit. The tuyere strakes and dielectric capacitor circuit function in unison and are hereinafter referred to as a “capacitor tuyere”. The capacitor tuyere is used to produce free electron charges (e−) for electrical generation and also for the simultaneous production of open bonded univalent aldehydes (CO2−H+) in the present application for commercial production of carbon chain polymers. The much heavier companion protons (H+) of Eq. 2 remain lodged within the interstice structure of the heated CO2 carrier gas and pass out of the capacitor tuyere through a subsonic expansion nozzle into a ceramic alignment chamber. The expansion of the diffuse mixture increases molecular polar moment of the heated CO2 carrier gas molecules and increases the mean free path of system associated particles producing stronger resonance at maximum ultrasonic absorbance at 20 kc/sec improving the opportunity for entach juxtaposition on entrance into the anodal stabilization chamber for polymerization. Nozzle expansion is also a cooling process which increases the heated CO2 carrier gas molecular interacting bonding strength thus tightening the hold on the proton (H+) lodged within the interstices forming unstable univalent aldehydes (CO2H+). The alignment of the univalent aldehydes entering the alignment chamber decreases the steric hindrance (bulk interference) of the univalent aldehyde structure allowing it to resonate more intensely at the 20 kc ultrasonic frequency and to incidentally respond to corresponding harmonic terahertz modulating carbon chain chopping frequencies, within the harmonic quantum frequency of the commercial product.
The electrons (e−) and protons (H+) of Eq. 2 that were separated in the tuyere, pass out of the capacitor tuyere on separate circuits and enter the alignment chamber. The electrons (e−) pass into the diactinic induction coil positioned over the outer surfaces of the ceramic cylinder of the alignment chamber. The protons (H+) remain in the ionic state enmeshed unstable within the fluidic interstice of the heated CO2 carrier gas and flow into the interior ceramic tubular structure of the alignment chamber.
The diactinic induction coil is formed in an undulative pattern of eight intermediate semi-elliptical bent wire divisions forming a singular circular winding pattern of the induction coil comprising a plurality of such windings.
The diatinic coil radiates two kinds of electron negative charge fields—spherical plenary fields and oblate divisional fields. When the electrons (e−) approach the juncture between elliptical segments of the coil winding they begin to lose momentum at the higher resistance of the sharper turning curve and become more closely compact. The like-on-like negative charge spherical fields become oblate on continued compaction. At critical compaction, which occurs at the highest point of coulombic surge of Eq. 2, the negative oblate field cannot follow the spin of the parent electrons and are ejected through the ceramic wall of the alignment chamber and are attracted toward the electrophilic univalent aldehyde (CO2H+) and this attractive force weakens the double bonds of the oxygen molecule. During the anodal stabilization process these weakened bonds are severed to form single bond (0-0) which is the weakest bond of all organic bonding energies (33.1 kcal/mole) releasing oxygen into the gaseous product stream of the anodal stabilization chamber. In the alignment process only the critical oblate negative electron field penetrate the ceramic wall of the alignment chamber. The electrons (e−) continue in conduction to pass out of the diactinic coil and pass into the anodal stabilization chamber magnetic siphon coil.
Electrons (e−) and protons (H+) of Eq. 2 that were separated in the capacitor tuyere and passed into the alignment chamber on separate paths are brought together again within the electrostatic field between negative charged metal plates of the anode electrode assembly of the anodal stabilization chamber. The union of the electron (e−) to the proton (H+) occurs in the direction in which the heavier proton (H+) lodged within the heated carrier gas molecule forming a univalent aldehyde (CO2H+). The mass of proton (H+) is 1836 times heavier than the electron (e−) which is nearly weightless weighing only (9.109×19−31 kg). The heated CO2 carrier gas is drawn into the space between the negative charged anode plates by a water aspirator assembly tube. The diffuse moisture between the negative charged anodal plates acts as a class 2 conductor carrying the electrons (e−) into the carrier gas releasing the protons (H+). The released protons strengthen the dielectric properties of the water to form H3 and reactive CO2 as shown in Eq. 3.
CO2H++H2O→CO2+H3O Eq. 3
The 1st terahertz harmonic modulation frequency beating against the 20 kc ultrasonic carrier frequency has sufficient kinetic energy to bring contiguous carbon atoms closer together at modulated harmonic incidence to form electrostatic negative charge between the anodal plates to react the activated CO2 molecule with the H3O molecules of Eq. 3 to produce a carbohydrate molecule.
The products formed as shown in Eq. 4 are carbohydrates and oxygen.
An Electrochemical procedure for the manufacture of carbon chain polymers from carbon dioxide emissions of coal-fired furnaces is presented.
Seven drawings of the invention are presented to illustrate the synthesis procedure. Drawing
An electrochemical procedure is used in commercial manufacture of carbon chain polymers and tertiary nitrile products from coal combustion emissions. Electrolytic fuels are used in the procedure for the generation of electric energy instead of steam generated electricity by fossil fuels. The electrolytic fuel used in the example presented in the present application is sodium.
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