Patent Application
20150044373
The present invention relates to a changing method, in particular to a carbon fiber surface oil changing method.
In general, carbon fiber is used in composite enhanced substances with different types of substrates, and the adhesiveness of a specific substrate is important to carbon the fiber to show the characteristics of the enhanced substances.
Non-surface treatment carbon fibers usually have insufficient adhesiveness for the substrate and poor transverse properties such as the separating strength and shear strength.
Naturally, the carbon fiber generally receives an oxidization treatment such as an electrolytic oxidation treatment, a gas-phase chemical oxidation treatment or a liquid-phase chemical oxidation treatment after a carbonization or graphitization takes place, and oxygen-containing functional groups are added into the carbon fiber to improve the wettability of the substrates.
With regard to the surface characteristics of the carbon fiber after being processed by the oxidization treatment, Japan Patent Publication 4-361619 disclosed a method of improving the adhesive strength of the carbon fiber to the substrate by depositing a specific functional group onto the uppermost surface of the carbon fiber. This patent also specifies the carbon fiber whose surface oxygen concentration and surface nitrogen concentration are both measured by X-ray optoelectronic spectroscopy measurement techniques (such as those disclosed in Japan Examined Patent Publication No. 4-44016, and Japan Unexamined Patent Application Publication Nos. 2-210059, 2-169763, 63-85167, and 62-276075), but these inventions do not include the study of a combination of a sizing agent. In addition, these patents are simply described by using the surface functional groups such as the drawback of having a poor adhesion with a substrate, particularly the substrate with a low reactivity.
On the other hand, carbon fiber and graphite fiber are peculiarly hard and brittle and lack of adhesiveness, bending strength and wear-resistance, so that various different types of sizing agents are generally added into the treated carbon fiber to prevent the formation of fine hair and the occurrence of thread fracture, so as to improve the adhesiveness, bending strength and wear-resistance. Studies on developing and using a sizing agent such as a paste or an adhesive to improve the treatment are conducted, but the study on the improvement of adhesiveness of the sizing agent to a substrate has not been actually performed. In addition, the study on modifying surface characteristics by a sizing agent has not been performed. For example, the functional groups on the aforementioned carbon fiber surface are used to improve the overall characteristics including adhesiveness and tension of a composite.
Since the most popular substrate used in a carbon fiber enhancing composite substance is epoxy resin, and the sizing agent is usually epoxy resin or modified epoxy resin which are biphenol A diglycidyl ether type epoxy resins such as aromatic compounds with a structure related to the substrate (as disclosed in Japan Examined Patent Publication No. 4-8542, Japan Unexamined Patent Application Publication No. 1-272867, and Japan Examined Patent Publication Nos. 62-56266 and 57-15229). However, the aforementioned common sizing agent is a thermosetting resin, so that if it is necessary to produce a thermoplastic carbon fiber composite material, then the interface will not be matched, and the carbon fiber and the resin will be unable to form a complete joint interface, and the sizing agent cannot be used extensively for electric/electronic components, mechanical components or automobile components which are manufactured by injection molding. Therefore, it is an urgent and important subject for related manufacturers to develop a changing method capable of changing the carbon fiber surface oil.
In view of the aforementioned problems of the conventional oil changing method, it is a primary objective of the present invention to provide a changing method capable of changing a carbon fiber surface oil in order to overcome the drawbacks of the prior art.
To achieve the aforementioned objective, the present invention provides a changing method comprising the steps of supplying a carbon fiber material with a surface covered by a thermosetting resin oil, performing a desizing step to remove the thermosetting resin oil from the surface of the carbon fiber material, performing a surfactant coating step to coat a surfactant onto the surface of the carbon fiber material, and performing a sizing step to cover a surface of the surfactant by a thermosetting resin oil, so as to obtain a carbon fiber material with a thermosetting resin oil coated onto the surface of the carbon fiber material.
The present invention will become clearer in light of the following detailed description of an illustrative embodiment of this invention described in connection with the drawings. It is intended that the embodiments and drawings disclosed herein are to be considered illustrative rather than restrictive.
With reference to
Provide a carbon fiber material as shown in
Perform a desizing step to remove the thermosetting resin oil from the surface of the carbon fiber material to form a carbon fiber material 10 without any oil on the surface (as shown at the position on the left of the center of
Perform a surfactant coating step, wherein the surfactant 30 is covered onto the surface of the carbon fiber material 10. In this step, ethanol is used for cleaning the surface of the carbon fiber material first, and then 0.5˜1 wt % of amine-containing surfactant and 99˜99.5 wt % of aqueous ethanol are used for coating the surface, and this method can be an aerosol spray method or a dipping method, such that the surfactant 30 is covered onto the surface of the carbon fiber material 10, and the surfactant 30 facilitates applying the oil onto the surface again and forming a complete interface with the carbon fiber surface.
Perform a sizing step, wherein a thermoplastic resin oil 40 is covered onto a surface of the surfactant 30. In this step, a soaking method or an immersion method can be used for attaching the thermoplastic resin oil 40 onto the surface of the surfactant 30, and the thermoplastic resin oil can be PU, PE, PP, acrylic or PC/ABS oil with a concentration of 0.1˜5 wt % for sizing.
Of course, a first drying process can be added between the surfactant coating step and the sizing step, and a second drying process can be added after the sizing step takes place as shown in
It is noteworthy that the present invention can change a carbon fiber surface oil, particularly can change the original thermosetting resin oil on the surface of the carbon fiber into a thermoplastic resin oil, so that when the carbon fiber is used for manufacturing a thermoplastic carbon fiber composite material, the carbon fiber and the resin can form a complete joint interface, and the carbon fiber can be applied extensively in various different types of electric/electronic components, mechanical components and automobile components manufactured by injection molding.
For example, Model No. T700, PAN type carbon fibers with a K number of 12K/24K (manufactured by Japanese Toray Company) can be used in the method of the present invention, and the thermoplastic resin oil (PP, PU, acrylic, or PC/ABS oil can be changed according to the changing step of the present invention; or Model No. TC36, PAN type carbon fibers with a K number of 12K/24K (manufactured by Taiwanese Formosa Company) can be used in the method of the present invention, and the thermoplastic resin oil (PP, PU, acrylic, or PC/ABS oil can be changed according to the changing step of the present invention; or Model No. K63712 , pitch type carbon fibers with a K number of 12K/24K (manufactured by Japanese Mitsubishi Company) can be used in the method of the present invention, and the thermoplastic resin oil (PP, PU, acrylic, or PC/ABS oil can be changed according to the changing step of the present invention.
In addition, the present invention further uses a changing device to carry out the aforementioned steps. With reference to
The feed component 50 is used for supplying a carbon fiber material 10, and a thermosetting resin oil 11 is covered onto a surface of the carbon fiber material 10, wherein the carbon fiber can be of any type or a different K number (standing for thousand of filaments per tow).
The winder 60 is installed behind the feed component 50 and includes at least one rewinding part 61, wherein an end of the carbon fiber material 10 is wound to the feed component 50, and the other end of the carbon fiber material 10 is manufactured to form a carbon fiber product 10′ to be wound to the rewinding part 61.
The desizing oven 70 is installed between the feed component 50 and the winder 60 for removing the thermosetting resin oil from the surface of the carbon fiber material to produce a carbon fiber material 10 without any oil on the surface as shown at the position on the left of the center of
The coating component 80 is connected behind the desizing oven 70, and a surfactant 12 is covered onto the surface of the carbon fiber material 10, wherein the coating component sequentially includes second and third reservoirs (not shown in the figure), and the second reservoir is provided to store ethanol for cleaning the surface of the carbon fiber material, and the third reservoir is provided to store 0.5˜1 wt % of amine-containing surfactant and 99˜99.5 wt % of aqueous ethanol, and an aerosol spray method or a soaking method is adopted to coat the surfactant 12 onto the surface of the carbon fiber material 10, and the surfactant 12 facilitates applying the oil onto the surface of the carbon fiber material 10 again and forming a complete interface with the carbon fiber surface.
The sizing component 90 is connected behind the coating component 80, and a thermoplastic resin oil 13 is covered onto a surface of the surfactant 12 to form a carbon fiber product 10′ to be wound onto a rewinding part 61 of the winder 60, wherein the sizing component 90 includes a fourth reservoir provided to store a thermoplastic resin oil which can be PU, PE, PP or acrylic oil and attached onto a surface of the surfactant 12 by a soaking method or an immersion method.
In
In summation of the description above, the present invention improves over the prior art, and is thus duly filed for patent application. While the invention has been described by means of specific embodiments, numerous modifications and variations could be made thereto by those skilled in the art without departing from the scope and spirit of the invention set forth in the claims.
