1. Field of the Invention
The invention relates to a new class of materials, called reactive materials or reactive material structures. These materials are inert in standard atmospheric conditions, but as they are used as weapon cases housing high explosives, when these high explosives detonate, they generate fine fuel particles such as aluminum or aluminum alloy particles. These fuel particles are sufficiently heated during the case expansion and breakup in such a way that they react with air immediately surrounding the weapon. This reaction with air enhances the blast strength of the weapon beyond that of the high explosives alone. In many situations, it would be beneficial to replace steel cases that are currently used in weapons with these new materials in order to enhance the blast power of the weapon.
2. Description of the Related Art
Three conditions need to be satisfied for the reactive materials to become good candidates for weapon cases. First, they have to break and generate fine fuel particles when they are subjected to a detonation of high explosives next to them (friability condition). Second, the fuel particles must have been heated to a high enough temperature so that when they become in contact with the surrounding air, they start burning immediately and fast (reactability condition). Once the above two conditions are met, enhanced blasts can be generated. However, the above two conditions are not enough themselves for the reactive materials to be used as weapon cases. The third condition is that they would have strong enough material properties to allow them to house the high explosives, to be handled and stored safely, to be fired upon command, and in some cases to penetrate certain targets and then to function as intended (material properties condition).
Although each of the three above mentioned requirements (friability, reactability with air, and material properties) can be easily satisfied independently by various methods, manufacture of reactive materials that satisfy all three requirements together has been challenging.
New materials are currently being developed by several government and industrial laboratories in small scales and they show promise of satisfying all three requirements. However, their methods of manufacturing is extremely time consuming and expensive. It will be challenging to mass produce these laboratory type research materials and use them as weapon cases.
This invention provides an answer to satisfy all of the above three requirements and to keep the manufacturing cost well below those of the current research materials.
The invention takes advantage of several observations. First, it is observed that particles of aluminum or aluminum alloys such as magnesium-aluminum alloys are easily ignited and burn fast at lower temperatures than most other metal particles. It is also observed that aluminum and magnesium releases very large heat of combustion. For aluminum, the heat of combustion is around 7400 cal/g and for magnesium it is around 6200 cal/g. In contrast, the detonation energy of TNT, a most common explosive, releases only about 1000 cal/g.
Second, it is observed that aluminum particles of the size of tens of microns ignite and burn within a few milliseconds or less. It is within the time limit of releasing and depositing the reaction energy into expanding blast waves such that the strength of the blast itself can be enhanced.
Third, it has been observed that aluminum or aluminum alloy particles mixed and pressed with high density metal particles can break into fine particles and can get heated to high enough temperatures for reaction initiation when subjected to a strong shock. The process is called shock-induced micromechanical deformation. Essentially, the aluminum or aluminum alloys will move around the high density metal particles when they are pushed by a shock. These fuel metals will undergo plastic deformation, and get heated. If the plastic deformation is large enough, it can cause the fuel metal to break into fine particles with sufficient heating of these particles. It has been shown that the size of these fuel particles depend, in some cases, upon the size of the high density metal particles originally mixed in with the fuel.
Fourth, the micromechanical plastic deformation may be enhanced further when mixed in with fibers, rather than particles, of high density metals, and at the same time, may enhance overall bulk mechanical strengths of these reactive material structures. On the other hand, mixing process becomes easier with the inclusion of high density particles to the fibers, especially at high weight percentages of high density metals. The micromechanical deformation can be further enhanced by the presence of small amounts of hard particles such as ceramic particles.
The invention would cast, into a mold, aluminum or aluminum alloys with high density metal fibers and/or particles at desirable weight percentages at below the melting temperature of high density metals so that structural integrity of those high density metal particles and fibers are not degraded by high temperatures.
There are no drawings for this invention.