TREA

Cat litter product

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Information

  • Patent Grant
  • 11026397
  • Patent Number
    11,026,397
  • Date Filed
    Monday, November 11, 2019
    5 years ago
  • Date Issued
    Tuesday, June 8, 2021
    3 years ago
Information
Abstract
Litter compositions are provided comprising sodium bentonite and various fillers. These litter compositions have substantially the same clumpability properties as a composition consisting of only the sodium bentonite.
Description
BACKGROUND
Field of the Invention

The present invention relates to cat litter products.


Related Art

Swelling clay made of sodium bentonite has been used to promote clumping in cat litter products but has the disadvantage of being relatively expensive.


SUMMARY

According to a first broad aspect, the present invention provides composition comprising: a blend comprising sodium bentonite and calcium bentonite, wherein sodium bentonite comprises at least 47% of the total external surface area of the blend, wherein the calcium bentonite comprises 5% to 53% of the total external surface area of the blend, wherein 90% of the particles of the sodium bentonite have a particle size of 345 to 1695 μm, and wherein 90% of the particles of the calcium bentonite have a particle size of 626 to 2000 μm.


According to a second broad aspect, the present invention provides a composition comprising: a blend of sodium bentonite and calcium bentonite, wherein the calcium bentonite is coated with a coating comprising polytetrafluoroethylene (PTFE).


According to a third broad aspect, the present invention provides a composition comprising a uniform blend of sodium bentonite and calcium bentonite.


According to fourth broad aspect, the present invention provides a composition comprising: a mixture comprising sodium bentonite and one or more granular filler materials, wherein the one or more granular filler materials comprise one or more cellulose-containing materials, wherein sodium bentonite comprises at least 47% of the total external surface area of the mixture, wherein the one or more granular filler materials comprise 5% to 53% of the total external surface area of the mixture, and wherein the mixture is removably clumpable.


According to fifth broad aspect, the present invention provides a composition comprising: a mixture comprising sodium bentonite and one or more granular filler materials, wherein the one or more granular filler materials comprise one or more non-calcium bentonite clays, wherein sodium bentonite comprises at least 47% of the total external surface area of the mixture, wherein the one or more granular filler materials comprise 5% to 53% of the total external surface area of the mixture, and wherein the mixture is removably clumpable.





BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are incorporated herein and constitute part of this specification, illustrate exemplary embodiments of the invention, and, together with the general description given above and the detailed description given below, serve to explain the features of the invention.



FIG. 1 is a flow chart showing a method of making a litter product according to one embodiment of the present invention.



FIG. 2 is a flow chart showing a method of making a fragrance-free litter product according to one embodiment of the present invention.



FIG. 3 is a schematic diagram of an apparatus for making a litter product according to one embodiment of the present invention.



FIG. 4 is a schematic front view of a dropping device for testing clump strength of a litter using a Standard Drop Method Test.



FIG. 5 is schematic side view of the dropping device of FIG. 4.



FIG. 6 is an image showing examples of clumps showing different levels of clump strength.



FIG. 7 is a schematic front view of an extreme dropping device for testing clump strength of a litter using an Extreme Drop Method Test.



FIG. 8 is schematic side view of the extreme dropping device of FIG. 7.



FIG. 9 is a graph of U.S. mesh versus ASTM multiplier for the sodium bentonite and calcium bentonite particles used in the litter compositions of Examples 3-35.



FIG. 10 is a plot of the percentage external surface area as sodium bentonite per pound of product plotted against the clump strength results for 30 second and 1 hour clumps for the litter compositions of Examples 3-35.



FIG. 11 is a plot of the percentage total particle count as sodium bentonite per pound of product versus the clump strength results for 30 second and 1 hour clumps for the litter compositions of Examples 3-35.



FIG. 12 shows a table providing information about the sodium bentonite used in Blend #1 of Example 3 and Blend #4 of Example 6.



FIG. 13 shows a table providing information about the calcium bentonite used in Blend #1 of Example 3 and Blend #4 of Example 6.



FIG. 14 shows a table providing information about the sodium bentonite used in Blend #2 of Example 4, Blend #3 of Example 5, Blend #15 of Example 17, Blend #16 of Example 18, Blend #17 of Example 19, Blend #18 of Example 20, Blend #19 of Example 21, Blend #20 of Example 22, Blend #21 of Example 23 and Blend #22 of Example 24.



FIG. 15 shows a table providing information about the calcium bentonite used in Blend #2 of Example 4, Blend #17 of Example 19, Blend #18 of Example 20 and Blend #19 of Example 21.



FIG. 16 shows a table providing information about the calcium bentonite used in Blend #3 of Example 5 and Blend #32 of Example 34.



FIG. 17 shows a table providing information about the sodium bentonite used in Blend #5 of Example 7 and Blend #6 of Example 8.



FIG. 18 shows a table providing information about the calcium bentonite used in Blend #5 of Example 7, Blend #6 of Example 8, Blend #7 of Example 9, Blend #8 of Example 10, Blend #9 of Example 11, Blend #10 of Example 12, Blend #11 of Example 13, Blend #12 of Example 14, Blend #13 of Example 15 and Blend #14 of Example 16.



FIG. 19 shows a table providing information about the sodium bentonite used in Blend #7 of Example 9, Blend #8 of Example 10, Blend #9 of Example 11, Blend #10 of Example 12 and Blend #11 of Example 13.



FIG. 20 shows a table providing information about the sodium bentonite used in Blend #12 of Example 14, Blend #13 of Example 15 and Blend #14 of Example 16.



FIG. 21 shows a table providing information about the calcium bentonite used in Blend #15 of Example 17 and Blend #16 of Example 18.



FIG. 22 shows a table providing information about the calcium bentonite used in Blend #20 of Example 22, Blend #21 of Example 23 and Blend #22 of Example 24.



FIG. 23 shows a table providing information about the sodium bentonite used in Blend #23 of Example 25.



FIG. 24 shows a table providing information about the calcium bentonite used in Blend #23 of Example 25.



FIG. 25 shows a table providing information about the sodium bentonite used in Blend #24 of Example 26, Blend #25 of Example 27, Blend #26 of Example 28, Blend #27 of Example 29, Blend #28 of Example 30. Blend #29 of Example 31, Blend #30 of Example 32, Blend #31 of Example 33, the litter of Example 35, Blend #41 of Example 44, Blend #42 of Example 45, Blend #43 of Example 46, Blend #44 of Example 47, Blend #45 of Example 48 and Blend #46 of Example 49.



FIG. 26 shows a table providing information about the paper granules used in Blend #24 of Example 26, Blend #25 of Example 27, Blend #26 of Example 28 and Blend #27 of Example 29.



FIG. 27 shows a table providing information about the wood fiber particles used in Blend #28 of Example 30.



FIG. 28 shows a table providing information about the barley grains used in Blend #29 of Example 31, Blend #30 of Example 32 and Blend #31 of Example 33.



FIG. 29 shows a table providing information about the sodium bentonite used in Blend #32 of Example 34.



FIG. 30 shows a table providing information about the sodium bentonite used in Blend #33 of Example 36, Blend #34 of Example 37, Blend #35 of Example 38, Blend #36 of Example 39, Blend #37 of Example 40 and Blend #37 of Example 40.



FIG. 31 shows a table providing information about the calcium bentonite used in Blend #33 of Example 36, Blend #34 of Example 37, Blend #35 of Example 38, Blend #36 of Example 39, Blend #37 of Example 40 and Blend #37 of Example 40.



FIG. 32 shows a table providing information about the attapulgite used in Blend #41 of Example 44, Blend #42 of Example 45 and Blend #43 of Example 46.



FIG. 33 shows a table providing information about the Taft clay used in Blend #44 of Example 47, Blend #45 of Example 48 and Blend #46 of Example 49.



FIG. 34 is a plot of detected ammonia versus days for three different litter compositions.





DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Definitions

Where the definition of terms departs from the commonly used meaning of the term, applicant intends to utilize the definitions provided below, unless specifically indicated.


For purposes of the present invention, it should be noted that the singular forms, “a,” “an” and “the” include reference to the plural unless the context as herein presented clearly indicates otherwise.


For purposes of the present invention, directional terms such as “top,” “bottom,” “upper,” “lower,” “above,” “below,” “left,” “right,” “horizontal,” “vertical,” “up,” “down,” etc., are merely used for convenience in describing the various embodiments of the present invention. The embodiments of the present invention may be oriented in various ways. For example, the diagrams, apparatuses, etc., shown in the drawing figures may be flipped over, rotated by 90° in any direction, reversed, etc.


For purposes of the present invention, a value or property is “based” on a particular value, property, the satisfaction of a condition or other factor, if that value is derived by performing a mathematical calculation or logical decision using that value, property or other factor.


For purposes of the present invention, the term “blend” refers to a uniform or substantially uniform mixture of two or more solid materials. One or more materials in a blend may be coated.


For purposes of the present invention, the term “cellulose-containing material” refers to a material in which 10% or more of the material is comprised of cellulose. Examples of cellulose-containing materials include paper, wood, seeds, fibers, etc. Examples of suitable seeds and grains for use as filler material include grass seeds and grains such as barley, rice, wheat, corn, maize, etc., pieces and parts thereof, reconstituted parts thereof and mixtures thereof.


For purposes of the present invention, the term “clumping additive” refers to a clumping agent other than sodium bentonite.


For purposes of the present invention, the term “clumping agent” refers to a material that increases the clump strength of a litter material. Examples of clumping agents include sodium bentonite, xanthan gum, guar gum, etc.


For purposes of the present invention, the term “clump strength” refers to the numerical value of average clump strength for a clump of litter material formed by exposing the litter material to a wetting agent approximating urine. The clump strength of a litter material may be determined using one of the clump strength test procedures described below. These procedures include the Standard Drop Method Test and Extreme Drop Method Test described below, as well as other procedures for determining clump strength.


For purposes of the present invention, the term “filler” and the term “filler material” refer to a material in a litter product other than a clumping agent, i.e., other than sodium bentonite or a clumping additive. In one embodiment of the present invention, a filler material may be calcium bentonite. In one embodiment of the present invention, the filler material may be a cellulose-containing material. In one embodiment of the present invention filler may constitute from 5% to 53% of the total external surface of a litter product. In one embodiment of the present invention filler may constitute from 10% to 53% of the total external surface of a litter product. In one embodiment of the present invention filler may constitute from 15% to 53% of the total external surface of a litter product. In one embodiment of the present invention filler may constitute from 50% to 53% of the total external surface of a litter product.


For purposes of the present invention, the term “fragrance coating” refers to a coating comprising a fragrance. A fragrance coating may include other components.


For purposes of the present invention, the term “granular” refers to a solid material having a particle size below 2 mesh. A solid material used in a mixture of the present invention may be ground to form a granular material.


For purposes of the present invention, the term “granular filler” and the term “granular filler material” refer to a filler that is granular.


For purposes of the present invention, the term “heterogeneous mixture” refers to a composition in which the components of the mixture may be readily separated from each other.


For purposes of the present invention, the term “homogeneous mixture” refers to a composition that is uniform.


For purposes of the present invention, the term “mixture” refers to a composition comprising two or more different components that are mixed but not combined chemically. An individual component of a heterogenous mixture may comprise two substances that are combined chemically, such as calcium bentonite particles coated with polytetrafluoroethylene (PTFE).


For purposes of the present invention, the term “non-calcium bentonite clay” refers to a clay other than calcium bentonite. Because a filler material cannot be sodium bentonite, a “non-calcium bentonite clay” cannot be sodium bentonite.


For purposes of the present invention, the term “removably clumpable” refers to a litter that, when exposed to a wetting agent forms one or more clumps having a firmness of sufficient structural integrity and hardness to withstand mechanical separation from unwetted litter for disposal. A litter material having a clump strength of ≤1.33 using the Standard Drop Method Test (described below) 30 seconds, 1 hour, 12 hours, 24 hours, 36 hours or 72 hours after the clump is formed by exposure to a liquid is removably clumpable. A litter that is removably clumpable, i.e., has a clump strength of ≤1.33 using the Standard Drop Method Test, has a clump strength that is substantially the same as a litter comprised of only the sodium bentonite of the litter.


For purposes of the present invention, the term “substantially uniform” refers to a mixture that has substantially the same density throughout the mixture.


For purposes of the present invention, the term “Taft clay” refers to Antelope shale. Taft clay is porcelanite that is composed of opalaceous material.


For purposes of the present invention, the term “uniform” refers to a mixture of two or more solid materials wherein a measured density of the composition for ten or more samples of the mixture has a standard deviation of no greater than 2.0 lbs/ft3 throughout the mixture. One or more of the solid materials may be coated.


For purposes of the present invention, the term “uniform blend” refers to a blend that is uniform.


For purposes of the present invention, the term “uniform mixture” refers to a mixture that is uniform.


For purposes of the present invention, the term “wetting agent” refers to a liquid that wets a litter. Examples of wetting agents include liquids such as water, aqueous solutions, urine, synthetic urine, etc.


DESCRIPTION

In one embodiment, the present invention provides a litter comprising sodium bentonite and calcium bentonite in which only the calcium bentonite particles are coated in polytetrafluoroethylene (PTFE) as a dedusting agent. Because clumpability for litters comprising mixtures of sodium bentonite with a filler, such as calcium bentonite, is dependent on the total external surface area of the sodium bentonite particles in the litter, by applying a PTFE coating to only the calcium bentonite particles, in one embodiment the present invention provides a litter that is low in dust while not substantially reducing the clumpabilility of the litter.


In one embodiment, the present invention provides a litter product blend of sodium bentonite and calcium bentonite in which 90% of the sodium bentonite particles have a particle size of between 345 and 1695 μm and 90% of the calcium bentonite particles have a particle size of between 626 and 1695 μm. In one embodiment of the present invention, the sodium bentonite particles have an average size of between 450 and 1000 μm and the calcium bentonite particles have an average range between 650 and 2000 μm.


In one embodiment, the present invention provides a litter product comprising a mixture of sodium bentonite and one or more fillers that has emissions of ammonia when exposed to urine that are less than for sodium bentonite alone.


In one embodiment, the present invention provides a litter product comprising sodium bentonite and one or more filler materials, in which the litter product has similar clumpability properties to sodium bentonite of the litter while being less dense than the sodium bentonite alone. In one embodiment, the present invention provides a clumpable litter product employing a cellulose-containing filler material to minimize the amount of sodium bentonite used while still providing clumpability similar to sodium bentonite of the litter.



FIG. 1 shows a method 102 for making a litter product according to one embodiment of the present invention that includes a fragrance. Method 102 starts with a tank 110 containing sodium bentonite granular particles and a tank 112 containing calcium bentonite particles. At step 114 the sodium bentonite particles are delivered from tank 112 to one of a series of conveyor belts that transport the sodium bentonite to a mixing station. At step 116 while the sodium bentonite particles are travelling on one of the conveyors, a fragrance slurry is added to the sodium bentonite particles as a coating. The fragrance slurry is a solution or suspension containing one or more fragrances and possibly other additives. Steps 124 and 126 are conducted at the same time as steps 114 and 116. At step 124 the calcium bentonite particles are delivered from tank 112 to one of a series of conveyor belts that transport the calcium bentonite to a mixing station. At step 126 while the calcium bentonite particles are travelling on one of the conveyors, a PTFE slurry is added to the calcium bentonite particles as a coating. The PTFE slurry is a solution or suspension containing PTFE. At step 132, the coated sodium bentonite particles and coated calcium bentonite particles are brought together to form a litter mixture. At step 134 the litter mixture is dedusted. At step 136 the sodium bentonite and the calcium bentonite are mixed together to form a litter product 138 that is a uniform blend. The fragrance slurry is sprayed onto the sodium bentonite particles in step 116 using a first hydraulic sprayer pump that sprays the fragrance slurry through a first set of flat fan sprayer nozzles to form a fragrance coating. The PTFE slurry is sprayed onto the calcium bentonite particles in step 126 using a second hydraulic sprayer pump that sprays the PTFE slurry through a second set of flat fan sprayer nozzles to form a PTFE coating.



FIG. 2 shows a method 202 for making a litter product according to one embodiment of the present invention that is fragrance-free. Method 202 starts with a tank 210 containing sodium bentonite granular particles and a tank 212 containing calcium bentonite particles. At step 214 the sodium bentonite particles are delivered from tank 212 to one of a series of conveyor belts that transport the sodium bentonite to a mixing station. Steps 224 and 226 are conducted at the same time as step 214. At step 224 the calcium bentonite particles are delivered from tank 212 to one of a series of conveyor belts that transport the calcium bentonite to a mixing station. At step 226 while the calcium bentonite particles are travelling on one of the conveyors, a PTFE slurry is added to the calcium bentonite particles as a PTFE coating. The PTFE slurry is a solution or suspension containing PTFE. At step 232, the coated sodium bentonite particles and coated calcium bentonite particles are brought together to form a litter mixture. At step 234 the litter mixture is dedusted. At step 236 the sodium bentonite and the calcium bentonite are mixed together to form a litter product 238 that is a uniform blend. The PTFE slurry is sprayed onto the calcium bentonite particles in step 226 using a hydraulic sprayer pump that sprays the PTFE slurry through a second set of flat fan sprayer nozzles.



FIG. 3 shows an apparatus 302 that may be employed in the methods of FIGS. 1 and 2, as well as other methods of making a litter product according to various embodiments of the present invention. Apparatus 302 includes a sodium bentonite tank 312 which is used to deliver sodium bentonite particles to a weigh conveyor belt 314 where the sodium bentonite particles are weighed. Weigh conveyor belt 314 conveys the sodium bentonite particles to a conveyor belt 316 where a fragrance slurry from a tank 318 may be sprayed onto the sodium bentonite particles, as indicated by arrow 320, to form coated sodium bentonite by using a hydraulic spray pump to pump the fragrance slurry through a set of flat fan sprayer nozzles. If a fragrance-free product is being produced, this step of spraying the fragrance slurry on the sodium bentonite particles may be omitted. For simplicity in the remainder of the description of the functioning of apparatus 302 it will be assumed that the sodium bentonite particles are coated with a fragrance slurry to form a fragrance coating. Conveyor belt 316 conveys the coated sodium bentonite particles to a base portion 322 of an elevator 324 as indicated by arrow 326.


Apparatus 302 also includes a calcium bentonite tank 332 which is used to deliver calcium bentonite particles to a weigh conveyor belt 334 where the calcium bentonite particles are weighed. Weigh conveyor belt 334 conveys the calcium bentonite particles to a conveyor belt 336 where a PTFE slurry from a tank 340 is sprayed onto the calcium bentonite particles, as indicated by arrow 342, to form coated calcium bentonite particles by using a hydraulic spray pump to pump the PTFE slurry through a set of flat fan sprayer nozzles. Conveyor belt 336 conveys the calcium bentonite particles to a base portion 322 of elevator 324.


The coated sodium bentonite particles and the coated calcium bentonite particles are mixed together at base portion 322 of elevator 324 and conveyed up to a top portion 328 of elevator 324 before falling through a dedust box 348 and a mass flow surge bin 350 and onto a weigh conveyor belt 352. The total amount of mixture is weighed on weigh conveyor belt 352. Weigh conveyer belt 352 conveys the mixture to a conveyor belt 354 where one or more additives may be added to the mixture from an additive feeder 356 as indicated by arrow 358. Conveyor belt 354 conveys the mixture to a conveyor belt 360 where the mixture is blended using stationary mixing plows 362. Conveyor belt 360 eventually conveys the mixture to a static mixer 364 to further blend the mixture. After the mixture is well blended to form a litter product, the litter product is dispensed from static mixer 364 into a mass flow packaging bin 366, as indicated by arrow 368, and is sent to a packaging apparatus as indicated by arrow 372. Dust collection is performed by various dust collection devices at various portions of apparatus 302 as shown by arrows 374.


The dedust box function dedusts the clay. Clay falls down a “flight of stairs” with air passing through the falling clay as it falls from each step. The air with entrained dust goes to a dust collector.


One purpose of the mass flow surge bin is to function as a typical surge bin. The mass flow surge bin also functions is to avoid segregation. A normal surge bin is a kind of “first in first out” and has funnel flow. This action may cause segregation. A mass flow bin does a much better job of avoiding segregation. When one mixes materials of either different particles sizes or densities, agitation and movement may cause segregation. A mass flow surge bin is a special design where material moves as a column down the silo so one gets a “first in, first out behavior. This greatly lessens agitation and decreases segregation.


In apparatus 302 of FIG. 3, the stationary plows are mounted over a moving belt to plow the material after a material addition. The stationary plows “fold” the material in. The stationary plows are set up to provide both a rolling action and a back and forth motion for blending. The stationary plows mix the final dry additives into the main flow of material on the belt by moving the flowing material back and forth from side to side turning it over onto itself. There are four plows alternately angled left and right. The action is similar to that inside a static mixer. The movement of the powered conveyor belt flowing the material past the plows imparts the necessary energy for mixing. The plows are immediately downstream of where minor quantities of solid powdered and granular additives are applied. The plows assure that these additives are well-mixed into the blend.


The static mixer of apparatus 302 of FIG. 3 is a section of vertical pipe with an arrangement of internal mixing baffles (flanges or louvers) that repeatedly split and recombine the flow to ensure a final uniform blend immediately before packaging.


Apparatus 302 of FIG. 3 is controlled by a control system 382 that is used to control the percentage of each component in the composition of the litter's blend. Flows of materials may be dynamically ratioed so that the blends formed by the apparatus have a specific composition of ingredients. The weight conveyor belt for sodium bentonite sets the pace for the operation of the apparatus and sends a signal to the control system that is used to properly ratio the flow of calcium bentonite and all other ingredients. During startup, shutdown and speed changes, the control system maintains quality of blend by accounting for different belt lengths, belt speeds and flow rates so that flows start and stop together at the point of mixing. Further protections on quality include upper and lower range specifications on key settings. Associated with these are warning limits and process shutdown limits to prevent off-specification production. Important areas for blending and avoidance of segregation are the material transfer points, where the stationary plows blend the mixture, the static mixer and the mass flow surge bin.


In making a cat litter blend, any time a blend is agitated at a material transfer point where there is a free flow or free fall of material, segregation may occur. Therefore, in one embodiment of the present invention, segregation of the materials in a blend may be minimized by minimizing the number of material transfer points and by minimizing the length that a blend falls at a material transfer point.


The additive feeder of the apparatus of FIG. 3 may be used to add materials such as a clumping agent, a fragrance, odor control additives, etc. Although for simplicity of illustration, only one additive feeder is shown in FIG. 3, there may be two or more additive feeders.


In one embodiment of the present invention, the sodium bentonite used in a litter mixture may have a bulk density of 60 to 75 lbs/ft3.


In one embodiment of the present invention, the calcium bentonite used in a litter mixture may have a bulk density of 35 to 45 lbs/ft3.


In one embodiment of the present invention, a sodium bentonite/calcium bentonite blend used in a litter may have a bulk density of 50 to 58 lbs/ft3. In one embodiment of the present invention, a sodium bentonite/calcium bentonite blend may be sufficiently uniform that differences in the bulk density throughout the blend are 2.0 lbs/ft3, or 0.97 lbs/ft3, or 0.96 lbs/ft3, or even 0.74 lbs/ft3, for 10 samples of the blend.


In addition to calcium bentonite, other materials that may be used as filler materials in litter compositions of the present invention include Taft clay, smectites, attapulgite (palygorskite), fuller's earth, diatomaceous earth, kaolinite, sepiolite, zeolite, vermiculite, pumice, perlite, gypsum, beads (polyethylene, polystyrene, polypropylene, glass, silica gel), cloth, cotton, straw, cellulose, bark, poultry litter, reconstituted materials and combinations of materials such as mineral cellulose and light weight fertilizer, recycled wastes such as Milorganite, organic material such as barley grains, corn kernels, wheat grains, coffee beans, rice grains, nut shells, paper, wood fiber, wood pulp, wood shavings, wood chips, wood flour, sawdust, etc., pieces and parts thereof, reconstituted parts thereof and mixtures thereof. In one embodiment, filler materials of the present invention may have a bulk density of less than of the sodium bentonite in a litter mixture.


In one embodiment, a filler of the present invention may be a granular filler.


Litter compositions of the present invention may include clumping additives. Examples of clumping additives that may be used in mixtures of the present invention include polysaccharides, guar gum, Arabic gum, karaya gum, tara gum, ghatti gum, galactomannan gum, locust bean gum, cellulose ester or ether, carboxymethyl cellulose, hydroxypropylmethyl cellulose, hydroxybutylmethyl cellulose, methyl cellulose, polyelectrolyte, xanthan gum, alginates, carrageenan gums, pectins, starches, psyllium husk powder, corn flour, pre-gelatinized corn flour, polyvinyl alcohol, polymers, copolymers, modified starches, etc.


Litter compositions of the present invention may include dedusting agents. Examples of dedusting agents that may be included in a litter composition of the present invention include polytetrafluoroethylene (PTFE), oils, water, glycerols, glycols, polyvinyl alcohol, polyvinyl acetate, polymers, silicones, calcium chloride, foams, etc.


In one embodiment of the present invention in which calcium bentonite particles are used as a filler material, a 1.2% slurry of PTFE in water may be sprayed onto the calcium bentonite particles at the application rate of 40 lbs/ton of calcium bentonite (0.48 lbs. active PTFE per ton of calcium bentonite) using an apparatus such as shown in FIG. 1. The PTFE coated calcium bentonite is later blended with sodium bentonite.


A litter of the present invention may include various other additives such as odor control additives, odor masking agents, emulsifiers, fixatives, indicators, pesticides, insecticides, herbicides, attractants, repellants, sanitizers, emollients, humectants, dessicants, dyes, pigments, etc.


Examples of odor control additives that may be included in a litter composition of the present invention include biocides, urease inhibitors, iodine, chlorophyllin sodium copper salts, probiotics, enzymes, baking soda, carbon, zeolites, salts, aldehydes (benzaldehyde, heptaldehyde, undecalcatone, benzyl cinnamate, cinnamaldehyde, citral, vanillin, coumarin, undecanal, etc.).


Examples of odor masking agents that may be included in a litter composition of the present invention include fragrances such as citrus, floral (lavender), green, fruity, herbaceous, musk, oriental, woody, etc.


Examples of emulsifiers that may be included in a litter composition of the present invention include: polysorbate 20, polysorbate 80, block copolymers such as Lutrol® and non-ionic solubilizers such as Cremophor® RH.


Examples of fixatives that may be included in a litter composition of the present invention include polypropylene glycol, polypropylene glycol, polyethylene glycols, glycerin, sugar alcohols, etc.


Examples of indictors that may be included in a litter composition of the present invention include pH indicators, ammonia indicators, etc. that change color to indicate a change in pH, the presence of ammonia, etc.


Examples of attractants that may be included in a litter composition of the present invention include pheromones, catnip, etc.


Examples of repellants that may be included in a litter composition of the present invention include flea repellants, tick repellants, mite repellants, etc.


Examples of sanitizers that may be included in a litter composition of the present invention include alcohols, chlorhexidine gluconate, phenols, iodine, quaternary salts, ammonium compounds, hydrogen peroxide, urea hydrogen peroxide, sodium perchlorate, etc.


Examples of dessicants that may be included in a litter composition of the present invention include calcium sulfate, calcium chloride, silica gel, etc.


Having described the many embodiments of the present invention in detail, it will be apparent that modifications and variations are possible without departing from the scope of the invention defined in the appended claims. Furthermore, it should be appreciated that all examples in the present disclosure, while illustrating many embodiments of the invention, are provided as non-limiting examples and are, therefore, not to be taken as limiting the various aspects so illustrated.


EXAMPLES

Materials and Methods


Clump Strength Test—Standard Drop Method Test



FIGS. 4 and 5 show a dropping device 402 used to test clump strength using the Stand Drop Method Test. To measure clump strength of litter formulations an aluminum pan is placed under a dropping device. The aluminum pan may include one or more sheets of paper product, such as a paper towel, as a liner. A small depression, approximately 1 cm, is made in a flat pile of a litter to be tested. 20 ml of a wetting agent is poured over the test litter. After 30 seconds a clump is removed from the test litter and placed on a swinging platform of a dropping device with the bottom side of the clump down. Prior to the clump being placed on the swinging platform, the swinging platform is raised by a user to be horizontal relative to the inner horizontal surface of the pan. The user releases the swinging platform allowing the clump to free fall into an aluminum pan placed exactly 12 inches (30.5 cm) below. Next, the clump is visually examined for breakage and assigned a rating on a scale from 1 to 3: 1: clump intact, no breakage; 2: slight breakage (clumps breaks into 2 pieces); and 3: moderate breakage (clump breaks into more than 2 pieces), as shown in FIG. 6. The test is repeated on 2 more clumps and the average rating of all 3 clumps is reported. In the Examples 3-49 below, synthetic urine was used as a wetting agent. The particular synthetic urine composition used in Drop Method Tests of Examples 3-49 is shown below in Table A:












TABLE A







Component
% by weight



















Water
89.84



Urea
5.44



Sodium chloride
3.00



Sodium phosphate
0.78



Ammonium nitrate
0.50



Sodium bisulfate
0.44



Total
100.00










Dropping device 402 includes a vertical back 412 mounted on two legs 414 and 416 that stand on a table surface 418. A swinging platform 422 is mounted on a vertical back 412 by means of a spring-loaded hinge 424 that is attached to swinging platform 422 and a base 426 by mounting plates 428 and 430. Base 426 is mounted on vertical back 412. An aluminum pan 432 is located on table surface 418 below swinging platform 422. FIG. 4 shows swinging platform 422 in a down position. FIG. 2 shows swinging platform 422 in an up position. Swinging platform 422 is maintained in the up position by a user holding swinging platform 422 in the up position.



FIG. 5 shows a clump 442 having a bottom side 444 resting on swinging platform 422 at a middle point 452 (shown in FIG. 4) of swinging platform 422 prior to dropping. When swinging platform 422 is released by a user, swinging platform 422 swings down as shown by dashed arrow 454 until swinging platform 422 rests against vertical back 412 as shown by shadow lines 456. When swinging platform 422 is released, clump 442 drops vertically as shown by dashed arrow 458 into aluminum pan 432. A dropped clump 462 drops a distance, shown by double-headed arrow 464, from a top surface 466 of swinging platform 422 to an inner horizontal surface 468 of pan 432, which is 12 inches (30.5 cm). Swinging platform 422 has a length, shown by double-headed arrow 472, of 7.5 (19.1 cm) inches and a width, shown by double-headed arrow 474, of 4.5 inches (11.4 cm).


Clumps are evaluated using the scale shown in FIG. 6. An intact clump, shown by arrow 612, is given a rating of 1. A clump that breaks into only 2 pieces, shown by arrow 614, is given a rating of 2. A clump that breaks into 3 or more pieces, shown by arrow 616, is given a rating of 3.


Clump Strength Test—Extreme Drop Method Test



FIGS. 7 and 8 show a dropping device 702 used to test clump strength using the Extreme Drop Method Test. To measure clump strength of litter formulations an aluminum pan is placed under a dropping device. A small depression, approximately 1 cm is made in a flat pile of a litter to be tested. 20 ml of synthetic urine is poured over the test litter. After 30 seconds a clump is carefully removed from the test litter and placed on a swinging platform of a dropping device with the bottom side of the clump down. Prior to the clump being placed on the swinging platform, the swinging platform is raised by a user to be horizontal relative to the inner horizontal surface of the pan. The user releases swinging platform allowing the clump to free-fall into an aluminum pan placed exactly 47 inches (119.4 cm) below. Next, the clump is visually examined for breakage and assigned a rating on a scale from 1 to 3: 1: clump intact, no breakage; 2: slight breakage (clumps breaks into 2 pieces); and 3: moderate breakage (clump breaks into more than 2 pieces). The test is repeated on 2 more clumps and the average rating of all 3 clumps is reported.


Dropping device 702 including a vertical back 712 mounted on two legs 714 and 716 that stand on a table surface 718. A swinging platform 722 is mounted on vertical back 712 by means of a spring-loaded hinge 724 that is attached swinging platform 722 and a base 726 by mounting plates 728 and 730. Base 726 is mounted on vertical back 712. An aluminum pan 732 is located on table surface 718 below swinging platform 722. FIG. 7 shows swinging platform 722 in a down position. FIG. 8 shows swinging platform 722 in an up position. Swinging platform 722 is maintained in the up position by a user holding swinging platform 722 in the up position.



FIG. 8 shows a clump 742 having a bottom side 744 resting on swinging platform 722 at a middle point 752 (shown in FIG. 7) of swinging platform 722 prior to dropping. When swinging platform 722 is released by a user, swinging platform 722 swings down as shown by dashed arrow 754 until swinging platform 722 rests against vertical back 712 as shown by shadow lines 756. When swinging platform 722 is released, clump 742 drops vertically as shown by dashed arrow 758 into aluminum pan 732. A dropped clump 762 drops a distance, shown by double-headed arrow 764, from a top surface 766 of swinging platform 722 to an inner horizontal surface 768 of pan 732 is 47 inches (119.4 cm). Swinging platform has a length, shown by double-headed arrow 772, of 7.5 (19.1 cm) inches and a width, shown by double-headed arrow 774, of 4.5 inches (11.4 cm).


Clumps are evaluated using the scale shown in FIG. 6. An intact clump, shown by arrow 612, is given a rating of 1. A clump breaks into only 2 pieces, shown by arrow 614, is given a rating of 2. A clump that breaks into 3 or more pieces, shown by arrow 616, is given a rating of 3.


Bulk Density—Loose-Fill (O'Haus) Method


The Bulk Density—Loose-Fill (O'Haus) Method is a standard test used to determine the density (in lbs/ft3, or kg/m3) of a granulated or powdered substance in its loose state. In this method a tared dry pint cup is filled to overflowing with a sample of a granulated or powdered substance or mixture. The sample is leveled. The weight of the sample is measured and the bulk density calculated in pounds per cubic foot or kilograms per cubic meter. Additional information about this testing method is provided in ASTM Standard Method E 727, the entire contents and disclosures of which are incorporated herein by reference.


Apparatus and Reagents

    • 1. Filling Hopper, O'Haus Model 150 or similar equipment
    • 2. Cup, standard dry pint
    • 3. Balance, accurate to ±0.1 gram
    • 4. Straightedge ruler or knife spatula
    • 5. Sample splitter


Procedure (Operator time is approximately 10 minutes):

    • 1. Weigh the standard pint cup to the nearest 0.1 gram and record (W1).
    • 2. Select 400 grams of material, in accordance with a riffle method.
    • 3. Close the slide gate on the bottom of the O'Haus filling hopper and pour the 400 grams of material into the hopper.
    • 4. Position the dry pint cup below the gate so the cup is centered and two inches below the gate.
    • 5. Open the gate quickly and let the sample fill the cup and overflow. Do not vibrate the cup or close the gate before all of the sample flows out of the hopper. (These test methods yield comparative data.)
    • 6. Using a gentle sawing motion, level the material in the cup with a straightedge ruler or knife spatula.
    • 7. Weigh the cup plus material to the nearest 0.1 gram (W2).


Calculations:

    • 1. Weight of standard pint cup, in grams (W1).
    • 2. Weight of cup plus sample, in grams (W2).
    • 3. Bulk density, in pounds/cubic foot (lb/ft3) D=(W2−W1)×0.113 (The value 0.113 is a conversion factor for converting from gm/pint=lb/ft3)
    • 4. Bulk density, in kg/cubic meter (kg/m3) D=(W2−W1)×1.81 (The value 1.81 is a conversion factor for converting from gm/pint=kg/m3)


      Odor Control—Magic Cat Box Method


Magic Cat Box testing provides an evaluation of a cat litter's ammonia control efficacy over time under stressful conditions. The test can be used to compare competitive products and to evaluate new fragrance/biocide systems. This test involves mixing feces-inoculated synthetic cat urine with test material, placing in capped, ventilated jars and testing periodically for ammonia formation using ammonia detection tubes.


Apparatus and Reagents:

    • 1. High shear blender
    • 2. 16 oz wide-mouth plastic jars
    • 3. Lids (fitting 16-oz jars) with pre-drilled holes, ¼″ in diameter in the center and 1/16″ in diameter off to side
    • 4. Inoculated urine (see formula and procedure below)
    • 5. Flow meter
    • 6. Vacuum rated tubing
    • 7. Rubber washers
    • 8. RAE ammonia detection tubes (25-500 ppm)
    • 9. Laboratory balance


Procedure:

    • 1. Prepare feces/synthetic urine slurry by combining the following ingredients in Table B below in a blender at high speed for one minute (or until, visually, it seems the feces is well dispersed):












TABLE B







Component
% by weight



















Water
91.43



Cat feces
1.00



Urea
5.22



Ammonium phosphate dibasic
0.70



Sodium bisulfate
0.45



Ammonia
0.33



Potassium chloride
0.32



Sodium chloride
0.27



Creatinine
0.18



Magnesium chloride
0.06



Creatine
0.03



Calcium chloride
0.02



Total
100.00












    • 2. Transfer 100 g of the feces/synthetic urine slurry into each of the sample jars (three jars per set of samples).

    • 3. Slowly pour in enough test material so the slurry gets entirely absorbed and the excess unsoiled litter particles are settled on the surface of inoculated litter.

    • 4. Allow the samples to sit undisturbed for five minutes and then remove the excess litter by inverting the jars over the trash can and gently tapping off the excess litter particles.

    • 5. Cover each jar with its lid.

    • 6. Evaluate the samples for ammonia every other day (or as needed), starting on day 2.

    • 7. Perform evaluation by first adjusting the vacuum flow to 310 cc/min. using flow meter.

    • 8. Place rubber washer ring on RAE detection tube 0.75″ from the tip.

    • 9. Snip glass ends off tube and place vacuum hose on tube (flow arrows on tube pointing toward vacuum hose).

    • 10. Insert RAE tube into the hole in the center of the lid up to the rubber washer. Draw sample air into tube for one minute and record ammonia level.

    • 11. Discontinue testing samples when ammonia is detected at the 100 ppm level (failure).

    • 12. Record day of failure.

    • 13. After all three samples per each set have failed, record average day to failure for sample set.





Example 1

A litter is produced using the manufacturing process shown in FIG. 1. This litter has the composition shown in Table 1 below:













TABLE 1









Application Rate



Ingredient
% (w/w)
(lbs/ton)




















Sodium bentonite
64.4
1300



Calcium bentonite
34.7
700



Fragrance slurry
0.3
6



PTFE slurry
0.7
14



Totals
100.0
2020










The fragrance slurry (coating) is applied only to the sodium bentonite. The fragrance slurry has a composition shown in Table 2 below:













TABLE 2









Amount



Ingredient
% (w/w)
(lbs/ton)




















Water
68.8
1376



Emulsifier
10.0
200



Fragrance
16.9
338



Odor control additive
3.4
68



Colorant
0.9
18



Totals
100.0
2000











The polytetrafluoroethylene (PTFE) slurry (coating) is applied only to the calcium bentonite. The PTFE slurry has a composition shown in Table 3 below:











TABLE 3







Application Rate


Ingredient
% (w/w)
(lbs/ton)

















Water
98.0
1960


60% PTFE suspension in water
2.0
40


Totals
100.0
2000










Based on information in Table 3, the slurry is 1.2% PTFE (w/w). Based on the information in Tables 1 and 3, PTFE makes up 0.0084% (w/w) of the litter composition.


Example 2

A fragrance-free litter is produced using the manufacturing process shown in FIG. 2. This litter has the composition shown in Table 4 below:













TABLE 4









Application Rate



Ingredient
% (w/w)
(lbs/ton)




















Sodium bentonite
64.5
1300



Calcium bentonite
34.8
700



PTFE slurry
0.7
14



Totals:
100.0
2014










Examples 3-49

In Examples 3-49 below, the following terms have the following meanings:

    • % w/w=percentage by weight of the total mixture
    • PC/lb=particle count per lb of product
    • PC Dist.=particle count distribution in product as a percentage of the total product
    • Ext. SA=external surface area (ft2/lb of product)
    • Ext. SA Dist.=external surface area distribution in product as a percentage of the total product


In Examples 3-49 below, tests are conducted on blends of a swelling clay and a non-swelling clay, a swelling clay alone, blends of a swelling clay with paper particles, a blend of a swelling clay with wood fiber particles and blends of a swelling clay with barley grains. The swelling clay used is sodium bentonite from Wyoming from the company Wyo-Ben. The non-swelling clay used is Oil-Dri's Blue Mountain RVM clay (calcium bentonite). Each experimental blend of sodium bentonite and calcium bentonite clay is prepared by weighing out each component into a clean, plastic cat litter bin and blending by hand until uniform. Immediately after blending, about 1,000 grams of each blend is transferred to an appropriately sized plastic container. Next, 20 ml of room temperature tap water is drawn using a transfer pipette and poured over the blend to form a clump. A total of three clumps are formed in each container. The clumps are allowed to sit for 30 seconds and one hour prior to testing. In some cases the clumps are prepared 12, 24 and 36 hours prior to testing. The clump strength is tested using the Standard Drop Method Test. The aluminum pan is lined with a paper towel. The clumps are each tested by placing a clump on the spring loaded hinged platform of the dropping device and releasing the platform to allow the clump to fall into the aluminum pan lined with the paper towel. Each clump was dropped from the height of 12 inches. The clumps are later evaluated visually and rated from 1 to 3 based on the scale shown in FIG. 6. Each blend tested consists of various particle sizes of sodium bentonite and calcium bentonite clay combined at different ratios based on weight. Multiple particle sizes of raw materials are either provided by a supplier or screened using a Sweeco vibrating particle separator with appropriate screens. The particle size distribution of each raw material is confirmed by using a Tyler RoTap mechanical sieve shaker with sieves ranging in size from 6 to 100 U.S. mesh. A solid material used in a mixture of the present invention may be ground to form smaller particles.


After completion of the particle size analysis, an external surface area of each particle cut is calculated based on an average mesh size of each particle cut, according to an equation: 4πr2. The external surface area calculation is based on a simplifying assumption that each particle is a perfect sphere. The particle count per unit weight of material is calculated according to the ASTM Standard Test Method E 1520-99. The multipliers for 4/6, 6/8, 8/10, 6/10 and <100 mesh particles are extrapolated from a power trendline with the R2=0.9923 for the plot of the U.S. mesh size versus ASTM multiplier. The particle count is also based on a simplified assumption that all particles are spherical; see FIG. 9.


Next, a total external surface area of each particle cut was calculated by multiplication of the external surface area value by the number of particles in each cut. Following the surface area calculation, a cumulative external surface of each raw material is calculated per pound of material by summation of the external surface area values of each particle size cut. Finally, a ratio of a total external surface area of sodium bentonite and Blue Mountain RVM (calcium bentonite) clay per pound of blended material is calculated. After completion of all experiments, the percentage of external surface area as sodium bentonite per pound of product is plotted against the clump strength results for 30 second and 1 hour clumps, as shown in FIG. 10.


A similar plot was compiled for the percentage of total particle count as sodium bentonite per pound of product versus the clump strength results for 30 second and 1 hour clumps, as shown in FIG. 11.


Example 3

Blend #1: 65% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 60.15 lb/ft3, external surface area 27.39 ft2/lb), 35% calcium bentonite (BL-RVM, bulk density 41.5 lb/ft3, external surface area 23.47 ft2/lb). Information about the sodium bentonite of Blend #1 is provided in Table 1202 of FIG. 12. Information about the calcium bentonite of Blend #1 is provided in Table 1302 of FIG. 13. The average particle size of the sodium bentonite is 484 μm. The average particle size of the calcium bentonite is 905 μm.


Information about Blend #1 is provided in Table 5 below:














TABLE 5








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
8,095,362
84
17.80
68


Calcium bentonite
35.00
1,487,906
16
8.21
32


Totals
100.00
9,583,268
100
26.02
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 6 below.









TABLE 6







Clump Strength













30 sec.
1 hr.
12 hrs.
24 hrs.
36 hrs.


















Test 1
1
1
1
1
1



Test 2
1
1
2
1
1



Test 3
2
1
1
2
2



Average
1.3
1.0
1.3
1.3
1.3










Example 4

Blend #2: 65% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 35% calcium bentonite (BL-RVM, bulk density 37.1 lb/ft3, external surface area 38.44 ft2/lb). Information about the sodium bentonite of Blend #2 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #2 is provided in Table 1502 of FIG. 15. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 949 μm.


Information about Blend #2 is provided in Table 7 below:














TABLE 7








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
1,236,816
26
11.36
46


Calcium bentonite
35.00
3,575,941
74
13.45
54


Totals
100.00
4,812,757
100
24.82
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 8 below.









TABLE 8







Clump Strength













30 sec.
1 hr.
12 hrs.
24 hrs.
36 hrs.


















Test 1
3
2
1
1
1



Test 2
3
1
2
1
1



Test 3
3
1
1
1
1



Average
1.3
1.3
1.3
1.0
1.0










Example 5

Blend #3: 65% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 35% calcium bentonite (BL-RVM, bulk density 41.1 lb/ft3, external surface area 15.63 ft2/lb). Information about the sodium bentonite of Blend #3 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #3 is provided in Table 1602 of FIG. 16. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 1995 μm.


Information about Blend #3 is provided in Table 9 below:














TABLE 9








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
1,236,816
39
11.36
68


Calcium bentonite
35.00
1,962,285
61
5.47
32


Totals
100.00
3,199,102
100
16.83
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 10 below.









TABLE 10







Clump Strength













30 sec.
1 hr.
12 hrs.
24 hrs.
36 hrs.


















Test 1
1
1
1
1
1



Test 2
1
1
1
1
1



Test 3
1
1
1
1
1



Average
1.0
1.0
1.0
1.0
1.0










Example 6

Blend #4: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 60.15 lb/ft3, external surface area 27.39 ft2/lb), 50% calcium bentonite (BL-RVM, bulk density 41.5 lb/ft3, external surface area 23.47 ft2/lb). Information about the sodium bentonite of Blend #4 is provided in Table 1202 of FIG. 12. Information about the calcium bentonite of Blend #4 is provided in Table 1302 of FIG. 13. The average particle size of the sodium bentonite is 484 μm. The average particle size of the calcium bentonite is 905 μm.


Information about Blend #4 is provided in Table 11 below:














TABLE 11








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
6,227,201
75
13.70
54


Calcium bentonite
50.00
2,125,580
25
11.74
46


Totals
100.00
8,352,781
100
25.43
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 12 below.









TABLE 12







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 7

Blend #5: 65% sodium bentonite (BPO sodium bentonite, bulk density 64.33 lb/ft3, external surface area 15.46 ft2/lb), 35% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #5 is provided in Table 1702 of FIG. 17. Information about the calcium bentonite of Blend #5 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 806 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #5 is provided in Table 13 below:














TABLE 13








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
2,263,767
40
10.05
45


Calcium bentonite
35.00
3,422,605
60
12.27
55


Totals
100.00
5,686,371
100
22.33
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 14 below.









TABLE 14







Clump Strength










30 sec.
1 hr.















Test 1
2
2



Test 2
2
1



Test 3
2
1



Average
2.0
1.3










Example 8

Blend #6: 70% sodium bentonite (BPM sodium bentonite, bulk density 64.33 lb/ft3, external surface area 15.46 ft2/lb), 30% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #6 is provided in Table 1702 of FIG. 17. Information about the calcium bentonite of Blend #6 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 806 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #6 is provided in Table 15 below:














TABLE 15








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
70.00
2,437,903
45
10.82
51


Calcium bentonite
30.00
2,933,661
55
10.52
49


Totals
100.00
5,371,564
100
21.35
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 16 below.









TABLE 16







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 9

Blend #7: 50% sodium bentonite (Wyo-Ben Exp. sodium bentonite, bulk density 62.49 lb/ft3, external surface area 18.75 ft2/lb), 50% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #7 is provided in Table 1902 of FIG. 19. Information about the calcium bentonite of Blend #7 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 650 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #7 is provided in Table 17 below:














TABLE 17








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
1,983,882
29
9.38
35


Calcium bentonite
50.00
4,889,435
71
17.53
65


Totals
100.00
6,873,317
100
26.91
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 18 below.









TABLE 18







Clump Strength










30 sec.
1 hr.















Test 1
3
3



Test 2
3
2



Test 3
3
2



Average
3.0
2.3










Example 10

Blend #8: 60% sodium bentonite (Wyo-Ben Exp. sodium bentonite, bulk density 62.49 lb/ft3, external surface area 18.75 ft2/lb), 40% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #8 is provided in Table 1902 of FIG. 19. Information about the calcium bentonite of Blend #8 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 650 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #8 is provided in Table 19 below:














TABLE 19








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium
60.00
2.380,658
38
11.25
45


bentonite


Calcium
40.00
3,911,548
62
14.03
55


bentonite





Totals
100.00
6,292,207
100
25.28
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 20 below.









TABLE 20







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
3
2



Test 3
3
2



Average
2.3
1.7










Example 11

Blend #9: 70% sodium bentonite (Wyo-Ben Exp. sodium bentonite, bulk density 62.49 lb/ft3, external surface area 18.75 ft2/lb), 30% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #9 is provided in Table 1902 of FIG. 19. Information about the calcium bentonite of Blend #9 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 650 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #9 is provided in Table 21 below:














TABLE 21








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
70.00
2,777,435
49
13.13
56


Calcium bentonite
30.00
2,933,661
51
10.52
44


Totals
100.00
5,711,096
100
23.65
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 22 below.









TABLE 22







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 12

Blend #10: 80% sodium bentonite (Wyo-Ben Exp. sodium bentonite, bulk density 62.49 lb/ft3, external surface area 18.75 ft2/lb), 20% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #10 is provided in Table 1902 of FIG. 19. Information about the calcium bentonite of Blend #10 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 650 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #10 is provided in Table 23 below:














TABLE 23








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
80.00
3,174,211
62
15.00
68


Calcium bentonite
20.00
1,955,774
38
7.01
32


Totals
100.00
5,129,985
100
22.01
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 24 below.









TABLE 24







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 13

Blend #11: 65% sodium bentonite (Wyo-Ben Exp. sodium bentonite, bulk density 62.49 lb/ft3, external surface area 18.75 ft2/lb), 35% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #11 is provided in Table 1902 of FIG. 19. Information about the calcium bentonite of Blend #11 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 650 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #11 is provided in Table 25 below:














TABLE 25








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
2,579,047
43
12.19
50


Calcium bentonite
35.00
3,422,605
57
12.27
50


Totals
100.00
6,001,651
100
24.46
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 26 below.









TABLE 26







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 14

Blend #12: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.2 lb/ft3, external surface area 17.13 ft2/lb), 50% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #12 is provided in Table 2002 of FIG. 20. Information about the calcium bentonite of Blend #12 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 799 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #12 is provided in Table 27 below:














TABLE 27








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
2,068,587
30
8.56
33


Calcium bentonite
50.00
4,889,435
70
17.53
67


Totals
100.00
6,958,022
100
26.10
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 28 below.









TABLE 28







Clump Strength










30 sec.
1 hr.















Test 1
3
2



Test 2
2
2



Test 3
3
2



Average
2.7
2.0










Example 15

Blend #13: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.2 lb/ft3, external surface area 17.13 ft2/lb), 40% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #13 is provided in Table 2002 of FIG. 20. Information about the calcium bentonite of Blend #13 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 799 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #13 is provided in Table 29 below:














TABLE 29








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
2,482,304
39
10.28
42


Calcium bentonite
40.00
3,911,548
61
14.03
58


Totals
100.00
6,393,853
100
24.31
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 30 below.









TABLE 30







Clump Strength










30 sec.
1 hr.















Test 1
2
2



Test 2
2
1



Test 3
1
1



Average
1.7
1.3










Example 16

Blend #14: 70% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.2 lb/ft3, external surface area 17.13 ft2/lb), 30% calcium bentonite (BL-RVM, bulk density 37.7 lb/ft3, external surface area 35.07 ft2/lb). Information about the sodium bentonite of Blend #14 is provided in Table 2002 of FIG. 20. Information about the calcium bentonite of Blend #14 is provided in Table 1802 of FIG. 18. The average particle size of the sodium bentonite is 799 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #14 is provided in Table 31 below:














TABLE 31








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
70.00
2,896,022
50
11.99
53


Calcium bentonite
30.00
2,933,661
50
10.52
47


Totals
100.00
5,829,683
100
22.51
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 32 below.









TABLE 32







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 17

Blend #15: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 40% calcium bentonite (BL-RVM, bulk density 41.9 lb/ft3, external surface area 31.60 ft2/lb). Information about the sodium bentonite of Blend #15 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #15 is provided in Table 2102 of FIG. 21. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #15 is provided in Table 33 below:














TABLE 33








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
1,141,676
21
10.49
45


Calcium bentonite
40.00
4,263,602
79
12.64
55


Totals
100.00
5,405,279
100
23.13
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 34 below.









TABLE 34







Clump Strength










30 sec.
1 hr.















Test 1
2
2



Test 2
2
2



Test 3
3
1



Average
2.3
1.7










Example 18

Blend #16: 65% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 35% calcium bentonite (BL-RVM, bulk density 41.9 lb/ft3, external surface area 31.60 ft2/lb). Information about the sodium bentonite of Blend #16 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #16 is provided in Table 2102 of FIG. 21. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 688 μm.


Information about Blend #16 is provided in Table 35 below:














TABLE 35








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
1,236,816
25
11.36
51


Calcium bentonite
35.00
3,730,652
75
11.06
49


Totals
100.00
4,967,468
100
22.42
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to water. No tests are conducted 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 36 below.









TABLE 36







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 19

Blend #17: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 50% calcium bentonite (BL-RVM, bulk density 37.1 lb/ft3, external surface area 24.04 ft2/lb). Information about the sodium bentonite of Blend #17 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #17 is provided in Table 1502 of FIG. 15. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 1117 μm.


Information about Blend #17 is provided in Table 37 below:














TABLE 37








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
951,397
58
8.74
42


Calcium bentonite
50.00
690,696
42
12.02
58


Totals
100.00
1,642,094
100
20.76
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 38 below.









TABLE 38







Clump Strength













30 sec.
1 hr.
12 hrs.
24 hrs.
36 hrs.


















Test 1
2
1
1
1
1



Test 2
3
1
1
1
1



Test 3
3
1
1
2
1



Average
2.7
1.0
1.0
1.3
1.0










Example 20

Blend #18: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 45% calcium bentonite (BL-RVM, bulk density 37.1 lb/ft3, external surface area 24.04 ft2/lb). Information about the sodium bentonite of Blend #18 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #18 is provided in Table 1502 of FIG. 15. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 1117 μm.


Information about Blend #18 is provided in Table 39 below:














TABLE 39








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
1,046,537
63
9.61
47


Calcium bentonite
45.00
621,627
37
10.82
53


Totals
100.00
1,668,164
100
20.43
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 40 below.









TABLE 40







Clump Strength













30 sec.
1 hr.
12 hrs.
24 hrs.
36 hrs.


















Test 1
1
1
1
1
1



Test 2
1
1
1
1
1



Test 3
1
1
1
1
1



Average
1.0
1.0
1.0
1.0
1.0










Example 21

Blend #19: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.48 ft2/lb), 40% calcium bentonite (BL-RVM, bulk density 37.1 lb/ft3, external surface area 24.04 ft2/lb). Information about the sodium bentonite of Blend #19 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #19 is provided in Table 1502 of FIG. 15. The average particle size of the sodium bentonite is 794 μm. The average particle size of the calcium bentonite is 1117 μm.


Information about Blend #19 is provided in Table 41 below:














TABLE 41








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
1,141,676
67
10.49
52


Calcium bentonite
40.00
552,557
33
9.62
48


Totals
100.00
1,694,234
100
20.11
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours, 24 hours and 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 42 below.









TABLE 42







Clump Strength













30 sec.
1 hr.
12 hrs.
24 hrs.
36 hrs.


















Test 1
1
1
1
1
1



Test 2
1
1
1
1
1



Test 3
1
1
1
1
1



Average
1.0
1.0
1.0
1.0
1.0










Example 22

Blend #20: 40% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.66 ft2/lb), 60% calcium bentonite (BL-RVM, bulk density 46.22 lb/ft3, external surface area 14.02 ft2/lb). Information about the sodium bentonite of Blend #20 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #20 is provided in Table 2202 of FIG. 22. The average particle size of the sodium bentonite is 778 μm. The average particle size of the calcium bentonite is 1960 μm.


Information about Blend #20 is provided in Table 43 below:














TABLE 43








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
40.00
2,524,423
49
7.06
46


Calcium bentonite
60.00
2,607,640
51
8.41
54


Totals
100.00
5,132,062
100
15.48
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours and 24 hours after exposure of the test litter to water. No tests are conducted 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 44 below.









TABLE 44







Clump Strength












30 sec.
1 hr.
12 hrs.
24 hrs.

















Test 1
1
1
3
1



Test 2
2
1
2
1



Test 3
2
1
1
1



Average
1.7
1.0
2.0
1.0










Example 23

Blend #21: 45% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.66 ft2/lb), 55% calcium bentonite (BL-RVM, bulk density 46.22 lb/ft3, external surface area 14.02 ft2/lb). Information about the sodium bentonite of Blend #21 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #21 is provided in Table 2202 of FIG. 22. The average particle size of the sodium bentonite is 778 μm. The average particle size of the calcium bentonite is 1960 μm.


Information about Blend #21 is provided in Table 45 below:














TABLE 45








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium
45.00
2,839,975
54
7.95
51


bentonite


Calcium
55.00
2.390,336
46
7.71
49


bentonite





Totals
100.00
5,230,312
100
15.66
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours and 24 hours after exposure of the test litter to water. No tests are conducted 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 46 below.









TABLE 46







Clump Strength












30 sec.
1 hr.
12 hrs.
24 hrs.

















Test 1
1
1
2
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.3
1.0










Example 24

Blend #22: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.4 lb/ft3, external surface area 17.66 ft2/lb), 50% calcium bentonite (BL-RVM, bulk density 46.22 lb/ft3, external surface area 14.02 ft2/lb). Information about the sodium bentonite of Blend #22 is provided in Table 1402 of FIG. 14. Information about the calcium bentonite of Blend #22 is provided in Table 2202 of FIG. 22. The average particle size of the sodium bentonite is 778 μm. The average particle size of the calcium bentonite is 1960 μm.


Information about Blend #22 is provided in Table 47 below:














TABLE 47








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
3,155,528
59
8.83
56


Calcium bentonite
50.00
2,173,033
41
7.01
44


Totals
100.00
5,328,561
100
15.84
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours and 24 hours after exposure of the test litter to water. No tests are conducted 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 48 below.









TABLE 48







Clump Strength












30 sec.
1 hr.
12 hrs.
24 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 25

Blend #23: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 64.86 lb/ft3, external surface area 16.33 ft2/lb), 45% calcium bentonite (BL-RVM, bulk density 39.75 lb/ft3, external surface area 22.80 ft2/lb). Information about the sodium bentonite of Blend #23 is provided in Table 2302 of FIG. 23. Information about the calcium bentonite of Blend #23 is provided in Table 2402 of FIG. 24. The average particle size of the sodium bentonite is 832 μm. The average particle size of the calcium bentonite is 1094 μm.


Information about Blend #23 is provided in Table 49 below:














TABLE 49








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
1,227,224
46
8.98
47


Calcium bentonite
45.00
1,424,663
54
10.26
53


Totals
100.00
2,651,887
100
19.24
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 12 hours and 24 hours after exposure of the test litter to water. No tests are conducted 36 hours after exposure of the test litter to water. The results of these tests are shown in Table 50 below.









TABLE 50







Clump Strength












30 sec.
1 hr.
12 hrs.
24 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 26

Blend #24: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 50% paper granules (paper granule Biodac, bulk density 46.5 lb/ft3, external surface area 18.17 ft2/lb). The final density of the blend is 55.90 lb/ft3. Information about the sodium bentonite of Blend #24 is provided in Table 2502 of FIG. 25. Information about the paper granules of Blend #24 is provided in Table 2602 of FIG. 26. The average particle size of the sodium bentonite is 927 μm. The average particle size of the paper granules is 1224 μm.


Information about Blend #24 is provided in Table 51 below:














TABLE 51








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
4,375,015
94
8.51
48


Paper granules
50.00
274,075
6
9.09
52


Totals
100.00
4,649,090
100
17.59
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 52 below.









TABLE 52







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
2
2
1
1



Test 3
2
2
2
3



Average
1.7
1.7
1.3
1.7










Example 27

Blend #25: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 45% paper granules (paper granule Biodac, bulk density 46.5 lb/ft3, external surface area 18.17 ft2/lb). The final density of the blend is 57.23 lb/ft3. Information about the sodium bentonite of Blend #25 is provided in Table 2502 of FIG. 25. Information about the paper granules of Blend #25 is provided in Table 2602 of FIG. 26. The average particle size of the sodium bentonite is 927 μm. The average particle size of the paper granules is 1224 μm.


Information about Blend #25 is provided in Table 53 below:














TABLE 53








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
4,812,516
95
9.36
53


Paper granules
45.00
246,668
5
8.18
47


Totals
100.00
5,059,184
100
17.53
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 54 below.









TABLE 54







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 28

Blend #26: 65% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 35% paper granules (paper granule Biodac, bulk density 46.5 lb/ft3, external surface area 18.17 ft2/lb). The final density of the blend is 57.25 lb/ft3. Information about the sodium bentonite of Blend #26 is provided in Table 2502 of FIG. 25. Information about the paper granules of Blend #26 is provided in Table 2602 of FIG. 26. The average particle size of the sodium bentonite is 927 μm. The average particle size of the paper granules is 1224 μm.


Information about Blend #26 is provided in Table 55 below:














TABLE 55








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
5,687,519
97
11.06
63


Paper granules
35.00
191,853
3
6.36
37


Totals
100.00
5,879,372
100
17.42
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 56 below.









TABLE 56







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 29

Blend #27: 70% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 30% paper granules (paper granule Biodac, bulk density 46.5 lb/ft3, external surface area 18.17 ft2/lb). The final density of the blend is 58.45 lb/ft3. Information about the sodium bentonite of Blend #27 is provided in Table 2502 of FIG. 25. Information about the paper granules of Blend #27 is provided in Table 2602 of FIG. 26. The average particle size of the sodium bentonite is 927 μm. The average particle size of the paper granules is 1224 μm.


Information about Blend #27 is provided in Table 57 below:














TABLE 57








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
70.00
6,125,021
97
11.91
69


Paper granules
30.00
164,445
3
5.45
31


Totals
100.00
6,289,466
100
17.36
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 58 below.









TABLE 58







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 30

Blend #28: 86% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 14% wood fiber particles (bulk density 7.5 lb/ft3, external surface area 102.56 ft2/lb). The final density of the blend is 41.13 lb/ft3. Information about the sodium bentonite of Blend #28 is provided in Table 2502 of FIG. 25. Information about the wood fiber of Blend #28 is provided in Table 2702 of FIG. 27. The average particle size of the sodium bentonite is 927 μm. The average particle size of the wood fiber particles is 1460 μm.


Information about Blend #28 is provided in Table 59 below:














TABLE 59








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
86.00
7,525,026
77
14.63
50


Wood fiber
14.00
2,264,048
23
14.36
50


Totals
100.00
9,789,074
100
28.99
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 60 below.









TABLE 60







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
2
1



Test 2
1
1
1
1



Test 3
2
1
3
1



Average
1.3
1.0
2.0
1.0










Example 31

Blend #29: 40% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 60% barley grains (bulk density 49.7 lb/ft3, external surface area 17.95 ft2/lb). The final density of the blend is 56.91 lb/ft3. Information about the sodium bentonite of Blend #29 is provided in Table 2502 of FIG. 25. Information about the barley grains of Blend #29 is provided in Table 2802 of FIG. 28. The average particle size of the sodium bentonite is 927 μm. The average particle size of the barley grains is 1321 μM.


Information about Blend #29 is provided in Table 61 below:














TABLE 61








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
40.00
3,500,012
72
6.80
39


Barley grains
60.00
1,363,828
28
10.77
61


Totals
100.00
4,863,840
100
17.57
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 62 below.









TABLE 62







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
2
1
1
1



Test 2
2
1
1
1



Test 3
1
1
1
1



Average
1.7
1.0
1.0
1.0










Example 32

Blend #30: 45% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 55% barley grains (bulk density 49.7 lb/ft3, external surface area 17.95 ft2/lb). The final density of the blend is 58.13 lb/ft3. Information about the sodium bentonite of Blend #30 is provided in Table 2502 of FIG. 25. Information about the barley grains of Blend #30 is provided in Table 2804 of FIG. 28. The average particle size of the sodium bentonite is 927 μm. The average particle size of the barley grains is 1321 μm.


Information about Blend #30 is provided in Table 63 below:














TABLE 63








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
45.00
3,937,513
76
7.65
44


Barley grains
55.00
1,250,175
24
9.87
56


Totals
100.00
5,187,689
100
17.53
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 64 below.









TABLE 64







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 33

Blend #31: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 50% barley grains (bulk density 49.7 lb/ft3, external surface area 17.95 ft2/lb). The final density of the blend is 58.66 lb/ft3. Information about the sodium bentonite of Blend #31 is provided in Table 2502 of FIG. 25. Information about the barley grains of Blend #31 is provided in Table 2802 of FIG. 28. The average particle size of the sodium bentonite is 927 μm. The average particle size of the barley grains is 1321 μM.


Information about Blend #31 is provided in Table 65 below:














TABLE 65








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
4,375.015
79
8.51
49


Barley grains
50.00
1,136,523
21
8.97
51


Totals
100.00
5,511,538
100
17.48
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 66 below.









TABLE 66







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
2
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.3
1.0
1.0
1.0










Example 34

Blend #32: 55% sodium bentonite (engineered light weight sodium bentonite, bulk density 49.66 lb/ft3, external surface area 21.00 ft2/lb), 45% calcium bentonite (BL-RVM, bulk density 41.1 lb/ft3, external surface area 22.06 ft2/lb). The final density of the blend is 45.40 lb/ft3. Information about the sodium bentonite of Blend #32 is provided in Table 2902 of FIG. 29. Information about the calcium bentonite of Blend #32 is provided in Table 1602 of FIG. 16. The average particle size of the sodium bentonite is 942 μm. The average particle size of the calcium bentonite is 1995 μm.


Information about Blend #32 is provided in Table 67 below:














TABLE 67








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
3,619,874
72
11.55
54


Calcium bentonite
45.00
1,410,439
28
9.93
46


Totals
100.00
5,030,313
100
21.48
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 68 below.









TABLE 68







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
2
1
1
1



Test 2
2
1
1
1



Test 3
2
1
1
1



Average
2.0
1.0
1.0
1.0










Example 35

A litter is prepared that is 100% sodium bentonite (bulk density 63.3 lb/ft3, total external surface area 17.01 ft2/lb). Information about the sodium bentonite litter is provided in Table 2502 of FIG. 25. The average particle size of the sodium bentonite is 927 μm.


Information about this litter is provided in Table 69 below:














TABLE 69








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.







Sodium bentonite
100.00
8,750,030
100
17.01
100


Total
100.00
8,750,030
100
17.01
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to water. The results of these tests are shown in Table 70 below.









TABLE 70







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 36

Blend #33: 45% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 55% calcium bentonite (BL-RVM, bulk density 42.1 lb/ft3, external surface area 21.40 ft2/lb). The final density of the blend is 52.03 lb/ft3. Information about the sodium bentonite of Blend #33 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #33 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #33 is provided in Table 71 below:














TABLE 71








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
45.00
860,164
47
7.93
40


Calcium bentonite
55.00
969,778
53
11.77
60


Totals
100.00
1,829,941
100
19.71
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 72 below.









TABLE 72







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
3
2
1
3



Test 2
2
3
1
1



Test 3
3
1
3
2



Average
2.7
2.0
1.7
2.0










Example 37

Blend #34: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 50% calcium bentonite (BL-RVM, bulk density 42.1 lb/ft3, external surface area 21.40 ft2/lb). The final density of the blend is 53.05 lb/ft3. Information about the sodium bentonite of Blend #34 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #34 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #34 is provided in Table 73 below:














TABLE 73








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
955,737
52
8.81
45


Calcium bentonite
50.00
881,616
48
10.70
55


Totals
100.00
1,837,353
100
19.52
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 74 below.









TABLE 74







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
2
1
2



Test 2
1
2
1
1



Test 3
2
1
2
3



Average
1.3
1.7
1.3
2.0










Example 38

Blend #35: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 45% calcium bentonite (BL-RVM, bulk density 42.1 lb/ft3, external surface area 21.40 ft2/lb). The final density of the blend is 54.13 lb/ft3. Information about the sodium bentonite of Blend #35 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #35 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #35 is provided in Table 75 below:














TABLE 75








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
1,051,311
57
9.70
50


Calcium bentonite
45.00
793,455
43
9.63
50


Totals
100.00
1,844,766
100
19.33
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 76 below.









TABLE 76







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
3



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.7










Example 39

Blend #36: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 40% calcium bentonite (BL-RVM, bulk density 42.1 lb/ft3, external surface area 21.40 ft2/lb). The final density of the blend is 54.21 lb/ft3. Information about the sodium bentonite of Blend #36 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #36 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size the calcium bentonite is 1096 μm.


Information about Blend #36 is provided in Table 77 below:














TABLE 77








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
1,146,885
62
10.58
55


Calcium bentonite
40.00
705,293
38
8.56
45


Totals
100.00
1,852,178
100
19.14
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 78 below.









TABLE 78







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.0
1.0
1.0










Example 40

Blend #37: 45% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 55% calcium bentonite (BL-RVM, bulk density 42.1 lb/ft3, external surface area 21.40 ft2/lb). The final density of the blend is 52.30 lb/ft3. Information about the sodium bentonite of Blend #37 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #37 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #37 is provided in Table 79 below:














TABLE 79








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
45.00
860,164
47
7.93
40


Calcium bentonite
55.00
969,778
53
11.77
60


Totals
100.00
1,829,941
100
19.71
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 80 below.









TABLE 80







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
3
2
1
3



Test 2
1
2
1
1



Test 3
2
2
1
1



Average
2.0
2.0
1.0
1.7










Example 41

Blend #38: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 50% PTFE-coated calcium bentonite (BL-RVM coated with 40 lbs of 1.2% PTFE solution per ton of clay, bulk density prior to coating 42.1 lb/ft3, external surface area prior to coating 21.40 ft2/lb). The final density of the blend is 53.13 lb/ft3. Information about the sodium bentonite of Blend #38 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #38 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #38 is provided in Table 81 below:














TABLE 81








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
955,737
52
8.81
45


PTFE-coated
50.00
881,616
48
10.70
55


calcium bentonite



Totals
100.00
1,837,353
100
19.52
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 82 below.









TABLE 82







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
2
1
2



Test 2
1
1
1
1



Test 3
2
3
2
3



Average
1.3
2.0
1.3
2.0










Example 42

Blend #39: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 45% PTFE-coated calcium bentonite (BL-RVM coated with 40 lbs of 1.2% PTFE solution per ton of clay, bulk density prior to coating 42.1 lb/ft3, external surface area prior to coating 21.40 ft2/lb). The final density of the blend is 54.27 lb/ft3. Information about the sodium bentonite of Blend #39 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #39 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #39 is provided in Table 83 below:














TABLE 83








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
1,051,311
57
9.70
50


PTFE-coated
45.00
793,455
43
9.63
50


calcium bentonite



Totals
100.00
1,844,766
100
19.33
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 84 below.









TABLE 84







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
1
1



Test 2
1
2
1
2



Test 3
1
3
1
1



Average
1.0
2.0
1.0
1.3










Example 43

Blend #40: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 65.74 lb/ft3, external surface area 17.63 ft2/lb), 40% PTFE-coated calcium bentonite (BL-RVM coated with 40 lbs of 1.2% PTFE solution per ton of clay, bulk density prior to coating 42.1 lb/ft3, external surface area prior to coating 21.40 ft2/lb). The final density of the blend is 54.50 lb/ft3. Information about the sodium bentonite of Blend #40 is provided in Table 3002 of FIG. 30. Information about the calcium bentonite of Blend #40 is provided in Table 3102 of FIG. 31. The average particle size of the sodium bentonite is 775 μm. The average particle size of the calcium bentonite is 1096 μm.


Information about Blend #40 is provided in Table 85 below:














TABLE 85








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
1,146,885
62
10.58
55


PTFE-coated
40.00
705,293
38
8.56
45


calcium bentonite



Totals
100.00
1,852,178
100
19.14
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 86 below.









TABLE 86







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
2
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.0
1.3
1.0
1.0










Example 44

Blend #41: 65% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 35% attapulgite (GA-RVM, bulk density 32.5 lb/ft3, external surface area 27.95 ft2/lb). Information about the sodium bentonite of Blend #41 is provided in Table 2502 of FIG. 25. Information about the attapulgite of Blend #41 is provided in Table 3202 of FIG. 32. The average particle size of the sodium bentonite is 927 μm. The average particle size of the attapulgite is 1099 μm.


Information about Blend #41 is provided in Table 87 below:














TABLE 87








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
65.00
5,687,519
90
11.06
53


Attapulgite
35.00
643,102
10
9.78
47


Totals
100.00
6,330,621
100
20.84
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 88 below.









TABLE 88







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
2
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.3
1.0
1.0
1.0










Example 45

Blend #42: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 40% attapulgite (GA-RVM, bulk density 32.5 lb/ft3, external surface area 27.95 ft2/lb). Information about the sodium bentonite of Blend #42 is provided in Table 2502 of FIG. 25. Information about the attapulgite of Blend #42 is provided in Table 3202 of FIG. 32. The average particle size of the sodium bentonite is 927 μm. The average particle size of the attapulgite is 1099 μm.


Information about Blend #42 is provided in Table 89 below:














TABLE 89








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
5,250,018
88
10.21
48


Attapulgite
40.00
734,973
12
11.18
52


Totals
100.00
5,984,991
100
21.39
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 90 below.









TABLE 90







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
2
1
1
1



Test 2
1
1
1
1



Test 3
1
1
1
1



Average
1.3
1.0
1.0
1.0










Example 46

Blend #43: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 45% attapulgite (GA-RVM, bulk density 32.5 lb/ft3, external surface area 27.95 ft2/lb). Information about the sodium bentonite of Blend #43 is provided in Table 2502 of FIG. 25. Information about the attapulgite of Blend #43 is provided in Table 3202 of FIG. 32. The average particle size of the sodium bentonite is 927 μm. The average particle size of the attapulgite is 1099 μm.


Information about Blend #43 is provided in Table 91 below:














TABLE 91








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
4,812,516
85
9.36
43


Attapulgite
45.00
826,845
15
12.58
57


Totals
100.00
5,639,362
100
21.93
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 92 below.









TABLE 92







Clump Strength












30 sec.
1 hr.
24 hrs.
72 hrs.

















Test 1
1
1
2
1



Test 2
3
1
1
1



Test 3
1
1
1
1



Average
1.7
1.0
1.3
1.0










Example 47

Blend #44: 60% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 40% Taft clay (TF-RVM, bulk density 40.0 lb/ft3, external surface area 24.22 ft2/lb). Information about the sodium bentonite of Blend #44 is provided in Table 2502 of FIG. 25. Information about the attapulgite of Blend #44 is provided in Table 3302 of FIG. 33. The average particle size of the sodium bentonite is 927 μm. The average particle size of the Taft clay is 1050 μm.


Information about Blend #44 is provided in Table 93 below:














TABLE 93








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
60.00
5,250,018
65
10.21
51


Taft clay
40.00
2,860,640
35
9.69
49


Totals
100.00
8,110,658
100
19.89
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 94 below.









TABLE 94







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0










Example 48

Blend #45: 55% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 45% Taft clay (TF-RVM, bulk density 40.0 lb/ft3, external surface area 24.22 ft2/lb). Information about the sodium bentonite of Blend #45 is provided in Table 2502 of FIG. 25. Information about the attapulgite of Blend #45 is provided in Table 3302 of FIG. 33. The average particle size of the sodium bentonite is 927 μm. The average particle size of the Taft clay is 1050 μm.


Information about Blend #45 is provided in Table 95 below:














TABLE 95








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
50.00
4,375,015
55
8.51
41


Taft clay
50.00
3,575,800
45
12.11
59


Totals
100.00
7,950,815
100
20.61
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 96 below.









TABLE 96







Clump Strength










30 sec.
1 hr.















Test 1
2
1



Test 2
2
1



Test 3
2
1



Average
2.0
1.0










Example 49

Blend #46: 50% sodium bentonite (Wyo-Ben sodium bentonite, bulk density 63.3 lb/ft3, external surface area 17.01 ft2/lb), 50% Taft clay (TF-RVM, bulk density 40.0 lb/ft3, external surface area 24.22 ft2/lb). Information about the sodium bentonite of Blend #46 is provided in Table 2502 of FIG. 25. Information about the attapulgite of Blend #46 is provided in Table 3302 of FIG. 33. The average particle size of the sodium bentonite is 927 μm. The average particle size of the Taft clay is 1050 μm.


Information about Blend #46 is provided in Table 97 below:














TABLE 97








PC
Ext.
Ext.


Component
% w/w
PC/lb
Dist.
SA
SA Dist.




















Sodium bentonite
55.00
4,812,516
60
9.36
46


Taft clay
45.00
3,218,220
40
10.90
54


Totals
100.00
8,030,737
100
20.25
100










Clump strength is tested for samples after using the Standard Drop Method Test described above. Tests are conducted 30 seconds and 1 hour after exposure of the test litter to synthetic urine. The results of these tests are shown in Table 98 below.









TABLE 98







Clump Strength










30 sec.
1 hr.















Test 1
1
1



Test 2
1
1



Test 3
1
1



Average
1.0
1.0











Results and Conclusions from Examples 3-49


Based on the results of Examples 3-25, 34 and 36-43, sodium bentonite/calcium bentonite clay blends with 47% or more of the total external surface area coming from sodium bentonite particles tested 1.0 (clumps intact) for clump strength at 30 seconds except for Blend #1 of Example 3 which tested 1.3 based on an average of 3 clumps. All of the blends with 47% or more of the total external surface area coming from sodium bentonite tested 1.0 for 1-hour clumps. The sodium bentonite/calcium bentonite blends have clumpability similar to the clumpability of the sodium bentonite alone (see Example 35 above).


Therefore, Examples 3-25 and 34-43 show that it is possible to form sodium bentonite/calcium bentonite blends having clumpability similar to the sodium bentonite wherein 50% or less, or even as little as 47%, of the total external surface area of all the particles in the blend are from sodium bentonite particles.


All remaining blends with 33% to 46% of the total external surface area coming from sodium bentonite tested between 1.7 and 3.0 (slight to moderate breakage) for 30-second clumps. and 1.0 to 2.3 (clump intact to slight breakage) for 1-hour clumps.


A direct relationship is found between clumping and percentage total external surface area of swelling clay in a swelling/non-swelling clay blend. A minimum of 47% of the total external surface area of all particles in a swelling/non-swelling clay blend needs to originate from the swelling clay in order for the product to form strong clumps at 30 seconds upon wetting. As the percentage total external surface area of swelling clay in a swelling/non-swelling clay blend increases, the clump strength also increases. The longer the clumps are allowed to sit prior to testing, the stronger they get.


Examples 36-43 show that sodium bentonite/calcium bentonite blends in which the calcium bentonite are coated with PTFE (Examples 41-43) have similar clumpability properties to sodium bentonite/calcium bentonite blends in which the calcium bentonite is uncoated (Examples 36-40).


Examples 26-33 show that sodium bentonite/paper granule blends (Examples 26-29), a sodium bentonite/wood fiber particle blend (Example 30) and sodium bentonite/barley grain blends (Examples 31-33) with 47% or more of the total external surface area coming from sodium bentonite particles have clumpability similar to the clumpability of the sodium bentonite alone (see Example 35 above).


Examples 44-46 show that sodium bentonite/attapulgite blends with 47% or more of the total external surface area coming from sodium bentonite particles have clumpability similar to the clumpability of the sodium bentonite alone (see Example 35 above).


Examples 47-49 show that sodium bentonite/Taft clay blends with 47% or more of the total external surface area coming from sodium bentonite particles have clumpability similar to the clumpability of the sodium bentonite alone (see Example 35 above).


Example 50

Ten litter mixtures are prepared having the following compositions:

    • Litter 1: 100% sodium bentonite/calcium bentonite blend.
    • Litter 2: 99.75% sodium bentonite/calcium bentonite blend, 0.25% xanthan gum (fine mesh). For this litter, fine mesh refers to a minimum of 70% of the particles passing through 200-mesh sieve. The clumping additive xanthan gum is added to the final blend.
    • Litter 3: 99.75% sodium bentonite/calcium bentonite blend, 0.25% sodium carboxymethyl cellulose (fine mesh). For this litter, “fine mesh” refers to a maximum of the 20% of the particles remaining on 200-mesh sieve. The clumping additive sodium carboxymethyl cellulose is added to the final blend.
    • Litter 4: 99.75% sodium bentonite/calcium bentonite blend, 0.25% guar gum (fine mesh). For this litter, “fine mesh” refers to a minimum of 90% of the particles passing through 270-mesh sieve. The clumping additive guar gum is added to the final blend.
    • Litter 5: 99.5% sodium bentonite/calcium bentonite blend, 0.5% guar gum (fine mesh). For this litter, “fine mesh” refers to a minimum of 90% of the particles passing through 270-mesh sieve. The clumping additive guar gum is added to the final blend.
    • Litter 6: 99.5% sodium bentonite/calcium bentonite blend, 0.5% guar gum (coarse mesh). For this litter, “coarse mesh” refers to a maximum of 20% of the particles passing through 200-mesh sieve. The clumping additive guar gum is added to the final blend.
    • Litter 7: 99.5% sodium bentonite/calcium bentonite blend, 0.5% sodium carboxymethyl cellulose (medium mesh). For this litter, “medium mesh” refers to 40% to 75% of the particles being retained on a 200-mesh sieve. The clumping additive sodium carboxymethyl cellulose is added to the final blend.
    • Litter 8: 99.5% sodium bentonite/calcium bentonite blend, 0.5% sodium carboxymethyl cellulose (coarse mesh). For this litter, “coarse mesh” refers to a minimum of 85% of the particles being retained on 200-mesh sieve. The clumping additive sodium carboxymethyl cellulose is added to the final blend.
    • Litter 9: 99.5% sodium bentonite/calcium bentonite blend, 0.5% psyllium 95%. Psyllium 95% is a psyllium husk powder that is 95% pure (medium mesh). For this litter, “medium mesh” refers to an average particle size of 40-mesh. The clumping additive psyllium is added to the final blend.
    • Litter 10: 99.5% sodium bentonite/calcium bentonite blend, 0.5% psyllium 95% (fine mesh). For this litter, “fine mesh” refers to an average particle size of 100-mesh. The clumping additive psyllium is added to the final blend.


In all of the above litters, the ratio of sodium bentonite to calcium bentonite in the sodium bentonite/calcium bentonite blend is 65% sodium bentonite to 35% calcium bentonite. In all of the above litters, the sodium bentonite is coated with a fragrance slurry coating having the composition shown in Table 2 of Example 1. In all of the above litters, the calcium bentonite is coated with a PTFE slurry coating having the composition shown in Table 3 of Example 1. The granulation size (fine, medium and coarse) for the clumping additives is defined by the suppliers of the clumping additive. Because the suppliers for the different clumping additives are different, the particle size specifications vary.


Table 99 below shows the results of a clump strength test with synthetic urine using the Standard Drop Method Test described above using the average of 3 drops for each clump strength value. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine.









TABLE 99







Clump Strength using Standard Drop Method Test














Litter
30 sec.
1 hr.
24 hrs.
72 hrs.
Average


















1
1.0
1.0
1.0
1.0
1.0



2
1.0
1.0
1.0
1.0
1.0



3
1.0
1.0
1.0
1.0
1.0



4
1.0
1.0
1.0
1.0
1.0



5
1.0
1.0
1.0
1.0
1.0



6
1.0
1.0
1.0
1.0
1.0



7
1.0
1.0
1.0
1.0
1.0



8
1.0
1.0
1.0
1.0
1.0



9
1.0
1.0
1.0
1.0
1.0



10
1.0
1.0
1.0
1.0
1.0










Table 100 below shows the results a clump strength test with synthetic urine using the Extreme Drop Method described above using the average of 3 drops for each clump strength value. Tests are conducted 30 seconds, 1 hour, 24 hours and 72 hours after exposure of the test litter to synthetic urine.









TABLE 100







Clump Strength using Extreme Drop Method Test














Litter
30 sec.
1 hr.
24 hrs.
72 hrs.
Average


















1
3.0
1.7
1.7
1.7
2.0



2
1.0
1.0
1.0
1.0
1.0



3
1.0
1.0
1.0
1.0
1.0



4
1.0
1.0
1.0
1.0
1.0



5
1.0
1.0
1.0
1.0
1.0



6
3.0
2.0
1.0
1.0
1.8



7
1.3
1.3
1.0
1.0
1.2



8
1.7
1.0
1.0
1.3
1.3



9
3.0
2.3
1.7
1.0
2.0



10
2.3
2.3
1.3
1.0
1.7










Example 51

Three litters are tested for odor control properties using the Magic Cat Box method described above. Litter A is an untreated sodium bentonite litter. Litter B is an untreated calcium bentonite litter. Litter C is an untreated 65/35 mixture of sodium bentonite and calcium bentonite (65% sodium bentonite, 35% calcium bentonite). The results of these tests are shown in Tables 101, 102 and 103 below and in plot 3402 of FIG. 34.









TABLE 101







Odor Control Litter A











Day
Sample 1
Sample 2
Sample 3
Average














0
0
0
0
0


1
10
10
5
8


2
10
10
5
8


3
10
10
5
8


7
50
30
65
48


8
60
40
80
60


10
90
70
130
97


11
130
140
160
143
















TABLE 102







Odor Control Litter B











Day
Sample 1
Sample 2
Sample 3
Average














0
0
0
0
0


1
0
0
0
0


2
0
0
0
0


3
0
0
0
0


7
35
50
25
37


8
180
160
80
140


10
270
220
130
207
















TABLE 103







Odor Control Litter C











Day
Sample 1
Sample 2
Sample 3
Average














0
0
0
0
0


1
0
0
0
0


2
0
0
0
0


3
0
0
0
0


7
25
25
25
25


8
25
25
25
25


10
60
60
50
57


11
90
90
70
83


14
220
210
210
213









In plot 3402, the squares are for Litter A (sodium bentonite, NaB), the circles are for Litter B (10/24 BL RVM clay, BL) and the triangles are for Litter C (65/35 blend, 65/35).


Example 52

Three litters are prepared and poured into boxes using the apparatus of FIG. 3. Each litter is 65% sodium bentonite and 35% calcium bentonite. Ten samples are taken from each litter and the density of each sample is determined using the Loose-Fill (O'Haus) Method described above.


Samples are taken from the top (sample 1) to the bottom (sample 2) of each box. Results of these density measurements are provided in Table 104 below.









TABLE 104







Density Measurements









Density, lbs/ft3












Sample #
Box #1
Box #2
Box #3
















1 (top)
55.6
56.5
56.4



2
56.2
56.3
55.9



3
56.3
57.3
57.3



4
56.9
57.5
56.4



5
56.9
57.2
56.7



6
57.1
58.3
58.2



7
57.2
58.3
57.8



8
57.1
58.5
57.8



9
55.9
57.7
57.0



10 (bottom)
55.0
55.5
55.0



Standard deviation
0.74
0.97
0.96



Average
56.41
57.31
56.84










Example 53

A litter composition comprising a sodium bentonite/calcium bentonite blend is formed using the apparatus of FIG. 1. The fragrance slurry of Example 1 is coated on the sodium bentonite and a PTFE slurry is coated on the calcium bentonite.


The PTFE slurry consists of 98.0% water and 2.0% of a 60% PTFE suspension in water. The PTFE slurry is applied to the calcium bentonite at rate of 40.0 lbs/ton of PTFE slurry/calcium bentonite to attain 14.0 lbs/ton of PTFE slurry/calcium bentonite in finished product.


While the present invention has been disclosed with references to certain embodiments, numerous modifications, alterations and changes to the described embodiments are possible without departing from the sphere and scope of the present invention, as defined in the appended claims. Accordingly, it is intended that the present invention not be limited to the described embodiments, but that it has the full scope defined by the language of the following claims, and equivalents thereof

Claims
  • 1. A litter comprising: 45% to 80% by weight of sodium bentonite, wherein the sodium bentonite comprises at least 47% of an external surface area of the litter, and20% to 55% by weight of a non-clumping filler material,wherein the litter has a bulk density less than about 58 lb/ft3, wherein the litter when exposed to a wetting agent forms at least one clump, and wherein each at least one clump is mechanically separable from unwetted litter for disposal.
  • 2. The litter of claim 1 wherein the litter has a bulk density less than about 47 lb/ft3.
  • 3. The litter of claim 1 wherein the litter has an average clump strength, 30 seconds after the at least one clump is formed, that is greater than or equal to 1.33 as determined by the testing of three clumps using the Standard Drop Method Test.
  • 4. The litter of claim 1 wherein the litter has an average clump strength, 1 hour after the at least one clump is formed, that is greater than or equal to 1.33 determined by the testing of three clumps using the Standard Drop Method Test.
  • 5. The litter of claim 1 wherein the litter has an average clump strength, 12 hours after the at least one clump is formed, that is greater than or equal to 1.33 determined by the testing of three clumps using the Standard Drop Method Test.
  • 6. The litter of claim 1 wherein the litter has an average clump strength, 12 hours after the at least one clump is formed, that is greater than or equal to 1.33 determined by the testing of three clumps using the Standard Drop Method Test.
  • 7. A litter comprising: 45% to 80% by weight of sodium bentonite, wherein sodium bentonite comprises at least 47% of an external surface area of the litter, and wherein the litter when exposed to a wetting agent forms at least one clump.
  • 8. The litter of claim 7 wherein the litter has a bulk density less than about 58 lb/ft3.
  • 9. The litter of claim 7 wherein the litter has a bulk density less than about 47 lb/ft3.
  • 10. The litter of claim 7 wherein each at least one clump is mechanically separable from unwetted litter for disposal.
  • 11. The litter of claim 7 further comprising 20% to 55% by weight of a non-clumping filler material.
  • 12. The litter of claim 7 further comprising a clumping agent.
  • 13. The litter of claim 10 wherein the at least one clump remains substantially intact after 30 seconds.
  • 14. The litter of claim 10 wherein the at least one clump remains substantially intact after 1 hour.
  • 15. The litter of claim 10 wherein the at least one clump remains substantially intact after 24 hours.
  • 16. The litter of claim 10 wherein the litter has a bulk density less than about 58 lb/ft3.
  • 17. The litter of claim 10 wherein the litter has a bulk density less than about 47 lb/ft3.
  • 18. The litter of claim 10 further comprising a clumping agent.
  • 19. The litter of claim 10 further comprising a fragrance.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No. 16/222,267, filed Dec. 17, 2018, now pending, which is a continuation of U.S. application Ser. No. 15/845,373, filed Dec. 18, 2017, now pending, which is a continuation of U.S. application Ser. No. 15/606,805 filed May 26, 2017, now U.S. Pat. No. 9,894,877, which is a continuation of U.S. application Ser. No. 15/492,566 filed Apr. 20, 2017, now abandoned, which is a continuation of U.S. application Ser. No. 15/260,660 filed Sep. 9, 2016, now abandoned, which is a continuation of U.S. application Ser. No. 15/162,296 filed May 23, 2016, now U.S. Pat. No. 9,439,393, which is a divisional of U.S. application Ser. No. 13/524,021 filed Jun. 15, 2012, now U.S. Pat. No. 9,345,227, which claims the benefit of priority to U.S. Provisional Patent Application No. 61/497,178, entitled “Cat Litter Product” filed Jun. 15, 2011. Reference is made to U.S. application Ser. No. 15/053,114 filed Feb. 25, 2016, now U.S. Pat. No. 9,408,368 and PCT/US12/42631 filed Jun. 15, 2012, which claim benefit of priority to U.S. application Ser. No. 13/524,021 filed Jun. 15, 2012, now U.S. Pat. No. 9,345,227. Reference is also made to co-pending application U.S. application Ser. No. 14/012,153 filed Aug. 28, 2013, now U.S. Pat. No. 9,185,878, which in turn claims benefit of priority to U.S. Provisional Patent Application No. 61/497,178 filed Jun. 15, 2011 and U.S. Provisional Patent Application No. 61/694,000, filed Aug. 28, 2012. The content of each of the aforementioned patent applications is incorporated herein by reference in their entirety.

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Related Publications (1)
Number Date Country
20200068845 A1 Mar 2020 US
Provisional Applications (1)
Number Date Country
61497178 Jun 2011 US
Divisions (1)
Number Date Country
Parent 13524021 Jun 2012 US
Child 15162296 US
Continuations (6)
Number Date Country
Parent 16222267 Dec 2018 US
Child 16679743 US
Parent 15845373 Dec 2017 US
Child 16222267 US
Parent 15606805 May 2017 US
Child 15845373 US
Parent 15492566 Apr 2017 US
Child 15606805 US
Parent 15260660 Jun 2016 US
Child 15492566 US
Parent 15162296 May 2016 US
Child 15260660 US