Claims
- 1. A catalyst composition comprising an intimate mixture of at least two metal oxides one of which is reducible to either a sub-oxide or substantially to the elemental metal state whereas the other is a refractory oxide which is substantially non-reducible, which mixture has been exposed to a reducing gas in sufficient quantity and at a temperature in the range of 550.degree. C. to 1000.degree. C. to cause a substantial inhibition or disruption of crystallite growth as evidenced by x-ray diffraction pattern analysis, concomitantly enhancing catalytic activity.
- 2. A catalyst composition according to claim 1 in which said reducible oxide is that of a metal or metals of the group consisting of thallium, tin, vanadium, antimony, bismuth, ruthenium, rhodium, palladium, platinum, iridium, osmium, silver, tungsten, cadmium, zinc, cerium, chromium, cobalt, copper, gadolinium, indium, iron, lead, manganese, molybdenum and nickel.
- 3. A catalyst composition according to claim 1 in which said refactory oxide is that of a metal or metals of the group consisting of aluminum, barium, beryllium, boron, calcium, gallium, silicon, titanium, hafnium, niobium, tantalum, uranium, chromium, indium, lanthanum, cerium and the remaining rare earths, magnesium, strontium, thorium, zinc and zirconium.
- 4. A catalyst composition according to claim 1 in which said reducible oxide consists of nickel oxide either alone or in intimate mixture with chromium oxide, plus at least one refractory oxide of the group consisting of magnesium, lanthanum, cerium, zirconium, calcium, thorium and aluminum.
- 5. A catalyst composition according to claim 1 in which said reducing gas is hydrogen.
- 6. A catalyst composition according to claim 1 in which said reducing gas is carbon monoxide, either alone or in mixture with hydrogen.
- 7. A catalyst composition according to claim 1 mounted on a refractory support.
- 8. A method for the manufacture of a catalyst composition comprising, in the following sequence:
- (a) co-precipitating a salt of a reducible metal having catalytic properties together with a salt of a metal capable of forming a refractory oxide,
- (b) calcining the co-precipitate of step (a) in an oxygen-containing atmosphere at a temperature above about 300.degree. C. for a period of time sufficient to produce a reducible metal oxide in mixture with a refractory metal oxide, and
- (c) heating the metal oxide mixture of step (b) in contact with a reducing gas at a temperature in the range of 550.degree. C. to 1000.degree. C. for a time sufficient to cause a substantial inhibition or disruption of crystallite growth as evidenced by X-ray diffraction pattern analysis concomitantly enhancing catalytic activity.
BACKGROUND OF THE INVENTION
This application is a continuation-in-part of Application Ser. No. 06/066,433, filed Aug. 14, 1979, now abandoned.
US Referenced Citations (6)
Foreign Referenced Citations (1)
Number |
Date |
Country |
1056685 |
Jan 1967 |
GBX |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
66433 |
Aug 1979 |
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