Claims
- 1. A conductive coating composition curable at temperatures lower than about 150.degree. C. comprising:
- (i) a blocked reactive component wherein said blocked reactive component is a blocked isocyanate or a blocked isothiocyanate;
- (ii) a functional compound reactive with said blocked reactive component, said functional compound containing active hydrogen;
- (iii) a triorganotin catalyst R.sub.3 SnA for promoting the reaction of said reactive component with said functional compound wherein each R is a hydrocarbyl group bonded directly to tin through carbon and may be the same or different, branched or unbranched, saturated or unsaturated, substituted or unsubstituted comprising C.sub.1 to about C.sub.18 alkyl, C.sub.6 to about C.sub.20 aryl, cycloalkyl, alkaryl, vinyl or allyl, A is --S--SnR.sub.3, --O--SnR.sub.2 X, --O--SnRX.sub.2, --SR, ##STR5## or X, in which R is as defined above A is --O--SnR.sub.3 or OH only when R is aryl, or, R is a divalent hydrocarbyl group which may be saturated or unsaturated, branched or unbranched, substituted or unsubstituted, aryl C.sub.6 to about C.sub.20, alkyne of about C.sub.4 to C.sub.20, X is an anion comprising chlorine, bromine, iodine, fluorine, carboxyl, alkoxy, hydride, sulfonate, toluene sulfonate, C.sub.1 -C.sub.5 alkyl sulfonate, phosphate, silicate, carbonate or isocyanate, with the proviso that when R is alkyl, X is not chlorine, bromine, iodine, or fluorine, and when
- A is ##STR6## the catalyst is a polymer of the formula: ##STR7## where each of R.sup.1 R.sup.2 R.sup.3 are equal to R is as defined above, R" is hydrogen, methyl or ethyl, a+b=5 to 1,000, and b.div.a=1 to about 20; and
- (iv) water.
- 2. The composition of claim 1 wherein said catalyst is:
- R.sup.1 R.sup.2 R.sup.3 Sn O.sub.2 C--X.sup.1 --CO.sub.2 --Sn--R.sup.4 R.sup.5 R.sup.6 wherein each R is a hydrocarbyl group bonded to tin through carbon and is taken from the same R groups as defined in claim 1, X.sup.1 is an alkyl group of C.sub.1 to about C.sub.18, alkenyl of C.sub.2 to about C.sub.18, or alkyne of about C.sub.4, cyclohexenyl; or
- R.sup.1 R.sup.2 R.sup.3 Sn X.sup.2 wherein each R is a hydrocarbyl group bonded to tin through carbon and is taken from the same R groups as defined in claim 1, X.sup.2 is chloro, bromo, iodo, fluoro, C.sub.1 to about C.sub.5 alkoxy, carbonate, phosphate, phosphinate, isocyanate, sulfonate, a carboxyl group containing a C.sub.1 to C.sub.20 carbon chain, whether substituted or unsubstituted, siloxinate, or ethoxylate, with the proviso that when R is alkyl, X.sup.2 is not chlorine, bromine, iodine or fluorine.
- 3. The composition of claim 1 wherein said catalyst is:
- (trioctyltin) adipate,
- bis (tributyltin) maleate,
- bis (trioctyltin) cyclohexene dicarboxylate,
- trioctyltinoctanoate,
- trioctyltincarbonate,
- trioctyltinphenate,
- trioctyltin-9, 10-dihydroxystearate,
- trioctyltin laurate, or
- trioctyltin acetate.
- 4. The composition of claim 3 wherein said catalyst is trioctyltin acetate.
- 5. A coating composition having a tin catalyst with improved environmental safety, for electrolytically coating a conductive substrate and curable at temperatures lower than about 150.degree. C. comprising:
- (i) a blocked reactive component wherein said blocked reactive component is a blocked isocyanate or a blocked isothiocyanate;
- (ii) a functional compound reactive with said blocked reactive component, said functional compound containing active hydrogen;
- (iii) a catalyst consisting essentially of a trialkyl tin catalyst in which said alkyl group has from 8 to 21 carbons, and wherein said catalyst is not a trialkyltin halide;
- (iv) water.
- 6. The composition of claim 5 wherein said alkyl group has eight carbons.
- 7. The composition of one of claims 1 and 2-6 wherein:
- (i) said blocked reactive component comprises a blocked polyisocyanate; and
- (ii) said functional compound reactive with said blocked reactive component comprises a polyfunctional compound containing active hydrogens.
- 8. The composition of claim 7 wherein said functional compound reactive with said blocked polyisocyanate comprises a polyfunctional compound containing active hydrogens wherein said active hydrogens comprise at least hydroxyl hydrogens of a primary amine epoxy adduct or a secondary amine epoxy adduct and said functional compound is solubilized with acid to provide cationic groups in said adduct.
- 9. A composition as in claims 1, 2, 3, or 5 wherein said catalyst is a liquid at about room temperature.
- 10. A composition as in claim 8 wherein said conductive coating composition is substantially free of solid pigments or fillers.
Parent Case Info
This is a continuation of application Ser. No. 08/465,327, filed Jun. 5, 1995 now abandoned, which is a divisional of 08/097,854, filed Jul. 28, 1993 now U.S. Pat. No. 5,718,817.
US Referenced Citations (9)
Foreign Referenced Citations (3)
Number |
Date |
Country |
1159633 |
Dec 1963 |
DEX |
947587 |
Jan 1964 |
GBX |
WO 9425534 |
Nov 1994 |
WOX |
Non-Patent Literature Citations (1)
Entry |
Sep. 28, 1995 Search Report from the European Patent Office in corresponding application EPA 94925683.8-2115 and Annex thereto. |
Divisions (1)
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Number |
Date |
Country |
Parent |
97854 |
Jul 1993 |
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Continuations (1)
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Number |
Date |
Country |
Parent |
465327 |
Jun 1995 |
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