Claims
- 1. A catalyst composition for use in converting synthesis gas into oxygenate-containing mixtures, which comprises a zeolite which is virtually free of acid sites and which has an acid activity, as measured by the C.P.I. Index, of no greater than 50, and characterized by a silica to alumina mole ratio of at least about 12, a constraint index within the range of 1 to 12, having intimately combined therewith a metal selected from the group consisting of rhodium, platinum, palladium and iridium.
- 2. A catalyst composition according to claim 1 wherein said acid activity, as measured by the C.P.I. Index, is no greater than 10.
- 3. A catalyst composition according to claim 1 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35 and ZSM-38.
- 4. A catalyst composition according to claim 3 wherein said zeolite is ZSM-5.
- 5. A catalyst composition according to claim 1 wherein said metal is rhodium.
- 6. A catalyst composition according to claim 1 wherein said metal is impregnated in said zeolite.
- 7. A catalyst composition according to claim 1 wherein said zeolite is rendered virtually free of acid sites by base exchange of an acidic zeolites.
- 8. A catalyst composition according to claim 7 wherein said base exchange is carried out with cations selected from the group consisting of metals from Group IA of the Periodic Chart, Group IIA of the Periodic Chart and ammonium cations.
- 9. A catalyst composition according to claim 8 wherein said Group IA cation is a sodium cation.
- 10. A catalyst composition according to claim 1 wherein said zeolite is highly siliceous and sodium exchanged.
- 11. A catalyst composition according to claim 1 wherein said metal intimately combined with said zeolite is in the range of from about 0.1 to about 10 weight percent of the total composition.
- 12. A catalyst composition according to claim 11 wherein said metal is in the range of from about 0.2 to about 5 weight percent of the total composition.
CROSS-REFERENCE TO RELATED APPLICATION
This is a continuation-in-part of application Ser. No. 065,821 filed Aug. 13, 1979 now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
4157338 |
Haag et al. |
Jun 1979 |
|
4172843 |
Dwyer et al. |
Oct 1979 |
|
4218573 |
Tabak et al. |
Aug 1980 |
|
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
65821 |
Aug 1979 |
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