The present invention relates to a catalyst for combustion of a portion of a gaseous fuel-oxidant mixture flowing through the catalyst, in particular for a burner of a power plant, having the features of the preamble of claim 1.
U.S. Pat. No. 4,154,568 has disclosed a catalyst of the type described in the introduction, the body of which is composed of a plurality of part-bodies arranged one behind the other in a main throughflow direction of the catalyst. The individual part-bodies are in each case designed as monoliths which in each case form a sector of the catalyst. The monolith through which medium flows first therefore includes an inlet of the catalyst and therefore forms an inlet sector, while the following monoliths form succeeding sectors. The individual monoliths include channels, also referred to as cells. In the known catalyst, the cell density increases in the main throughflow direction, while the cell size decreases. In other words, the inlet channels which are formed in the inlet sector and are present in a smaller number each have larger internal cross-sectional areas than the succeeding channels, which are present in a greater number, of the succeeding sectors which follow it. The intention of this configuration of the known catalyst is to effect improved ignition at the inlet and complete combustion of the fuel-oxidant mixture within the catalyst.
U.S. Pat. No. 5,346,389 has disclosed a catalyst which has a plurality of catalytically active channels and a plurality of catalytically inactive channels. This catalyst is produced with the aid of plates which are corrugated or folded in zigzag form and are formed into a layered arrangement by being placed on top of one another, wound helically or by being folded to and fro. The corrugations or folds then form the channels of the catalyst. One side of the respective plate is designed to be catalytically active with the aid of a catalyst coating. Therefore, the layered arrangement produces the catalytically active channels and the catalytically inactive channels. The conversion or combustion of the fuel-oxidant mixture takes place in the catalytically active channels. There is substantially no conversion or combustion of the mixture in the uncoated or catalytically inactive channels, and consequently this part of the flow of mixture can be used to dissipate heat, i.e. to cool the catalyst.
The known catalysts generally require a relatively large installation space, which may not be available in certain installation situations, in particular in the case of a burner of a power plant. In particular if a relatively high degree of conversion of the fuel carried in the mixture is to be achieved during flow through the catalyst, this generally leads to a relatively long construction in the main throughflow direction. However, a relatively short construction in combination with a relatively high degree of conversion is desirable in particular for gas turbine applications.
The invention seeks to remedy this problem. The invention, as characterized in the claims, deals with the problem of providing an improved embodiment, which in particular is of comparatively compact structure and can be used to achieve a relatively high degree of conversion in the fuel-oxidant mixture, for a catalyst of the type described in the introduction.
This problem is solved by the subject matter of the independent claim. Advantageous embodiments form the subject matter of the dependent claims.
The invention is based on the general concept of forming the succeeding channels which are equipped with the smaller internal cross-sectional areas by introducing separation walls into channels in the succeeding sector which extend into the inlet sector, where they form the inlet channels. In this way, the channels provided with the separation walls in the succeeding sector are divided into two or more succeeding channels, which each have a smaller internal cross-sectional area than the inlet channels. The outlay involved in producing a catalyst of this type is relatively low, since given a suitable design the separation walls can be integrated in the succeeding sector relatively easily. Moreover, the proposed design makes it possible to achieve a relatively high cell density, which increases the conversion rate and reduces the dimensions of the catalyst.
According to a preferred embodiment, the length of the inlet sector in the main through flow direction is selected in such a way that, in a rated operating state of the catalyst, in particular of the burner equipped with the catalyst, there is a diffusion-controlled reaction within the inlet sector at the catalytic surfaces of the catalytically active inlet channels. This embodiment takes account of the fact that when the reaction process which is controlled by the diffusion and is therefore limited is reached, only a relatively slight rise in the conversion rate can be achieved over a greater length of the inlet sector, whereas, in the downstream succeeding sector, the conversion rate rises significantly if the length increases, in particular on account of the larger catalytically active surface area. In particular, a state with a thermally limited reaction, in which limiting the reaction through diffusion phenomena is of no importance or only limited importance, can be achieved in the succeeding sector, so that the conversion rate is substantially determined by the prevailing temperature.
The catalyst can also be configured in such a way that the length of the inlet sector in the main throughflow direction is greater than the development length of a hydrodynamic boundary layer which is formed in the channels in a rated operating state of the catalyst, in particular of the burner equipped with the catalyst. This design takes account of the fact that a diffusion-limited or diffusion-controlled reaction (tends to) form(s) in a developed boundary layer flow. Furthermore, this takes account of the knowledge that with larger internal cross-sectional areas, the development length of the boundary layer is shorter, on account of the faster conversion from laminar flow to turbulent flow, and that only a reduced dissipation of heat is possible in a developed boundary layer compared to a boundary layer which is still developing. Accordingly, a heterogeneous catalyst reaction can be ignited in the inlet channels having the larger internal cross-sectional areas even over a short length. Consequently, the overall catalyst is of relatively short construction.
In a refinement, the dimensioning of the catalyst is deliberately selected in such a way that there is a predetermined distance between the location beyond which, in the rated operating state of the catalyst, the diffusion-controlled surface reaction is present and/or beyond which, in the rated operating state of the catalyst, a developed hydrodynamic boundary layer is present and a transition from the inlet sector to the succeeding sector, which predetermined distance is selected in such a way that the heterogeneous combustion reaction is not extinguished in the catalytically active succeeding channels in the rated operating state of the catalyst. Since a very much larger surface area and—depending on the particular embodiment—considerably improved cooling are present at the transition to the succeeding channels, a transition which lies too close to the development length of the boundary layer or too close to the ignition point of the heterogeneous catalyst reaction could lead to the heterogeneous reaction being extinguished.
A particularly inexpensive structure can be achieved for the catalyst according to the invention in particular if the channels are formed by corrugated and/or folded channel plates which are layered on top of one another transversely with respect to the main throughflow direction and the corrugations and/or folds of which extend in the main throughflow direction. The separation walls are in this case formed by separation plates which are arranged transversely with respect to the main throughflow direction between two adjacent channel plates in the succeeding sector. The plates are designed to be catalytically active on at least one side, such that when the catalyst is assembled both catalytically active inlet channels and catalytically active succeeding channels are present. With this design, the separation walls in the form of the separation plates can be integrated in the catalyst even as early as while the catalyst is being built. This considerably simplifies production of the sectors with channels of different internal cross-sectional areas.
In this context, a refinement in which the separation plates are likewise corrugated and/or folded is of particular interest, with the corrugations and/or folds of the separation plates extending parallel to the corrugations and/or folds of the channel plates, and with the corrugations and/or folds of the separation plates having smaller amplitudes than the corrugations and/or folds of the channel plates. This construction ensures that the separation plates form separate succeeding channels with smaller internal cross-sectional areas when the plates are stacked or layered on top of one another in the succeeding sector within the corrugations or folds of the channel plates.
To allow better cooling of the catalyst in order to achieve an increased conversion rate, it is possible for catalytically active channels and catalytically inactive channels to be arranged alternately with one another both in the region of the inlet channels and in the region of the succeeding channels. The flow which is passed through the catalytically inactive channels is then used for cooling, i.e. to dissipate the heat which is formed during the reaction in the catalytically active channels. To achieve a high conversion rate, it is expedient for the catalytically active succeeding channels each to be formed by succeeding channels which are provided with the smaller internal cross-sectional area. For cooling, it is not imperative that the catalytically inactive succeeding channels be equipped with the reduced internal cross-sectional areas, i.e. with the separation walls.
In an advantageous refinement, however, the catalyst has catalytically inactive succeeding channels with a smaller internal cross-sectional area. Installing the separation walls in the catalytically inactive succeeding channels as well allows the flow resistance of the catalytically inactive succeeding channels to be influenced, so that it is possible to influence the distribution of the flow fed to the catalyst between the catalytically active channels and the catalytically inactive channels. By way of example, a distance from the catalyst inlet to the beginning of the catalytically inactive succeeding channels with a smaller internal cross-sectional area may be greater than a distance from the catalyst inlet to the beginning of the catalytically active succeeding channels with a smaller internal cross-sectional area. In this embodiment, the pressure drop in the catalytically active succeeding channels is lower than in the corresponding catalytically inactive succeeding channels. The mass flow of combustible fuel-oxidant mixture through the catalytically active channels is correspondingly greater, with the result that a greater conversion rate of the fuel can be achieved. If, by contrast, the distance from the catalyst inlet to the beginning of the catalytically inactive succeeding channels with a smaller internal cross-sectional area is less than the distance from the catalyst inlet to the beginning of the catalytically active succeeding channels, the pressure drop is lower in the catalytically inactive succeeding channels. This leads to reduced flow velocities in the catalytically active succeeding channels, which allows the heterogeneous reaction to be ignited at relatively low temperatures. Irrespective of their length, the separation walls used to form the catalytically inactive succeeding channels with smaller internal cross-sectional areas can improve the dissipation of the heat which is formed in the catalytically active succeeding channels, since the intermediate walls are heated by the heat radiated from the walls of the adjacent catalytically active channels and at the same time have the cooling mixture flowing around them.
Moreover, narrower succeeding channels, i.e. those succeeding channels which have a smaller internal cross-sectional area, impede spontaneous ignition of a homogeneous combustion reaction in the fuel-oxidant mixture within the succeeding channels, since with smaller internal cross-sectional areas radicals which are formed during the heterogeneous combustion reaction can be bonded more successfully, an action which is also described as an improvement to the “radical quenching” (elimination of radicals).
Further important features and advantages of the invention will emerge from the subclaims, from the drawings and from the associated description of figures with reference to the drawings.
Preferred exemplary embodiments of the invention are illustrated in the drawings and explained in more detail in the description which follows, in which identical designations refer to identical or functionally equivalent or similar components. In the drawings, in each case schematically:
In accordance with
As can be seen from
Inlet sector 5 and succeeding sector 6 differ from one another by virtue of the fact that some of the succeeding channels 10 each have a smaller internal cross-sectional area than the inlet channels 9. In the embodiment shown in
According to the invention, the small succeeding channels 10 are produced by separation walls 11 being introduced into the channels 3, which pass through the entire structure 2 of the catalyst 1, in the succeeding sector 6. These separation walls 11 divide the respective channel 3 within the succeeding sector 6 into a plurality of, i.e. at least two, parallel, separate partial channels which form the narrow succeeding channels 10. Since the separation walls 11 extend only within the succeeding sector 6, the continuous channels 3 in the inlet sector 5 form the large inlet channels 9. Accordingly, the inlet channels 9 have the same large internal cross-sectional area as the continuous channels 3.
In accordance with
In this design, therefore, portions of the channels 3 which lie in the inlet sector 5 form the inlet channels 9, while portions of the channels 3 which lie in the succeeding sector 6 include the separation walls 11 and therefore form the succeeding channels 10 (cf.
It is expedient for the separation plates 14 also to be corrugated and/or folded, with the corrugations or folds of the separation plates 14 running within the corrugations or folds of the adjacent channel plate 12. As a result, the corrugations or folds of the separation plates 14 also extend parallel to the corrugations or folds of the channel plates 12. To allow the narrow succeeding channels 10 to be formed in accordance with the invention within the channels 3 formed by the corrugations or folds of the channel plates 12, the amplitudes of the corrugations or folds of the separation plates 14 are dimensioned to be smaller than the amplitudes of the corrugations or folds of the channel plates 12.
The layer formation of the structure 2 may be effected, for example, by stacking a suitable number of channel plates 12, intermediate plates 13 and separation plates 14 on top of one another. The plates 12, 13, 14 can also be layered on top of one another by being folded to and fro or by being wound up helically. Therefore, after it has been assembled, the catalyst 1 has a common structure 2 or supporting structure 2, which forms an integral unit for the inlet sector 5 and the succeeding sector 6, for all of its channels 3, 9, 10.
The catalyst 1 is used to burn a portion of a gaseous fuel-oxidant mixture which flows through the catalyst 1. A catalyst 1 of this type is preferably used in a burner of a power plant. To enable it to provide its catalytic action, in the embodiment shown here the channel, intermediate and separation plates 12, 13, 14 are each designed to be catalytically active on one side, in particular by coating with a catalytically active layer or catalyst layer 15. When the structure 2 is being assembled, the orientation of the plates 12, 13, 14 is expediently such that catalytically active channels and catalytically inactive channels alternate both in the inlet sector 5 and in the succeeding sector 6. The catalytically inactive channels differ from the catalytically inactive channels in that at least one boundary wall of the catalytically active channels is provided with the catalyst layer 15, whereas none of the boundary walls of the catalytically inactive channels is provided with the catalyst layer 15. By way of example, in
Accordingly, in the embodiment shown in
In the embodiment shown in
In another embodiment, it is also possible for the length Lsmall,u of the separation walls 11 of the catalytically inactive succeeding channels 10 to be less than the length Lsmall,c of the separation walls 11 in the catalytically active succeeding channels 10. This variant results in reduced flow velocities in the catalytically active channels 3, allowing reliable ignition of the heterogeneous combustion reaction with a shortened path length in particular in the catalytically active inlet channels 9.
In accordance with
In accordance with
The transition between inlet channel 9 and succeeding channels 10 or between inlet sector 5 and succeeding sector 6 within the catalytically active channels 9, 10 is located at the leading edge 19 of the separation wall 11 shown. To ensure that the reaction which has been ignited in the inlet channel 9 is not extinguished during the transition to the succeeding channels 10, the catalyst 1 is dimensioned in such a way that a first distance 20 is maintained between the leading edge 19 or the transition 19 and the beginning 18 of the diffusion-controlled reaction, and a second distance 21 is maintained between the leading edge 19 or the transition 19 and the beginning of the developed boundary layer 16. The boundary line between developing boundary layer and developed boundary layer 16 is denoted by 22 in
The dimension conditions referred to above in each case relate to a rated operating state of the catalyst 1, i.e. in particular to a rated operating state of the burner equipped with the catalyst 1.
Further dimension criteria may be as follows:
In accordance with
A further particular feature which results from the construction of the present catalyst 1 according to the invention is that the inlet channels 9, at least in the vicinity of the transition to the succeeding channels 10, can transfer heat to the separation wall 11 through radiation, thereby improving the cooling of the catalyst 1 at least at the end of the inlet sector 5. Calculations have shown that up to 30% of the heat generated by the hot walls can be radiated onto the cooler surfaces. Furthermore, this can boost the catalytic activity at the start of the separation wall 11.
In accordance with
To increase the residence time of the fuel-oxidant mixture in the catalytically active channels 3 and/or to improve the heat transfer, it is possible for at least some of the small catalytically active succeeding channels 10 to be equipped with turbulence stimulators (not shown here).
To allow better neutralization of the radicals which are formed at high temperatures in the gas phase of the catalytically inactive channels, it is moreover possible to provide for at least some of the narrow catalytically inactive succeeding channels 10 to be provided with a material, for example aluminum or aluminum alloy, which has an absorbing action for these radicals. This neutralization or deactivation of the radicals impedes the ignition of a homogeneous combustion in the gas mixture.
In the embodiment shown in
The catalytically active coating or catalyst layer 15 can be configured in various ways. By way of example, the catalyst material can be applied in a punctiform manner, in order to produce the maximum possible catalytically active surface areas. It is also possible for the catalyst material to be applied in strips which extend transversely with respect to the direction of flow and are spaced apart from one another in the direction of flow. Furthermore, it is possible for zones with different activities to be distributed appropriately.
Number | Date | Country | |
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Parent | PCT/CH03/00406 | Jun 2003 | US |
Child | 11066736 | Feb 2005 | US |