Claims
- 1. A process for preparing O-polyalkoxylated high molecular weight alkanone or alkanal oximes which comprises contacting a paraffin oxime corresponding to the formula: ##EQU5## where R and R' are hydrogen or alkyl groups having from 1 to 11 carbon atoms and where the sum of R and R' is 9 to 12 carbon atoms with a basic nitrogen catalyst selected from the group consisting of triethylamine, pyridine, methylpiperidine, N,N-dimethylethylamine, N,N-diethylmethylamine, N,N-dimethylpropylamine, N,N-diethylpropylamine and N,N-ethylmethylpropylamine and from 2 to 40 moles of an oxirane per mole of said oxime in the substantial absence of water and where said O-polyalkoxylated oxime is subsequently contacted with a mild oxidizing agent.
- 2. A process for preparing O-polyalkoxylated high molecular weight alkanone or alkanal oximes which comprises contacting a paraffin oxime corresponding to the formula: ##EQU6## where R and R' are hydrogen or alkyl groups having from 1 to 11 carbon atoms and where the sum of R and R' is 9 to 12 carbon atoms with a basic nitrogen catalyst, said catalyst corresponding to the formula: ##EQU7## where R, R.sup.1 and R.sup.2 are alkyl, cycloalkyl or aryl groups or where R, R.sup.1 and/or R.sup.2 together with N are heterocyclic and where R, R.sup.1 and R.sup.2 are 1 to 12 carbons and where the sum of R, R.sup.1 and R.sup.2 is 3 to 36 carbons, and from 2 to 40 moles of an oxirane per mole of said oxime in the substantial absence of water.
- 3. A process according to claim 2 wherein said paraffin oxime is a mixture of C.sub.10 to C.sub.13 n-paraffin oximes.
- 4. A process according to claim 2 wherein from 6 to 15 moles of said oxirane are contacted per mole of said oxime.
- 5. A process according to claim 2 wherein said catalyst is a trialkylamine.
- 6. A process according to claim 2 wherein said catalyst is selected from the group consisting of triethylamine, pyridine, methylpiperidine, N,N-dimethylethylamine, N,N-diethylmethylamine, N,N-dimethylpropylamine, N,N-diethylpropylamine and N,N-ethylmethylpropylamine.
- 7. A process according to claim 2 wherein said catalyst is triethylamine.
- 8. A process according to claim 2 wherein said oxirane is ethylene oxide.
- 9. A process according to claim 2 wherein said oxirane is methyloxirane.
- 10. A process according to claim 2 wherein said oxirane is phenyloxirane.
- 11. A process according to claim 2 wherein said O-polyalkoxylated oximes are subsequently contacted with a mild oxidizing agent.
- 12. A process according to claim 11 wherein said oxidizing agent is selected from the group consisting of hydrogen peroxide, alkali hypochlorites, alkaline earth hypochlorites, alkali hypobromites and alkaline earth hypobromites.
- 13. A process according to claim 11 wherein said oxidizing agent is hydrogen peroxide.
- 14. A process for preparing O-polyalkoxylated high molecular weight alkanone or alkanal oximes which comprises contacting a paraffin oxime corresponding to the formula: ##EQU8## where R and R' are hydrogen or alkyl groups having from 1 to 11 carbon atoms and where the sum of R and R' is from 9 to 12 carbon atoms with a basic nitrogen catalyst selected from the group consisting of triethylamine, diethylmethylamine and dimethylethylamine, and from 6 to 15 moles of an oxirane per mole of said oxime in the substantial absence of water.
- 15. A process according to claim 14 wherein said catalyst is triethylamine.
- 16. A process according to claim 14 wherein said oxirane is ethylene oxide.
- 17. A process according to claim 14 wherein said oxime is a mixture of C.sub.10 to C.sub.13 n-paraffin oximes.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of our copending application Ser. No. 250,020 filed May 3, 1972 now abandoned which in turn is a continuation-in-part of applications Ser. No. 202,022 filed Nov. 24, 1971, now U.S. Pat. No. 3,799,984 issued Mar. 26, 1974 and Ser. No. 737,866 filed June 18, 1968, now U.S. Pat. No. 3,683,024 issued Aug. 8, 1972.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
3040097 |
Bachman et al. |
Jun 1962 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
2,011,157 |
Mar 1970 |
FR |
Non-Patent Literature Citations (1)
Entry |
Gaylord, "High Polymers vol. XIII," Polyethers part I, pp. 105-109, (1963). |
Related Publications (1)
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Number |
Date |
Country |
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737866 |
Jun 1968 |
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Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
250020 |
May 1972 |
|
Parent |
202022 |
Nov 1971 |
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