Patent Application
20140356713
The present invention relates to an anode active material with whole particle concentration gradient for a lithium secondary battery, a method for preparing same, and a lithium secondary battery having same, and more specifically, to a anode active material with whole particle concentration gradient for a lithium secondary battery, a method for preparing same, and a lithium secondary battery having same, which has excellent lifetime characteristics and charge/discharge characteristics through the stabilization of crystal structure without rapid change on the concentration of a metal inside of the anode active material particle, and has thermostability even in high temperatures.
On the strength of recent rapid development of electronics, communications, computer industry, etc., the use of portable electronic devices such as camcorders, mobile phones, notebook PCs and the like becomes generalized. Accordingly, there is increasing demand for batteries which are lightweight and highly reliable, and can be used longer.
In particular, lithium secondary batteries, whose operating voltage is 3.7 V or more, have higher energy density per unit weight than nickel-cadmium batteries and nickel-hydrogen batteries. Accordingly, the demand for the lithium secondary batteries as a power source to drive the portable electronic communication devices is increasing day by day.
Recently, studies on power sources for electric vehicles by hybridizing an internal combustion engine and a lithium secondary battery are actively conducted in the United States, Japan, Europe and the like. The development of a plug-in hybrid (P-HEV) battery used in the car with a mileage of less than 60 miles is actively proceeding around United States. The P-HEV battery is a battery having characteristics, which are nearly the characteristics of an electric vehicle, and the biggest challenge is to develop high-capacity batteries. In particular, the biggest challenge is to develop anode materials having higher tap density of 2.0 g/cc or more and high capacity characteristics of 230 mAh/g or more.
The materials, which are currently available or under development, are LiCoO2, LiNiO2, LiMnO2, LiMn2O4, Lii+X[Mn2−xMx]O4, LiFePO4 and the like. Of them, the LiCoO2 is an excellent material having stable charge/discharge characteristics, excellent electronic conductivity, high cell voltage, high stability and even discharge voltage characteristics. However, because Co has low reserves and is expensive and toxic to the human body, it is needed to develop other anode materials. Further, it has a defect of very poor thermal properties by unstable crystal structure by delithiation during discharging.
In order to improve it, there may be many attempts to shift the exothermic onset temperature to the side of the higher temperature and to make an exothermic peak broad in order to prevent rapid heat-emitting, by substitute a part of the nickel with transition metals. However, there is no satisfactory result yet.
Namely, LiNi1−1CoxO2 (x=0.1-0.3) material, wherein a part of the nickel is substituted with cobalt, shows excellent charge/discharge characteristics and lifetime characteristics, but the thermostability problem is not solved yet. Furthermore, European Patent No. 0872450 discloses LiaCobMncMdNi1−(b+c+d)O2 (M═B, Al, Si. Fe, Cr, Cu, Zn, W, Ti, Ga)-type, where the Ni is substituted with other metals as well as Co and Mn, but the thermostability of the Ni-based material is not solved yet.
In order to eliminate these shortcomings, Korean Patent Publication No. 2005-0083869 suggests lithium-transition metal oxides having metal composition representing concentration gradient. This method is a method that an internal materials with a certain composition is synthesized and materials with other composition is coated on the exterior thereof to obtain a bi-layer, and is mixed with a lithium salt followed by heat-treatment. The internal material may be commercially available lithium transition metal oxides. However, this method has a problem that the internal structure is unstable because the metal composition of the anode active material between the produced internal material and the external material is discontinuously changed, and is not continuously and gradually changed. Further, the powder synthesized by the invention, which does not use ammonia as a chelating agent, was not suitable for an anode active material for a lithium secondary battery due to its lower tap density.
In order to improve this problem, Korean Patent Publication No. 2007-0097923 suggests an anode active material, which has an internal bulk part and an external bulk part, and the metal ingredients have continuous concentration distribution depending on their position at the external bulk part. However, in this method, there was a need to develop an anode active material of a new structure having better stability and capacity because the concentration is constant at the internal bulk part and the metal composition is changed at the external bulk part.
In order to solve the above-described problems associated with prior art, the present invention is objected to provide an anode active material with whole particle concentration gradient for a lithium secondary battery, which has excellent lifetime characteristics and charge/discharge characteristics through the stabilization of crystal structure, and has thermostability even in high temperatures.
Further, the present invention is objected to provide a method for preparing the anode active material for lithium secondary battery.
Further, the present invention is objected to provide a lithium secondary battery including the anode active material.
In order to accomplish one object of the present invention, the present invention provides, in an anode active material for a lithium secondary battery, an anode active material with whole particle concentration gradient for a lithium secondary battery, wherein the concentration of a metal making up the anode active material shows continuous concentration gradient in the entire region, from the particle core to the surface part.
The anode active material for a lithium secondary battery is characterized that it may comprise:
the core expressed by the following formula 1; and
the surface part expressed by the following formula 2,
wherein the concentration of the M1 is constant from the core to the surface part; and
the concentration of the M2 and the concentration of the M3 have continuous concentration gradient from the core to the surface.
Lia1M1xM2y1M3z1M4wO2+δ [Formula 1]
Lia2M1xM2y2M3z2M4wO2+δ [Formula 2]
(in the formulas 1 and 2, M1, M2 and M3 are selected from the group consisting of Ni, Co, Mn and a combination thereof; M4 is selected from the group consisting of Fe, Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga, B and a combination thereof; 0<a1≦1.1, 0<a2≦1.1, 0≦x≦1, 0≦y1≦1, 0≦y2≦1, 0≦z1≦1, 0≦z2≦1, 0≦w≦0.1, 0.0≦δ≦0.02, 0≦x+y1+z1≦1, 0<x+y2+z2≦1, and y1≦y2, z2≦z1.
Further, the present invention provides a method for preparing the anode active material for a lithium secondary battery comprises:
a first step of preparing a metal salt aqueous solution for forming the core and a metal salt aqueous solution for forming the surface part, which contain the M1, the M2 and the M3 as a metal salt aqueous solution, wherein the concentration of the M1 is the same each other, and the concentration of the M2 and the concentration of the M3 are different each other;
a second step of forming precipitates by mixing the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part at a mixing ratio from 100 v % :0 v % to 0 v % :100 v % with gradual change and by mixing a chelating agent and a basic aqueous solution to a reactor at the same time, wherein the concentration of the M1 is constant from the core to the surface part, and the concentrations of the M2 and the M3 have continuous concentration gradient from the core to the surface part;
a third step of preparing an active material precursor by drying or heat-treating the obtained precipitates; and
a fourth step of mixing the active material precursor and a lithium salt and then heat-treating thereof.
Further, the present invention provides a lithium secondary battery comprising the anode active material.
In the anode active material for a lithium secondary battery according to the present invention, the concentration of one metal is constant from the core to the surface part, and the concentrations of the other two metals are increased or decreased with continuous concentration gradient from the core to the surface part.
Accordingly, the crystal structure of the particle is stabilized and the thermostability is increased because there is no phase boundary having rapid concentration change from the particle core to the surface part.
Accordingly, the lithium secondary battery having the anode active material shows excellent capacity characteristics as well as excellent lifetime characteristics and charge/discharge characteristics, and has thermostability even in high temperatures. Particularly, when the Ni concentration of the anode active material according to the present invention, which shows the whole particle concentration gradient, is maintained constantly, a stable active material showing high capacity can be prepared.
The above and other objects and features of the present invention will become apparent from the following description of the invention taken in conjunction with the following accompanying drawings, which respectively show:
Hereinafter, the present invention will be described in detail.
Unlike the prior art that the metal concentration is constant at the interior region, but the metal concentration shows gradual concentration gradient at the exterior region, in the anode active material of the present invention, a part of the metal shows continuous concentration gradient at the whole region from the particle core to the surface part, but the other one metal shows constant metal concentration at the whole region from the particle core to the surface part.
In the anode active material particle of the present invention, one of metals making up the anode active material shows constant metal concentration at the whole region from the particle core to the surface part, but the other two metals show decreased or increased continuous concentration gradient at the whole region from the particle core to the surface part.
Namely, the present invention is characterized that the concentration of the M2 is increased with continuous concentration gradient from the core to the surface part, and the concentration of the M3 is decreased with continuous concentration gradient from the core to the surface part.
In the present invention, “metal concentration shows continuous concentration gradient” refers that the concentration of metal except for lithium exists with concentration distribution, which is changed gradually from the core of the active material particle to the surface part. The concentration gradient refers that there may be metal concentration difference of 0.1 to 30 mol %, preferably 0.1 to 20 mol %, more preferably 1 to 10 mol % per 0.1 μm, from the particle core to the surface part. In the present invention, the particle core refers to the range within the diameter 0.2 μm from the center of the active material particle, and the particle surface part refers to the range within the diameter 0.2 μm from the outermost of the particle.
The present invention is characterized that the concentration gradients of the M2 and the M3 should be constant from the particle core to the surface, i.e., the concentrations of the M2 and the M3 may be continuously changed at the whole particle, preferably.
The present invention is characterized that the M1 is Ni, the M2 is Mn and the M3 is Co. The Ni concentration is maintained constantly so as to obtain high capacity, and the Mn concentration becomes increased at the surface and the Co concentration becomes decreased at the surface so as to obtain higher stability.
In the present invention, the constant concentration range of the M1, i.e., Ni, x may be 0.4≦x≦1, and it is more preferred that the Ni concentration should be maintained at high concentration of 0.6≦x≦0.9.
In the present invention, when the M1 is Ni, the concentration difference of the Co and the Mn between the particle core and the particle surface may be 0.2≦|y2−y1 |0.4, 0.2≦|z2−z1|≦0.4, preferably, because there may be no rapid concentration change. And the concentrations of the Mn and the Co at the surface may be 0.2≦y2≦0.4, 0≦z2≦0.1, preferably. The Mn content at the surface should be 0.2 or more to obtain thermostability and to prevent capacity reduction.
The present invention is characterized that the M1 is Co, the M2 is Mn and the M3 is Ni.
The present invention is characterized that the M1 is Mn, the M2 is Co and the M3 is Ni.
Hereinafter, the method for preparing the anode active material of the present invention will be described.
First of all, a metal salt aqueous solution for forming the core and a metal salt aqueous solution for forming the surface part, which contain the M1, the M2 and the M3 as a metal salt aqueous solution, wherein the concentration of the M1 is the same each other, and the concentration of the M2 and the concentration of the M3 are different each other, are prepared. The present invention is characterized that in order to constantly maintain the concentration of the M1 in the whole particle, the M1 concentration may be maintained same at the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part.
The metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part may be prepared by adding nickel salt, cobalt salt, manganese salt and salts containing M to a solvent, or may be prepared by preparing aqueous solution containing nickel salt, cobalt salt, manganese salt and salts containing M, respectively followed by mixing thereof for using. The metal salt may be sulfate, nitrate, acetate, halide, hydroxide and the like, and it may be any salt, which can be dissolved in water, without particular limitation.
Then, the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part are mixed together and simultaneously, the chelating agent and the basic aqueous solution are mixed in a reactor so as to obtain a precipitate wherein the M1 concentration is constant from the core to the surface, and the M2 and M3 concentrations have continuous concentration gradients from the core to the surface part. Namely, the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part are mixed at the mixing ratio, which is gradually changed from 100 v %:0 v % to 0 v % :100 v %, and simultaneously, the chelating agent and the basic aqueous solution are mixed in a reactor, so as to form a precipitate, wherein the M1 concentration is constant from the core to the surface, and the M2 and M3 concentrations have continuous concentration gradients from the core to the surface part.
In the present invention, a precipitate having continuous concentration gradient from the particle core to the surface part, from the particle forming process through one coprecipitation process, by mixing the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part from the initial stage of the particle forming process and supplying thereof continuously at the same time. The produced concentration gradient and its gradient may be controlled according to the compositions and the mixing ratio of the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part. The entire particle size may be controlled by adjusting the reaction time to 1 to 10 hours.
Further, the present invention is characterized that the molar ratio of the chelating agent and the metal salt may be 0.2 to 1.0:1.
The chelating agent may be ammonia aqueous solution, ammonium sulfate aqueous solution and a combination thereof. It is preferred that the molar ratio of the chelating agent and the metal salt may be 0.2 to 0.5:1, 0.2 to 0.4:1. The reason to set the molar ratio of the chelating agent to 0.2 to 1.0 based on the metal aqueous solution 1 mole, is that the chelating agent forms a complex by reacting with metal at the ratio of 1:1 or more, but the chelating agent remained after the reaction of sodium hydroxide and the complex may be changed to intermediates and then recovered as the chelating agent. Furthermore, the reason is that it is the best condition for improving and stabilizing the crystallinity of the anode active material.
The concentration of the basic aqueous solution may be 2 M to 10 M, preferably. If the concentration of the basic aqueous solution is less than 2 M, particle forming may take longer, tap density may be deteriorated, and the yield of the co-precipitation reaction product may be reduced. And, if the concentration is over 10 M, it is not preferred because it may be difficult to form homogeneous particles due to rapid particle growth by rapid reaction, and the tap density may be also reduced.
In the second step, the reaction atmosphere of the transition metal aqueous solution may be under a nitrogen flow, pH may be within 10 to 12.5, reaction temperature is within 30 to 80° C., and reaction stirring speed may be within 100 to 2000 rpm, preferably.
Then, in the third step, the obtained precipitate may be dried or heat-treated to prepare an active material precursor. The drying process may be conducted at 110° C. to 400° C. for 15 to 30 hours.
Finally, the active material precursor and the lithium salt are mixed and then heat-treated to obtain an active material.
It is preferred that the heat-treating process after mixing the active material precursor and the lithium salt may be conducted at 700° C. to 1100° C. The heat-treating atmosphere may be in an oxidative atmosphere of air or oxygen or a reductive atmosphere of nitrogen or hydrogen, preferably, and the heat-treating time may be 10 to 30 hours, preferably. During this heat-treating process, metal may be diffused even at the part where the internal metal concentration is constant at the initial stage of the particle forming process, and consequently, a metal oxide having continuous metal concentration distribution from the core to the surface part in the whole particle may be obtained.
Before the heat-treating process, a pre-calcining process may be conducted by maintaining at 250 to 650° C. for 5 to 20 hours. Further, after the heat-treating process, an annealing process may be conducted at 600 to 750° C. for 10 to 20 hours.
Further, the present invention may further include a step of adding sintering additives when mixing the active material precursor and the lithium salt, preferably. The sintering additives may be any one selected from the group consisting of compounds containing ammonium ion, metal oxides, metal halides and a combination thereof, preferably.
The compounds containing ammonium ion may be any one selected from the group consisting of NH4F, NH4NO3, (NH4)2SO4, and a combination thereof, preferably; the metal oxides may be any one selected from the group consisting of B2O3, Bi2O3, and a combination thereof, preferably; and the metal halides may be any one selected from the group consisting of NiCl2, CaCl2, and a combination thereof, preferably.
The sintering additives may be used in an amount of 0.01˜0.2 mole based on the active material precursor 1 mole, preferably. If the amount of the sintering additives is too low, the sintering effect of the active material precursor may not be improved a lot, and if the amount is higher than the said range, the initial capacity during charging/discharging may be reduced or the performance of the anode active material may be deteriorated.
Further, the present invention provides a lithium secondary battery including the anode active material according to the present invention.
The lithium battery may include an anode including the anode active material having the above constitution, a cathode including cathode active material and a separator existing between thereof. Further, it may include an electrolyte, which is immersed in the anode, the cathode and the separator. The cathode active material may be a material which can reversibly absorb or release lithium ions, preferably, for example, a material including artificial graphite, natural graphite, graphitized carbon fiber, Amorphous Carbon, and metal lithium also can be used as a cathode active material. The electrolyte may be a liquid electrolyte containing lithium salts and non-aqueous organic solvent, or polymer gel electrolyte.
Hereinafter, the present invention is explained by the following Examples and Test Examples in more detail. The following Examples and Test Examples are intended to further illustrate the present invention, and the scope of the present invention cannot be limited thereby in any way.
In order to prepare a compound, wherein the Ni concentration is constant from the core to the surface, the Co concentration is decreased, and the Mn concentration is increased, a 2.4 M metal aqueous solution, prepared by mixing nickel sulfate and cobalt sulfate at the molar ratio of 80:20, as a metal salt aqueous solution for forming the core and a metal aqueous solution containing nickel sulfate and manganese sulfate at the molar ratio of 80:20 as a metal salt aqueous solution for forming the surface part were prepared. Distilled water 4 L was put into a coprecipitation reactor (Capacity: 4 L, power of a rotation motor: 80 W); nitrogen gas was supplied to the reactor at the speed of 0.5 L/min so as to remove dissolved oxygen; and stirred at 1000 rpm while maintaining the temperature of the reactor at 50° C.
The metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part were mixed at a certain ratio, and simultaneously supplied into the reactor at the rate of 0.3 L/hour. Further, 3.6 M ammonia solution was continuously supplied into the reactor at the rate of 0.03 L/hour. Further, for adjusting pH, 4.8 M NaOH aqueous solution was supplied to maintain pH in the reactor at 11. Then, the impeller speed of the reactor was controlled to 1000 rpm, and the co-precipitation reaction was conducted until the diameter of the obtained precipitate became 1 μm. At this time, the flow rate was controlled to make the average retention time of the solution in the reactor about 2 hours, and after the reaction reached to the steady state, the reactant was kept at the steady state for a certain time to so as to obtain a co-precipitated compound having higher density. The compound was filtered, washed with water, and dried with 110° C. warm air dryer for 15 hours so as to obtain an active material precursor.
LiNO3 as a lithium salt was mixed to the obtained active material precursor, heated at a rate of 2° C./min, and then pre-calcined by maintaining at 280° C. for 10 hours followed by calcining at 750° C. for 15 hours to obtain a final active material particle. The size of the finally obtained active material particle was 12 μm.
In order to prepare a compound, wherein the Ni concentration is constant from the core to the surface, the Co concentration is decreased and the Mn concentration is increased, the procedure of Example 1 was repeated except for mixing nickel sulfate, cobalt sulfate and manganese sulfate of the metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part at the molar ratio as listed in the following Table 1 so as to obtain an active material particle.
An anode active material, which has the same composition and the same structure with Examples 1-3 was prepared by using a batch reactor.
Distilled water 2.5 L was put into a coprecipitation batch reactor (Capacity: 8 L, power of a rotation motor:180 W); nitrogen gas was supplied to the reactor at the speed of 0.6 L/min so as to remove dissolved oxygen; and stirred at 450 rpm while maintaining the temperature of the reactor at 50° C.
The metal salt aqueous solution for forming the core and the metal salt aqueous solution for forming the surface part having the same concentration with Example 1-3 were mixed at a certain ratio, and simultaneously supplied into the reactor at the rate of 0.2 L/hour. Further, 4.8 M ammonia solution was continuously supplied into the reactor at the rate of 0.1 L/hour. Further, for adjusting pH, 10 M NaOH aqueous solution was supplied to maintain pH in the reactor at 11. Then, the impeller speed of the reactor was controlled to 450 rpm, and the reaction solution was supplied until the total amount of the initially added distilled water, the added metal aqueous solution, the ammonia solution and the NaOH solution became 8 L. The compound was filtered, washed with water, and dried with 110° C. warm air dryer for 15 hours so as to obtain an active material precursor.
LiNO3 as a lithium salt was mixed to the obtained active material precursor, heated at a rate of 2° C./min, and then pre-calcined by maintaining at 280° C. for 10 hours followed by calcining at 750° C. for 15 hours to obtain a final active material. The size of the finally obtained active material particle was 12 μm
An anode active material, wherein the molar ratio of the nickel, the cobalt and the manganese is as listed in the following Table 2, respectively, and each concentration in the whole active material is not changed so as to have constant composition, was prepared.
In order to confirm the concentration gradient structure of each metal from the core to the surface of the precursor particle of the present invention, the atomic ratio in each precursor particle prepared in Examples 1-1 to 1-5 was measured by using EPMA (Electron Probe Micro Analyzer) while moving form the core to the surface part, and the results are shown in
In
Further, for Example 5 prepared by using the batch type reactor, as shown in
In order to confirm whether each metal shows concentration gradient from the particle core to the surface part after heat-treating the precursor of the present invention, the particles prepared in Examples 1-1 to 1-5 were heat-treated. And then the atomic ratio was measured by using EPMA (Electron Probe Micro Analyzer) while moving from the core to the surface, and the results are shown in
In
Further, as shown in
In
Surface images of the precursors and the final active materials prepared in Examples 1-1 to 1-5 were taken by using a scanning electron microscope, and the results are shown in
Each of the pictures is a surface image with different magnification, and it could be confirmed that each particle was homogeneously formed.
Anodes were prepared by using the active materials prepared in Examples 1-1 to 1-5 and the active materials prepared in Comparative Examples 1-1 to 1-4, and applied to cylindrical lithium secondary batteries, respectively.
For the batteries prepared by using the active materials prepared in Examples 1-1 to 1-4, charging/discharging test and cycle characteristics were measured, and the results are shown in
In
Further, in
<Test Example 1-5:Evaluation of Thermostability by DSC Measurement>The anodes containing the active materials prepared in Examples 1-1 to 1-4 and the active materials prepared in Comparative Examples 1-1 to 1-4, were charged at 4.3 V, respectively, and thermostability was measured by using a differential scanning calorimeter (DSC) and heating at a rate of 10° C./min. The results are shown in
As shown in
Namely, in the present invention, the concentration of one metal is constant, and the concentrations of the other two metals are increased or decreased with continuous concentration gradient from the core to the surface part. Accordingly, because the concentrations of the metals inside of the particle are not rapidly changed and show stable structure, it could be confirmed that the thermostability is largely increased.
Further, in
In order to prepare a compound, wherein the Co concentration is constant from the core to the surface, the NI concentration is decreased, and the Mn concentration is increased, a 2.4 M metal aqueous solution, prepared by mixing nickel sulfate and cobalt sulfate at the molar ratio of 90:10, as a metal salt aqueous solution for forming the core and a metal aqueous solution containing nickel sulfate, cobalt sulfate and manganese sulfate at the molar ratio of 65:10:25 as a metal salt aqueous solution for forming the surface part were prepared, and a precursor was prepared as described in Example 1-1.
LiNO3 as a lithium salt was mixed to the obtained active material precursor, heated at a rate of 2° C./min, and then pre-calcined by maintaining at 280° C. for 10 hours followed by calcining at 750° C. for 15 hours to obtain a final active material particle. The size of the finally obtained active material particle was 12 μm.
As Comparative Example, a precursor containing the nickel, cobalt and manganese at the molar ratio of 72:10:18, wherein each metal concentration is the same in the whole particle was prepared.
In order to confirm the concentration gradient structure of each metal from the core to the surface of the precursor particle of the present invention, the atomic ratio of the precursor particle prepared in Example 2-1 was measured by using EPMA (Electron Probe Micro Analyzer) while moving form the core to the surface part as described in Test Example 1-1, and the results is shown in
In
In order to confirm whether each metal shows concentration gradient from the core to the surface part after heat-treating the precursor particle of the present invention, the atomic ratio of the particle prepared in Example 2-1 was measured by using EPMA (Electron Probe Micro Analyzer) while moving from the core to the surface as described in Test Example 1-2, and the result is shown in
Surface images of the precursors and the final active materials prepared in Example 2-1 and Comparative Example 2-1 were taken by using a scanning electron microscope, and the results are shown in
Each of the pictures is a surface image with different magnification, and it could be confirmed that each particle was homogeneously formed.
Anodes were prepared by using the active material prepared in Example 2-1 and the active material prepared in Comparative Example 2-1, and applied to cylindrical lithium secondary batteries, respectively.
For the batteries prepared by using the active material prepared in Example 2-1 and the active material prepared in Comparative Example 2-1, charging/discharging test and cycle characteristics were measured, and the results are shown in
In
However, Example 2-1 showing concentration gradient showed better performance than Comparative Example 2-1.
The anodes containing the active materials prepared in Example 2-1 and Comparative Example 2-1 were charged at 4.3 V, respectively, and thermostability was measured by using a differential scanning calorimeter (DSC) and heating at a rate of 10° C./min. The results are shown in
As shown in
Namely, in the present invention, the concentration of one metal is constant, and the concentrations of the other two metals are increased or decreased with continuous concentration gradient from the core to the surface part. Accordingly, because the concentrations of the metals inside of the particle are not rapidly changed and show stable structure, it could be confirmed that the thermostability is largely increased.
In the anode active material for a lithium secondary battery according to the present invention, the concentration of one metal is constant from the core to the surface part, and the concentrations of the other two metals are increased or decreased with continuous concentration gradient from the core to the surface part. Accordingly, the crystal structure of the particle is stabilized and the thermostability is increased because there is no phase boundary having rapid concentration change from the particle core to the surface part.
Accordingly, the lithium secondary battery having the anode active material shows excellent capacity characteristics as well as excellent lifetime characteristics and charge/discharge characteristics, and has thermostability even in high temperatures. Particularly, when the Ni concentration of the anode active material according to the present invention, which shows the whole particle concentration gradient, is maintained constantly, a stable active material showing high capacity can be prepared.
While the invention has been described with respect to the above specific embodiments, it should be recognized that various modifications and changes may be made and also fall within the scope of the invention as defined by the claims that follow.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2011-0000841 | Jan 2011 | KR | national |
| 10-2011-0021579 | Mar 2011 | KR | national |
| 10-2011-0122542 | Nov 2011 | KR | national |
This Application is a continuation of U.S. application Ser. No. 13/978,067 filed Oct. 8, 2013, wich is a 371 of PCT/KR2011/010173 filed Dec. 27, 2011, which claimed the priority of KR Patent Application No. 10-2011-0000841 filed Jan. 5, 2011; KR Patent Application No. 10-2011-0021579 filed Mar. 10, 2011 and KR Patent Application No. 10-2011-0122542 filed Nov. 22, 2011, contents of each of which are incorporated herein by reference in their entirety.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 13978067 | Oct 2013 | US |
| Child | 14463170 | US |
