Information
                
                    - 
                        
 Patent Grant
                     
                    - 
                        
 6784606
                     
                
             
         
    
    
        
            
                - 
                    
Patent Number
                    6,784,606
                 
                - 
                    
Date Filed
                    Wednesday, December 20, 200024 years ago
                 
                - 
                    
Date Issued
                    Tuesday, August 31, 200421 years ago
                 
            
         
     
    
        
            
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Inventors
        
                 
                - 
                            
Original Assignees
        
                 
                - 
                                
Examiners
            
                    - Glick; Edward J.
 
                    - Keaney; Elizabeth
 
            
                            Agents
        
                - Tripoli; Joseph S.
 
                - Herrera; Carlos M.
 
                - Verlangieri; Patricia A.
 
        
                 
            
         
     
    
        
            
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CPC
        
                 
                - 
                            
US Classifications
        
                            Field of Search
        
                US
 
                    - 313 402
 
                    - 313 403
 
                    - 313 404
 
                    - 313 405
 
                    - 313 406
 
                    - 313 407
 
                    
                 
                - 
                            
International Classifications
        
                 
                - 
                            
            - 
                                    
Disclaimer
Terminal disclaimer                                    Term Extension
227             
        
                 
            
         
     
        
     
    
        
        
    
        
            
        Abstract
A color cathode-ray tube (CRT) having an evacuated envelope with an electron gun therein for generating at least one electron beam is provided. The envelope further includes a faceplate panel having a luminescent screen with phosphor elements on an interior surface thereof. A focus mask, having a plurality of spaced-apart first conductive strands, is located adjacent to an effective picture area of the screen. The spacing between the first conductive strands defines a plurality of apertures substantially parallel to the phosphor elements on the screen. Each of the first conductive strands has a substantially continuous insulating material layer formed on a screen facing side thereof. A plurality of second conductive wires are oriented substantially perpendicular to the plurality of first conductive lines and are bonded thereto by the insulating material layer. The insulating material layer comprises a low porosity lead-zinc-borosilicate glass.             
         
        
            
                    Description
  
    
      
        BACKGROUND OF THE INVENTION
      
    
    
      
        1. Field of the Invention
      
    
    
      
        This invention relates to a color cathode-ray tube (CRT) and, more particularly to a color CRT including a focus mask.
      
    
    
      
        2. Description of the Background Art
      
    
    
      
        A color cathode-ray tube (CRT) typically includes an electron gun, an aperture mask, and a screen. The aperture mask is interposed between the electron gun and the screen. The screen is located on an inner surface of a faceplate of the CRT tube. The screen has an array of three different color-emitting phosphors (e.g., green, blue, and red) formed thereon. The aperture mask functions to direct electron beams generated in the electron gun toward appropriate color-emitting phosphors on the screen of the CRT tube.
      
    
    
      
        The aperture mask may be a focus mask. Focus masks typically comprise two sets of conductive lines (or wires) that are arranged approximately orthogonal to each other, to form an array of openings. Different voltages are applied to the two sets of conductive lines so as to create multipole focusing lenses in each opening of the mask. The multipole focusing lenses are used to direct the electron beams toward the color-emitting phosphors on the screen of the CRT tube.
      
    
    
      
        One type of focus mask is a tensioned focus mask, wherein at least one of the two sets of conductive lines is under tension. Typically, for tensioned focus masks, the vertical set of conductive lines is under tension, with the horizontal set of conductive lines overlying such vertical tensioned lines.
      
    
    
      
        Where the two sets of conductive lines overlap, such conductive lines are typically attached at their crossing points (junctions) by an insulating material. When the different voltages are applied between the two sets of conductive lines of the mask, to create the multipole focusing lenses in the openings thereof, high voltage (HV) flashover may occur at one or more junctions. HV flashover is the dissipation of an electrical charge across the insulating material separating the two sets of conductive lines. HV flashover is undesirable because it may cause an electrical short circuit between the two sets of conductive lines, leading to the subsequent failure of the focus mask.
      
    
    
      
        Also, when the electron beams from the electron gun are directed toward the color-emitting phosphors on the screen, backscattered electrons from the screen may cause the insulator material on the focus mask to accumulate an electrical charge. Such charging is undesirable because it may interfere with the ability of the focus mask to direct the electron beams toward the color-emitting phosphors formed on the screen, as well as cause HV flashover between the conductive lines of the focus mask.
      
    
    
      
        Thus, a need exists for suitable insulating materials that overcome the above-mentioned drawbacks.
      
    
    
      
        SUMMARY OF THE INVENTION
      
    
    
      
        The present invention relates to a color cathode-ray tube (CRT) having an evacuated envelope with an electron gun therein for generating at least one electron beam. The envelope further includes a faceplate panel having a luminescent screen with phosphor elements on an interior surface thereof. A focus mask, having a plurality of spaced-apart first conductive strands, is located adjacent to an effective picture area of the screen. The spacing between the first conductive strands defines a plurality of apertures substantially aligned with the phosphor elements on the screen. Each of the first conductive strands has a substantially continuous insulating material layer formed on a screen facing side thereof. A plurality of second conductive wires are oriented substantially perpendicular to the plurality of first conductive strands and are bonded thereto by the insulating material layer. The insulating material layer comprises a low porosity lead-zinc-borosilicate glass.
      
    
  
  
    
      
        BRIEF DESCRIPTION OF THE DRAWING
      
    
    
      
        The invention will now be described in greater detail, with relation to the accompanying drawing, in which:
      
    
    
      
        
          FIG. 1
        
         is a plan view, partly in axial section, of a color cathode-ray tube (CRT) including a focus mask-frame assembly embodying the present invention;
      
    
    
      
        
          FIG. 2
        
         is a plan view of the focus mask-frame assembly of 
        
          FIG. 1
        
        ;
      
    
    
      
        
          FIG. 3
        
         is a front view of the mask-frame assembly taken along line 
        
          
            3
          
        
        —
        
          
            3
          
        
         of 
        
          FIG. 2
        
        ;
      
    
    
      
        
          FIG. 4
        
         is an enlarged section of the focus mask shown within the circle 
        
          
            4
          
        
         of 
        
          FIG. 2
        
        ;
      
    
    
      
        
          FIG. 5
        
         is a view of the focus mask and the luminescent screen taken along lines 
        
          
            5
          
        
        —
        
          
            5
          
        
         of 
        
          FIG. 4
        
        ; and
      
    
    
      
        
          FIG. 6
        
         is an enlarged view of a portion of the focus mask shown within the circle 
        
          
            6
          
        
         of FIG. 
        
          
            5
          
        
        .
      
    
  
  
    
      
        DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
      
    
    
      
        
          FIG. 1
        
         shows a color cathode-ray tube (CRT) 
        
          
            10
          
        
         having a glass envelope 
        
          
            11
          
        
         comprising a faceplate panel 
        
          
            12
          
        
         and a tubular neck 
        
          
            14
          
        
         connected by a funnel 
        
          
            15
          
        
        . The funnel 
        
          
            15
          
        
         has an internal conductive coating (not shown) that is in contact with, and extends from, a first anode button 
        
          
            16
          
        
         to the neck 
        
          
            14
          
        
        . A second anode button 
        
          
            17
          
        
        , located opposite the first anode button 
        
          
            16
          
        
        , is not contacted by the conductive coating.
      
    
    
      
        The faceplate panel 
        
          
            12
          
        
         comprises a viewing faceplate 
        
          
            18
          
        
         and a peripheral sidewall 
        
          
            20
          
        
        , or skirt, that is sealed to the funnel 
        
          
            15
          
        
         by a glass frit 
        
          
            21
          
        
        . A three-color luminescent screen 
        
          
            22
          
        
         of phosphor elements is coated onto the inner surface of the faceplate 
        
          
            18
          
        
        . The screen 
        
          
            22
          
        
         is a line screen, shown in detail in 
        
          FIG. 5
        
        , that includes a multiplicity of screen elements comprising red-emitting, green-emitting, and blue-emitting phosphor elements, R, G, and B, respectively, arranged in triads, each triad including a phosphor line of each of the three colors. Preferably, a light absorbing matrix 
        
          
            23
          
        
         separates the phosphor elements. A thin conductive layer 
        
          
            24
          
        
        , preferably made of aluminum, overlies the screen 
        
          
            22
          
        
         on the side away from the faceplate 
        
          
            18
          
        
        , and provides means for applying a uniform first anode potential to the screen as well as for reflecting light, emitted from the phosphor elements, through the faceplate 
        
          
            18
          
        
        .
      
    
    
      
        A cylindrical multi-aperture color selection electrode, or focus mask 
        
          
            25
          
        
        , is mounted, by conventional means, within the faceplate panel 
        
          
            12
          
        
        , in predetermined spaced relation to the screen 
        
          
            22
          
        
        . An electron gun 
        
          
            26
          
        
        , shown schematically by the dashed lines in 
        
          FIG. 1
        
        , is centrally mounted within the neck 
        
          
            14
          
        
         to generate and direct three inline electron beams 
        
          
            28
          
        
        , a center and two side or outer beams, along convergent paths through the focus mask 
        
          
            25
          
        
         to the screen 
        
          
            22
          
        
        . The inline direction of the center beam 
        
          
            28
          
        
         is approximately normal to the plane of the paper.
      
    
    
      
        The CRT of 
        
          FIG. 1
        
         is designed to be used with an external magnetic deflection yoke, such as the yoke 
        
          
            30
          
        
        , shown in the neighborhood of the funnel-to-neck junction. When activated, the yoke 
        
          
            30
          
        
         subjects the three electron beams to magnetic fields that cause the beams to horizontally and vertically scan a rectangular raster across the screen 
        
          
            22
          
        
        .
      
    
    
      
        The focus mask 
        
          
            25
          
        
         is formed, preferably, from a thin rectangular sheet of about 0.05 mm (2 mil) thick low carbon steel (about 0.005% carbon by weight). Suitable materials for the focus mask 
        
          
            25
          
        
         may include high expansion, low carbon steels having a coefficient of thermal expansion (CTE) within a range of about 120-160×10
        
          
            −7
          
        
        /° C.; intermediate expansion alloys such as, iron-cobalt-nickel (e.g., KOVAR™) having a coefficient of thermal expansion within a range of about 40-60×10
        
          
            −7
          
        
        /° C.; as well as low expansion alloys such as, iron-nickel (e.g., INVAR™) having a coefficient of thermal expansion within a range of about 9-30×10
        
          
            −7
          
        
        /° C.
      
    
    
      
        As shown in 
        
          FIG. 2
        
        , the focus mask 
        
          
            25
          
        
         includes two horizontal sides 
        
          
            32
          
        
        , 
        
          
            34
          
        
         and two vertical sides 
        
          
            36
          
        
        , 
        
          
            38
          
        
        . The two horizontal sides 
        
          
            32
          
        
        , 
        
          
            34
          
        
         of the focus mask 
        
          
            25
          
        
         are parallel with the central major axis, X, of the CRT while the two vertical sides 
        
          
            36
          
        
        , 
        
          
            38
          
        
         are parallel with the central minor axis, Y, of the CRT.
      
    
    
      
        The focus mask 
        
          
            25
          
        
         (shown schematically by the dashed lines in 
        
          FIG. 2
        
        ) includes an apertured portion that is adjacent to and overlies an effective picture area of the screen 
        
          
            22
          
        
        . Referring to 
        
          FIG. 4
        
        , the focus mask 
        
          
            25
          
        
         includes a plurality of first conductive metal strands 
        
          
            40
          
        
         (conductive lines), each having a transverse dimension, or width, of about 0.3 mm to about 0.5 mm (12-20 mils) separated by spaced apertures 
        
          
            42
          
        
        , each having a width of about 0.27 mm to about 0.43 mm (11-16 mils) that parallel the minor axis, Y, of the CRT and the phosphor elements of the screen 
        
          
            22
          
        
        . For a color CRT having a diagonal dimension of 68 cm, the first metal strands have widths in a range of about 0.30 mm to about 0.38 mm (12-14.5 mils) and an aperture 
        
          
            42
          
        
         width of about 0.27 mm to about 0.33 mm (11-13.3 mils). In a color CRT having a diagonal dimension of 68 cm (27 V), there are about 760 of the first metal strands 
        
          
            40
          
        
        . Each of the apertures 
        
          
            42
          
        
         extends from one horizontal side 
        
          
            32
          
        
         of the mask to the other horizontal side 
        
          
            34
          
        
         thereof (not shown in FIG. 
        
          
            4
          
        
        ).
      
    
    
      
        A frame 
        
          
            44
          
        
        , for the focus mask 
        
          
            25
          
        
        , is shown in 
        
          FIGS. 1-3
        
        , and includes four major members, two torsion tubes or curved members 
        
          
            46
          
        
        , 
        
          
            48
          
        
         and two tension arms or straight members 
        
          
            50
          
        
        , 
        
          
            52
          
        
        . The two curved members 
        
          
            46
          
        
        , 
        
          
            48
          
        
         are parallel to the major axis, X, and each other.
      
    
    
      
        As shown in 
        
          FIG. 3
        
        , each of the straight members 
        
          
            50
          
        
        , 
        
          
            52
          
        
         includes two overlapped partial members or parts 
        
          
            54
          
        
        , 
        
          
            56
          
        
        , each part having an L-shaped cross-section. The overlapped parts 
        
          
            54
          
        
        , 
        
          
            56
          
        
         are welded together where they are overlapped. An end of each of the parts 
        
          
            54
          
        
        , 
        
          
            56
          
        
         is attached to an end of one of the curved members 
        
          
            46
          
        
        , 
        
          
            48
          
        
        . The curvature of the curved members 
        
          
            46
          
        
        , 
        
          
            48
          
        
         matches the cylindrical curvature of the focus mask 
        
          
            25
          
        
        . The horizontal sides 
        
          
            32
          
        
        , 
        
          
            34
          
        
         of the focus mask 
        
          
            25
          
        
         are welded between the two curved members 
        
          
            46
          
        
        , 
        
          
            48
          
        
        , which provides the necessary tension to the mask. Before welding the horizontal sides 
        
          
            32
          
        
        , 
        
          
            34
          
        
         of the focus mask 
        
          
            25
          
        
         to the frame 
        
          
            44
          
        
        , the mask material is pre-stressed and blackened by tensioning the mask material while heating it, in a controlled atmosphere of nitrogen and oxygen, at a temperature of about 500° C., for about 120 minutes. The frame 
        
          
            44
          
        
         and the mask material, when welded together, comprise a mask assembly.
      
    
    
      
        With reference to 
        
          FIGS. 4 and 5
        
        , a plurality of second conductive metal wires (cross wires) 
        
          
            60
          
        
        , each having a diameter of about 0.025 mm (1 mil), are disposed substantially perpendicular to the first metal strands 
        
          
            40
          
        
         and are spaced therefrom by an insulator 
        
          
            62
          
        
        , formed on the screen-facing side of each of the first metal strands 
        
          
            40
          
        
        . The second metal wires 
        
          
            60
          
        
         form cross members that facilitate the application of a second anode, or focusing, potential to the focus mask 
        
          
            25
          
        
        . Suitable materials for the second metal wires include iron-nickel alloys such as INVAR™ and/or carbon steels such as HyMu80 wire (commercially available from Carpenter Technology, Reading, Pa.).
      
    
    
      
        The vertical spacing, or pitch, between adjacent second metal wires 
        
          
            60
          
        
         is about 0.33 mm (13 mils) for a color CRT having a diagonal dimension of 68 cm (27 V). The relatively thin second metal wires 
        
          
            60
          
        
         (as compared to the first metal strands 
        
          
            40
          
        
        ) provide the essential focusing function of the focus mask 
        
          
            25
          
        
        , without adversely affecting the electron beam transmission thereof. The focus mask 
        
          
            25
          
        
        , described herein, provides a mask transmission, at the center of the screen 
        
          
            22
          
        
        , of about 40-45%, and requires that the second anode, or focussing, voltage, ΔV, applied to the second metal wires 
        
          
            60
          
        
        , differs from the first anode voltage applied to the first metal strands 
        
          
            40
          
        
         by less than about 1 kV, for a first anode voltage of about 30 kV.
      
    
    
      
        The insulators 
        
          
            62
          
        
        , shown in 
        
          FIG. 4
        
        , are disposed substantially continuously on the screen-facing side of each of the first metal strands 
        
          
            40
          
        
        . The second metal wires 
        
          
            60
          
        
         are bonded to the insulators 
        
          
            62
          
        
         to electrically isolate the second metal wires 
        
          
            60
          
        
         from the first metal strands 
        
          
            40
          
        
        .
      
    
    
      
        The insulators 
        
          
            62
          
        
         are formed of a suitable material that has a thermal expansion coefficient that is matched to the material of the focus mask 
        
          
            25
          
        
        . The material of the insulators 
        
          
            62
          
        
         should preferably have a relatively low melting temperature so that it may flow, harden, and adhere to both the first metal strands 
        
          
            40
          
        
         and the second metal wires 
        
          
            60
          
        
        , within a temperature range of about 450° C. to about 500° C. The insulator material should also preferably have a dielectric breakdown strength of about 40000 V/mm (1000 V/mil), with bulk and surface electrical resistivities of about
      
    
    
      
        10
        
          
            11 
          
        
        ohm-cm and 10
        
          
            12 
          
        
        ohm/square, respectively. Additionally, the insulator material should be stable at temperatures used for sealing the CRT faceplate panel 
        
          
            12
          
        
         to the funnel (temperatures of about 450° C. to about 500° C.), as well as having adequate mechanical strength and elastic modulus, and be low outgassing during processing and operation for an extended period of time under electron beam bombardment.
      
    
    
      
        The insulators 
        
          
            62
          
        
         are formed of a low porosity lead-zinc-borosilicate glass. The low porosity lead-zinc-borosilicate glass was formed using a lead-zinc-borosilicate glass powder having a median particle size less than about 1 μm.
      
    
    
      
        The use of a median particle size less than about 1 μm increases the packing density of the insulator material, reducing the crystallite size therein. It is believed that reducing the crystallite size in the insulator material also reduces radiation damaged regions therein, such that charge accumulation under electron beam bombardment is reduced.
      
    
    
      
        The smaller median particle size for the lead-zinc-borosilicate glass additionally provides a substantially smooth surface for the insulators. It is believed that the substantially smooth surface is advantageous for insulator behavior, since sharp features are minimized, thereby reducing the number of initiation points for HV breakdown.
      
    
    
      
        The low porosity lead-zinc-borosilicate glass optionally includes one or more transition metal oxides. The one or more transition metal oxides can either be melted with the lead-zinc-borosilicate glass or mixed together with a lead-zinc-borosilicate glass powder. The addition of the one or more transition metal oxides to the low porosity lead-zinc-borosilicate glass is believed to slightly increase the electrical conductivity of the insulator material, such that it does not accumulate charge under electron beam bombardment.
      
    
    
      
        The weight percent of the one or more transition metal oxides in the low porosity lead-zinc-borosilicate glass is used to control the electrical conductivity of the insulator material. The weight percent of the one or more transition metal oxides in the low porosity lead-zinc-borosilicate glass is preferably within a range of about 2% by weight to about 12% by weight.
      
    
    
      
        Suitable lead-zinc-borosilicate glasses include SCC-11 glass powder commercially available from SEM-COM, Toledo, Ohio. The SCC-11 glass powder, as purchased, typically has a median particle size of about 3.5 μm. The 3.5 μm SCC-11 glass powder may be milled to reduce the median particle size thereof to less than about 1.0 μm.
      
    
    
      
        Suitable transition metal oxides include iron oxides (Fe
        
          
            2
          
        
        O
        
          
            3 
          
        
        and Fe
        
          
            3
          
        
        O
        
          
            4
          
        
        ), molybdenum oxide (MoO
        
          
            3
          
        
        ), titanium oxide (TiO
        
          
            2
          
        
        ), zinc oxide (ZnO), chromium oxide (Cr
        
          
            2
          
        
        O
        
          
            3
          
        
        ), nickel oxide (NiO), and tin oxide (SnO
        
          
            2
          
        
        ), among others.
      
    
    
      
        According to a preferred method of making the focus mask 
        
          
            25
          
        
        , and referring to 
        
          FIG. 6
        
        , a first coating of the insulator 
        
          
            64
          
        
         is provided, e.g., by spraying, onto the screen-facing side of the first metal strands 
        
          
            40
          
        
        . The first metal strands 
        
          
            40
          
        
        , in this example, are formed of flat tension mask steel (FTM), having a coefficient of thermal expansion within the range of 110-150×10
        
          
            −7
          
        
        /° C. The first insulator coating, for example, may be a low porosity lead-zinc-borosilicate glass having a mean particle size of less than about 1 μm. The first coating of the insulator typically has a thickness of about 0.05 mm to about 0.09 mm (2-3.5 mils).
      
    
    
      
        The frame 
        
          
            44
          
        
        , including the coated first metal strands 
        
          
            40
          
        
        , is dried at room temperature. After drying, the first coating of the insulator material 
        
          
            64
          
        
         is hardened (sintered) by heating the frame and the first metal strands 
        
          
            40
          
        
        , in an oven. The frame 
        
          
            44
          
        
         is heated over a period of about 30 minutes to a temperature of about 250° C., and held at 250° C., for about 20 to 60 minutes. This first dwell step removes organic substances added to the insulator suspension.
      
    
    
      
        After the first dwell step, the temperature of the oven is increased to about 420° C. over a period of about 20 minutes, and held at that temperature for about one hour to melt and crystallize the first coating of the insulator material 
        
          
            64
          
        
         on the first metal strands 
        
          
            40
          
        
        . Thereafter, the temperature of the oven is increased to about 460° C. and held at that temperature for about 30 minutes to stabilize the structure for subsequent tube fabrication steps. The first coating of the insulator material 
        
          
            64
          
        
        , after crystallization, will typically not remelt at normal process temperatures. The first coating of the insulator material 
        
          
            64
          
        
         is typically dome-shaped and has a thickness within a range of about 0.05 mm to about 0.09 mm (2-3.5 mils) across each of the strands 
        
          
            40
          
        
        .
      
    
    
      
        After the first coating of the insulator material 
        
          
            64
          
        
         is fired, a second coating of the insulator material 
        
          
            66
          
        
         is applied over the first coating of the insulator material 
        
          
            64
          
        
        . The second coating of the insulator material 
        
          
            66
          
        
         may have the same composition as the first coating. The second coating of the insulator material 
        
          
            66
          
        
         has a thickness of about 0.005 mm to about 0.025 mm (0.2-1 mil).
      
    
    
      
        Thereafter, the second metal wires 
        
          
            60
          
        
         are applied to the frame 
        
          
            44
          
        
        , over the second coating of the insulator material 
        
          
            66
          
        
        , such that the second metal wires 
        
          
            60
          
        
         are substantially perpendicular to the first metal strands 
        
          
            40
          
        
        . The second metal wires 
        
          
            60
          
        
         are applied using a winding fixture (not shown) that accurately maintains a desired spacing of for example, about 0.33 mm (13 mils) between adjacent metal strands for a color CRT having a diagonal dimension of about 68 cm (27 V).
      
    
    
      
        The frame 
        
          
            44
          
        
        , including the winding fixture, is heated to bond the second metal wires to the second coating of the insulator material 
        
          
            66
          
        
        . The second coating of the insulator material 
        
          
            66
          
        
         is heated according to the same process temperatures described above with reference to the first coating of the insulator material 
        
          
            64
          
        
        .
      
    
    
      
        After the second coating of the insulator material is sintered, the frame 
        
          
            44
          
        
         is taken out of the holding device, electrical connections are made to the first and second strands 
        
          
            40
          
        
        , 
        
          
            60
          
        
        , and the focus mask 
        
          
            25
          
        
         is inserted into a tube envelope.
      
    
  
             
            
                        Claims
        
                - 1. A cathode-ray tube comprising an evacuated envelope having therein an electron gun for generating at least one electron beam, a faceplate panel having a luminescent screen with phosphor elements on an interior surface thereof, and a focus mask, wherein the focus mask includes a plurality of spaced-apart first conductive strands having an insulating material thereon, and a plurality of spaced-apart second conductive wires oriented substantially perpendicular to the plurality of spaced-apart first conductive strands, the plurality of spaced-apart second conductive wires being bonded to the insulating material, wherein the insulating material comprises a low porosity lead-zinc-borosilicate glass powder having a median particle size less than about 1 μm.
 
                - 2. The cathode-ray tube of claim 1 wherein the low porosity lead-zinc-borosilicate glass includes one or more transition metal oxides.
 
                - 3. The cathode-ray tube of claim 2 wherein the one or more transition metal oxides are selected from the group consisting of iron oxide Fe2O3 and Fe3O4), titanium oxide (TiO2), zinc oxide (ZnO), molybdenum oxide (MoO3), chromium oxide (Cr2O3), tin oxide (SnO2), nickel oxide (NiO), and combinations thereof.
 
                - 4. The cathode-ray tube of claim 2 wherein the one or more transition metal oxides in the low porosity lead-zinc-borosilicate glass have a weight % in a range of about 2% by weight to about 12% by weight.
 
                - 5. The cathode-ray tube of claim 2 wherein the low porosity lead-zinc-borosilicate glass is SCC-11, or a mixture of lead, zinc, boron, and silicon oxides melted together to form an SCC-11 like glass.
 
                - 6. The cathode-ray tube of claim 2 wherein the one or more transition metal oxides are added to the lead-zinc-borosilicate glass either by premelting or by mixing them with a lead-zinc-borosilicate powder.
 
        
                
                
                
                
                
                            US Referenced Citations (6)