Claims
- 1. An aqueous hair rinse antistatic composition consisting essentially of: a hair treatment substance and a cationic antistatic agent present in an antistatic effective amount, which agent is an epoxidized, aminated, 1,3-diene salt cationic polymer that is the reaction product of:
- (1) a 1,3-diene homopolymer or predominantly 1,3-diene copolymer, having at least 10 1,3-diene units per molecule, in which at least 10% of the double bonds present have been epoxidized, and which contains about 3-6% by weight of epoxide oxygen; which has been aminated with
- (2) amine of the formula R.sup.1 NR.sup.2 R.sup.3 wherein: R.sup.1 is a C.sub.1-4 alkyl, or a C.sub.2-4 hydroxyalkyl; and R.sup.2 and R.sup.3 are the same or different and are hydrogen, C.sub.1-4 alkyl, or a C.sub.2-4 hydroxyalkyl; or an amine selected from the group consisting of morpholine, piperidine, and piperazine; and converted to a salt by
- (3) (a) reacting the aminated epoxidized 1,3-diene polymer with an acid which is a C.sub.1-7 carboxylic acid or a mineral acid; or (b) alkylating the aminated epoxidized 1,3-diene polymer with 3-chloro-2-hydroxypropyl trimethyl ammonium chloride or with RCl, RBr, or R.sup.2 SO.sub.4 wherein R is methyl or ethyl, to form a quarternary ammonium salt; or (c) quaternizing the aminated epoxidized 1,3-diene polymer with ethylene oxide, propylene oxide, glycidol, or glycidyl trimethylammonium chloride; and then further reacting the resulting quaternary ammonium salt with an acid which is a C.sub.1-7 carboxylic acid or a mineral acid.
- 2. An aqueous hair raise antistatic composition according to claim 1, wherein the -,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer of 1,3-butadiene, 1,3-pentadiene, isoprene, or chloroprene; or is a copolymer of two or more of 1,3-butadiene, 1,3-pentadiene, isoprene, chloroprene, ethylene, propylene, styrene, and an acrylic acid derivative.
- 3. An aqueous hair rinse antistatic composition according to claim 2, wherein more than 50% of the double bonds of the 1,3-diene homopolymer or predominantly 1,3-diene copolymer are in a cis 1,4-configuration
- 4. An aqueous hair rinse antistatic composition according to claim 2, wherein the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer or copolymer of butadiene and is liquid under ambient conditions.
- 5. An aqueous hair rinse antistatic composition according to claim 4, wherein the homopolymer or copolymer of butadiene has a viscosity of about 3 poises at 20.degree. C. when measured by the method of DIN 53.015.
- 6. An aqueous hair rinse antistatic composition according to claim 1, wherein epoxidation of the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is by reaction with peracetic acid.
- 7. An aqueous hair rinse antistatic composition according to claim 1, wherein the amine is methylamine, ethylamine, isopropylamine, ethanolamine, dimethylamine, diethylamine, diethanolamine, morpholine, piperidine, piperazine, trimethylamine, triethylamine, triethanolamine, or N,N-dimethylethanolamine.
- 8. An aqueous hair rinse antistatic composition according to claim 7, wherein the amine is dimethylamine, ethanolamine, methyl amine, or morpholine.
- 9. An aqueous hair rinse antistatic composition according to claim 1, wherein step (3)(a) or step (3)(c) is used and the acid is acetic acid, lactic acid, glycolic acid, or hydrochloric acid.
- 10. An aqueous hair rinse antistatic composition according to claim 9, wherein step (3)(c) is used and the quaternizing is with ethylene oxide.
- 11. An aqueous hair rinse antistatic composition according to claim 1, wherein:
- (A) the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer of 1,3-butadiene, 1,3-pentadiene, isoprene, or chloroprene; or is a copolymer of two or more of 1,3-butadiene, 1,3-pentadiene, isoprene, chloroprene, ethylene, propylene, styrene, and an acrylic acid derivative;
- (B) the amine is methylamine, ethylamine, isopropylamine, ethanolamine, dimethylamine, diethylamine, diethanolamine, morpholine, piperidine, piperazine, trimethylamine, triethylamine, triethanolamine, or N,N-dimethylethanolamine; and
- (C) the acid is acetic acid, lactic acid, glycolic acid, or hydrochloric acid.
- 12. An aqueous hair rinse antistatic composition according to claim 1, wherein:
- (A) the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer or copolymer of butadiene that is liquid under ambient conditions, and more than 50% of the double bonds of the homopolymer or copolymer of butadiene are in a cis 1,4-configuration;
- (B) the amine is dimethylamine, monoethylamine, methylamine, or morpholine;
- (C) the acid is hydrochloric acid;
- (D) the alkylating agent is 3-chloro-2-hydroxyethyltrimethylammonium chloride; and
- (E) the quaternizing is with glycidyl trimethyl ammonium chloride.
- 13. An aqueous hair rinse antistatic composition according to claim 1, wherein:
- (A) the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer or copolymer of butadiene that is liquid under ambient conditions, and more than 50% of the double bonds of the homopolymer or copolymer of butadiene are in a cis 1,4-configuration;
- (B) the amine is morpholine; and
- (C) the aminated epoxidized 1,3-diene homopolymer or copolymer of butadiene is reacted with hydrochloric acid to form a salt.
- 14. An aqueous hair rinse antistatic composition according to claim 1, wherein:
- (A) the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer or copolymer of butadiene that is liquid under ambient conditions, and more than 50% of the double bonds of the homopolymer or copolymer of butadiene are in a cis 1,4-configuration;
- (B) the amine is morpholine; and
- (C) the aminated epoxidized homopolymer or copolymer of butadiene is quaternized with glycidyl trimethylammonium chloride and is then further reacted with hydrochloric acid to form a water soluble salt.
- 15. An aqueous hair rinse antistatic composition according to claim 1, wherein
- (A) the 1,3-diene homopolymer or predominantly 1,3-diene copolymer is a homopolymer or copolymer of butadiene that is liquid under ambient conditions, and more than 50% of the double bonds of the homopolymer or copolymer of butadiene are in a cis 1,4-configuration;
- (B) the amine is dimethylamine; and
- (C) the aminated epoxidized homopolymer or copolymer of butadiene is alkylated with ethylene oxide and then further reacted with hydrochloric acid to form a water soluble salt.
- 16. An aqueous hair rinse antistatic composition according to claim 1, wherein the cationic antistatic agent is present in about 0.1 to about 10% by weight, based on the total weight of the composition.
- 17. An aqueous hair rinse antistatic composition according to claim 16, wherein the cationic antistatic agent is present in about 0.5 to about 5% by weight, based on the total weight of the composition.
- 18. A method for imparting an antistatic effect to hair, comprising rinsing the hair with a hair rinse effective amount of a composition according to claim 1.
- 19. A method for imparting an antistatic effect to hair, comprising rinsing the hair with a hair rinse effective amount of a composition according to claim 12.
- 20. A method for imparting an antistatic effect to hair, comprising rinsing the hair with a hair rinse effective amount of a composition according to claim 13.
Priority Claims (1)
Number |
Date |
Country |
Kind |
3305964 |
Feb 1983 |
DEX |
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Parent Case Info
This application is a continuation of application Ser. No. 667,383, filed Nov. 1, 1984, now abandoned which is a continuation of Ser. No. 525,972 filed Aug. 24, 1983, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
3626029 |
Young |
Dec 1971 |
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Foreign Referenced Citations (6)
Number |
Date |
Country |
958644 |
Dec 1974 |
CAX |
1021264 |
Nov 1977 |
CAX |
1022075 |
Dec 1977 |
CAX |
1342269 |
Mar 1974 |
GBX |
2067196 |
Jul 1981 |
GBX |
1602560 |
Nov 1981 |
GBX |
Non-Patent Literature Citations (3)
Entry |
Chem. Abstracts, vol. 76, 1972, 100692q, Young, David W. |
Chem. Abstracts, vol. 95, 1981, 12570k, Ajinomoto Co. Inc. |
Ajinomoto Co., Inc. cited in Chem. Abstracts vol. 95, 12570k, 1981, *cited and supplied in parent Ser. No. 525972. |
Continuations (2)
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Number |
Date |
Country |
Parent |
667383 |
Nov 1984 |
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Parent |
525972 |
Aug 1983 |
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