The invention relates to a cement production plant and a method for producing cement clinker, wherein inert gas is introduced into at least one combustion process.
It is known from the prior art to feed oxygen-containing gas for the combustion of carbonaceous fuel into the rotary furnace or the calciner of a cement production plant. In order to reduce the amount of exhaust gas and to be able to dispense with complex purification processes, it is known, for example, from DE 10 2018 206 673 A1 to use a combustion gas that is as rich in oxygen as possible so that the CO2 content in the exhaust gas is high, Document DE 10 2018 206 673 A1 discloses the introduction of an oxygen-rich gas into the cooler inlet region for preheating the gas and cooling the clinker.
When using oxygen-enriched combustion gases that have a high oxygen content of at least 30% to 100%, very high temperatures can occur in the calciner and the furnace. If these high temperatures occur for a longer period of time or permanently in the region near the wall of the calciner, this can result in damage to the inner wall of the calciner. When hot zones occur in combination with the hot meal introduced, melting phases of the hot meal to be calcined are also to be expected. Based on this, it is the object of the present invention to provide a cement production plant and a method for producing cement, wherein a safe operation of the furnace line is ensured and at the same time an exhaust gas with a high CO2 content is obtained. An extended object is to charge the preheated raw meal into the calciner in an evenly distributed manner and to bring it into interaction with the hot gases produced as a result of the calciner firing. A preferred object of the invention is to realize the calciner firing by the targeted introduction of fuels, oxygen-containing gases, and hot raw meal in a staged form, so that a complete conversion of the introduced fuels, a complete calcination of the introduced raw meal particles, and the transport of the solid particles along the riser of the calciner are ensured without overheating in the riser and agglomeration of the solid particles along the riser.
In accordance with the invention, this object is achieved by a cement production plant having the features of independent Device claim 1 and by a method having the features of independent Method claim 12. Advantageous developments can be found in the dependent claims.
According to one aspect of the invention, a cement production plant comprises:
wherein the calciner and the furnace each have at least one respective fuel inlet for admitting fuel into the calciner and into the furnace.
The calciner and the furnace each have at least one respective inert gas inlet for respectively admitting inert gas into the calciner and the furnace.
The preheater of the cement production plant preferably comprises a plurality of cyclone stages, each with at least one cyclone for separating solids from the gas flow. The invention makes it possible to operate the preheater with a significantly lower gas volume compared to a cement production plant that uses air as combustion gas. For example, the exhaust gas volume flow after the preheater is about 0.50 to 0.90 Nm3/kg clinker. The ratio of the feed quantity of raw meal to exhaust gas is accordingly higher possibly than in plants that are operated with air and is, for example, up to 3 kg/kg solids to gas, preferably 1.3 to 1.9 kg/kg solids to gas. In the preheater, the raw meal fed to the uppermost, first cyclone stage is preheated in counterflow to the furnace exhaust gases and passes here through the cyclone stages one after the other.
Between the last and the penultimate cyclone stage, the calciner is arranged, which has a riser into which the raw meal is heated by means of a calciner firing, which may consist of one or more firing positions. The calciner preferably comprises a fuel charging apparatus comprising the fuel inlet and the inert gas inlet. The fuel charging apparatus is for example tubular or formed as a radial bulge on the riser pipe of the calciner, Preferably, the fuel charging apparatus opens out into the riser pipe of the calciner so that fuel and/or inert gas are fed into the riser pipe of the calciner via the fuel charging apparatus. The fuel charging apparatus is a thermal treatment chamber that is used for heating and controlled addition of fuel into the riser.
Advantageously, the solids-to-gas ratio in the calciner is significantly higher compared to conventional systems with air as the oxidizer. For example, solids loadings of more than 2 kg per kg of gas occur locally, for example 2 to 8 kg per kg of gas. In the calciner, preferably the largest part, more than 60%, for example about 80%, of the fuel heat is converted. Due to the raw meal introduced at the lower end of the calciner, despite an initial oxygen concentration of 40-80%, which initiates intensive firing, there is a sufficient heat sink to prevent overheating. If lumpy substitute fuel, for example with edge lengths of >100 mm, is to be burned, an inclined region with a higher residence time for the fuel should preferably be provided. Examples of such inclined regions are stair treads, push grates, push-back grates or other mechanical or pneumatic devices. These devices function, for example, as combustion chambers, pre-combustion chambers or serve only for drying and preheating or partial gasification of the introduced fuels. The fuels can be of any type with regard to their particle size distribution and calorific value.
For example, the calcination reaction takes place under CO2 partial pressures between 10%-60% at the beginning of the calciner and up to 98% at the end of the calciner. Accordingly, the calcination reaction preferably proceeds at higher temperatures of 700 to 1100° C., preferably 900-1000° C., than in the conventional plant.
The raw meal preheated in the preheater and calcined in the calciner is then fed to the furnace. The furnace is preferably a rotary furnace with a rotary tube that can be rotated about its longitudinal axis and is preferably slightly inclined in the direction of conveyance of the material to be fired, so that the material is moved in the direction of conveyance due to the rotation of the rotary tube and gravity. The furnace preferably has a material inlet at one end thereof for admitting preheated, calcined raw meal and a material outlet at its end opposite the material inlet for discharging the fired clinker into the cooler. At the end of the furnace on the material outlet side, there is preferably a furnace head comprising the furnace burner for firing the material and preferably at least one fuel inlet for admitting fuel into the furnace, preferably via a furnace burner and/or via a fuel lance. The furnace preferably comprises a sintering zone in which the material is at least partially melted and in particular has a temperature of 1500° C. to 1900° C., preferably 1450° C. to 1750° C. The sintering zone comprises, for example, the furnace head, preferably the rear third of the furnace in the direction of conveyance of the material.
For example, all or part of the oxygen-containing combustion gas is introduced directly into the furnace head, wherein the furnace head has, for example, a combustion gas inlet. Preferably, the combustion gas is fully or partially introduced into the furnace via the material outlet of the furnace. The combustion gas supplied to the furnace has, for example, an oxygen content of more than 30% to 75%, preferably more than 95%. For example, the combustion gas consists entirely of pure oxygen, wherein in this case the oxygen content of the combustion gas is 100%. The furnace burner may be, for example, a burner lance. The cooler for cooling the cement clinker is preferably connected to the material outlet of the furnace.
The cooler has a conveying device for conveying the bulk material in the direction of conveyance through the cooling gas chamber. The cooling gas chamber comprises a first cooling gas chamber portion with a first cooling gas flow and, adjoining this in the direction of conveyance of the bulk material, a second cooling gas chamber portion with a second cooling gas flow. The cooling gas chamber is preferably bounded at the top by a cooling gas chamber ceiling and at the bottom by a dynamic and/or static grate, preferably by the bulk material lying thereon. The cooling gas chamber is in particular the entire chamber of the cooler above the bulk material through which cooling gas flows. The cooling gas flow passes through the dynamic and/or static grate, in particular through the conveying device, through the bulk material and into the cooling gas chamber. The first cooling gas chamber portion is preferably arranged, in the direction of flow of the bulk material to be cooled, directly after the cooler inlet, in particular the material outlet of the furnace. Preferably, the clinker falls out of the furnace into the first cooling gas chamber portion.
The first cooling chamber portion preferably has a static grate and/or dynamic grate arranged below the material outlet of the furnace so that the clinker exiting the furnace falls onto the static grate due to gravity. Preferably, only the first cooling gas flow flows into the first cooling gas chamber portion and is accelerated, for example, by means of a fan or pressure-loaded boiler or corresponding other device. The second cooling gas chamber portion adjoins the first cooling gas chamber portion in the direction of conveyance of the bulk material and is preferably separated from the first cooling gas chamber portion in terms of gas by means of a separating device. Preferably, only the second cooling gas flow, which is accelerated by means of at least one fan, flows into the second cooling gas chamber portion.
The second cooling gas chamber portion preferably has a dynamic grate for conveying the bulk material through the cooling gas chamber. The first cooling gas flow flowing through the first cooling gas chamber portion is, for example, pure oxygen or a gas with a content of less than 35 vol %. in particular less than 21 vol %, preferably 15 vol % or less of nitrogen and/or argon and/or with an oxygen content of more than 20.5%, in particular more than 30% to 75%, preferably more than 95%. The first cooling gas chamber portion preferably connects directly to the material outlet of the furnace, preferably to the furnace head of the furnace, so that the cooling gas is heated in the cooler and subsequently flows into the rotary furnace and is used as combustion gas. The second cooling gas flow is, for example, air.
The cooler preferably has a separating device for separating the cooling gas chamber portions from each other in terms of gas.
The inert gas is for example CO2 or water vapour. The introduction of inert gas into the calciner and/or the furnace offers the advantage of delaying, in particular slowing down, the combustion so that damage to the furnace and/or the calciner is prevented.
According to a first embodiment, the fuel inlet and the inert gas inlet are arranged separately from one another and each form an inlet into the furnace and/or the calciner. For example, the inert gas inlet is formed as an annular inlet around the fuel inlet. The conduit for conducting the fuel and the inert gas is formed, for example, as a double pipe, preferably as concentric pipes with different diameters. Preferably, the inert gas is conducted directly in the vicinity of the fuel inlet or the fuel charging apparatus. This enables an economical supply of the costly inert gas.
According to a further embodiment, the fuel inlet and the inert gas inlet together form an inlet. The fuel and the inert gas are preferably each fed to the calciner or the furnace in a common line. This is constructively less complex and thus more cost-effective.
According to a further embodiment, the calciner and/or the furnace have/has a respective plurality of inert gas inlets, in particular for admitting different inert gases. R is also conceivable that the calciner has a plurality of fuel charging apparatuses, in particular two or three fuel charging apparatuses, each of which is assigned an inert gas inlet. The fuel charging apparatuses are preferably arranged at a distance from one another along the length and/or width of the riser. For example, the fuel charging apparatuses are arranged offset from one another at an angle of 0°, preferably 60° to 270° across the cross section of the riser of the calciner. Different types of fuel charging apparatuses can be combined with each other and also arranged differently.
According to a further embodiment, the calciner has at least one raw meal inlet for admitting raw meal into the calciner, said raw meal inlet being arranged upstream of the fuel inlet and the inert gas inlet in the direction of flow of the gas within the calciner. For example, the raw meal inlet is located between two fuel charging apparatuses or fuel inlets in the calciner. Preferably, at least one raw meal inlet is arranged upstream of the fuel inlet in the direction of flow. This prevents overheating of the raw meal. The combustion zone created by the calciner firing can deliver the heat directly to the particles of the raw meal. The inert gas preferably additionally serves as a temperature sink and also prevents spontaneous ignition of the introduced fuel directly at the burner or burner lance mouth or at the inlet of the fuel charging apparatus.
According to a further embodiment, the calciner has at least one, preferably two or more raw meal inlets for admitting raw meal into the calciner and wherein at least one of the raw meal inlets and preferably at least one fuel inlet is arranged upstream of the fuel inlet, in particular upstream of the fuel charging apparatus, in the direction of flow of the gas within the calciner riser. Preferably, at least one or all of the raw meal inlets is arranged upstream of one or all of the fuel inlets. For example, the raw meal inlet is arranged at a distance from the fuel charging apparatus in the calciner.
According to a further embodiment, the cement production plant comprises a control device which is connected to a temperature measuring device within the calciner and which is configured in such a way that it controls/regulates the quantity of raw meal, inert gas and/or fuel in the calciner in dependence on the temperature ascertained by the temperature measuring device. The temperature measuring device is preferably connected to the control device in such a way that it transmits the ascertained temperature to the control device. The temperature measuring device is arranged, for example, downstream of one of the fuel charging apparatuses. The calciner has, for example, a plurality of temperature measuring devices, each of which is connected to the control device for transmitting the ascertained temperature. For example, a temperature measuring device is connected downstream of each fuel charging apparatus. It is also conceivable that a plurality of temperature measuring devices are arranged within the riser of the calciner, preferably evenly distributed.
For example, the quantity of fuel in the individual fuel charging apparatuses is controlled depending on the temperature. This ensures even and controlled combustion within the calciner with a homogenized temperature distribution and avoids temperature peaks that can damage the calciner or cause the material to melt.
The control device is designed, for example, in such a way that it compares the ascertained temperature with a predetermined setpoint value and, if the ascertained temperature deviates from the setpoint value, it controls the quantity of fuel, the quantity of inert gas and/or the quantity of raw meal in the calciner. If the ascertained temperature exceeds the predetermined setpoint, for example, the control device is designed in such a way that it reduces the fuel quantity, increases the raw meal quantity and/or increases the inert gas quantity. If the ascertained temperature falls below the predetermined setpoint, for example, the control device is designed in such a way that it increases the fuel quantity, reduces the raw meal quantity and/or reduces the inert gas quantity.
According to a further embodiment, at least one cross-sectional constriction of the calciner cross section is configured within the calciner. For example, the calciner has a plurality of cross-sectional constrictions in the riser. This accelerates the flow within the riser and then slows it down, so that flow-calmed regions are preferably formed.
According to a further embodiment, at least one guide element for guiding the gas flow is arranged within the calciner. This preferably achieves better mixing of the gas with the raw meal. This function is of particular importance for process control with high oxygen and low nitrogen contents in that the reduced gas quantity in the calciner due to the lack of nitrogen content results in a higher loading after the material has been fed in than in systems operated with air as the oxidant. It is therefore advantageous for the load-bearing capacity of the particles if the material is distributed evenly over the cross section of the riser of the calciner, Sinking of the meal into a deeper downstream zone of the calciner riser is prevented. The guide element is designed, for example, as a plate, a box, a cone and/or a pyramid. Preferably, a plurality of guide elements are arranged within the riser, for example evenly spaced apart. The guide elements are made of ceramic or a ceramic fibre composite material, for example. The guide elements are arranged in particular within the riser and/or in the fuel charging apparatus. Preferably, a guide element is arranged at the outlet of the fuel charging apparatus into the riser, so that the inlet of fuel into the riser is guided by means of the guide element. Preferably, the guide element extends from the fuel charging apparatus into the riser, For example, the guide element is formed and arranged to guide the fuel at an angle to the inner wall of the riser. For example, the guide element forms a diffuser with a widening cross section relative to the fuel charging apparatus.
According to a further embodiment, the calciner has a plurality of fuel charging apparatuses which each comprise a fuel inlet and an inert gas inlet, and wherein a guide element is assigned to each fuel charging apparatus. The respective fuel charging apparatus is arranged, for example, at the same height level as the guide element or is connected directly upstream or downstream of the guide element. This allows an optimized distribution of the raw meal and the inert gas within the riser, in particular in the region of the fuel charging apparatus.
According to a further embodiment, a combustion chamber is arranged between the furnace and the calciner or only in the calciner, said combustion chamber having a meal inlet, a fuel inlet, for example a fuel charging apparatus, and an inert gas inlet. The combustion chamber has, for example, a round cross section or is cyclone-shaped. It is also conceivable that the combustion chamber is designed as a calciner reaction chamber for simultaneous calcination, so that two calciners are connected in series or in parallel. This provides for regulation of the fuel conversion and calcination within the calciner or calciners.
The invention also comprises a method for producing cement clinker, comprising the following steps:
An inert gas is supplied to each of the furnace and the calciner.
The above-described embodiments and advantages of the cement production plant also apply to the method for producing cement clinker.
According to a further embodiment, the inert gas is supplied to the calciner and/or to the furnace together with or separately from the fuel and/or the raw meal. For example, at least two different inert gases are introduced into the calciner and/or the furnace.
According to a further embodiment, the raw meal is admitted into the calciner in the direction of flow of the gas within the calciner prior to the fuel and the inert gas. For example, at least part of the raw meal and the fuel is admitted into the calciner in the direction of flow of the gas within the calciner upstream of a fuel charging apparatus. Preferably, the raw meal has a temperature of 700 C to 900° C. when admitted into the calciner.
According to a further embodiment, the temperature within the calciner is ascertained and the quantity of raw meal, inert gas and/or fuel that is supplied to the calciner is controlled/regulated in dependence on the ascertained temperature.
According to a further embodiment, a flow-calmed region is configured within the calciner by means of at least one guide element or at least one cross-sectional constriction of the calciner cross section.
The invention is explained in more detail below by means of several exemplary embodiments with reference to the accompanying figures.
The preheater 12 comprises a plurality of cyclones 20 for separating the raw meal from the raw meal gas flow. By way of example, the preheater 12 has five cyclones 20 arranged in four cyclone stages one below the other. The preheater 12 has a material inlet, not shown, for admitting raw meal into the uppermost cyclone stage of the preheater 12 comprising two cyclones 20. The raw meal successively flows through the cyclones 20 of the cyclone stages in counterflow to the furnace and/or calciner exhaust gas and is thereby heated. The calciner 14 is arranged between the last and the penultimate cyclone stage. The calciner 14 has a riser, in particular a riser pipe, with at least one calciner firing for heating the raw meal, so that calcination of the raw meal takes place in the calciner 14. Furthermore, the calciner 14 comprises a fuel inlet for admitting fuel and an inert gas inlet for admitting an inert gas into the riser. The calciner 14 further comprises a combustion gas inlet 26 for admitting oxygen-containing combustion gas into the riser of the calciner 14. The combustion gas is in particular the furnace exhaust gas enriched with oxygen. The oxygen content of the combustion gas is at most 85% between the furnace 16 and the calciner 14. The calciner exhaust gas is introduced into the preheater 12, preferably into the penultimate cyclone stage, and leaves the preheater 12 downstream of the uppermost cyclone stage as preheater exhaust gas 22.
The furnace 16 is connected downstream of the preheater 12 in the direction of flow of the raw meal, so that the raw meal preheated in the preheater 12 and calcined in the calciner 14 flows into the furnace 16. The material inlet/gas outlet 25 of the furnace 16 is directly connected to the riser of the calciner 14, so that the furnace exhaust gas flows into the calciner 14 and then into the preheater 12. The furnace 16 is, by way of example, a rotary furnace with a rotary tube rotatable about its longitudinal axis and arranged at a slight downward angle. The furnace 12 has a furnace burner 28 and an assigned fuel inlet 30 at the material outlet end within the rotary furnace tube. The material outlet of the furnace 16 is located at the opposite end of the rotary tube from the material inlet 25, such that the raw meal is conveyed within the rotary tube by rotation of the rotary tube towards the furnace burner 28 and the material outlet. The raw meal is fired within the furnace 16 to form cement clinker. The sintering zone 32 comprises the rear region of the rotary tube on the material outlet side, preferably the rear third in the direction of material flow.
The cooler 18 for cooling the clinker is connected to the material outlet of the furnace 16. The cooler 18 has a cooling gas chamber 34 in which the clinker is cooled by a cooling gas flow. The clinker is conveyed in a direction of conveyance F through the cooling gas chamber 34. The cooling gas chamber 34 has a first cooling gas chamber portion 36 and a second cooling gas chamber portion 38, which adjoins the first cooling gas chamber portion 36 in the direction of conveyance F. The furnace 16 is connected to the cooler 18 via the material outlet of the furnace 16, so that the clinker fired in the rotary furnace 20 falls into the cooler 18.
The first cooling gas chamber portion 36 is arranged below the material outlet of the furnace 16, so that the clinker from the furnace 16 falls into the first cooling gas chamber portion 36. The first cooling gas chamber portion 36 constitutes an inflow region of the cooler 18 and preferably comprises a static grate 40 which receives the clinker exiting the furnace 16. In particular, the static grate 40 is completely arranged in the first cooling gas chamber portion 36 of the cooler 10. Preferably, the clinker from the furnace 16 falls directly onto the static grate 40. The static grate 40 preferably extends completely at an angle of 10° to 35°, preferably 14° to 33°, in particular 21 ° to 25° to the horizontal, so that the clinker slides along the static grate 40 in the direction of conveyance.
The first cooling gas chamber portion 36 is adjoined by the second cooling gas chamber portion 38 of the cooler 18. In the first cooling gas chamber portion 36 of the cooler 18, the clinker is cooled in particular to a temperature of less than 1000° C., wherein the cooling is performed in such a way that a complete solidification of liquid phases present in the clinker into solid phases takes place. When leaving the first cooling gas chamber portion 36 of the cooler 18, the clinker is preferably completely in the solid phase and at a temperature of 1000° C. or less. In the second cooling gas chamber portion 38 of the cooler 18, the clinker is further cooled, preferably to a temperature of less than 100° C. Preferably, the second cooling gas flow can be divided into a plurality of partial gas flows which have different temperatures.
The static grate of the first cooling gas chamber portion 36 has, for example, passages through which a cooling gas enters the cooler 18 and the clinker. The cooling gas is generated, for example, by at least one fan, blower or pressure vessel arranged below the static grate 40, so that a first cooling gas flow 42 flows from below through the static grate into the first cooling gas chamber portion 36. The first cooling gas flow 42 is, for example, pure oxygen or a gas containing 15 vol % or less of nitrogen and 30 vol % or more of oxygen. The first cooling gas flow 42 flows through the clinker and then flows into the furnace 16. The first cooling gas flow forms, for example, part or all of the combustion gas of the furnace 16. The high proportion of oxygen in the combustion gas results in a preheater exhaust gas consisting substantially of CO2 and water vapour, and has the advantage of eliminating the need for costly downstream purification processes for exhaust gas purification. Furthermore, a reduction of the process gas quantities is achieved, so that the plant can be dimensioned considerably smaller.
Inside the cooler 18, the clinker to be cooled is moved in the direction of conveyance F. The second cooling gas chamber portion 38 preferably has a dynamic, in particular movable, grate 44, which adjoins the static grate 40 in the direction of conveyance F. Below the dynamic grate 44, a plurality of fans are arranged by way of example, by means of which the second cooling gas flow 46 is blown from below through the dynamic grate 44. The second cooling gas flow 46 is, for example, air.
In
For example, cooler exhaust air 54 is discharged from the second cooling gas chamber portion 38 and fed into a separator 56, such as a cyclone, for separating solids. The solids are fed back to the cooler 18, for example. An air-to-air heat exchanger 58 is connected downstream of the separator 56, so that the cooler exhaust air preheats air within the heat exchanger 58, which is fed to a raw mill, for example.
In
The calciner 14 has, by way of example, a temperature measuring device 66 for ascertaining the temperature inside the calciner 14. The cement plant 10 further comprises a control device 72 which is connected to the temperature measuring device in such a way that the temperature measuring device 66 transmits the ascertained temperature to the control device 72. The control device 72 is connected to the fuel inlet 24, the raw meal inlet 70 and/or the inert gas inlet 64 and is designed in such a way that it controls/regulates the quantity of fuel, raw meal and/or inert gas in the calciner 14 in dependence on the ascertained temperature.
The cross-sectional constrictions ensure balanced mixing within the riser and thus lead to even combustion and temperature distribution in the longitudinal and transverse directions of the riser of the calciner.
In
In the left-hand illustration, the guide element 73 is arranged in such a way that it causes a constriction of the cross section of the riser 62. The guide element 73 is in particular in plate form, chamber form or box form and is attached to the inner wall of the riser 62, moreover, by way of example, at the same height and opposite the fuel charging apparatus 60.
In the right-hand illustration, the guide element 73 has the exemplary form of a diffuser, wherein the cross section of the guide element 73 increases in the direction of flow of the fuel. The guide element 73 is attached to the fuel charging apparatus 60, in particular at the mouth of the fuel charging apparatus 60 into the riser 62, and in particular allows a targeted introduction of the fuel into the riser 62. It is also conceivable that the guide element 73 is flush with the riser and does not project into it, so that a uniform inlet of the fuel into the riser 62 is allowed.
The guide element 73 is formed, for example, from a high-temperature-resistant ceramic or a fibre composite material.
10 cement production plant
12 preheater
14 calciner
16 furnace
18 cooler
20 cyclone
22 preheater exhaust gas
24 fuel inlet of the calciner
25 material inlet into the furnace
26 combustion gas inlet of the calciner
28 burner or burner lance of the furnace
30 fuel inlet of the furnace
32 sintering zone
34 cooling gas chamber
36 first cooling gas chamber portion
38 second cooling gas chamber portion
40 static grate
42 first cooling gas flow
44 dynamic grate
46 second cooling gas flow
48 comminution device
50 dynamic grate 50
52 cold clinker
54 cooler exhaust air
56 separator
58 heat exchanger
60 fuel charging apparatus
62 riser of the calciner
66 temperature measuring device
64 inert gas inlet
68 inert gas inlet into the furnace
70 raw meal inlet into the calciner
72 control device
73 guide element
Number | Date | Country | Kind |
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BE 2020/5300 | May 2020 | BE | national |
10 2020 205 672.2 | May 2020 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2021/061409 | 4/30/2021 | WO |