Ceramic composite vane with metallic substructure

Information

  • Patent Grant
  • 6514046
  • Patent Number
    6,514,046
  • Date Filed
    Friday, September 29, 2000
    24 years ago
  • Date Issued
    Tuesday, February 4, 2003
    21 years ago
Abstract
A vane assembly for a turbine assembly includes an inner endcap, an outer endcap, and a body. The body includes a metallic core assembly, a ceramic shell assembly and a support assembly. The metallic core assembly is coupled to the inner and outer endcaps and bears most of the mechanical loads, including aerodynamic loads. The ceramic shell bears substantially all of the thermal stress placed on the vane assembly. The support assembly is disposed between the metallic core assembly and said ceramic shell assembly and is coupled to the metallic core assembly.
Description




BACKGROUND OF THE INVENTION




1. Field of the Invention




This invention relates to the vanes of a turbine assembly and, more specifically, to a ceramic composite vane having a metallic substructure.




2. Background Information




Combustion turbine power plants, generally, have three main assemblies: a compressor assembly, a combustor assembly, and a turbine assembly. In operation, the compressor assembly compresses ambient air. The compressed air is channeled into the combustor assembly where it is mixed with a fuel. The fuel and compressed air mixture is ignited creating a heated working gas. The heated working gas is typically at a temperature of between 2500 to 2900° F. (1371 to 1593° C.). The working gas is expanded through the turbine assembly. The turbine assembly includes a plurality of stationary vane assemblies and rotating blades. The rotating blades are coupled to a central shaft. The expansion of the working gas through the turbine assembly forces the blades to rotate creating a rotation in the shaft.




Typically, the turbine assembly provides a means of cooling the vane assemblies. The first row of vane assemblies, which typically precedes the first row of blades in the turbine assembly, is subject to the highest temperature of working gas. To cool the first row of vane assemblies, a coolant, such as steam or compressed air, is passed through passageways formed within the vane structure. These passageways often include an opening along the trailing edge of the vane to allow the coolant to join the working gas.




The cooling requirements for a vane assembly can be substantially reduced by providing the vane assembly with a ceramic shell as its outermost surface. Ceramic materials, as compared to metallic materials, are less subject to degrading when exposed to high temperatures. Ceramic structures having an extended length, such as vanes associated with large, land based turbines, are less able to sustain the high mechanical loads or deformations incurred during the normal operation of a turbine vane. As such, it is desirable to have a turbine vane that incorporates a metallic substructure, which is able to resist the mechanical loads on the vane, and a ceramic shell, which is able to resist high thermal conditions.




Prior art ceramic vane structures included vanes constructed entirely of ceramic materials. These vanes were, however, less capable of handling the mechanical loads typically placed on turbine vanes and had a reduced length. Other ceramic vanes included a ceramic coating which was bonded to a thermal insulation disposed around a metallic substructure. Such a ceramic coating does not provide any significant structural support. Additionally, the bonding of the ceramic coating to the thermal insulation precludes the use of a composite ceramic. Additionally, because the ceramic was bonded to the insulating material, the ceramic could not be cooled in the conventional manner, i.e., passing a fluid through the vane assembly. The feltmetal typically has a lower tolerance to high temperature than the metallic substructure, thus additional cooling was required.




Alternative ceramic shell/metallic substructure vanes include vanes having a ceramic leading edge and a metallic vane body, and a rotating blade having a metallic substructure and a ceramic shell having a corrugated metal partition therebetween. These structures require additional assembly steps during the final assembly of the vane or blade which are time-consuming and require a rotational force to activate certain internal seals.




There is, therefore, a need for a composite ceramic vane assembly for a turbine assembly having a metallic core assembly with attached support structures and a ceramic shell assembly.




There is a further need for a composite ceramic vane assembly having a ceramic shell assembly which is structured to be cooled by the cooling system for the vane assembly.




There is a further need for a composite ceramic vane assembly which transmits the aerodynamic forces of the ceramic shell assembly to the metallic core assembly without imparting undue stress to the ceramic shell assembly.




There is a further need for a composite ceramic vane assembly which accommodates differential thermal expansion rates between the ceramic shell assembly and the metallic core assembly while maintaining a positive pre-load on the ceramic shell assembly.




SUMMARY OF THE INVENTION




These needs, and others, are satisfied by the invention which provides a turbine vane assembly having a ceramic shell assembly and a metallic core assembly. The metallic core assembly includes an attached support assembly. The metallic core assembly includes passages for a cooling fluid to pass therethrough. The support assembly is structured to transmit the aerodynamic forces of the ceramic shell assembly to the metallic core assembly without imparting undue stress to the ceramic shell assembly. The support assembly can be any one of, or a combination of, a compliant layer, such as a feltmetal, contact points, such as a raised ribs or dimples on the metallic core assembly, or a biasing means, such as a leaf spring.




The metallic core assembly includes at least one cooling passage therethrough. The ceramic shell assembly has an exterior surface, which is exposed to the working gas, and an interior surface. The ceramic shell assembly interior surface is in fluid communication with the metallic core assembly cooling passage. For example, if the ceramic shell assembly is supported by ribs on the metallic core assembly, a cooling fluid may pass between adjacent ribs. If the ceramic shell assembly is supported by a biasing means, the cooling fluid may be passed over the biasing means. If the ceramic shell assembly is supported by a compliant layer, the compliant layer may have cooling passages formed therein.











BRIEF DESCRIPTION OF THE DRAWINGS




A full understanding of the invention can be gained from the following description of the preferred embodiments when read in conjunction with the accompanying drawings in which:





FIG. 1

is a cross sectional view of a compressor turbine power plant.





FIG. 2

is an isometric view of a vane assembly.





FIG. 3

is a cross-sectional view of a metallic core assembly, ceramic shell assembly, and support assembly comprising a layer of feltmetal.





FIG. 4

is a cross-sectional view of a metallic core assembly, ceramic shell assembly, and a support assembly comprising a plurality of contact points.





FIG. 5

is a cross-sectional view of a metallic core assembly, ceramic shell assembly, and a support assembly comprising a biasing means such as leaf springs.





FIG. 6

is a cross-sectional view of a metallic core assembly, ceramic shell assembly, and a support assembly comprising a layer of feltmetal, a plurality of contact points, and a biasing means.





FIG. 7

is a view of an alternate embodiment.





FIG. 8

is a view of an alternate embodiment.





FIG. 9

is a view of an alternate embodiment.





FIG. 10

is a view of an alternate embodiment.











DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS




As is well known in the art and shown in

FIG. 1

, a combustion turbine


1


includes a compressor assembly


2


, at least one combustor assembly


3


, a transition section


4


, and a turbine assembly


5


. A flow path


10


exists through the compressor assembly


2


, combustor assembly


3


, transition section


4


, and turbine assembly


5


. The turbine assembly


5


is mechanically coupled to the compressor assembly


2


by a central shaft


6


. Typically, an outer casing


7


encloses a plurality of combustor assemblies


3


and transition sections


4


. The outer casing


7


creates a compressed air plenum


8


. The combustor assemblies


3


and transition sections


4


are disposed within the compressed air plenum


8


. The combustor assemblies


3


are disposed circumferentiality about the central shaft


6


.




In operation, the compressor assembly


2


inducts ambient air and compresses it. The compressed air travels through the flow path


10


to the compressed air plenum


8


defined by the casing


7


. Compressed air within the compressed air plenum


8


enters a combustor assembly


3


where the compressed air is mixed with a fuel and ignited to create a working gas. The heated working gas is typically at a temperature of between 2500 to 2900° F. (1371 to 1593° C.). The working gas passes from the combustor assembly


3


through the transition section


4


into the turbine assembly


5


. In the turbine assembly


5


the working gas is expanded through a series of rotatable blades


9


, which are attached to the shaft


6


, and a plurality of stationary ceramic vane assemblies


20


. As the working gas passes through the turbine assembly


5


, the blades


9


and shaft


6


rotate creating mechanical force. The turbine assembly


5


can be coupled to a generator to produce electricity.




The ceramic vane assemblies


20


, especially those adjacent to the transition sections


4


, are exposed to the high temperature working gas. To reduce thermal degradation of the vane assemblies


20


, the turbine assembly includes a casing


12


having cooling passages


14


therethrough. The casing cooling passages


14


are coupled to a cooling system


16


, such as an air or steam system. The casing cooling passages


14


are coupled to vane assembly main cooling passages


36


(described below).




As shown in

FIG. 2

, the vane assemblies


20


have an inner endcap


22


, an outer endcap


24


and a body


26


. The end caps


22


,


24


are structured to be coupled to casing


12


. The body


26


is preferably an airfoil which, in operation, will have a high pressure side and a low pressure side. As shown in

FIG. 3

, the body


26


includes a metallic core assembly


30


, a ceramic shell assembly


40


, and a support assembly


50


. As shown in

FIG. 3

, the support assembly


50


is a compliant layer


52


, as will be described below. As shown in

FIGS. 4 and 5

, respectively, the support assembly


50


may also be a plurality of hard contact points


54


or a biasing means


56


, both described below. As shown in

FIG. 6

, the support assembly


50


may also be a combination of two or more of a compliant layer


52


, a plurality of hard contact points


54


, or a biasing means


56


.




As shown in

FIG. 3

, the metallic core assembly


30


includes a frame


31


. The metallic core assembly


30


is coupled to, including being integral with, the inner endcap


22


and/or outer endcap


24


. As such, the metallic core assembly


30


bears almost all mechanical loading, including aerodynamic loading, during operation. The frame


31


of the metallic core assembly


30


form at least one main cooling passage


36


that extend between the outer endcap


24


and the inner endcap


22


. The main cooling passages


36


are in fluid communication with the cooling system


16


. As shown in

FIG. 6

, the metallic core assembly


30


may also include at least one, and possibly two or more, spars


32


, and a metallic trailing edge assembly


34


. If a spar


32


is used, the metallic core assembly forms at least two cooling passages


36


.




As shown on

FIG. 3

, the ceramic shell assembly


40


includes at least one layer, and preferably two layers, of a ceramic material


42


. The ceramic layer


42


is not bonded or fixed to the metallic core assembly


30


. The ceramic material


42


, as will be described below, is supported on the metallic core assembly


30


by the support assembly


50


. The ceramic layer may also extend over the end caps


22


,


24


. When there are more than one ceramic layers


42


, it is preferable to have an outer layer


44


and an inner layer


46


. The inner layer


46


is preferably a strain tolerant continuous fiber reinforced ceramic composite matrix which can deform to accommodate slight manufacturing tolerance mismatches and distortions due to loading such as AS-N720, A-N720, AS-N610, or A-N610 from COI Ceramics, 9617 Distribution Avenue, San Diego, Calif., 92121. The outer layer


44


may be a monolithic ceramic. The outer layer


44


is, however, preferably a high temperature insulating ceramic. The outer layer may have an outer coating such as a conventional environmental coating or thermal barrier


45


.




The ceramic shell assembly


40


is supported on the metallic core assembly


30


by the support assembly


50


. The support assembly


50


is coupled to, including being integral with, the metallic core assembly


30


. The support assembly


50


may include one or more of the following support members: a compliant layer


52


, a plurality of hard contact points


54


, or a biasing means


56


. As shown in

FIG. 3

, the compliant layer


52


may be in the form of a continuous layer of material between the metallic core assembly


30


and the ceramic shell assembly


40


. Alternatively, as shown in

FIG. 6

, compliant strips may be placed between hard contact points


54


(described below). Of course, any combination of a semi-continuous layer and strips may also be used. When a continuous compliant layer


52


is used, passages


53


(See

FIG. 7

) may be formed therein to allow cooling fluid to reach the ceramic shell assembly


40


(described below). The compliant layer passages


53


are in fluid communication with the main cooling passages


36


of the metallic core assembly


30


. Alternatively, the compliant layer


52


may have a sufficiently porous consistency to allow a cooling fluid to pass therethrough to contact the ceramic shell assembly


40


.




The compliant layer


52


is preferably a feltmetal, such as Hastelloy-X material FM528A, FM515B, FM509D, Haynes 188 material FM21B, FM522A, or FeCrAlY material FM542, FM543, FM544, all from Technetics Corporation, 1600 Industrial Drive, DeLand, Fla. 32724-2095. When the compliant layer


52


is a feltmetal, the feltmetal may be bonded or brazed to the metallic core assembly


30


. The compliant layer


52


may also be a porous metallic foam, such as open cell foam made by Doucel ® Foams made by ERG, 900 Stanford, Calif., 94608 or closed cell foam made from hollow metal powders.




As used herein, a “hard contact point” may still be somewhat compliant. As shown on

FIG. 4

, The hard contact points


54


are, preferably, raised ribs


55


which extend over the length of the body


26


. The hard contact points may be raised dimples as well. The ribs


55


may be formed integrally with the metallic core assembly


30


extending toward the ceramic shell assembly


40


, or the ribs


55




a


may be integral with the inner layer


46


and extend toward the metallic core assembly


30


. When the hard contact points


54


are formed as part of the ceramic shell assembly


40


, the ribs aid in heat transfer thereby increasing the effectiveness of the cooling system


16


. The hard contact points


54


are generally located on the high pressure side of the airfoil shaped body


26


. Between the ribs


55


are interstices


58


. The interstices


58


are in fluid communication with the main cooling passages


36


. As described above, strips of a compliant layer


52


may be disposed in the interstices


58


.




A vane assembly


20


having a biasing means


56


for a support structure


50


is shown in FIG.


5


. The biasing means


56


is preferably a plurality of leaf springs


57


, however, any type of spring may be used. The biasing means


56


maintains a supporting force on the ceramic shell assembly


40


. This supporting force also accommodates the differential thermal expansion between the metallic core assembly


30


and the ceramic shell assembly


40


. The biasing means


56


preferably interacts with the low pressure side of the body


26


. A cooling fluid may flow in and around the structure of the biasing means


56


and be in fluid communication with the ceramic shell assembly


40


.




The combination of the metallic core assembly


30


, ceramic shell assembly


40


and support assembly


50


, may be structured in many configurations. As shown in

FIG. 4

, the ceramic shell assembly


40


may include a trailing edge portion


48


of the body


26


. As with the metallic trailing edge assembly


34


, the ceramic trailing edge portion


48


may include cooling passages


49


which are in fluid communication with the cooling system


16


via openings


60


. Another alternate design is shown in FIG.


7


. This embodiment includes a two piece metallic core assembly


30




a,




30




b,


a ceramic shell assembly


40


having a two piece inner layer


46




a,




46




b


and a one piece outer layer


44


, and a compliant layer


52


disposed between metallic core assembly


30




a,




30




b


and the two piece inner layer


46




a,




46




b.



FIG. 7

further shows a plurality of connecting passages


60


which are in fluid communication with the main passages


36


and the compliant layer


52


.





FIG. 8

shows another alternate embodiment. As before, this embodiment includes a two piece metallic core assembly


30




a,




30




b,


and a ceramic shell assembly


40


having a two piece inner layer


46




a,




46




b


and a one piece outer layer


44


. The support assembly


50


is a plurality of leaf springs


57


. Again the metallic core assembly


30


includes a plurality of connecting passages


60


that permit fluid communication between the main passages


36


and the support assembly


50


. A support pin


80


extending between the endcaps


22


,


24


, may be used to reduce the movement between the inner layer portions


46




a,




46




b.


Alternatively, as shown in

FIG. 9

, the inner layer portions


46




a,




46




b


may include deflections


82


,


84


along an interface


86


to reduce the movement between the inner layer portions


46




a,




46




b.






As shown in

FIG. 10

, the metallic core assembly


30


and ceramic shell assembly


40


may include a structural lock


90


formed by the metallic core assembly


30


and the inner layer


46




a,




46




b.


The structural lock


90


includes tabs


91


,


92


,


93


, and


94


, which extend toward the interface


86


between the inner layer portions


46




a,




46




b.


The inner layer portions


46




a,




46




b


include tabs


95


,


96


,


97


, and


98


which are structured to extend around tabs


91


,


92


,


93


, and


94


respectively.




While specific embodiments of the invention have been described in detail, it will be appreciated by those skilled in the art that various modifications and alternatives to those details could be developed in light of the overall teachings of the disclosure. Accordingly, the particular arrangements disclosed are meant to be illustrative only and not limiting as to the scope of invention which is to be given the full breadth of the claims appended hereto and any and all equivalents thereof.



Claims
  • 1. A vane assembly for a turbine assembly comprising:an inner endcap; an outer endcap; a body: said body comprises:a metallic core assembly which is coupled to said inner endcap and said outer endcap; a ceramic shell assembly; a support assembly coupled to said metallic core assembly; and said support assembly being disposed between said metallic core assembly and said ceramic shell assembly and adapted to transmit substantially all aerodynamic loads from said shell assembly to said core assembly during operation.
  • 2. The vane assembly of claim 1, wherein said support assembly is one or more of the structures selected from the group consisting of: a compliant layer, hard contact points and a biasing means.
  • 3. The vane assembly of claim 2, wherein said ceramic shell assembly comprises an inner layer of ceramic material and an outer layer of ceramic material.
  • 4. The vane assembly of claim 3, wherein said inner layer is a ceramic matrix composite.
  • 5. The vane assembly of claim 4, wherein:said metallic core assembly comprises a frame forming at least one main cooling passage.
  • 6. The vane assembly of claim 5, wherein:said frame includes a plurality of connecting passages that are in fluid communication with both said at least one main passage and said support assembly.
  • 7. The vane assembly of claim 6, wherein:said support assembly hard contact points includes a plurality of ribs; and said support assembly includes a plurality of strips of a compliant material disposed between said ribs.
  • 8. The vane assembly of claim 3, wherein said biasing means is a plurality of leaf springs.
  • 9. The vane assembly of claim 8, wherein:said body has a high pressure side and a low pressure side; and said plurality of leaf springs is disposed between said metallic core assembly and said ceramic shell assembly adjacent to said low pressure side and a plurality of ribs is disposed between said metallic core assembly and said ceramic shell assembly adjacent to said high pressure side.
  • 10. The vane assembly of claim 3, wherein said outer layer is an insulating ceramic.
  • 11. The vane assembly of claim 10, wherein said outer layer is ceramic insulation comprising hollow ceramic spheres.
  • 12. A vane assembly for a turbine assembly comprising:an inner endcap; an outer endcap; a body: said body comprises:a metallic core assembly which is coupled to said inner endcap and said outer endcap; a ceramic shell assembly; a support assembly coupled to said metallic core assembly; and said support assembly being a layer of a compliant material, wherein said compliant material includes a plurality of cooling passages therethrough being in fluid communication with said ceramic shell assembly.
  • 13. The vane assembly of claim 12, wherein said ceramic shell assembly comprises an inner layer of ceramic material and an outer layer of ceramic material.
  • 14. The vane assembly of claim 13, wherein said inner layer is a ceramic matrix composite.
  • 15. The vane assembly of claim 14, wherein said outer layer is an insulating ceramic.
  • 16. The vane assembly of claim 15, wherein said outer layer is ceramic insulation comprising hollow ceramic spheres.
  • 17. The vane assembly of claim 14, wherein said metallic core assembly comprises a frame forming at least one main cooling passage.
  • 18. The vane assembly of claim 17, wherein said frame assembly includes a plurality of connecting passages that are in fluid communication with both said at least one main cooling passage and said support assembly.
  • 19. The vane assembly of claim 1, wherein said support assembly is a plurality of leaf springs.
  • 20. The vane assembly of claim 19, wherein said ceramic shell assembly comprises an inner layer of ceramic material and an outer layer of ceramic material.
  • 21. The vane assembly of claim 20, wherein said inner layer is a ceramic matrix composite.
  • 22. The vane assembly of claim 21, wherein said outer layer is an insulating ceramic.
  • 23. The vane assembly of claim 22, wherein said outer layer is ceramic insulation comprising hollow ceramic spheres.
  • 24. The vane assembly of claim 23, wherein:said metallic core assembly comprises a frame forming at least one main cooling passage.
  • 25. The vane assembly of claim 24, wherein:said frame assembly includes a plurality of connecting passages that are in fluid communication with both said at least one main cooling passage and said support assembly.
  • 26. The vane assembly of claim 1 wherein said support assembly comprises a plurality of hard contact points and wherein said plurality hard contact points include a plurality of ribs extending from said ceramic shell assembly towards said metallic core assembly.
  • 27. A turbine comprising:a casing; a cooling system; and a plurality of vane assemblies comprising: an inner endcap; an outer endcap; a body: said body comprises:a metallic core assembly which is coupled to said inner endcap and said outer endcap; a ceramic shell assembly; a support assembly coupled to said metallic core assembly; and said support assembly being disposed between said metallic core assembly and said ceramic shell assembly and adapted to transmit substantially all aerodynamic loads from said shell assembly to said core assembly during operation.
  • 28. The turbine of claim 27, wherein said support assembly is one or more of the structures selected from the group consisting of: a compliant layer, hard contact points and a biasing means.
  • 29. The turbine of claim 28, wherein said ceramic shell assembly comprises an inner layer of ceramic material and an outer layer of ceramic material.
  • 30. The turbine of claim 29, wherein said inner layer is a ceramic matrix composite.
  • 31. The turbine of claim 29, wherein said outer layer is an insulating ceramic.
  • 32. The turbine of claim 31, wherein said outer layer is ceramic insulation comprising hollow ceramic spheres.
  • 33. The turbine of claim 31, wherein:said metallic core assembly comprises a frame forming at least one main cooling passage.
  • 34. The turbine of claim 33, wherein:said frame includes a plurality of connecting passages that are in fluid communication with both said at least one main passage and said support assembly.
  • 35. The turbine of claim 34, wherein:said support assembly hard contact points includes a plurality of ribs; and said support assembly includes a plurality of strips of a compliant material disposed between said ribs.
  • 36. The turbine of claim 29, wherein said biasing means is a plurality of leaf springs.
  • 37. The turbine of claim 36, wherein:said body has a high pressure side and a low pressure side; and said plurality of leaf springs is disposed between said metallic core assembly and said ceramic shell assembly adjacent to said low pressure side and a plurality of ribs is disposed between said metallic core assembly and said ceramic shell assembly adjacent to said high pressure side.
  • 38. The turbine of claim 28, wherein said support assembly is a layer of a compliant material.
  • 39. A turbine comprising:a casing; a cooling system; and a plurality of vane assemblies comprising: an inner endcap; an outer endcap; a body: said body comprises:a metallic core assembly which is coupled to said inner endcap and said outer endcap; a ceramic shell assembly; a support assembly coupled to said metallic core assembly; and said support assembly disposed between said metallic core assembly and said ceramic shell assembly, wherein said support assembly is a layer of a compliant material, wherein said compliant material includes a plurality of cooling passages therethrough being in fluid communication with said ceramic shell assembly.
  • 40. The turbine of claim 39, wherein said ceramic shell assembly comprises an inner layer of ceramic material and an outer layer of ceramic material.
  • 41. The turbine of claim 40, wherein said inner layer is a ceramic matrix composite.
  • 42. The turbine of claim 41, wherein said outer layer is an insulating ceramic.
  • 43. The turbine of claim 42, wherein said outer layer is ceramic insulation comprising hollow ceramic spheres.
  • 44. The turbine of claim 41, wherein said metallic core assembly comprises a frame forming at least one main cooling passage.
  • 45. The turbine of claim 44, wherein said frame assembly includes a plurality of connecting passages that are in fluid communication with both said at least one main cooling passage and said support assembly.
  • 46. The turbine of claim 27, wherein said support assembly is a plurality of leaf springs.
  • 47. The turbine of claim 46, wherein said ceramic shell assembly comprises an inner layer of ceramic material and an outer layer of ceramic material.
  • 48. The turbine of claim 47, wherein said inner layer is a ceramic matrix composite.
  • 49. The turbine of claim 48, wherein said outer layer is an insulating ceramic.
  • 50. The turbine of claim 49, wherein said outer layer is ceramic insulation comprising hollow ceramic spheres.
  • 51. The turbine of claim 50, wherein:said metallic core assembly comprises a frame forming at least one main cooling passage.
  • 52. The turbine of claim 51, wherein:said frame assembly includes a plurality of connecting passages that are in fluid communication with both said at least one main cooling passage and said support assembly.
  • 53. A turbine assembly comprising:a casing; a cooling system; and a plurality of vane assemblies comprising: an inner endcap; an outer endcap; a body: said body comprises:a metallic core assembly which is coupled to said inner endcap and said outer endcap; a ceramic shell assembly; a support assembly coupled to said ceramic shell assembly; said support assembly being disposed between said metallic core assembly and said ceramic shell assembly and adapted to transmit substantially all aerodynamic loads from said shell assembly to said core assembly during operation; and said support assembly comprises a plurality of hard contact points.
  • 54. The turbine assembly of claim 53 wherein said plurality hard contact points include a plurality of ribs extending from said ceramic shell assembly towards said metallic core assembly.
US Referenced Citations (14)
Number Name Date Kind
4376004 Bratton et al. Mar 1983 A
4396349 Hueber Aug 1983 A
4519745 Rosman et al. May 1985 A
4563128 Rossmann Jan 1986 A
4629397 Schweitzer Dec 1986 A
4645421 Huether Feb 1987 A
4790721 Morris et al. Dec 1988 A
4838031 Cramer Jun 1989 A
5358379 Pepperman et al. Oct 1994 A
5516260 Damlis et al. May 1996 A
6013592 Merrill et al. Jan 2000 A
6283708 Zelesky Sep 2001 B1
6284390 Bose et al. Sep 2001 B1
6291084 Darolia et al. Sep 2001 B1