This application claims priority under 35 U.S.C. § 119 to Korean Application Nos. 10-2014-0004003, filed on Jan. 13, 2014, and 10-2014-0007764, filed on Jan. 22, 2014, in the Korean Intellectual Property Office, whose entire disclosures are hereby incorporated by reference.
1. Field
Embodiments of the present disclosure relate to a lighting device and a phosphor plate constituting the lighting device.
2. Background
Low power/high efficiency light sources use a phosphor as low-wave light sources that emit light in a relatively thin spectrum width, and accordingly, in order to be actually used, the phosphor should be converted into white light. During this conversion process, the problem of a reduction in reliability such as deterioration and decomposition of the phosphor caused by a high temperature/high density and low wavelength beam may be generated. In order to solve such a problem, the study regarding the phosphor has been needed so that the light source and the phosphor can be disposed to be separated from each other.
In order to coat the phosphor, a separate base substrate is needed. This substrate simply serves as a support layer of a phosphor film and becomes a factor that causes an increase in material costs for a lighting member. Also, the substrate optically serves as an intermediate layer, thereby causing partial transmittance and light losses. As shown in
Also, when the phosphor is applied to lighting as a remote phosphor, a portion of the phosphor exposed to the outside of the lighting has a high possibility of being contaminated by moisture and dust of the outside. Furthermore, a fluorescent screen can be partially damaged due to scratches and the like, and this becomes a main factor of the reduction of optical efficiency. Even though the conventional phosphor may be applied to lighting showing a low output as an UV curing form, it has a limit in extending an application scope because a phosphor layer is easily damaged by heat when the phosphor is applied to lighting showing a high output.
Furthermore, a phosphor plate for an LED element is produced using glass powder (glass frit) and a phosphor. The phosphor plate has a composite structure in which a phosphor based on an inorganic crystal is dispersed in a glass matrix. When producing the phosphor plate by firing glass powder, a structural defect such as pores and the like is generated. Such a structural defect becomes a factor that causes a reduction of strength of the phosphor plate. The structural defect causes destruction or damage by physical damage generated during post processes such as a grinding process, a dicing process, a packaging process or the like and during driving the LED element for a long time.
The embodiments will be described in detail with reference to the following drawings in which like reference numerals refer to like elements wherein:
(A) of
(A) of
(A) of
Hereinafter, the configurations and operations according to embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. The present disclosure may, however, be embodied in different forms and should not be construed as limited to the embodiments set forth herein. In the explanation with reference to the accompanying drawings, regardless of reference numerals of the drawings, like numbers refer to like elements through the specification, and repeated explanation thereon is omitted. Terms such as a first term and a second term may be used for explaining various constitutive elements, but the constitutive elements should not be limited to these terms. These terms are only used for the purpose for distinguishing a constitutive element from other constitutive element.
Referring to
The inorganic phosphor is mixed in a powder form. The inorganic phosphor is mixed with ceramic powder that is a transparent ceramic matrix, and the mixture is sufficiently mixed and dispersed using a ball mill. With regard to the kind of the ceramic powder, based on a thickness of 100 μm, ceramic having a light transmittance of 40% or more may be used. For example, a transparent silicate-based ceramic and an aluminum oxide-based ceramic, which are appropriate as an optical material such as borate glass, phosphate glass or the like, may be used in the ceramic powder. The phosphor of the short wavelength area is contained in an amount of 1 to 10 wt % in the transparent ceramic matrix.
The mixture of the inorganic phosphor and glass powder is put into a SUS (Stainless Use Steel) mold and is subjected to uniaxial compression so as to have a plate or disc form. At this time, the compression is performed for 5 minutes at 7 ton. The compressed mixture of the inorganic phosphor and glass powder is put into a firing furnace, thereby performing firing. At this time, a temperature and time for performing firing may be adjusted according to a glass transition temperature Tg of the inorganic phosphor and the glass powder.
The fired phosphor plate (first phosphor layer 110) is subjected to surface polishing so that a thickness and a surface roughness of the fired phosphor plate can be adjusted so as to be matched with a property required by the present embodiment. At this time, the first phosphor layer 110 is ground to have a thickness of 200 to 1000 μm, and a surface roughness of 0.1 to 0.3 μm.
The second phosphor layer 120 is formed by coating one surface on the first phosphor layer 110 prepared in a plate form with a paste containing a phosphor of the long wavelength area. The phosphor of the long wavelength area may be an inorganic phosphor of a red area having a wavelength of 580 to 680 nm. A mixture in which at least two kinds of phosphors within the wavelength range are mixed may be used as the phosphor of the long wavelength area.
The phosphor paste is prepared by mixing the phosphor of the long wavelength area with ceramic powder and an ethyl cellulose-based organic vehicle. Glass powder may be used as the transparent ceramic powder, and appropriate transparent glass for an optical material such as borate glass, phosphate glass or the like may be used in the glass powder. The phosphor of the long wavelength may have a particle size of 1 to 20 μm, and the glass powder may have a particle size of 1 to 20 μm. When the particle size of the powdered glass is so small, agglomeration may be generated upon mixing the organic vehicle. On the contrary to this, when the particle size is so large, an amount of light passing through the phosphor than an amount of light excited in the phosphor is increased, so white light having a good property may not be obtained. Also, a mixture formed by mixing powder having a relatively large particle size and powder having a relatively small particle size may be used in the powdered glass. The transparent ceramic powder may be mixed in an amount of 35 to 50 wt %, and the organic vehicle may be added in an amount of 35 to 50 wt %. According to each desired optical property, the transparent ceramic powder and the organic vehicle may be added by adjusting a mixing rate with the phosphor.
When the particle size of the long-wavelength phosphor is less than 1 μm, agglomeration may be generated upon mixing the organic vehicle. On the contrary, when the particle size of the phosphor is more than 20 μm, a sufficient viscosity may not be obtained. Thus, it is difficult to obtain a pattern having a form required when printing the phosphor paste on the transparent substrate. Also, since a space between phosphor particles is increased, an amount of light passing through the phosphor than an amount of light excited in the phosphor may be increased. The long-wavelength phosphor may be contained in an amount of 15 to 30 wt %. An amount of the phosphor may range from 25 to 55% compared to the amount of the transparent ceramic powder. When the amount of the phosphor is less than 25%, an amount of the red phosphor is very reduced, so it is difficult to express red light. Furthermore, since the amount of the transparent ceramic powder is increased, total transmittance of the paste may be reduced. On the contrary, when the amount of the phosphor is more than 55%, the amount of the phosphor is very increased so that the phosphor cannot be sufficiently encapsulated in the transparent ceramic, thereby causing a physical scratch and a reduction of reliability at a high-temperature and humidity environment. The content of the phosphor may be adjusted according to the kind of the phosphor.
Also, a solid content rate of the phosphor and the transparent ceramic powder contained in the phosphor paste may be 1.5:1 to 1:1 compared to the content of the organic vehicle. When the solid content rate is less than 1, the viscosity of the phosphor paste is very reduced, so that the shape of a pattern can be distorted and cannot be completely maintained upon printing. On the contrary, when the solid content rate is more than 1.5, the viscosity of the phosphor paste is increased, a printing ability may be remarkably reduced.
The phosphor of the long-wavelength area, the transparent ceramic powder, and the organic vehicle are put into a paste mixer and are then mixed by performing revolution and rotation mixing at 100 to 1000 rpm for 1 to 30 minutes. Then, the mixture is put into a three-roll mill and is mixed again at 100 to 1000 rpm for 1 to 30 minutes. The first phosphor layer 110 is coated with the mixture, which has been mixed again, using a bar coating method, a screen coating method or the like, thereby forming the second phosphor layer 120. Then, the ceramic phosphor plate of the present embodiment in which the second phosphor layer 120 is formed on the first phosphor layer 110 is completed by drying or heat treatment. The heat treatment is intended to sinter the phosphor paste and to remove the organic vehicle. The heat treatment method is not largely limited. The heat treatment may be performed in a heat treating furnace or an oven.
Referring to
Unlike the phosphor paste coated on the entire surface of the first phosphor layer (reference numeral 110 of
The pattern 222 may be formed using a method of simultaneously performing patterning and coating such as a screen printing method, a gravure coating method and the like. When the screen printing method is used, the number of the patterns may be easily adjusted by adjusting the number of screen meshes, but it is relatively difficult to adjust a separation distance between the patterns due to a shape of the pattern. On the contrary, when the gravure coating method is used, desired patterns are formed in a copper plate, thereby facilitating patterning, but an additional cost for production of the copper plate is needed. Accordingly, an appropriate printing method according to each desired property of lighting may be used.
Referring to
Also, a transparent ceramic matrix constituting the short-wave phosphor layer 1210, has the same refractive index as that of a matrix constituting the long-wave phosphor layer 1220, or even through there is a difference between the refractive indexes, the matrix constituting the long-wave phosphor layer 1220 may be made of a material having a higher refractive index than that of the matrix constituting the short-wave phosphor layer. Since the materials and the configurations of the short-wave phosphor layer 1210 and the long-wave phosphor layer 1220 have been previously explained, the description thereof is omitted for avoiding overlapping.
The light incoming part 1100 may emit the light of a blue wavelength area. When incident light LI emitted from the light incoming part 1100 is irradiated to the ceramic phosphor plate 1200, the kind of wavelengths of each excited light LE1, LE2 is changed according to each area of the ceramic phosphor plate 1200. That is, when the incident light LI is irradiated to a portion to which the short-wave phosphor layer 1210 is exposed, the light is excited from the short-wave phosphor. However, when the incident light LI passes through the transparent ceramic matrix of the short-wave phosphor layer 1210, the excited light LE1 is transmitted as the light of a blue wavelength area. On the contrary, when the incident light LI is irradiated to an area in which patterns of the long-wave phosphor layer 1220 are present, the excited light LE2 is excited as the light of a red wavelength area.
Accordingly, a color temperature of the excited light is changed according to the rate of a total area of the pattern 1222 of the long-wave phosphor layer 1220 to an area of the short-wave phosphor layer 1210. That is, when the rate of the total area of the pattern 1220 of the long-wave phosphor layer 1220 to the area of the short-wave phosphor layer 1210 is 20 to 35%, a rate of the light of a blue, yellow or green wavelength area is increased, so that white light having a cool white color and a color temperature of 4000 to 6000K can be implemented. On the contrary, when the rate of the total area of the pattern 1220 of the long-wave phosphor layer 1220 to the area of the short-wave phosphor layer 1210 is more than 35%, a rate of the light of a red wavelength area is increased, so that white light having a warm white color and a color temperature of 4000 to 6000K can be implemented.
Referring to
The lighting device includes a housing 2300 configured to be gradually increased from a bottom surface to a top surface with the light source 2100 based on the light source 2100. The light source 2100 is an optical element for emitting light, and as one example, a solid light emitting element may be applied as the light source. Any one selected from among an LED (Light emitting Diode), an OLED (Organic Light Emitting Diode), an LD (laser diode), a laser, and a VCSEL (Vertical Cavity Surface Emitting Laser) may be applied as the solid light emitting element. The ceramic phosphor plate 2200 is provided at an upper end of the housing 2300 and is disposed to be separated from the light source 2100. As previously described, the ceramic phosphor plate 2200 includes a matrix composed of a glass frit and a ceramic phosphor dispersed in the matrix. The inside of the housing may be filled with a material having a refractive index that is higher than or the same as that of the ceramic phosphor plate 2200.
Also, optical properties may be measured by an integrating sphere in such a form. The integrating sphere has internal luminance that is regular at any angle, and captures light reflected from a sample surface so that the light can be distributed to a surface of the integrating sphere with uniform roughness. A special paint, polytetrafluoroethylene (PTFE) or the like may be used as a coating material of an internal wall of the integrating sphere. The inside of the integrating sphere should not be contaminated. In the case of spectral transmittance, the rate of transmitted light without a sample is 100%, and the rate of light completely blocked by an opaque object such as an iron plate or the like is 0%. When one of transmission colors has a large dispersion effect in a transmission material, it is preferable to measure the property using the integrating sphere.
The integrating sphere is prepared in a size showing a WT of 55 to 60 mm, a WB of 35 to 40 mm and an H of 15 to 20 mm. First, in a state where the ceramic phosphor plate 2200 is not present, the radiant flux of a blue LED, which is the light source 2100, is measured. Then, the ceramic phosphor plate 2200 is mounted, and a luminous flux (lumens) is measured. Thus, when the luminous flux is divided by the radiant flux of the blue LED previously measured, the value of optical efficiency may be obtained.
(A) of
(A) of
Referring to
Hereinafter, the present disclosure will be described in greater detail based on examples. The present disclosure may, however, be embodied in different forms and should not be construed as limited to the examples described for the purpose for understanding of the present disclosure.
A PiG (Phosphor in Glass Matrix) matrix was prepared in a circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including an LuAg phosphor (green) having a light-emitting wavelength of 550 nm. 20 wt % of a nitride phosphor (red) having a light-emitting wavelength of 620 nm, 40 wt % of a glass powder, and 60 wt % of an ethyl cellulose were mixed to prepare a red phosphor paste, and the circular plate was coated with the red phosphor paste using a silk screen method. Pattern conditions and property measurement results are shown in Table 1.
A PiG matrix was prepared in a circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including an LuAG phosphor having a light-emitting wavelength of 550 nm and a nitride phosphor having a light-emitting wavelength of 620 nm. Production conditions and property measurement results are shown in Table 1.
As shown in Table 1 above, unlike the ceramic phosphor plate of Comparative Example 1 in which both the red phosphor and the green phosphor are included in the PiG matrix, in the ceramic phosphor plate according to the present example, the demand quantity of the high-priced red phosphor could be reduced up to about 1/100 to 1/250. Also, physical properties such as the color rendering index, optical efficiency, luminous flux and the like were similarly or highly maintained with various changes of the color temperature. Based on this result, a correlation between a pattern area rate and the color temperature CCT and a correlation between a content of the red phosphor and the color temperature CCT are illustrated in
A PiG (Phosphor in Glass Matrix) matrix was prepared in a circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including 7 wt % of an LuAg phosphor (green) having a light-emitting wavelength of 550 nm. 20 wt % of a nitride phosphor (red) having a light-emitting wavelength of 620 and 630 nm, 40 wt % of a glass powder, and 60 wt % of an ethyl cellulose were mixed to prepare a red phosphor paste, and the circular plate was coated with the red phosphor paste using a silk screen method. Pattern conditions and property measurement results are shown in Table 2.
A PiG matrix was prepared in a circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including an LuAG phosphor having a light-emitting wavelength of 550 nm and a nitride phosphor having a light-emitting wavelength of 620 nm. Production conditions and property measurement results are shown in Table 1.
A PiG matrix was prepared in a two-layered circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including an LuAG phosphor having a light-emitting wavelength of 550 nm and a nitride phosphor having a light-emitting wavelength of 620 nm. Production conditions and property measurement results are shown in Table 1.
As shown in Table 2 above, when performing evaluation on an LuAG-based yellow phosphor, it could be seen that the ceramic phosphor plate according to the present example has excellent properties with small consumption of the red phosphor compared to the ceramic phosphor plate according to the PiG method (Comparative Example 2) showing pattern application in which two kinds of phosphors are included in a single layer or the method (Comparative Example 3) including each phosphor into the two-layered plate. Also, when the red phosphor has a wavelength of 630 nm, the demand quantity of the red phosphor could be reduced.
A PiG (Phosphor in Glass Matrix) matrix was prepared in a circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including a nitride phosphor (green) having a light-emitting wavelength of 550 nm. 20 wt % of a nitride phosphor (red) having a light-emitting wavelength of 620 and 630 nm, 40 wt % of a glass powder, and 60 wt % of an ethyl cellulose were mixed to prepare a red phosphor paste, and the circular plate was coated with the red phosphor paste using a silk screen method. Pattern conditions and property measurement results are shown in Table 3.
A PiG matrix was prepared in a circular plate form having a thickness of 1 mm and a diameter of 60 mm by including a nitride phosphor having a light-emitting wavelength of 550 nm and a nitride phosphor having a light-emitting wavelength of 620 nm. Production conditions and property measurement results are shown in Table 3.
A PiG matrix was prepared in a circular plate form having a thickness of 0.5 mm and a diameter of 60 mm by including a nitride phosphor having a light-emitting wavelength of 550 nm and a nitride phosphor having a light-emitting wavelength of 620 nm. Production conditions and property measurement results are shown in Table 3.
As shown in
An Example of another composition for implementing the ceramic phosphor plate will be hereinafter described with reference to
A phosphor-transparent ceramic composite composition according to the present example contains: transparent ceramic powder; at least one powdered inorganic phosphor; at least one silicate; and a binder compound cross-linked by heat treatment.
In the phosphor-transparent ceramic composite composition according to the present example, the transparent ceramic powder serves as a matrix in which the inorganic phosphor is dispersed. The transparent ceramic powder enables protection of the phosphor from a physical or chemical impact by encapsulating the inorganic phosphor. The transparent ceramic powder may be a silicate-based glass powder such as sodium borosilicate, aluminosilicate, zinc borosilicate, barium zinc silicate, or a mixture thereof. The glass powder may be appropriately used as an optical material. The transparent ceramic powder may have an average particle size D50 of 1 to 50 μm. When the average particle size D50 of the transparent ceramic powder is less than 1 μm, the phosphor may not be sufficiently encapsulated by the transparent ceramic powder, or the powder may be agglomerated not to be sufficiently dispersed. On the contrary, when the average particle size D50 is more than 50 μm, an amount of light passing through the phosphor than an amount of light excited in the phosphor is increased, so white light having good properties cannot be obtained. Also, a mixture of powder having a relatively large average particle size and powder having a relatively small average particle size may be used as the transparent ceramic powder. It is preferable to select transparent ceramic powder having appropriate particle-size distribution in consideration of the average particle size of the phosphor powder.
A yttrium aluminum garnet (YAG), lutetium aluminum garnet (LuAG), nitride, silicate, or sulfide-based inorganic phosphor powder may be used as the inorganic phosphor powder. According to each desired property of light, one kind or two kinds of phosphors may be used in a state of being mixed. The inorganic phosphor powder may be contained in an amount of 5 to 30 parts by weight with respect to 100 parts by weight of the transparent ceramic powder. When the amount of the inorganic phosphor is less than 5 parts by weight, an amount of transmitted light than an amount of excited light is increased. On the contrary, when the amount of the inorganic phosphor is more than 30 parts by weight, the inorganic phosphor may not be sufficiently encapsulated by the transparent ceramic powder, and an increase in costs may be caused. Also, according to each thickness of the phosphor plate, the content of the inorganic phosphor is adjusted. When the thickness of the phosphor plate is reduced, the content of the inorganic phosphor should be increased. For example, when the thickness of the phosphor plate is 120 μm, the content of the inorganic phosphor is increased up to about 1.5 times of the content of the inorganic phosphor when the thickness of the phosphor plate is 200 μm. The average particle size D50 of the inorganic phosphor powder may range from 5 to 25 μm. When the average particle size of the inorganic phosphor powder is selected, it may by selected in consideration of an average particle size of the transparent ceramic powder.
The binder compound functions to improve strength of the mixture of the transparent ceramic powder and the phosphor powder. A material having at least one silicate (SiO2) in a molecule may be used as the binder compound. Furthermore, a material, which does not have an effect on optical properties of the phosphor plate and a lighting device, may be used as the binder compound. Even through it will be described in detail later, when the phosphor-transparent ceramic composite composition is subjected to heat treatment, the silicate is cross-linked with that of the transparent ceramic powder. Accordingly, the formation of pores, which may be generated after the heat treatment of the phosphor-transparent ceramic composite composition, is prevented so that strength of the phosphor plate can be improved. Tetraethyl orthosilicate (TEOS), tetramethyl orthosilicate, tetrapropyl orthosilicate, tetraisopropyl orthosilicate or a mixture thereof may be used as the binder compound. The binder compound is contained in an amount of 0.2 to 5 parts by weight with respect to 100 parts by weight of the transparent ceramic powder. When the amount of the binder compound is less than 0.2 parts by weight, an amount of the cross-linked silicate is not sufficient, so that pores may be generated in the phosphor plate. On the contrary, when the amount of the binder compound is more than 5 parts by weight, impurities such as an excessive organic compound may remain in a state of being not removed after the heat treatment. The phosphor-transparent ceramic composite composition explained through the embodiment may be applied to the first phosphor layer or the second phosphor layer of each ceramic phosphor plate according to Examples 1 to 10. In such a case, physical hardness of the phosphor plate can be increased.
A phosphor-transparent ceramic composite plate according to another aspect of the present example is formed by firing the phosphor-transparent ceramic composite composition including at least one powdered inorganic phosphor dispersed in the transparent ceramic powder and a cross-linking agent being cross-linked by heat treatment in at least two steps. Since the description of the phosphor-transparent ceramic composite composition has been previously performed, the description is omitted for avoiding overlapping.
The phosphor-transparent ceramic composite composition is put into a ball mill device and is then sufficiently pulverized and mixed at 130 to 150 rpm for 10 to 30 hours at room temperature. The pulverized and mixed phosphor-transparent ceramic composite composition is subjected to uniaxial compression to have a plate or disc form in a state of being put into a SUS (Stainless Use Steel) mold. At this time, the compression is performed at the pressure of 1 to 10 ton for 1 to 10 minutes. The mold may have a circular form having a thickness of 100 to 300 μm, and a diameter of 50 to 100 mm. The phosphor-transparent ceramic composite composition molded in the plate form is subjected to heat treatment through at least two steps. This phosphor-transparent ceramic composite composition may be also applied to the first phosphor layer or the second phosphor layer of each ceramic phosphor plate according to Examples 1 to 10.
When the phosphor-transparent ceramic composite composition is subjected to primary heat treatment T1 for 10 to 60 minutes at the temperature of 200 to 300° C., the binder compound B is hydrolyzed to form the transparent ceramic powder G and a cross link B′, thereby creating a composite 310 after primary firing. That is, the binder compound B is hydrolyzed upon the primary heat treatment T1 so that a carbon compound group can be separated, and the remaining silicate can be cross-linked with that of the transparent ceramic powder G. However, the phosphor plate in the step of the primary heat treatment T1 has many pores among the composites 310 as shown in
A temperature of the secondary heat treatment T2 is changed according to each temperature resulting from the kind of the transparent ceramic and the binder compound B. The heat treatment temperature is changed according to each glass transition temperature Tg of the transparent ceramic and the binder compound B. At this time, when the temperature is very high, it may have a bad effect on the phosphor, and accordingly, the heat treatment is performed for 10 to 60 minutes at the temperature of 600 to 650° C. The primarily fired composite 310 heated at a temperature beyond each glass transition temperature Tg of the transparent ceramic and the binder compound B is melted and thus becomes a molded body 320 having a porosity reduced up to less than 1% after secondary firing. Since the phosphor-transparent ceramic composite plate according to the present embodiment is composed of the inorganic compound, a defect such as pores and the like has a large effect on strength and hardness of the molded body. Accordingly, the defect is sufficiently removed during the secondary heat treatment T2.
In order to adjust a surface roughness of the phosphor-transparent ceramic composite plate according to the present embodiment, a surface polishing process is performed after the secondary heat treatment. The more a surface roughness of the phosphor-transparent ceramic composite plate is reduced, the more light irradiated from the light source is uniformly incident to the phosphor-transparent ceramic composite plate, thereby enabling the improvement of optical properties. At this time, a grinding process is performed so that the phosphor-transparent ceramic composite plate can have a surface roughness of 0.2 μm or less.
The phosphor-transparent ceramic composite plate produced as described above is subjected to a dicing process, a drilling process and a packaging process so as to be used in a lighting device. The post processes including a grinding process cause physical damage to the phosphor-transparent ceramic composite plate. Also, when an LED element is driven, under an operation environment (150° C.) and a reflow environment (250° C.), a stress of several N/mm2(MPa) is applied to the phosphor-transparent ceramic composite plate. Since the phosphor-transparent ceramic composite plate according to the present embodiment has a curvature strength of 100 N/mm2 or more, the phosphor-transparent ceramic composite plate can have small damage even upon a process causing physical impacts, such as the grinding process, dicing process, drilling process, packaging process and the like.
The curvature strength may be calculated by the following formula.
Here, L represents a whole length (mm) of the phosphor-transparent ceramic composite plate, F represents a maximum load, b represents an effective width (mm) of the phosphor-transparent ceramic composite plate, and d represents a thickness of the phosphor-transparent ceramic composite plate.
Hereinafter, the present disclosure will be described in greater detail based on examples. The present disclosure may, however, be embodied in different forms and should not be construed as limited to the examples described for the purpose for understanding of the present disclosure.
In order to implement a color temperature of 6000K, 15 g of an LuAG:Ce (Cerium doped lutetium aluminum garnet)-based phosphor having a wavelength of 550 nm, 1.5 g of a nitride-based phosphor (α-SiAION) having a wavelength 595 nm, and 73.5 g of a zinc borosilicate glass powder were mixed, and 10 g of a tetraethyl orthosilicate (TEOS) was added to the mixture. Then, the composition was pulverized and mixed at 136 rpm for 24 hours using a ball mill device.
The composition was put into a SUS mold and was subjected to uniaxial compression at the pressure of 7 ton for 5 minutes so as to be molded in a phosphor plate form having a thickness of 500 μm and a diameter of 60 mm. The molded green body was put into a firing finance and was subjected to primary heat for 30 minutes at the temperature of 250° C. Then, firing was performed for 30 minutes at the temperature of 640° C. The fired phosphor plate was subjected to surface polishing to have a surface roughness of 0.2 μm.
The phosphor plate was processed in a size of 15 mm×200 mm and a thickness of 200 μm, and thus a curvature strength thereof was measured using a micro-autoradiography. The results thereof are shown in Table 1. Also, after cutting a cross section of the phosphor plate, a surface thereof was observed using an SEM (scanning electron microscope) ((A) of
Other conditions are the same as those of Example 1. By producing a phosphor plate to which no TEOS is added, a curvature strength thereof was measured using a micro-autoradiography. The results thereof are shown in Table 1. Also, after cutting a cross section of the phosphor plate, a surface thereof was observed using an SEM (scanning electron microscope) ((B) of
As shown in Table 4 and
An application example in which a lighting device having a different structure is implemented using the phosphor-transparent ceramic composite composition previously described with reference to
Referring to
The phosphor-glass composite plate 420 is packaged on an optical element 410. The optical element 410 may be a device for emitting light, and as one example, a solid light emitting element may be applied. Any one selected from among an LED, an OLED, an LD (laser diode), a laser, and a VCSEL (vertical cavity surface emitting laser) may be applied as the solid light emitting element. When the phosphor-glass composite plate is packaged on the optical element 410, the phosphor-glass composite plate 420 is mounted by interposing an adhesive layer 430 between the phosphor-glass composite plate and the optical element. The phosphor-glass composite plate 420 is mounted to the optical element 410 by applying pressure in a state of bringing the phosphor-glass composite plate 420 in contact with the optical element 410 after coating or laminating the adhesive layer 430 on one surface of the phosphor-glass composite plate 420 or on one surface of the optical element 410. The lighting device may further include an electrode 440 and a wire 442 as other constitutive elements.
With regard to the lighting device according to the present embodiment, the phosphor-transparent ceramic composite composition including 5 to 30 parts by weight of at least one powdered inorganic phosphor, and 0.2 to 15 parts by weight of the binder compound containing at least one silicate and cross-linked by heat treatment with respect to 100 parts by weight of the transparent ceramic powder is implemented, and the high strength phosphor-transparent ceramic composite plate having a porosity of less than 1% is produced via heat treatment of two steps so that physical damage can be reduced during post processes such as a grinding process, a dicing process, a packaging process and the like and in an operational environment, thereby enabling the reduction of a defect rate.
As set forth above, according to some embodiments of the present disclosure, as the ceramic phosphor plate including the first phosphor layer containing a short-wavelength phosphor and the second phosphor layer containing a long-wavelength phosphor is implemented in the transparent ceramic matrix, the amount used of the high-priced long-wavelength phosphor (red phosphor) is reduced so that a production cost can be reduced.
Also, according to some embodiments of the present disclosure, a color temperature can be easily adjusted according to each desired property, and physical properties such as a color rendering index (CRI), optical efficiency and the like can be improved.
According to some embodiments of the present disclosure, the phosphor-transparent ceramic composite composition including 5 to 30 parts by weight of at least one powdered inorganic phosphor, and 0.2 to 15 parts by weight of the binder compound containing at least one silicate and cross-linked by heat treatment with respect to 100 parts by weight of the transparent ceramic powder is implemented, and the high strength phosphor-transparent ceramic composite plate having a porosity of less than 1% is produced via heat treatment of two steps so that physical damage can be reduced during post processes such as a grinding process, a dicing process, a packaging process and the like and in an operational environment, thereby enabling the reduction of a defect rate.
As previously described, in the detailed description of the disclosure, having described the detailed exemplary embodiments of the disclosure, it should be apparent that modifications and variations can be made by persons skilled without deviating from the spirit or scope of the disclosure. Therefore, it is to be understood that the foregoing is illustrative of the present disclosure and is not to be construed as limited to the specific embodiments disclosed, and that modifications to the disclosed embodiments, as well as other embodiments, are intended to be included within the scope of the appended claims and their equivalents.
The present disclosure has been made keeping in mind the above problems, an aspect of embodiments of the present disclosure provides a ceramic phosphor plate including a first phosphor layer containing a short-wave phosphor and a second phosphor layer containing a long-wave phosphor in a transparent ceramic matrix, wherein the ceramic phosphor plate reduces a production cost by reducing an amount used of the high-priced long-wave phosphor (red phosphor) and enables a color temperature to be easily adjusted according to each desired property, enabling the improvement of physical properties such as a color rendering index (CRI), optical efficiency and the like.
Another aspect of the embodiments of the present disclosure provides a ceramic phosphor plate that can enable the reduction of a defect rate thanks to small physical damage generated during post processes such as a grinding process, a dicing process, a drilling process, a packaging process and the like and in an operational environment by implementing a high intensity phosphor-transparent ceramic composite plate.
According to an aspect of the embodiments of the present disclosure, there is provided a ceramic phosphor plate, including: a first phosphor layer containing a short-wave phosphor in a transparent ceramic matrix; and a second phosphor layer containing a long-wave phosphor.
Also, according to another aspect of the embodiments of the present disclosure, there is provided a lighting device, including: a first phosphor layer containing a short-wave phosphor having a wavelength 510 to 580 nm in a transparent ceramic matrix; a second phosphor layer containing a long-wave phosphor having a wavelength 580 to 680 nm; and a light incoming part.
In an embodiment of the present disclosure, there is provided a phosphor-transparent ceramic composite composition including 5 to 30 parts by weight of at least one powdered inorganic phosphor, and 0.2 to 15 parts by weight of a binder compound containing at least one silicate and cross-linked by heat treatment with respect to 100 parts by weight of a transparent ceramic powder, and there is provided a ceramic phosphor plate including the phosphor-transparent ceramic composite composition.
Also, according to a further another aspect of the embodiments of the present disclosure, there is provided a phosphor-transparent ceramic composite plate formed by firing a phosphor-glass composite composition including at least one powdered inorganic phosphor dispersed in transparent ceramic powder and a cross-linking agent cross-linked by heat treatment in at least two steps.
Also, according to yet another aspect of the embodiments of the present disclosure, there is provided a lighting device including a phosphor-transparent ceramic composite plate having a porosity of less than 1% formed by firing a phosphor-glass composite composition including at least one powdered inorganic phosphor dispersed in transparent ceramic powder and a cross-linking agent cross-linked by heat treatment in at least two steps.
Any reference in this specification to “one embodiment,” “an embodiment,” “example embodiment,” etc., means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment of the disclosure. The appearances of such phrases in various places in the specification are not necessarily all referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with any embodiment, it is submitted that it is within the purview of one skilled in the art to effect such feature, structure, or characteristic in connection with other ones of the embodiments.
Although embodiments have been described with reference to a number of illustrative embodiments thereof, it should be understood that numerous other modifications and embodiments can be devised by those skilled in the art that will fall within the spirit and scope of the principles of this disclosure. More particularly, various variations and modifications are possible in the component parts and/or arrangements of the subject combination arrangement within the scope of the disclosure, the drawings and the appended claims. In addition to variations and modifications in the component parts and/or arrangements, alternative uses will also be apparent to those skilled in the art.
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