The present application relates to laboratory analysis of fluids, particularly fluids with drag reducing additives added thereto.
Drag reducers are chemical additives, which being added to a fluid, significantly reduce friction pressure losses on fluid transport in a turbulent regime through pipelines. Such chemical additives, usually polymers, may decrease pressure drop by up to 80 percent, and thus allows reducing the friction losses to the same extent.
The efficiency of drag reducers is usually tested in a flow loop. For a given drag reducer type and concentration a pressure drop along a laboratory pipe is measured at the Reynolds number that is maximally close to that expected in an industrial pipeline. A relative reduction in the pressure drop, in comparison to that in a flow free of drag reducers, is a measure of the additive efficiency.
Kalashnikov, V. N., “Dynamical Similarity and Dimensionless Relations for Turbulent Drag Reduction by Polymer Additives,” Journal of Non-Newtonian Fluid Mechanics, Vol. 75, 1998, pp. 1209-1230, describes a Taylor-Couette device used for studies of turbulent drag reduction caused by polymer additives. The Taylor-Couette device includes a rotating outer cylinder and an immobile inner cylinder. An effect of a drag reducer was evaluated by the torque, applied to the inner cylinder. The greater reduction in torque resulting from the additive resulted in improved drag reducer performance. The drag reduction was investigated for a wide range of Reynolds numbers and the author suggests dimensionless criteria for drag reduction characterization.
Koeltzsch et al., “Drag Reduction Using Surfactants in a Rotating Cylinder Geometry,” Experiments in Fluids, Vol. 24, 2003, pp. 515-530, studies turbulent drag reduction in a device of a similar design. Note that measurement of the torque applied to the inner cylinder has a limited accuracy due to unavoidable friction in bearings.
The present application provides a method of characterizing fluid flow in a pipe where the fluid includes a drag reducing polymer of a particular type and particular concentration. A computational model is configured to model flow of a fluid in a pipe. The computational model utilizes an empirical parameter for a drag reducing polymer of the particular type and the particular concentration. The computational model can be used to derive information that characterizes the flow of the fluid in the pipe.
In one embodiment, the empirical parameter for the particular type and concentration of the drag reducing polymer can be derived by solving another computational model that is configured to model turbulent flow in a Couette device for a fluid that includes a drag reducing polymer of the particular type and concentration. The solution of the empirical parameter for the particular type and concentration of the drag reducing polymer can calculated from experimental data derived from operation of the Couette device with a fluid that includes a drag reducing polymer of the particular type and concentration.
In another embodiment, the computational model of the pipe flow includes a drag reduction parameter that is a function of the empirical parameter. The drag reduction parameter is a function of a dimensionless pipe radius R+. For example, the computational model of the pipe flow can be configured to relate the drag reduction parameter to the empirical parameter by an equation of the form:
D*=1+α*R+
where
In yet another embodiment, the computational model of the pipe flow includes a friction factor that is a function of the drag reduction parameter, wherein the friction factor relates pressure loss due to friction along a given length of pipe to the mean flow velocity through the pipe. For example, the computational model of the pipe flow can be configured to relate the friction factor to the drag reduction parameter by an equation of the form:
where
The computational model of the pipe flow can be based upon a representation of the flow as two layers consisting of a viscous outer sublayer that surrounds a turbulent core.
The computational model for the turbulent Couette flow can be based upon a representation of the turbulent Couette flow as three layers consisting of viscous outer and inner sublayers with a turbulent core therebetween.
In one embodiment, the Couette device defines an annulus between first and second annular surfaces, and the computational model for the turbulent Couette flow includes a first drag reduction parameter associated with the first annular surface and a second drag reduction parameter associated with the second annular surface, wherein both the first and second drag reduction parameters are also functions of the empirical parameter specific to a drag reducing polymer of the particular type and the particular concentration. The first and second drag reduction parameters are also functions of a dimensionless torque G applied to the Couette device rotor.
The computational model for the turbulent Couette flow can also be based on an equation that defines a fluid velocity at a boundary of a viscous sublayer adjacent one of the first and second annular surfaces. Such equation can be derived by momentum conservation for a turbulent core.
The inner cylinder 120 is mounted on bearings and is coaxial with the outer cylinder 104. The outer cylinder 104 is fixed in position and thus remains stationary. The inner cylinder 120 rotates independently of the outer cylinder 104. A shaft 122 extends down from the bottom of the inner cylinder 120. A motor 124 has an output shaft 124A that is mechanically coupled to the shaft 122 by means of a coupling device 128, which can be a magnetic coupler, a rigid coupler, a flexible coupler, or other suitable coupling mechanism. In the preferred embodiment, the motor 124 can operate over a wide range of rotational speeds (e.g., 100-20,000 rpm) for rotating the inner cylinder 120 at different angular velocities.
Instrumentation can be added to the Couette device 100 as needed. For example, devices for heating and/or cooling the fluids within the annulus 108 of the Couette device 100 may be added. Such devices may be used in conjunction with loading fluid into the annulus 108 to achieve a predetermined pressure in the annulus 108. Pumps are used to transfer the fluids into the annulus 108. The pumps define and maintain the pressure of the system. One or more temperature sensors and one or more pressure sensors can be mounted adjacent the annulus 108 to measure fluid temperature and pressure therein. In one embodiment, the rotational speed of the inner cylinder 120 is measured through the use of a proximity sensor, which measures the rotational speed of the shaft 122 mechanically coupled to the inner cylinder 120.
A schematic diagram of the Couette device 100 is shown in
The shear stress of the fluid at the inner surface 104A of the wall of the outer cylinder 104 is measured using the Lenterra technique that combines a floating element 301 and a mechanical cantilever beam 303 with a micro-optical strain gauge (fiber Bragg grating or FBG) 305 as shown in
A. Couette Device Computational Model
The Couette fluid flow in the annulus 108 of the Couette device 100 can be studied in terms of the dimensionless torque G and the Reynolds number Rec for such fluid flow. The dimensionless torque G is defined as a function of the torque T derived from shear stress τw measured at the inner wall surface 104A of the outer cylinder 104 of the Couette device 100 as follows:
The Reynolds number Rec for Couette fluid flow in the annulus 108 of the Couette device 100 can be calculated as:
To model the Couette flow in the Couette device 100, the flow field of turbulent Couette fluid flow in the Couette device 100 can be described by three layers including a relatively viscous outer sublayer 151 adjacent the inner surface 104A of the outer cylinder 104, a viscous inner sublayer 155 adjacent the outer surface 120A of the inner cylinder 120, and a turbulent layer or core 153 between the viscous inner and outer sublayers 151, 155 as shown in
The model assumes a linear velocity distribution across the viscous outer sublayer 151:
u+=y+,y+≤δ0+ (3)
The initial condition for Eq. (4) is the normalized velocity at the viscous outer sublayer surface boundary u+ (δ0+) equal to a parameter λ (i.e., u+(δ0+)=λ). In one embodiment, the parameter λ is set to a predetermined value such as 11.6 assuming the dimensionless velocity distribution across the laminar sublayer in a Couette flow is identical to that in the pipe wall vicinity.
The analytical solution of Eq. (4) is given by:
R+ can be expressed through the dimensionless torque G as follows:
The momentum conservation equation for the turbulent core 153 for the region confined by the gap centerline 154 at Rm=0.5(r0+R) and the outer surface of the viscous inner sublayer 155 can be given as:
The initial condition for Eq. (8) can derived from the normalized velocity at the gap centerline 154 at Rm=0.5(r0+R) according to Eq. (5) as follows:
Then, the analytical solution of Eq. (8) is given by:
The circumferential velocity Ui is the velocity of the rotating cylinder surface 120A of the inner cylinder 120 and calculated as:
Ui=ωr0. (11a)
The circumferential velocity Ui can also be calculated by:
Ui=u(r0+δi)+λui* (11b)
Eq. (11b) can be rewritten as follows:
The left-hand side of Eq. (12) can be expressed through the dimensionless torque G and the Reynolds number Rec to obtain:
For the right-hand side of Eq. (13), the velocity u (r0+δi) can be equated to u (r0+δ0η) and then calculated by Eq. (10) to give:
Eqs. (9), (13) and (14) represent a computation model for Couette flow without a drag reducer that can be solved to calculate the relationship of the dimensionless torque G as a function of the Reynolds number Ree for the Couette flow without a drag reducer.
B. Extension of Couette Device Computational Model to Account for Drag Reducer
The computational model for the Couette flow without a drag reducer as described above can be extended by considering two distinct drag reduction parameters: the drag reduction parameter D0* for the viscous outer sublayer 151, and the drag reduction parameter Di* for the viscous inner sublayer 155.
The drag reduction parameter D0* for the viscous outer sublayer 151 can be related to the parameter α* that is a function of the drag reducer agent type and its concentration as follows:
where
Similarly, the drag reduction parameter Di* for the viscous inner sublayer 155 can be related to the parameter α* that is a function of the drag reducer agent type and its concentration as follows:
where
The Reynolds number of the Couette flow Rec is given by:
where
Eq. (16) can be used to rewrite Eq. (15a) as follows:
Similarly, Eq. (16) can be used to rewrite Eq. (15b) as follows:
As described in Eqs. (11) and (12) above, the ratio
of Eq. (17a) can be defined as:
Eq. (18) can be used to rewrite Eq. (17a) as follows:
Similarly, the ratio
of Eq. (17b) can be defined as:
Eq. (20) can be used to rewrite Eq. (17b) as follows:
By analogy with a pipe flow, the thickness δ0+ of the viscous outer sublayer 151 is related to the drag reduction parameter D0* for the viscous outer sublayer 151 as follows:
δ0+=11.6D0*3 (22)
Similarly, the thickness δi+ of the viscous inner sublayer 155 is related to the drag reduction parameter Di* for the viscous inner sublayer 155 as follows:
δi+=11.6Di*3 (23)
The corresponding dimensionless velocity λ0 at the boundary of the viscous outer sublayer 151 can be given as:
The corresponding dimensionless velocity λi at the boundary of the viscous inner sublayer 155 can be given as:
The normalized velocity at the boundary of the inner viscous sublayer 155 can be derived on the basis of Eq. (10) above to provide:
where m=δi+/r0+, r0+=R+ where R+ is calculated by Eq. (7).
The normalized velocity at the gap centerline 154 of Eq. (26)
is given by Eqs. (9) and (6) as repeated below:
The parameter α=δ0+/R+ and λ=λ0 needed for Eq. (28) can be determined for the outer cylinder by Eqs. (19), (22) and (24).
The set of Eqs. (13), (19), (21)-(27) define a computational model for the Couette flow that accounts for the drag reducing effects of the drag reducer. The computational model is dependent on the dimensions of the Couette device 100, including the radius R of the inner wall surface 104A of the outer cylinder 104, the ratio η (which is the ratio r0/R), and the height L of the gap of the Couette device 100. The parameter α* is the major model variable that is a function of the drag reducer agent type and its concentration.
The fluid density ρ and the kinematic viscosity ν of the fluid are measured separately.
The shear stress τw and corresponding rotor angular velocity ω of the Couette device 100 are measured during operation of the Couette device 100 for a given drag reducer agent type and its concentration.
The value of the parameter α* for the given drag reducer agent type and concentration of the test can be provided by statistical analysis of experimental data. Specifically, experiments can be carried out with the Couette device for a fluid solution that employs a given drag reducing additive at a particular concentration where the shear stress τw is measured for a set of different rotor angular velocities ω. The set of measurements of shear stress and corresponding rotor angular velocity as well as the measured fluid density ρ and the kinematic viscosity ν are input to the computation model based on Eqs. (13), (19), (21)-(27) to solve for the parameter α* for the given drag reducer agent type and its concentration.
An important aspect of drag reduction phenomenon, not accounted for by the drag reduction model presented, is the maximum drag reduction asymptote. This asymptote provides the minimum Fanning friction factors obtainable. The minimum friction factor obtainable in a pipe flow is described by the empirical equation of Virk (1971):
The Fanning friction factor f for the inner cylinder of the Couette device is calculated from the shear-stress equation applied to the inner cylinder using Eqs. (1) and (7) and takes the following form:
The preferable radius ratio η for the Couette device is below 0.7. It follows from the dependences 1/f0.5 versus Re f0.5 calculated for different coefficients α*
C. Application of Couette Device Computational Model Solution of Part B to Pipe Flow Modeling and Analysis
For a fluid solution employing a drag reducing agent that flows in a pipe, the flow field for turbulent flow in the pipe can be described by two layers, which include a relatively viscous outer sublayer adjacent the pipe wall and a turbulent inner core surrounded by the viscous outer sublayer.
Applying the approach proposed by Yang and Dou in “Turbulent Drag Reduction with Polymer Additive in Rough Pipes,” Journal of Fluid Mechanics, Vol. 642, 2010, pp. 279-294, the velocity distribution across the viscous sublayer at the pipe wall may be obtained in the following form:
u+=2.5 ln y++11.6D*2−7.5 ln D*−6.1 (31)
where
The drag reduction parameter D* of Eq. (31) is related to the parameter α* that is a function of the drag reducer agent type and its concentration as described above in the computational model of Part B as follows:
D*=1+α*R+ (32)
where R+ is the dimensionless pipe radius.
The normalized mean flow velocity
can be calculated by averaging the velocity u+ of Eq. (31) over the pipe cross-section as:
Furthermore, the normalized mean flow velocity
is related to the friction factor f by:
The integration of Eq. (33) can be performed analytically to obtain an equation for the friction factor f as follows:
As given by Eq. (32), the drag reduction parameter D* of Eq. (35) is a function of the dimensionless pipe radius R+, which can be related to the Reynolds number Re of the flow in the pipe and the friction factor f by:
R+=0.5Re√{square root over (f/2)} (36)
The Reynolds number Re of Eq. (36) is Oven by:
The dimensionless pipe radius is calculated as:
Equation (35) is the major model equation for calculating the friction factor f* The friction factor can be used for engineering calculations of the pipe flow, such as the predicted pressure drop in the pipe (over the length L) for the flow employing a particular drag reducer agent type and concentration, which is given as
The fluid density ρ and the kinematic viscosity ν of the fluid are measured separately.
The Reynolds number Re of the fluid flow is determined by the mean flow velocity, the pipe diameter and the fluid kinematic viscosity, which are known.
The parameter α* that is a function of the drag reducer agent type and its concentration is given by the solution of the computational model in Part B for the given drag reducer agent type and its concentration.
These operations can be carried out for a number of different concentrations of a particular drag reducer agent type or over different drag reducer agents to characterize the expected pipe flow for these different scenarios. It can also be carried out for a number of fluid flows with different Reynolds number Re to characterize the expected pipe flow for these different scenarios.
The computational models of Parts A, B, and C of the present application can be realized by one or more computer programs (instructions and data) that are stored in the persistent memory (such as hard disk drive or solid state drive) of a suitable data processing system and executed on the data processing system. The data processing system can be a realized by a computer (such as a personal computer or workstation) or a network of computers.
Advantageously, the computational model of Part C characterizes the pipe flow of a dilute drag reducer polymer solution through the use of an empirical parameter that is a function of the drag reducer polymer type and concentration. This empirical parameter can be derived from the solution of a computation model for turbulent Couette flow of such drag reducer polymer solutions based upon experiments that generate and measure properties of the turbulent Couette flow for such dilute drag reducer polymer solutions as described in Part B above.
Furthermore, the computational models of the present application employ a two layer representation of the boundary layer interfaces for both the turbulent Couette flow and the pipe flow in order to simplify the equations for such fluid flow. Specifically, the turbulent Couette flow is represented by three layers including viscous inner and outer sublayers with a turbulent core therebetween, and the pipe flow is represented by a viscous outer sublayer that surrounds a turbulent core. The computation model of the turbulent Couette flow also provides for computation of the dimensionless torque applied to the Couette device as a function of the rotation speed for a given drag reducer polymer type and its concentration.
There have been described and illustrated herein embodiments of computational models that characterize the pipe flow of a dilute drag reducer polymer solution with the use of an empirical parameter that is a function of the drag reducer polymer type and its concentration. This empirical parameter can be derived from the solution of a computation model for turbulent Couette flow of such drag reducer polymer solutions based upon experiments that generate and measure properties of the turbulent Couette flow for such dilute drag reducer polymer solutions. While particular embodiments have been described, it is not intended that the embodiments be limited thereto. It will therefore be appreciated by those skilled in the art that yet other modifications could be made to the provided embodiments without deviating from its scope as claimed.
Filing Document | Filing Date | Country | Kind |
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PCT/US2013/068940 | 11/7/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2015/069260 | 5/14/2015 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
3692676 | Culter | Sep 1972 | A |
3938536 | Metzner | Feb 1976 | A |
4077251 | Winter | Mar 1978 | A |
4734103 | Fong | Mar 1988 | A |
4896098 | Haritonidis | Jan 1990 | A |
5538191 | Holl | Jul 1996 | A |
6471392 | Holl | Oct 2002 | B1 |
6782735 | Walters | Aug 2004 | B2 |
6874353 | Johnson | Apr 2005 | B2 |
6959588 | Zougari | Nov 2005 | B2 |
7288506 | Jovancicevic | Oct 2007 | B2 |
7581436 | Eskin | Sep 2009 | B2 |
8004414 | Angell | Aug 2011 | B2 |
8020617 | Shenoy | Sep 2011 | B2 |
8039055 | Moore | Oct 2011 | B2 |
8276463 | Sheverev | Oct 2012 | B2 |
8794051 | Morgan | Aug 2014 | B2 |
10228296 | Yang | Mar 2019 | B2 |
10413901 | Slepian | Sep 2019 | B2 |
20030056575 | Hettwer | Mar 2003 | A1 |
20030192693 | Wellington | Oct 2003 | A1 |
20040255649 | Zougari | Dec 2004 | A1 |
20080047328 | Wang | Feb 2008 | A1 |
20080289435 | Slater | Nov 2008 | A1 |
20090053811 | Black | Feb 2009 | A1 |
20090294122 | Hansen | Dec 2009 | A1 |
20100004890 | Tonmukayakul | Jan 2010 | A1 |
20100326200 | Sheverev | Dec 2010 | A1 |
20110274875 | Lang | Nov 2011 | A1 |
20130036829 | Van Steenberge | Feb 2013 | A1 |
20130041587 | Gomaa | Feb 2013 | A1 |
20140137638 | Liberzon | May 2014 | A1 |
20150017385 | Lang | Jan 2015 | A1 |
20150027702 | Godoy-Vargas | Jan 2015 | A1 |
20150226657 | Foster | Aug 2015 | A1 |
20160339434 | Toner | Nov 2016 | A1 |
Entry |
---|
V.N. Kalashnikov (Dynamical similarity and dimensionless relations for turbulent drag reduction by polymer additives, Elsevier Science B.V., 1998, pp. 209-230) (Year: 1998). |
Yang et al. hereafter Yang (“Turbulent drag reduction with polymer additive in rough pipes”, J. Fluid Mech. (2010), vol. 642, pp. 279-294) (Year: 2010). |
Michael D. Graham (“Drag Reduction in Turbulent Flow of Polymer Solutions”, Rheology Reviews 2004, pp. 143-170) (Year: 2004). |
Greidanus et al. (“Drag reduction by surface treatment in turbulent Taylor-Couette flow”,13th European Turbulence Conference, 2011, pp. 1-9) (Year: 2011). |
Japper-Jaafar et al. (“Turbulent pipe flow of a drag-reducing rigid “rod-like” polymer solution”, J. Non-Newtonian Fluid Mech. 161 (2009) 86-93) (Year: 2009). |
Ptasinski et al, (“Experiments in Turbulent Pipe Flow with Polymer Additives at Maximum Drag Reduction”, 2001 Kluwer Academic Publishers, pp. 159-182) (Year: 2001). |
Drappier et al. (“Turbulent drag reduction by surfactants”, Europhys. Lett., 74 (2), pp. 362-368 (2006)) (Year: 2006). |
Dmitry Eskin (“An engineering model of a developed turbulent flow in a Couette device”, Chemical Engineering and Processing 49 (2010) 219-224) (Year: 2010). |
Kalashnikov, V. N., “Dynamical Similarity and Dimensionless Relations for Turbulent Drag Reduction by Polymer Additives,” Journal of Non-Newtonian Fluid Mechanics, 1998, 75(2-3), pp. 209-230. |
Koeltzsch, K. et al., “Drag Reduction Using Surfactants in a Rotating Cylinder Geometry”, Experiments in Fluids, 2003, 34, pp. 515-530. |
Yang, S.-Q. et al., “Turbulent Drag Reduction with Polymer Additive in Rough Pipes”, Journal of Fluid Mechanics, 2010, 642, pp. 279-294. |
Li et al., “A direct measurement of wall shear stress in multiphase flow—Is it an important parameter in CO2 corrosion of carbon steel pipelines?”, Corrosion Science, vol. 110, pp. 35-45, 2016. |
Number | Date | Country | |
---|---|---|---|
20160275221 A1 | Sep 2016 | US |