The present disclosure relates to the field of valves, more particularly valves used in high pressure applications wherein a poppet is selectively seated against a seat surrounding a high pressure fluid flow passage, and the seating thereof against the seat prevents the high pressure fluid from flowing through the high pressure fluid flow passage to a vent or outlet passage of the valve. In an overpressure condition, the poppet will lift off of the seat, allowing the high pressure fluid to flow through the high pressure fluid flow passage to a vent or outlet passage of the valve, thereby relieving the overpressure condition at the high pressure fluid flow passage.
High pressure fluid circuits require pressure relief valves therein, which when an overpressure condition is present in the high pressure fluid circuit, allow fluid in the high pressure fluid circuit to pass therethrough to a lower pressure environment, and thereby relieve the overpressure condition in the high pressure fluid circuit. One issue with such valves is the use thereof in high fluid pressure circuits where the fluid is also carrying therein abrasives, for example a fracing fluid circuit wherein a fracing fluid, having proppants therein, is pumped to a high pressure to fracture rock formations in subsurface formations.
The abrasive nature of fracing fluids has limited the use of poppet based pressure relief valves in fracing fluid circuits, particularly high pressure fracing fluid circuits, as the rapidly abrade the seat or facing sealing face of the poppet to the condition where the valve will no longer seal off the high pressure fluid from passage therethrough, or otherwise erode the internal structures of the valve rendering it no longer useful for its intended purpose.
Provided herein are valve constructs configured to provide a poppet valve for use as a pressure relief valve for a high pressure fluid circuit, including a high pressure fluid circuit for highly abrasive laden fluids, for example fracing fluids.
In one aspect, there is provided a valve having a first body having an inlet and a ledge surrounding the inlet at a location inwardly of the body, a second body having an outlet and a poppet bore having a circumferential poppet bore surface, a poppet located in the poppet bore and having a sealing face, the sealing face facing the ledge of the first body, and a sealing arrangement having a circumferential support surface, a compressible seal ring having an uncompressed free state and a compressed state, an outer circumferential surface, and an inner circumferential surface facing the circumferential support surface, and a split ring disposed over the outer circumferential surface of the compressible seal ring, the compressible seal ring in a compressed state between the split ring and the inner circumferential surface.
In another aspect, there is provided a valve, having a first body having an inlet and a ledge surrounding the inlet at a location inwardly of the body, a second body having an outlet and a poppet bore having a circumferential poppet bore surface, a poppet located in the poppet bore and having a sealing face, the sealing face facing the ledge of the first body and comprising at least one of a single crystal sapphire ring or a single crystal ruby ring having a seal ring annular surface facing the inlet, a sealing arrangement comprising a circumferential support surface, and a compressible seal ring, and a biasing member biasing the poppet in the direction of the inlet, wherein the seal ring annular surface is selectively engageable against the compressible seal ring.
In another aspect, there is provided a valve having a first body having an inlet and a ledge surrounding the inlet at a location inwardly of the body, a second body having an outlet and a poppet bore having a circumferential poppet bore surface, a poppet located in the poppet bore and having an annular sealing face, the sealing face facing the ledge of the first body, a sealing arrangement comprising a circumferential support surface, and a compressible seal ring, a poppet guide, the poppet guide comprising a central bore and a plurality of flow passages extending therethrough and circumferentially spaced from one another about the central bore; and a biasing member configured to bias the annular sealing face in the direction of the compressible seal ring.
In another aspect, a valve includes a first body having an inlet and a ledge surrounding the inlet at a location inwardly of the body, a second body having an outlet and a poppet bore having a circumferential poppet bore surface, a poppet located in the poppet bore, the poppet having a sealing face, the sealing face facing the ledge of the first body and a recess extending inwardly of the poppet and terminating at a base thereof, the base facing the inlet, the sealing face extending around the recess at a location intermediate of the base and the inlet, a sealing arrangement comprising a circumferential support surface, and a compressible seal ring and a biasing member biasing the poppet in the direction of the inlet, wherein the seal ring annular surface is selectively engageable against the compressible seal ring.
In another aspect, a method of forming a valve includes providing a first body having a first flow passage extending therethrough, and a circumferential ledge surrounding at least a portion of the first flow passage positioning a seal ring having an inner circumferential surface and an outer circumferential surface over the circumferential ledge positioning a split ring having a first portion comprising a first arcuate inner surface and a second portion having a second arcuate inner surface over the outer circumferential surface of the seal ring, with the first arcuate inner surface of the first portion of the split ring contacting a first portion of the outer circumferential surface of the seal ring and the second arcuate inner surface of the second portion of the split ring contacting a second portion of the outer circumferential surface of the seal ring and forming and maintaining a biasing force biasing the first arcuate inner surface of the first portion of the split ring contacting a first portion of the outer circumferential surface of the seal ring in the direction of the second portion of the split ring contacting a second portion of the outer circumferential surface of the seal ring.
Referring initially to
As shown in
Inlet body 12 is configured of a material such as steel, such as a high strength alloy steel. It includes an outer surface 42, a first bore 44 having a first circumference and extending inwardly of the inlet body 12 generally centered about a valve centerline 46, a second bore 48 having a second circumference greater than the first circumference, and an annular base wall 50. The second bore 48 includes an inner second bore wall 52 extending inwardly of the receiving end 54 of the inlet body 12, which is bounded by an annular end wall 56 surrounding the opening of the second bore 48 at the receiving end 54 of the inlet body 12. Annular base wall 50 extends generally perpendicular to, and from the inward terminus of, the second bore wall 52 to the opening of the first bore 44 into the second bore 48. Threads 58 extend along the inner bore wall 52 from the opening thereof at the annular end wall 56 of the inlet body 12 and at least partially along the expanse thereof in the direction of annular base wall 50.
Outlet body 16 includes an outer wall 60, outlet bore 62 opening into the outlet body 16 inwardly of the annular outlet end wall thereof, a tapered bore 66 extending inwardly of outlet body 16 therefrom, a spring bore 68 extending inwardly of outlet body 16 from the tapered bore 66, and major bore 70 extending from the spring bore 68 and terminating at the second body annular end wall 72. Spring bore 68 is larger in circumference than is outlet bore 62, and major bore 70 is larger in circumference than spring bore 68. Spring bore 68 is also larger in circumference than any circumference of the tapered bore 66, and tapered bore 66 extends from the end of the outlet bore 62 distal to outlet end wall to the spring bore 68. An annular spring ledge 74 extends from the inner terminus of the tapered bore 66 into the outlet body 16 to the spring bore 68, generally perpendicular to the valve centerline 46. Additionally, an annular retainer ledge 76 extends from the opening of the spring bore 68 into the major bore 70 to the inner circumferential surface 78 of the major bore 70. Outer wall 60 includes a spool 80 surrounding the outlet bore 62 and terminating in a raised circumferential flange 64, the spool 80 extending from the raised circumferential flange 64 to an annular outer wall 82. Annular outer wall 82 extends radially outwardly thereof and terminates at an outer short wall 84, which extends therefrom and terminates at annular limit wall 86. Annular limit wall 86 extends radially inwardly from outer short wall 84 to a stub wall 88 which surrounds inner circumferential surface 78 of the major bore 70, and terminates at the annular end wall 72. Stub wall 88 is threaded at least from a location thereof adjacent to the annular limit wall 86 to a location thereof intermediate of annular limit wall 86 and annular end wall 72. Thus, stub wall 88 may be threaded into the threads of the inner second bore wall 52 of the inlet body to secure the outlet body 16 to the inlet body 12. An undercut groove 90 is located on the stub wall 88 between the annular end wall 86 and the beginning of the threaded portion 92 of the stub wall 88.
The inner circumferential surface 78 of the major bore 70, the annular base wall of the inlet body 12, the annular retainer ledge 76, annular spring ledge 74 and a spring bore circumferential wall 94 bound the inner volume 24 of the valve 10 where the seal assembly 26, poppet 28 and biasing member 38 are maintained. Biasing member 38 is here configured as a spring coil 100 having a first end 96 in contact with the annular spring ledge 74 and a second end 98 thereof in contact with the backing ring 36 of the poppet 28. The spring coil 100 provides a bias against the backing ring 36 in the direction of the inlet 20 where the second end 98 thereof contacts the backing ring 36 of the poppet 28, to bias the seal 32 carried in the poppet body 30 of the poppet 28 into contact with the seal assembly 26. In this position of the poppet 28, fluid at the inlet 20 is prevented from passing through the valve 10 to the outlet 22.
Here, poppet 28 is configured as a unitary member comprising the poppet body 30 having the seal 32 secured thereto, the backing ring 36, and a plurality of struts 110 extending between the poppet body 30 and the backing ring 36, the struts 110 spaced circumferentially about the poppet 28 with flow gaps therebetween. As shown in
Poppet body 30 here includes an annular inlet facing poppet face 122, from which and into the body extends a first counterbore 124 defining a seal recess composed of an annular seal support wall 126 at the inward terminus of the first counterbore 124 and a circumferential seal support wall 128 forming the circumferential side wall of the first counterbore 124. A circumferential undercut relief recess 130 extends inwardly of the outer circumferential region of the annular seal support wall 126 and terminates radially outwardly at the base of the circumferential seal support wall 128. A second counterbore 132, having a smaller circumference than the first counterbore 124 and generally centered therein and centered with respect to the first bore 44 of the inlet body 12 extends inwardly of the poppet body 30 from the first counterbore 124. The second counterbore is bounded by a counterbore base wall 136, from which extends in the direction of the inlet 20 a circumferential curved wall 138, from which extends a circumferential second counterbore wall 134, extending therefrom to the inner radial end of the annular seal support wall 126. The outer surfaces of the poppet body 30 include a poppet body major wall 140 extending in a direction away from the annular inlet facing poppet face 122, a chamfered cylindrical wall 142 extending from the end of the poppet body major wall 140 distal to the annular inlet facing poppet face 122, an annular outlet facing wall 144 extending radially inwardly from the end of the chamfered cylindrical wall 142 distal to the poppet body major wall 140, and a circumferential hub wall extending therefrom and terminating at a generally circular end wall 146.
The struts 110 are an integral part of the poppet 28 and interconnect the poppet body 30 to the backing ring 36, such that the poppet body 30 is spaced from the inner circumferential surface 78 of the major bore 70 to form a portion of the plurality of poppet bypass passages 120. Here, each strut 110 has a generally planar aspect having opposed, parallel first and second side walls 148, 150 (
In the aspect of the valve 10 shown in
Seal 32 here is configured of a single crystal material, preferably a corundum material, such as a grown single crystal corundum known as sapphire or ruby. Seal 32 here includes an outer cylindrical seal surface 172 facing the circumferential seal support wall 128, an inner circumferential seal surface 174, a first seal annular side wall 176 facing the annular seal support wall 126, and a second seal annular side wall 178 facing the seal assembly 26. Here, the seal 32 is press fit into the seal recess defined by the annular seal support wall 126 circumferential seal support wall 128. Thus in a free state, before being press fit into the seal recess defined by the annular seal support wall 126 circumferential seal support wall 128, the outer circumferential seal surface 172 has a greater diameter than the diameter of the circumferential seal support wall 128, and the pressing of the seal 32 into the seal recess results in an interference fit securing the seal 32 in the seal recess. Alternatively, the poppet body 30 can be heated to increase the diameter of the circumferential seal support wall 128 to be greater than the outer diameter of the outer circumferential seal surface 172 and the seal 32 placed into the seal recess and the poppet body 30 cooled to shrink and thereby secure the seal assembly 26 therein. The seal 32 may be configured as a rectangle, in section, where each face of the rectangle join at a right angle, or otherwise. For example, as shown in
Seal assembly 26 here includes a guide hub 180 including a guide hub boss 182, over which is piloted a conformable seal ring 184, and two halves of a split ring 186 disposed between the seal ring outer circumferential surface 188 and the inner circumferential sleeve wall 164 of the inner sleeve 40. Split ring 186 is configured to radially inwardly bias the conformable seal ring 184. Where the inner sleeve 40 is not used, the split ring assembly is disposed between the seal ring outer circumferential surface 188 and the inner circumferential surface 78 of the major bore 70.
Guide hub 180 is a generally annular disk shaped member, having an inner circumferential hub bore bounded by an inner spool bore surface 192, which extends from an inlet side annular wall 194 to an outlet side annular wall 196 of the guide hub 180. A hub flange 198 extends radially outwardly from the base of the guide hub boss 182 and radially outwardly therefrom to guide hub outer circumferential surface 200. Here, the diameter of the hub bore 190 is substantially the same or larger than the diameter of the first bore 44 of the inlet 20, such that the inlet side annular wall 194 does not extend radially inwardly of the first bore 44 of the inlet 20. Guide hub outer circumferential surface 200 includes a circumferential seal ring groove 202 extending inwardly thereof, within which a seal, such as an O-ring, or an O-ring with a backing ring or backing rings, is disposed. On the outlet facing side of the hub flange 198 is provided a stepped surface 206, including an inner first portion 208 extending radially outwardly from the base of the guide hub boss 182, a recessed outer second portion 210 extending radially inwardly from the guide hub outer circumferential surface 200, and a circumferential undercut surface 212 extending between the radially outwardly of the guide boss end 214 of the first portion 208 and the radially inwardly of the outer circumferential surface end 216 of the second portion 210.
As shown in
The second annular side face 226 of the half rings 218a, b here include an integral flow guide surface 250 and sleeve recess 252 formed thereon. Thus, second annular side face 226 is configured with a first flow surface 254 extending generally perpendicular to the split ring 196 centerline 235 and radially outwardly from the intersection of the second annular side face 226 with the first half ring inner wall surface 242. First flow surface 254 extends from the intersection thereof with the first half ring inner wall surface 242 to a frustoconical second flow surface 256, which extends radially outwardly therefrom to an inwardly projecting guide ledge 258 extending from the radially outward end of the second flow surface 256 inwardly of the half rings 218a, b. Guide ledge 258 is a surface extending generally parallel to the split ring centerline 234, and terminates at a sleeve limit wall 260 extending radially outwardly thereof, generally perpendicular to the split ring centerline 234, which ends at the outer semi-circumferential surface 220 of the half rings 218a, b. Guide ledge 258 is configured to extend over the outer surface of the inner circumferential sleeve wall 176 of inner sleeve for a portion thereof inwardly thereof from the second sleeve end wall 170.
Referring to
As the poppet 28 begins moving away from the seal assembly 26, such that the poppet 28 is positioned within the inner volume 24 to locate the seal 32 in the poppet body 30 spaced from the seal ring 184, a circumferential gap 262 is created between the annular side wall 178 of the seal 32 and the facing annular seating surface 264 of the conformable seal ring 184. Initially, the higher pressure fluid at the inlet 20, of which the pressure is higher as compared to the pressure of the fluid present in the outlet bore 62, is now able to flow inwardly of the inlet 20, then in a radially outward direction through the circumferential gap 262, where it continues to flow through the poppet bypass passages 120 and the through passages 104 and into the major bore 70, spring bore 68 and tapered bore 66 and thence through the outlet bore 62 to the outlet 22. As the fluid flow from the inlet 20 to the outlet initiates, the size of the gap 262 between the seal 32 and the seal ring 184 and between the inlet facing poppet face 122 and the integral flow guide surface 250 is small, and thus the circumferential gap 262 is small in the direction of the valve centerline 46 as shown in
The width of the gap 262 between the poppet body 30 and the seal assembly 26 is a function of the pressure difference between the inlet 20 and the outlet 22, where the greater the pressure in the inlet is higher than the pressure at the outlet, the farther in the direction of the outlet 22 the poppet 28 will move, limited to its maximum stroke or movement distance where the biasing member 38 can be no further compressed. The flow of the fluid from the inlet 20 to the outlet 22 when the valve is in the open condition shown in
Additionally, the outer circumferential surface of the inner sleeve 40 includes a circumferential sleeve seal groove 272 extending therein, circumferentially around the outer circumferential surface of the inner sleeve 40, and a seal ring 274, such as an O-ring, is received thereinto, to form a seal between the outer circumferential surface of the inner sleeve 40 and the inner circumferential surface 78 of the major bore 70 of the outlet body 16.
Also, here the circumferential seal support wall 128 forming the circumferential side wall of the counterbore 124 includes the seal circumferential sidewall seal groove 278 extending thereinto, and the surface 282 of the seal 32 element and the circumferential seal support wall 128. seal circumferential sidewall seal ring 280 such as an O-ring, received in the seal circumferential sidewall seal groove 278, to form a seal between the outer circumferential The seal circumferential sidewall seal ring 280 is received in the seal circumferential sidewall seal groove 278 can be sized to slightly space the outer circumferential surface 282 of the seal 32 from the circumferential seal support wall 128 to allow the seal 32 to float therein, allowing for the seal 32 to tilt or cock with respect to the circumferential seal support wall 128 as it is engaged against the conformable seal ring 184. Additionally, the seal circumferential sidewall seal ring 280 can be configured to be squeezed between the seal out circumferential surface 282 and the base of, or base and sidewall of, the seal circumferential sidewall seal groove 278, sufficiently to maintain the seal 32 in the seal recess composed of an annular seal support wall 126 at the inward terminus of the first counterbore 124 and a circumferential seal support wall 128 forming the circumferential side wall of the counterbore 124.
Additionally, the outer circumferential surface of the inner sleeve 40 includes the circumferential sleeve seal groove 272 extending therein, circumferentially around the outer circumferential surface of the inner sleeve 40, and the seal ring 274, such as an O-ring, is received thereinto, to form a seal between the outer circumferential surface of the inner sleeve 40 and the inner circumferential surface 78 of the major bore 70 of the outlet body 16.
The poppet body 30 here is configured to create a stagnation region 270 in the second counterbore 132 where the fluid flowing from the inlet 20 through the through the circumferential gap 262 fills the second counterbore 132 but either comes to rest, or is moving relatively slowly, along the surfaces of the second counterbore 132. This reduces the erosion on the surfaces of the poppet 28 facing the inlet 20 as compared to a poppet having a flat surface facing the inlet 20. Additionally, the fluid velocity will be greatest along and generally parallel to the second seal annular side wall 178, where the corundum material presents high resistance to erosion. Thus, the valve 10 provides a number of features resulting in lower wear of the components thereof as compared to traditional poppet valves, including the use of a corundum seal 32 on the poppet 28, and the flow directing features of the seal assembly 26. Additionally, the use of a corundum seal contacting a conformable seal ring 184 configured of, for example, PEEK, Delran, engineered plastics or polymers, or an elastomer, allows the facing surfaces of the seal 32 and seal ring 184 to seal with particulates therebetween, as the seal ring 184 will conform and compress over the particulate materials and still contact the facing surface of the seal. The use of a poppet 28 having struts 110 to center the poppet 28 in the valve inner volume 24 reduces the friction between the poppet and the inner surface of the outlet body 16, or of the inner sleeve 40 where used, and, the relatively area of the facing surfaces of the struts 110 and the inner surface of the outlet body 16 or inner sleeve 40 reduces the likelihood that the poppet 28 will become jammed in the valve due to particulates present between the struts and the facing surface of the outlet body 16 or inner sleeve 40. Additionally, the construct of the poppet 28 facing the inlet 20 to cause flow to stagnate thereat reduces the erosion of the front face of the poppet 28. These and other features of the disclosure are found in the appended claims.
This application claims benefit of U.S. provisional patent application Ser. No. 63/285,639, filed Dec. 3, 2021 and U.S. provisional patent application Ser. No. 63/339,571, filed May 9, 2022, which are herein incorporated by reference.
| Number | Name | Date | Kind |
|---|---|---|---|
| 402600 | Kemp | May 1889 | A |
| 1654642 | Geissinger | Jan 1928 | A |
| 1751664 | Smith | Mar 1930 | A |
| 2140735 | Gross | Dec 1938 | A |
| 2311851 | McClure | Feb 1943 | A |
| 2560841 | Bishop | Jul 1951 | A |
| 2605108 | Stephens | Jul 1952 | A |
| 2685296 | Boosman | Aug 1954 | A |
| 2729226 | Jones | Jan 1956 | A |
| 2799523 | Parker | Jul 1957 | A |
| 2811979 | Presnell | Nov 1957 | A |
| 2821972 | Banker | Feb 1958 | A |
| 2847027 | Kumpman | Aug 1958 | A |
| 2862520 | Cordova | Dec 1958 | A |
| 2867463 | Snider | Jan 1959 | A |
| 2892644 | Collins | Jun 1959 | A |
| 2906290 | Harding et al. | Sep 1959 | A |
| 2973746 | Jupa | Mar 1961 | A |
| 3022794 | Pippenger | Feb 1962 | A |
| 3114391 | Kurtz | Dec 1963 | A |
| 3145723 | Chorkey | Aug 1964 | A |
| 3189049 | Carlson | Jun 1965 | A |
| 3219060 | Pearl et al. | Nov 1965 | A |
| 3225786 | Elliott | Dec 1965 | A |
| 3279805 | Quinson | Oct 1966 | A |
| 3316930 | Garduer | May 1967 | A |
| 3352394 | Longshore | Nov 1967 | A |
| 3421533 | Conn | Jan 1969 | A |
| 3474828 | Wheeler et al. | Oct 1969 | A |
| 3485225 | Bailey et al. | Dec 1969 | A |
| 3533431 | Kuenzel et al. | Oct 1970 | A |
| 3536085 | Taplin | Oct 1970 | A |
| 3540695 | Taylor | Nov 1970 | A |
| 3587647 | Walters | Jun 1971 | A |
| 3598148 | Kroffke | Aug 1971 | A |
| 3635436 | Tillman | Jan 1972 | A |
| 3662950 | McIntosh et al. | May 1972 | A |
| 3683694 | Granberg | Aug 1972 | A |
| 3749122 | Gold | Jul 1973 | A |
| 3797525 | Lieser | Mar 1974 | A |
| 3913620 | Pauliukonis | Oct 1975 | A |
| 3949645 | Masclet | Apr 1976 | A |
| 3978888 | Naono | Sep 1976 | A |
| 4220174 | Spitz | Sep 1980 | A |
| 4240634 | Wiczer | Dec 1980 | A |
| 4253481 | Sarlls, Jr. | Mar 1981 | A |
| 4263938 | Peters | Apr 1981 | A |
| 4281677 | Hoffman | Aug 1981 | A |
| 4336946 | Wheeler | Jun 1982 | A |
| 4396071 | Stephens | Aug 1983 | A |
| 4444216 | Loup | Apr 1984 | A |
| 4457489 | Gilmore | Jul 1984 | A |
| 4475568 | Loup | Oct 1984 | A |
| 4491154 | Peters | Jan 1985 | A |
| 4493335 | Watson | Jan 1985 | A |
| 4554940 | Loup | Nov 1985 | A |
| 4793590 | Watson | Dec 1988 | A |
| 4856557 | Watson | Aug 1989 | A |
| 4877057 | Christensen | Oct 1989 | A |
| 4890645 | Andersen | Jan 1990 | A |
| 4968197 | Chen | Nov 1990 | A |
| 5035265 | Chen | Jul 1991 | A |
| 5069240 | Kurkjian, Jr. | Dec 1991 | A |
| 5190078 | Stoll et al. | Mar 1993 | A |
| 5222521 | Kihlberg | Jun 1993 | A |
| 5301637 | Blount | Apr 1994 | A |
| 5771931 | Watson | Jun 1998 | A |
| 5771993 | Anderson et al. | Jun 1998 | A |
| 5778918 | McLelland | Jul 1998 | A |
| 5797431 | Adams | Aug 1998 | A |
| 5901749 | Watson | May 1999 | A |
| 6041804 | Chatufale | Mar 2000 | A |
| 6257268 | Hope et al. | Jul 2001 | B1 |
| 6264206 | Hashizawa et al. | Jul 2001 | B1 |
| 6296008 | Boyer et al. | Oct 2001 | B1 |
| 6318400 | Hope et al. | Nov 2001 | B1 |
| 6382256 | Kim et al. | May 2002 | B2 |
| 6520478 | Hope et al. | Feb 2003 | B1 |
| 6523613 | Rayssiguier et al. | Feb 2003 | B2 |
| 6651696 | Hope et al. | Nov 2003 | B2 |
| 6668861 | Williams | Dec 2003 | B2 |
| 6702024 | Neugebauer | Mar 2004 | B2 |
| 6843266 | Hope et al. | Jan 2005 | B2 |
| 6901960 | Roberts et al. | Jun 2005 | B2 |
| 6983803 | Watson et al. | Jan 2006 | B2 |
| 7000890 | Bell et al. | Feb 2006 | B2 |
| 7073590 | Neugebauer et al. | Jul 2006 | B2 |
| 7159605 | Thrash, Jr. et al. | Jan 2007 | B2 |
| 7428913 | Benson | Sep 2008 | B2 |
| 7438086 | Bento et al. | Oct 2008 | B2 |
| 7464722 | Jansen | Dec 2008 | B2 |
| 7520297 | Bell et al. | Apr 2009 | B2 |
| 7628170 | Kok-Hiong et al. | Dec 2009 | B2 |
| 7784553 | Moreno | Aug 2010 | B2 |
| 7959161 | Seki et al. | Jun 2011 | B2 |
| 8052119 | Numazaki et al. | Nov 2011 | B2 |
| 8245729 | Zub | Aug 2012 | B2 |
| 8246055 | Asplund et al. | Aug 2012 | B2 |
| 8342202 | Nishio et al. | Jan 2013 | B2 |
| 8397742 | Thrash et al. | Mar 2013 | B2 |
| 8408244 | Gilcher | Apr 2013 | B2 |
| 8453678 | Neff et al. | Jun 2013 | B2 |
| 8469059 | Forst | Jun 2013 | B1 |
| 8474792 | Kubo et al. | Jul 2013 | B2 |
| 8490652 | Bohaychuk et al. | Jul 2013 | B2 |
| 8627893 | Otto et al. | Jan 2014 | B2 |
| 8714193 | Marica | May 2014 | B2 |
| 9121244 | Loretz et al. | Sep 2015 | B2 |
| 9133944 | Haeckel et al. | Sep 2015 | B2 |
| 9297462 | Hattori et al. | Mar 2016 | B2 |
| 9334946 | Mason | May 2016 | B1 |
| 9354638 | Rebreanu et al. | May 2016 | B2 |
| 9423031 | Weintraub et al. | Aug 2016 | B2 |
| 9719600 | Patterson | Aug 2017 | B2 |
| 9874282 | Wetzel et al. | Jan 2018 | B2 |
| 10012325 | Bohaychuk et al. | Jul 2018 | B2 |
| 10385982 | Patterson et al. | Aug 2019 | B2 |
| 11041358 | Jones et al. | Jun 2021 | B2 |
| 20040047748 | Roberts et al. | Mar 2004 | A1 |
| 20040173976 | Boggs | Sep 2004 | A1 |
| 20040262007 | Neugebauer et al. | Dec 2004 | A1 |
| 20050028864 | Thrash et al. | Feb 2005 | A1 |
| 20050067031 | Lee | Mar 2005 | A1 |
| 20060137744 | Anastas | Jun 2006 | A1 |
| 20060237064 | Benson | Oct 2006 | A1 |
| 20070000544 | Thompson | Jan 2007 | A1 |
| 20070069576 | Suzuki | Mar 2007 | A1 |
| 20070113906 | Sturman et al. | May 2007 | A1 |
| 20100044605 | Veilleux | Feb 2010 | A1 |
| 20100140881 | Matsuo | Jun 2010 | A1 |
| 20100154896 | Thrash, Jr. et al. | Jun 2010 | A1 |
| 20100243084 | Yoshioka et al. | Sep 2010 | A1 |
| 20110253240 | Otto et al. | Oct 2011 | A1 |
| 20120248358 | Pic et al. | Oct 2012 | A1 |
| 20120292550 | Meek | Nov 2012 | A1 |
| 20130032222 | Bresnahan | Feb 2013 | A1 |
| 20130037736 | Bresnahan | Feb 2013 | A1 |
| 20130146303 | Gustafson | Jun 2013 | A1 |
| 20130181154 | Robison et al. | Jul 2013 | A1 |
| 20130220441 | Zanettacci | Aug 2013 | A1 |
| 20140116551 | Smith | May 2014 | A1 |
| 20140377111 | Bagagli et al. | Dec 2014 | A1 |
| 20150060715 | Hoang | Mar 2015 | A1 |
| 20150152959 | Mangiagli et al. | Jun 2015 | A1 |
| 20150191996 | Weintraub | Jul 2015 | A1 |
| 20150191997 | Weintraub et al. | Jul 2015 | A1 |
| 20150276072 | Rebreanu et al. | Oct 2015 | A1 |
| 20150276083 | Druhan et al. | Oct 2015 | A1 |
| 20150362083 | Patterson | Dec 2015 | A1 |
| 20150369002 | Patterson | Dec 2015 | A1 |
| 20160103456 | Cho et al. | Apr 2016 | A1 |
| 20160123478 | Wetzel et al. | May 2016 | A1 |
| 20160230900 | Schulz et al. | Aug 2016 | A1 |
| 20160258531 | Ito et al. | Sep 2016 | A1 |
| 20160258537 | Heiderman et al. | Sep 2016 | A1 |
| 20170037984 | Frippiat et al. | Feb 2017 | A1 |
| 20170097100 | Patterson | Apr 2017 | A1 |
| 20170175916 | Huynh et al. | Jun 2017 | A1 |
| 20170189730 | Ernfjall | Jul 2017 | A1 |
| 20170220054 | Zhu et al. | Aug 2017 | A1 |
| 20170241563 | Simpson | Aug 2017 | A1 |
| 20170260831 | Green | Sep 2017 | A1 |
| 20170314689 | Osterbrink et al. | Nov 2017 | A1 |
| 20170370481 | Glazewski | Dec 2017 | A1 |
| 20180073652 | Weintraub | Mar 2018 | A1 |
| 20190316687 | Bonanno | Oct 2019 | A1 |
| 20200096114 | Stetzer et al. | Mar 2020 | A1 |
| 20200124181 | Liu et al. | Apr 2020 | A1 |
| Number | Date | Country |
|---|---|---|
| 469928 | Mar 1969 | CH |
| 102014224979 | Jun 2016 | DE |
| 102018107053 | Oct 2018 | DE |
| 2019086086 | Jun 2019 | JP |
| 20050045760 | May 2005 | KP |
| 20160115751 | Oct 2016 | KR |
| WO-2013113827 | Aug 2013 | WO |
| 2020236853 | Nov 2020 | WO |
| Entry |
|---|
| PCT International Search Report and Written Opinion dated Dec. 1, 2017, for International Application No. PCT/US2017/051567. |
| PCT International Search Report and Written Opinion dated Jan. 31, 2018, for International Application No. PCT/US2017/051550. |
| PCT International Search Report and Written Opinion dated Jun. 23, 2015, for International Application No. PCT/US2014/062114. |
| PCT/US2020/067625, International Search Report and Written Opinion dated May 4, 2021, 15 pages. |
| PCT/US2021/044762, International Search Report and Written Opinion dated Oct. 27, 2021, 12 pages. |
| India Application No. 2021137010322, Examination Report datd Jun. 5, 2021, 5 pages. |
| Indonesian Patent Application No. P00202101829-TA, Office Action dated Jul. 4, 2022. |
| PCT/US2022/080763, International Search Report and Written Opinion dated Mar. 27, 2023, 10 pages. |
| European Patent Application No. 20853585.6, Office Action dated Sep. 5, 2023, 6 pages. |
| Indian Application No. 202217042243, Examination Report dated Feb. 7, 2023, 6 pages. |
| Chinese Application No. 201980064890.3, Office Action dated Sep. 15, 2022, 22 pages. |
| PCT/US2024/049516, International Search Report and Written Opinion dated Feb. 10, 2025, 19 pages. |
| Number | Date | Country | |
|---|---|---|---|
| 20230175603 A1 | Jun 2023 | US |
| Number | Date | Country | |
|---|---|---|---|
| 63339571 | May 2022 | US | |
| 63285639 | Dec 2021 | US |