Chewing gum containing salatrim

Information

  • Patent Application
  • 20040052898
  • Publication Number
    20040052898
  • Date Filed
    September 12, 2003
    20 years ago
  • Date Published
    March 18, 2004
    20 years ago
Abstract
Improved chewing gum formulations and bases, as well as methods of producing chewing gum and bases are provided. The chewing gum includes salatrim. Salatrim can be used in the base and/or gum as a plasticizer, softener, compatibilizer, and emulsifier. In an embodiment, salatrim is added to sucrose-type gum formulations replacing a small or large quantity of other fats, oils, and emulsifiers. A variety of base and chewing gum formulations including salatrim can be created and/or utilized pursuant to the present invention.
Description


BACKGROUND OF THE INVENTION

[0002] The present invention relates generally to chewing gum. More specifically, the present invention relates to improved formulations for chewing gum and bases.


[0003] Chewing gum generally consists of a water insoluble gum base and a water soluble portion along with flavors. The water soluble portion and flavors dissipate during chewing and the gum base is retained in the mouth throughout the chew.


[0004] The insoluble gum base generally comprises elastomers, resins, fats and oils, softeners, and inorganic fillers. Elastomers can include synthetic elastomers including polyisobutylene, isobutylene-isoprene copolymers, styrene-butadiene copolymers, polyvinyl acetate, polyisoprene, polyethylene, vinyl acetate-vinyl laurate copolymers, and combinations thereof. Natural elastomers that can be used include natural rubber.


[0005] The gum base can include elastomer plasticizers. Such elastomer plasticizers can include natural rosin esters, as well as other elastomer plasticizers. Additionally, the gum base can include fillers/texturizers and softeners/emulsifiers. Softeners are added to chewing gum in order to optimize the chewability and mouth feel of the gum. Softeners/emulsifiers that are typically used include tallow, hydrogenated tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, glycerol monostearate, glycerol triacetate, lecithin, and combinations thereof.


[0006] In addition to a water insoluble gum base portion, a typical chewing gum composition includes a water soluble portion and one or more flavoring agents. The water soluble portion can include bulk sweeteners, high intensity sweeteners, flavoring agents, softeners, emulsifiers, colors, acidulants, fillers, antioxidants, and other components that provide desirable attributes.



SUMMARY OF THE INVENTION

[0007] The present invention provides improved chewing gum formulations and bases, as well as methods of producing chewing gum and bases. Pursuant to the present invention, chewing gum is provided that includes salatrim (short and long chain acyltriglyceride molecules). Salatrim can be used in base and/or gum formulations as a plasticizer, softener, and/or emulsifier. In an embodiment, salatrim is added to sucrose-type gum formulations replacing a small or large quantity of other fats, oils, and emulsifiers.


[0008] The salatrim can also act as a base compatibilizer to help blend elastomers and polyvinyl acetate. Salatrim thereby reduces phase separation of gum base during chewing.


[0009] A variety of base and chewing gum formulations including salatrim can be created and/or utilized pursuant to the present invention. The base formulations of the present invention may be conventional bases that include wax or are wax-free, tacky or non-tacky and/or bubble gum-type bases. The gum formulations can be low or high moisture formulations containing low or high amounts of moisture-containing syrup. Salatrim can also be used in low sugar and non-sugar containing gum formulations made with sorbitol, mannitol, other polyols, and non-sugar carbohydrates. Non-sugar formulations can include low or high moisture sugar-free chewing gums.


[0010] In an embodiment, salatrim is used as a softener and is combined with other base softeners for use in chewing gum base. Such other softeners include, but are not limited to, fats and oils, such as tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, mono- and di-glycerides, acetylated monoglycerides, softeners such as glycerol triacetate, waxes such as paraffin and microcrystalline waxes, and emulsifiers such as lecithin.


[0011] In an embodiment, salatrim is used as a softener in chewing gum formulations to replace typical chewing gum softeners. In an embodiment, salatrim is used in the chewing gum formulations to replace typical plasticizers and emulsifying agents that are used in chewing gum formulations. For example, salatrim can be used to replace glycerin, lecithin, glycerol triacetate, acetylated monoglycerides, and mono- and di-glycerides.


[0012] In an embodiment, the salatrim softener is used in a chewing gum formulation combined with other softeners, emulsifiers, and/or plasticizing agents. If desired, salatrim can be used alone or combined with an inert material which may be added in a dry form. The salatrim softener can also be added to the flavor as a carrier for its use in chewing gum.


[0013] The salatrim softener, when used according to the present invention, affords the chewing gum an improved texture, improved shelf life, and improved flavor quality. Even though salatrim is similar to other fats and oils in some respects, salatrim has a lower caloric value and creates a resultant chewing gum product that has a high consumer-acceptability.


[0014] Additionally, the salatrim can act as a base compatibilizer to help blend elastomers and polyvinyl acetate to reduce phase separation of gum base during chewing.


[0015] It is an advantage of the present invention to provide an improved chewing gum formulation.


[0016] A further advantage of the present invention is to provide an improved base that can be used to create chewing gum.


[0017] Furthermore, an advantage of the present invention is to provide an improved method of blending elastomers and polyvinyl acetate and preventing phase separation.


[0018] Another advantage of the present invention is that it provides an improved chewing gum softener.


[0019] Still further, an advantage of the present invention is that it provides an improved chewing gum plasticizer.


[0020] Additionally, an advantage of the present invention is that it provides an improved emulsifying agent for chewing gum.


[0021] Moreover, an advantage of the present invention is that it provides an improved method for creating chewing gum.


[0022] Furthermore, an advantage of the present invention is that it provides a chewing gum having improved texture.


[0023] An advantage of the present invention is that it provides a chewing gum having an improved shelf life.


[0024] Still further, an advantage of the present invention is that it provides a chewing gum having improved flavor quality.


[0025] Additional features and advantages of the present invention are described in, and will be apparent from, the detailed description of the presently preferred embodiments.



DETAILED DESCRIPTION OF THE PRESENTLY PREFERRED EMBODIMENTS

[0026] The present invention provides improved chewing gum formulations and base formulations. Pursuant to the present invention, short and long chain acyltriglyceride molecules (hereinafter referred to as “salatrim”) are used. Salatrim can be used in chewing gum formulations and/or bases. Specifically, salatrim can be used as a softener, plasticizer, base compatibilizer and/or emulsifying agent.


[0027] Salatrim is the generic name for a family of low calorie fats. Examples of such fats are described in U.S. Pat. No. 5,258,197, assigned to Nabisco, Inc. Other documents which discuss the use of salatrim are: U.S. Pat. No. 5,362,508; WO 94/12052; WO 94/13150; WO 94/16573; WO 94/19961; Inform, Vol. 5, No. 8 (August 1994) p. 935; Candy Industry, (August 1994) p. 9; The Manufacturing Confectioner (August 1994) p. 7; Food Engineering (August 1994), p. 24; and Food Processing, (September 1994) p. 64.


[0028] Under a licensed agreement, salatrim is being manufactured and marketed by Pfizer, Inc. of Groton, Conn. Nabisco has submitted a GRAS petition to the U.S. FDA which has accepted the filing of Nabisco's petition.


[0029] Salatrim is a family of low calorie fats, which have only 5 calories per gram compared to regular fats that provided 9 calories per gram. Salatrim is a mixture of long chain fatty acids (mostly stearic) and short chain fatty acids (acetic, propionic, and/or butyric) on a glycerol backbone. The fats are prepared by interesterifying vegetable oil with the triacylglycerol.


[0030] An advantage of salatrim is that it has physical properties similar to regular fats, but is low in calories.


[0031] Some of the fats in the salatrim family include:
1SalatrimShort ChainLong ChainMoleFamilySourceSourceRatio4CATributyrinHydrogenated2.5:1Canola Oil23CATriacetinHydrogenated 11:1:1TripropioninCanola Oil234CSTriacetinHydrogenated  4:4:4:1TripropioninCotton seedTributyrinOil234CATriacetinHydrogenated  4:4:4:1TripropioninCanola OilTributyrin2350TriacetinHydrogenated 11:1:1TripropioninSoybean Oil


[0032] The inventors believe that salatrim can be used in base formulations, and/or chewing gum formulations.


[0033] In this regard, salatrim can be used as a softener, plasticizer, and/or emulsifying agent. Preferably, salatrim will comprise about 0.02% to about 40% by weight of the gum base, and about 0.01% to about 10% by weight of the chewing gum formulation.


[0034] Salatrim being a saturated fatty acid triglyceride can be used to replace fats in gum base that are saturated fatty acid triglycerides. Most triglycerides used as fat in gum bases are derived from fatty acids such as stearic acid (C18), palmitic (C16), myristic acid (C14), oleic acid (C18:1 unsaturated) and linoleic acid (C18:2 unsaturated). These common fatty acids are available from saturated soybean oil, olive oil, canola oil, cottonseed oil, coconut oil, palm oil, corn oil, palm kernel oil, safflower oil, lard, tallow, and a wide variety of short and long chain fatty acids.


[0035] Generally, these fats or lipids are hydrogenated to make them saturated for use in gum base. Saturation of the lipids significantly improves their oxidation stability, which is very important for shelf life of gum base and gum. When oil is hydrogenated it becomes a solid at room temperature, thus a fat.


[0036] The above mentioned fats contain a natural fatty acid distribution dependent on its source. When the triglyceride is interesterified the triglyceride is broken down to glycerol and free fatty acids, and is then recombined to give different triglycerides molecules. If the fatty acids are separated to specific fatty acids and recombined with glycerol, this is called a structur lipid. Salatrim is one such lipid.


[0037] As noted above, salatrim is made with hydrogenated fatty acids from vegetable oils, preferably stearic acid and palmitic acid as the long chain fatty acid, and acetic acid, propionic acid, and butyric acid as the short chain fatty acids. Some structured lipids like salatrim may have properties that are different than conventional saturated triglycerides.


[0038] Stearic (C18) and palmitic (C16) fatty acid triglycerides being lipophilic are good softeners that lubricate gum base elastomers similar to the isobutylene-isoprene copolymer. On the other hand, short chain fatty acid triglycerides being less lipophilic do not act as good softeners for elastomers.


[0039] However, most gum base formulas also contain a significant amount of food grade polyvinyl acetate (PVAc). Polyvinyl acetate can be readily softened or plasticized by compounds such as triacetin, tripropionin, and tributyrin.


[0040] Elastomers and polyvinyl acetate are generally not compatible and are softened or melted, and physically mixed to make a gum base. Along with these materials elastomer plasticizers, such as resins, fats and emulsifiers, are used to plasticize and soften the elastomers. The emulsifiers include lecithin or glycerol monostearate. In the base matrix, the typical non-compatible nature of the elastomers and polyvinyl acetate may result in a gum base matrix that may be unstable and cause problems during the course of mastication. One such problem is polyvinyl acetate globules in a non-tack gum base become larger and reassociate causing stickiness to dentures during mastication.


[0041] Salatrim may act as a “compatibilizers” when combining elastomers and polyvinyl acetate so that the gum base matrix may become more homogenized to give a more stable matrix. Lower melting point salatrims may be most effective as a compatibilizer. The acetic, propionic, and butyric acid portions could plasticize polyvinyl acetate, and the longer chain fatty acids may soften the elastomer. Acetylated monoglycerides may have a similar function as a compatibilizer, but salatrim with longer short chain acids such as butyric and propionic or two long chain stearic fatty acids with one acetic acid may be more effective as a compatibilizer for this type of base matrix. In addition other fats/oils may be used with salatrim to soften the elastomer to obtain a quality gum base formula.


[0042] Gum base typically consists of a polyvinyl acetate phase, a rubber/fat/resin phase (rubber phase), and filler. Usually, the polyvinyl acetate and rubber phases are immiscible or almost immiscible as can be predicted by the solubility parameter.


[0043] Solubility is believed to occur between materials, for example when the Gibbs free energy of mixing is less than zero. The energy of mixing is discussed by Dr. Billmeyer in the “Textbook Of Polymer Science”, Second Edition, John Wiley and Sons, Inc. (1975), pages24-26. The free energy of mixing ΔG is defined according to the following equation:


ΔG=ΔH−TΔS


[0044] wherein ΔH represents the enthalpy of mixing, ΔS represents the entropy of mixing, and T is the absolute temperature.


[0045] For reasonably nonpolar molecules, and where the degree of hydrogen bonding is insignificant or nonexistent, the enthalpy of mixing is positive and can be derived from the following equation:


ΔH=V1V21−δ2)2


[0046] wherein V is the volume fraction and subscripts 1 and 2 refer to the solvent and the polymer, respectively. The quantity δ2 is the cohesive energy density of an ingredient. The quantity δ, which represents the square root of the cohesive energy density, is known as the Solubility Parameter.


[0047] Generally, in the absence of significant hydrogen bonding, solubility can be expected to occur between a solvent and a polymer if the difference in Solubility Parameters (δ1−δ2) is less than about 1.7-2.0. In other words, materials having similar Solubility Parameters tend to reach thermodynamic equilibrium when they are mixed together, and this tendency toward equilibrium causes the different molecules to attract and mix with each other. Materials having dissimilar Solubility Parameters tend to reach thermodynamic equilibrium when separated, and this causes the different molecules to repel and separate from each other.


[0048] The Solubility Parameters of different substances have been the subject of various calculations and publications. For a polymer, a relatively easy way to determine δ2 is from a summation of molar attraction constants multiplied by the density and divided by the repeating unit molecular weight:
1δ2=ρEiM.W.


[0049] wherein Σ is the summation operator, Ei is the molar attraction constant for each chemical moiety making up the repeating unit, M.W. is the molecular weight of the repeating unit, and ρ is the polymer density.


[0050] The Solubility Parameter (δ1−δ2) can be expressed in Solubility Parameter Units (S.P.U.'s), with one S.P.U. being equal to one [J/m3]1/4×10−3, where J=Joules and m=meters. For a more detailed explanation of the Solubility Parameter and its values for various compounds, see the Third Edition of “Polymer Handbook”, edited by Bandrup and Immergut, and published by John Wiley and Sons, Inc., New York, N.Y., in 1989.


[0051] The solubility parameter of polyvinyl acetate is about 19.1 to 19.6. Typically, the solubility parameter of rubber is about 16-17. As the solubility parameter of any two materials becomes more than 2 S.P.V.'s different from one another, these materials are less miscible.


[0052] To overcome the potential problem between polyvinyl acetate and rubber, a compatibilizer may be used such as salatrim. The compatibilizer should have two groups in the molecule—one which is a rubber liking group such as long chain fatty acid, having a solubility parameter of about 16-17. The other group should have a polyvinyl acetate liking group such as acetic, propionic, or butyric acid having a solubility parameter of about 19.5.


[0053] Pursuant to the present invention, salatrim can be used as a compatibilizer in gum base. There are a variety of benefits that can be achieved by using a compatibilizer in gum base.


[0054] First, a compatibilizer can effectively inhibit separation and promote dispersion of the components. Since gum base is a mixture of lipophilic and nonlipophilic substances, even if the mixture is molten when blended, it can separate during storage. This can make the mixture non-uniform. The addition of a compatibilizer can remedy this drawback.


[0055] Second, compatibilizers can prevent gum from sticking to teeth. To prevent gum base from sticking to teeth, it is important to use a large amount of non-polar gum base ingredients and by judiously choosing and utilizing compatibilizers one can reduce the sticking of the gum base to teeth.


[0056] Third, it has been found that compatibilizers provide a softening action of the gum base. These materials will reduce the elasticity of high molecular weight substances such as gums, and adjust the sensation of hardness.


[0057] Salatrim may be used as a partial or full replacement of saturated fats of emulsifiers in gum bases made with an elastomer and polyvinyl acetate. Gum bases may contain natural and synthetic elastomers and may be wax free or contain wax, may be bubble gum type bases or have reduced tack properties. It is preferred that salatrim be mixed in the gum base, but may also added early to mix with the base during chewing gum manufacturing. Gums made with salatrim will have improved texture, may have improved flavor lasting properties, and will not cause problems during mastication.


[0058] It is also believed that salatrim will provide a cooling sensation during chewing. Thus salatrim may afford an increased cooling sensation to mint or fruit flavored chewing gum products.


[0059] Accordingly, salatrim can be used in a variety of different chewing gum and base formulations. Salatrim can exist as either a liquid or solid at room temperature. Where salatrim is a liquid at room temperature, salatrim may be added in its liquid form. Where salatrim is a solid at room temperature, salatrim should be melted before being added to a gum base or gum formulation.


[0060] Chewing gum generally consists of a water insoluble gum base, a water soluble portion, and flavors.


[0061] The insoluble gum base generally comprises elastomers, resins, fats and oils, softeners, and inorganic fillers. The gum base may or may not include wax. The insoluble gum base can constitute approximately 5 to about 95 percent, by weight, of the chewing gum, more commonly, the gum base comprises 10 to about 50 percent of the gum, and in some preferred embodiments, 20 to about 35 percent, by weight, of the chewing gum.


[0062] In an embodiment, the chewing gum base of the present invention contains about 20 to about 60 weight percent synthetic elastomer, 0 to about 30 weight percent natural elastomer, about 5 to about 55 weight percent elastomer plasticizer, about 4 to about 35 weight percent filler, about 5 to about 35 weight percent softener, and optional minor amounts (about one percent or less) of miscellaneous ingredients such as colorants, antioxidants, etc. Preferably, the salatrim does not comprise more than 40% by weight of the gum base.


[0063] Synthetic elastomers may include, but are not limited to, polyisobutylene with a GPC weight average molecular weight of about 10,000 to about 95,000, isobutylene-isoprene copolymer (butyl elastomer), styrene-butadiene copolymers having styrene-butadiene ratios of about 1:3 to about 3:1, polyvinyl acetate having a GPC weight average molecular weight of about 2,000 to about 90,000, polyisoprene, polyethylene, vinyl acetate-vinyl laurate copolymer having vinyl laurate content of about 5 to about 50 percent by weight of the copolymer, and combinations thereof.


[0064] Preferred ranges are, for polyisobutylene, 50,000 to 80,000 GPC weight average molecular weight, for styrene-butadiene, 1:1 to 1:3 bound styrene-butadiene, for polyvinyl acetate, 10,000 to 65,000 GPC weight average molecular weight with the higher molecular weight polyvinyl acetates typically used in bubble gum base, and for vinyl acetate-vinyl laurate, vinyl laurate content of 10-45 percent.


[0065] Natural elastomers may include natural rubber such as smoked or liquid latex and guayule as well as natural gums such as jelutong, lechi caspi, perillo, sorva, massaranduba balata, massaranduba chocolate, nispero, rosindinha, chicle, gutta hang kang, and combinations thereof. The preferred synthetic elastomer and natural elastomer concentrations vary depending on whether the chewing gum in which the base is used is adhesive or conventional, bubble gum or regular gum, as discussed below. Preferred natural elastomers include jelutong, chicle, sorva and massaranduba balata.


[0066] Elastomer plasticizers may include, but are not limited to, natural rosin esters, often called estergums, such as glycerol esters of partially hydrogenated rosin, glycerol esters polymerized rosin, glycerol esters of partially dimerized rosin, glycerol esters of rosin, pentaerythritol esters of partially hydrogenated rosin, methyl and partially hydrogenated methyl esters of rosin, pentaerythritol esters of rosin; synthetics such as terpene resins derived from alpha-pinene, beta-pinene, and/or d-limonene; and any suitable combinations of the foregoing. The preferred elastomer plasticizers will also vary depending on the specific application, and on the type of elastomer which is used.


[0067] Fillers/texturizers may include magnesium and calcium carbonate, ground limestone, silicate types such as magnesium and aluminum silicate, clay, alumina, talc, titanium oxide, mono-, di- and tri-calcium phosphate, cellulose polymers, such as wood, and combinations thereof.


[0068] In an embodiment, in addition to salatrim, pursuant to the present invention, softeners/emulsifiers may include tallow, hydrogenated tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, glycerol monostearate, glycerol triacetate, lecithin, mono-, di- and triglycerides, acetylated monoglycerides, fatty acids (e.g. stearic, palmitic, oleic and linoleic acids), and combinations thereof.


[0069] Colorants and whiteners may include FD&C-type dyes and lakes, fruit and vegetable extracts, titanium dioxide, and combinations thereof.


[0070] The base may or may not include wax. An example of a wax-free gum base is disclosed in U.S. Pat. No. 5,286,500, the disclosure of which is incorporated herein by reference.


[0071] In addition to a water insoluble gum base portion, a typical chewing gum composition includes a water soluble bulk portion and one or more flavoring agents. The water soluble portion can include bulk sweeteners, high intensity sweeteners, flavoring agents, softeners, emulsifiers, colors, acidulants, fillers, antioxidants, and other components that provide desired attributes.


[0072] The softeners, which are also known as plasticizers and plasticizing agents, generally constitute between approximately 0.5 to about 15% by weight of the chewing gum. The softeners may, in addition to including salatrim, include glycerin, lecithin, and combinations thereof. Aqueous sweetener solutions such as those containing sorbitol, hydrogenated starch hydrolysates, corn syrup and combinations thereof, may also be used as softeners and binding agents in chewing gum.


[0073] Bulk sweeteners include both sugar and sugarless components. Bulk sweeteners typically constitute 5 to about 95% by weight of the chewing gum, more typically, 20 to 80% by weight, and more commonly, 30 to 60% by weight of the gum.


[0074] Sugar sweeteners generally include saccharide-containing components commonly known in the chewing gum art, including, but not limited to, sucrose, dextrose, maltose, dextrin, dried invert sugar, fructose, levulose, galactose, corn syrup solids, and the like, alone or in combination.


[0075] Sorbitol can be used as a sugarless sweetener. Additionally, sugarless sweeteners can include, but are not limited to, other sugar alcohols such as mannitol, xylitol, hydrogenated starch hydrolysates, maltitol, lactitol, and the like, alone or in combination.


[0076] High intensity artificial sweeteners can also be used in combination with the above. Preferred sweeteners include, but are not limited to sucralose, aspartame, salts of acesulfame, alitame, saccharin and its salts, cyclamic acid and its salts, glycyrrhizin, dihydrochalcones, thaumatin, monellin, and the like, alone or in combination. In order to provide longer lasting sweetness and flavor perception, it may be desirable to encapsulate or otherwise control the release of at least a portion of the artificial sweetener. Such techniques as wet granulation, wax granulation, spray drying, spray chilling, fluid bed coating, coacervation, and fiber extrusion may be used to achieve the desired release characteristics.


[0077] Usage level of the artificial sweetener will vary greatly and will depend on such factors as potency of the sweetener, rate of release, desired sweetness of the product, level and type of flavor used and cost considerations. Thus, the active level of artificial sweetener may vary from 0.02 to about 8%. When carriers used for encapsulation are included, the usage level of the encapsulated sweetener will be proportionately higher.


[0078] Combinations of sugar and/or sugarless sweeteners may be used in chewing gum. Additionally, the softener may also provide additional sweetness such as with aqueous sugar or alditol solutions.


[0079] If a low calorie gum is desired, a low caloric bulking agent can be used. Example of low caloric bulking agents include: polydextrose; Raftilose, Raftilin; Fructooligosaccharides (NutraFlora); Palatinose oligosaccharide; Guar Gum Hydrolysate (Sun Fiber); or indigestible dextrin (Fibersol). However, other low calorie bulking agents can be used.


[0080] A variety of flavoring agents can be used. The flavor can be used in amounts of approximately 0.1 to about 15 weight percent of the gum, and preferably, about 0.2 to about 5%. Flavoring agents may include essential oils, synthetic flavors or mixtures thereof including, but not limited to, oils derived from plants and fruits such as citrus oils, fruit essences, peppermint oil, spearmint oil, other mint oils, clove oil, oil of wintergreen, anise and the like. Artificial flavoring agents and components may also be used. Natural and artificial flavoring agents may be combined in any sensorially acceptable fashion.


[0081] The present invention, it is believed, can be used with a variety of processes for manufacturing chewing gum.


[0082] Chewing gum is generally manufactured by sequentially adding the various chewing gum ingredients to commercially available mixers known in the art. After the ingredients have been thoroughly mixed, the chewing gum mass is discharged from the mixer and shaped into the desired form, such as by rolling into sheets and cutting into sticks, extruding into chunks, or casting into pellets.


[0083] Generally, the ingredients are mixed by first melting the gum base and adding it to the running mixer. The gum base may alternatively be melted in the mixer. Color and emulsifiers can be added at this time.


[0084] A chewing gum softener such as glycerin can be added next along with part of the bulk portion. Further parts of the bulk portion may then be added to the mixer. Flavoring agents are typically added with the final part of the bulk portion. The entire mixing process typically takes from five to fifteen minutes, although longer mixing times are sometimes required.


[0085] Liquid salatrim or melted salatrim (solid salatrim in its liquid form) may be added to chewing gum during manufacture of the base. Liquid salatrim or melted salatrim may be added at any time during processing of the base, but preferably, near the end of the batch to act as a softener.


[0086] Salatrim may be added to conventional bases that contain wax or are wax-free bases, that may or may not contain polyvinyl acetate or terpene resins, or bases that contain natural gums or synthetic bases, bases that are non-tacky, or are bubble gum bases.


[0087] At levels of approximately 0.02% to about 40% by weight of the gum base, salatrim may replace some or most of the partially hydrogenated or hydrogenated vegetable oils, mono- and di-glycerides, acetylated monoglycerides, or other softeners used in the gum base. Salatrim may also be blended with the other softeners in the gum base and added during the base manufacturing process. A chewing gum base made with salatrim will have greater oxidative stability due to the presence of salatrim, and may give chewing gum a cleaner taste.


[0088] Liquid salatrim or melted salatrim may also be added to a chewing gum formulation in its liquid form or may be mixed with other gum or base softeners and added to a gum formulation during processing. Liquid salatrim or melted salatrim may be added during the gum manufacturing at any time during processing, but preferably, early in the batch to allow thorough mixing with the gum base.


[0089] Salatrim can be added to the chewing gum formulation so that it comprises approximately 0.01% to about 10% by weight of the chewing gum formulation. In a preferred embodiment, salatrim comprises approximately 0.02% to about 2% and most preferably, about 0.05% to about 0.5% by weight of the chewing gum formulation. Salatrim may be blended with other softeners such as lecithin, glycerol triacetate, acetylated monoglycerides, mono- and di-glycerides, or other vegetable oils and fats that may be added to a gum formulation. When a solid softener is used, such as lecithin, liquid salatrim or melted salatrim may act as a carrier or solvent for the particulate lecithin. Lecithin when mixed with liquid salatrim or melted salatrim may allow for an easier dispersion of lecithin in a gum formulation. This should be contrasted with soy bean oil that is typically used as a carrier for lecithin.


[0090] Liquid salatrim or melted salatrim may also be blended with a wide range of natural and artificial flavor oils and act as a carrier for flavor oils. Liquid salatrim or molten salatrim can be an excellent carrier for flavors such as spearmint, peppermint, cinnamon, wintergreen, and fruit flavors. The level of salatrim mixed with flavors can vary over a wide range from approximately 1% to about 99% by weight since most gum flavors are oil soluble.


[0091] Salatrim can also act as a carrier for artificial and natural colors such as in FD&C lake dispersions and natural colors like betacarotene. Salatrim can reduce the off-taste associated with some fat/oil carriers and allows higher usage of color.


[0092] Salatrim may also be used as a release agent for encapsulated flavors. Salatrim can be added to an encapsulating media to allow for faster and easier dissolution of the encapsulating media.


[0093] By way of example, and not limitation, examples of the present invention will now be given:







EXAMPLES

[0094] The following contemplative examples of the invention and comparative examples are provided by way of explanation and illustration.


[0095] The formulas listed in Table I comprise various contemplative sugar formulas in which salatrim can be added at various levels to gum.
2TABLE 1(WEIGHT PERCENT)Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Sugar61.5561.561.3562.562.061.0Base19.219.219.219.219.219.2Corn Syrup16.916.916.916.916.916.9Peppermint0.90.90.90.90.90.9FlavorGlycerin1.41.41.40.00.00.0Salatrim0.050.100.250.501.02.0


[0096] In Table 2, dextrose monohydrate is added to a sugar formula with various levels of salatrim.
3TABLE 2Ex. 7Ex. 8Ex. 9Ex. 10Ex. 11Ex. 12Sugar55.6555.655.4556.255.754.7Base19.219.219.219.219.219.2Corn Syrup12.912.912.912.912.912.9Glycerin1.41.41.40.40.40.4DextroseMonohydrate9.99.99.99.99.99.9PeppermintFlavor0.90.90.090.90.90.9Salatrim0.050.100.250.501.02.0


[0097] Examples 13-18 are the same as Examples 7-12 except that salatrim is pre-blended with the peppermint flavor and added to the gum formulation.


[0098] The following Tables 4 through 11 give examples of gum formulations demonstrating formula variations in which liquid or molten salatrim, in the form of liquid oil, can be used.


[0099] Examples 19-23 in Table 4 demonstrate the use of salatrim in low-moisture sugar formulations having less than 2% theoretical moisture:
4TABLE 4Ex. 19Ex. 20Ex. 21Ex. 22Ex. 23Sugar58.7558.658.352.751.9Gum Base19.219.219.219.219.2Corn Syrupa6.06.06.06.06.0DextroseMonohydrate10.010.010.010.010.0Lactose0.00.00.05.05.0Glycerinb5.05.05.05.05.0Flavor0.90.90.9d0.9d0.9dLecithinc0.10.10.10.2Salatrimc0.050.20.5d1.0d2.0daCorn syrup is evaporated to 85% solids, 15% moisture. bGlycerin and syrup can be blended and co-evaporated. cLecithin and Salatrim can be pre-blended. dFlavor and Salatrim can be pre-blended.


[0100] Examples 24-28 in Table 5 demonstrate the use of salatrim in medium-moisture sugar formulations having about 2% to about 5% moisture.
5TABLE 5Ex. 24Ex. 25Ex. 26Ex. 27Ex. 28Sugar53.3553.252.952.351.5Gum Base19.219.219.219.219.2Corn Syrupa15.015.015.015.015.0DextroseMonohydrate10.010.010.010.010.0Glycerinb1.41.41.41.41.4Flavor0.9d0.9d0.9d0.9d0.9dLecithinc0.10.10.10.2Salatrimc0.05d0.2d0.5d1.0d2.0daCorn syrup is evaporated to 85% solids, 15% moisture. bGlycerin and syrup can be blended and co-evaporated. cSalatrim and Lecithin can be pre-blended. dFlavor and Salatrim can be pre-blended.


[0101] Examples 29-33 in Table 6 demonstrate the use of salatrim in high moisture sugar formulations having more than about 5% moisture.
6TABLE 6Ex. 29Ex. 30Ex. 31Ex. 32Ex. 33Sugar50.9550.750.448.948.0Gum Base24.024.024.024.024.0Corn Syrup24.024.024.024.624.6Glycerin0.00.00.00.40.4Flavor1.01.01.01.01.0Lecithin*0.10.10.1Salatrim0.050.20.51.02.0*Lecithin and Salatrim can be pre-blended.


[0102] Examples 34-38 in Table 7 and Examples 39-48 in Tables 8 and 9 demonstrate the use of salatrim in low- and high-moisture gums that are sugar-free. Low-moisture gums have less than about 2% moisture, and high-moisture gums have greater than 2% moisture.
7TABLE 7Ex. 34Ex. 35Ex. 36Ex. 37Ex. 38Base25.525.525.525.525.5Sorbitol50.8550.750.550.048.0Mannitol12.012.012.012.013.0Glycerin10.010.010.010.010.0Flavor1.51.51.51.51.5Lecithin*0.10.1Salatrim0.050.20.51.02.0*Lecithin and Salatrim can be pre-blended. ** Flavor and Salatrim can be pre-blended.


[0103]

8










TABLE 8









Ex. 39
Ex. 40
Ex. 41
Ex. 42
Ex. 43




















Base
25.5
25.5
25.5
25.5
25.5


Sorbitol
50.95
50.8
50.5
51.9
49.8


Sorbitol
10.0
10.0
10.0
10.0
11.0


Liquid*


Mannitol
10.0
10.0
10.0
10.0
10.0


Glycerin
2.0
2.0
2.0
0.0
0.0


Flavor
1.5
1.5
1.5
1.5
1.5


Lecithin**



0.1
0.2


Salatrim
0.05
0.2
0.5
1.0
2.0






*Sorbitol liquid contains 70% sorbitol, 30% water.




**Lecithin and Salatrim can be pre-blended.




*** Flavor and Salatrim can be pre-blended.








[0104]

9










TABLE 9









Ex. 44
Ex. 45
Ex. 46
Ex. 47
Ex. 48




















Base
25.5
25.5
25.5
25.5
25.5


Sorbitol
50.95
50.7
50.4
52.0
51.0


HSH Syrup*
10.0
10.0
10.0
10.0
10.0


Mannitol
8.0
8.0
8.0
8.0
9.0


Glycerin**
4.0
4.0
4.0
2.0
1.0


Flavor
1.5
1.5
1.5
1.5
1.5


Lecithin***

0.1
0.1




Salatrim****
0.05
0.2
0.5
1.0
2.0






*Lycasin brand hydrogenated starch hydrolyzate syrup.




**Glycerin and HSH syrup may be blended or co-evaporated.




***Lecithin and Salatrim can be pre-blended.




****Flavor and Salatrim can be pre-blended.








[0105] Table 10 shows sugar chewing gum formulations that can be made with salatrim and various types of sugars.
10TABLE 10Ex. 49Ex. 50Ex. 51Ex. 52Ex. 53Ex. 54Gum Base19.219.219.219.219.219.2Sucrose49.448.544.443.534.443.5Glycerin1.41.41.41.41.41.4Corn Syrup14.014.014.014.014.014.0Dextrose5.05.010.05.0Lactose5.05.010.010.0Fructose5.05.010.010.010.05.0Invert Sugar10.010.0MaltoseCorn SyrupSolidsPeppermintFlavor0.90.90.90.90.90.9Salatrim0.11.00.11.00.11.0Ex. 55Ex. 56Ex. 57Ex. 58Ex. 59Ex. 60Gum Base19.219.219.219.219.219.2Sucrose34.443.534.443.542.446.5Glycerin1.41.41.41.41.41.4Corn Syrup14.014.014.014.011.011.0Dextrose10.05.010.05.010.05.0LactoseFructose10.05.010.05.05.05.0Invert Sugar10.010.05.05.0Maltose10.010.0Corn SyrupSolids5.05.0PeppermintFlavor0.90.90.90.90.90.9Salatrim0.11.00.11.00.11.0Ex. 61Ex. 62Gum Base19.219.2Sucrose42.436.5Glycerin6.46.4Corn Syrup11.011.0Dextrose5.05.0LactoseFructose5.05.0Invert Sugar5.05.0MaltoseCorn SyrupSolids5.0*10.0*PeppermintFlavor0.90.9Salatrim0.11.0*5-25DE maltodextrin can be used.


[0106] Table 11 shows chewing gum formulations that are free of sugar. These formulations can use a wide variety of other non-sugar alditols.
11TABLE 11(WEIGHT PERCENT)Ex. 63Ex. 64Ex. 65Ex. 66Ex. 67Ex. 68Gum Base25.525.525.525.525.525.5Glycerin2.02.02.02.02.02.0Sorbitol43.943.043.938.037.939.0Mannitol10.010.010.010.06.0Sorbitol17.017.0LiquidLycasin17.012.08.010.0Maltitol10.010.0Xylitol15.015.0LactitolPalatinitFlavor1.51.51.51.51.51.5Salatrim0.11.00.11.00.11.0Ex. 69Ex. 70Ex. 71Ex. 72Ex. 73Ex. 74Gum Base25.525.525.525.525.525.5Glycerin8.08.08.02.01.00.0Sorbitol41.936.031.940.026.921.0Mannitol8.08.08.0Sorbitol5.0LiquidLycasin5.05.05.010.010.0Maltitol5.0Xylitol15.010.020.0Lactitol10.010.010.0Palatinit10.010.025.021.0Flavor1.51.51.51.51.51.5Salatrim0.11.00.11.00.11.0


[0107] The following examples of the invention are also shown in Table 12 for natural and synthetic gum bases with wax, Table 13 for chewing gum bases that are wax-free and have some reduced tack properties, Table 14 for wax free bubble gum bases, and Table 15 for wax-free gum bases having non-tack characteristics. These examples illustrate how salatrim can be added to a wide variety of chewing gum bases to partially replace some of the oils, fats, and base softeners.
12TABLE 12NATURAL AND SYNTHETIC BASES WITH WAX(WEIGHT PERCENT)Ex. 75Ex. 76Ex. 77Butyl Rubber11.710.09.0Styrene Butadiene RubberPolyisobutylene10.45.3JelutongEster Gum14.8Terpene Resin9.96.816.7Low MW Polyvinylacetate21.223.224.6High MW PolyvinylacetateTalcCalcium Carbonate11.214.720.1Acetylated MonoglycerideHydrogenated Cotton Seed Oil10.03.3Hydrogenated Soybean Oil9.011.13.3Partially Hydrogenated Soybean and2.3Palm OilPartially HydrogenatedCottonseed OilSalatrim5.74.34.2Lecithin2.70.8Glycerol Monostearate4.84.14.2TriacetinMicrocrystalline Wax (MP 180° F.)6.03.18.5Paraffin Wax (MP 135° F.)3.0100.0100.0100.0BUBBLE BASESEx. 78Ex. 79Ex. 80Butyl Rubber2.5Styrene Butadiene Rubber10.31.6Polyisobutylene9.19.0JelutongEster Gum24.722.515.0Terpene ResinLow MW PolyvinylacetateHigh MW Polyvinylacetate30.024.1Talc25.4Calcium Carbonate56.821.7Acetylated Monoglyceride4.0Hydrogenated Cotton Seed Oil1.5Hydrogenated Soybean OilPartially Hydrogenated Soybean and2.0Palm OilPartially HydrogenatedCottonseed OilSalatrim1.51.52.0Lecithin1.5Glycerol Monostearate1.17.1Triacetin4.53.2Microcrystalline Wax (MP 180° F.)1.2Paraffin Wax (MP 135° F.)4.17.15.0100.0100.0100.0Ex. 81Ex. 82Ex. 83Butyl Rubber6.86.88.8Styrene Butadiene RubberPolyisobutylene3.03.24.1Jelutong21.118.24.0Ester Gum16.716.6Terpene Resin17.3Low MW Polyvinylacetate16.616.125.0High MW PolyvinylacetateTalc18.1Calcium Carbonate13.219.7Acetylated MonoglycerideHydrogenated Cotton Seed Oil2.34.5Hydrogenated Soybean Oil3.22.7Partially Hydrogenated Soybean andPalm OilPartially Hydrogenated2.0Cottonseed OilSalatrim3.01.83.3LecithinGlycerol Monostearate2.14.54.1TriacetinMicrocrystalline Wax (MP 180° F.)15.26.86.1Paraffin Wax (MP 135° F.)1.12.0100.0100.0100.0Ex. 84BubbleBaseEx. 85Ex. 86Butyl Rubber9.19.3Styrene Butadiene RubberPolyisobutylene8.03.510.5Jelutong3.1Ester Gum14.71.5Terpene Resin15.013.0Low MW Polyvinylacetate22.823.0High MW Polyvinylacetate34.5Talc28.6Calcium Carbonate23.014.9Acetylated Monoglyceride2.5Hydrogenated Cotton Seed Oil4.68.0Hydrogenated Soybean Oil2.95.2Partially Hydrogenated Soybean and3.1Palm OilPartially Hydrogenated1.5Cottonseed OilSalatrim0.92.42.1Lecithin0.8Glycerol Monostearate4.42.84.5Triacetin4.6Microcrystalline Wax (MP 180° F.)7.04.4Paraffin Wax (MP 135° F.)1.81.50.5100.0100.0100.0Ex. 89BubbleEx. 87Ex. 88BaseButyl Rubber6.18.1Styrene Butadiene Rubber6.0Polyisobutylene7.15.57.5JelutongEster Gum7.112.2Terpene Resin14.17.1Low MW Polyvinylacetate28.122.2High MW Polyvinylacetate29.0Talc28.9Calcium Carbonate18.925.6Acetylated Monoglyceride3.7Hydrogenated Cotton Seed Oil10.113.22.7Hydrogenated Soybean Oil5.15.1Partially Hydrogenated Soybean andPalm OilPartially HydrogenatedCottonseed OilSalatrim4.14.11.3Lecithin0.70.5Glycerol Monostearate1.51.53.1Triacetin1.2Microcrystalline Wax (MP 180° F.)3.14.4Paraffin Wax (MP 135° F.)1.1100.0100.0100.0


[0108]

13





TABLE 13








WAX-FREE GUM BASES FOR USE IN CHEWING GUM


HAVING SOME REDUCED TACK CHARACTERISTICS


(EXAMPLES 90-119)







EXAMPLES 90-94









IDENTIFICATION - EXAMPLES #:












GENERIC INGREDIENTS
90
91
92
93
94





** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER
5.3

2.1
1.8



BUTYL (ISOPRENE-ISOBUTYLENE)
8.6
7.9
7.2

8.1


ELASTOMER


POLYISOBUTYLENE ELASTOMER
7.1

7.4
24.8 
3.6


POLYVINYL ACETATE
10.5 
27.2 
15.3 
10.1 
27.3 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN
2.1

19.0 
3.7



GLYCEROL ESTERS OF PART
4.3
18.2 

7.9



HYD ROSIN


TERPENE RESINS
10.8 


7.1
26.8 


** FILLER **


CALCIUM CARBONATE

15.9 
20.7 
17.7 
11.4 


TALC
25.5 






** SOFTENER **


HYDROGENATED COTTONSEED OIL

6.0

7.0



HYDROGENATED SOYBEAN OIL
4.3

6.1




PARTIALLY HYDROGENATED SOYBEAN
3.3

6.0

9.1


AND PALM OIL


PARTIALLY HYDROGENATED

5.3

7.0



COTTONSEED OIL


SALATRIM
7.7
11.3 
12.2 
7.0
5.2


GLYCEROL MONOSTEARATE
8.2
7.4
4.0
3.5
4.8


LECITHIN
2.3
0.8

2.4
3.7


TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 
100.0 










EXAMPLES 95-97









IDENTIFICATION -



EXAMPLES #:










GENERIC INGREDIENTS
95
96
97





** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER
5.2
2.1
5.9


BUTYL (ISOPRENE-ISOBUTYLENE)
4.1
7.2
6.9


ELASTOMER


POLYISOBUTYLENE ELASTOMER
5.9
7.3
2.0


POLYVINYL ACETATE
25.7 
15.3 
24.8 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN
23.5 
19.1 
8.6


GLYCEROL ESTERS OF PART HYD ROSIN


8.0


TERPENE RESINS
3.2

1.9


** FILLER **


CALCIUM CARBONATE
15.1 
20.7 
9.9


TALC


7.2


** SOFTENER **


HYDROGENATED COTTONSEED OIL


7.0


HYDROGENATED SOYBEAN OIL





PARTIALLY HYDROGENATED SOYBEAN
5.5
8.3
4.0


AND PALM OIL


PARTIALLY HYDROGENATED COTTONSEED OIL
3.0
9.6



SALATRIM
3.7
6.4
10.1 


GLYCEROL MONOSTEARATE
5.1
4.0
3.7


LECITHIN





TOTAL PERCENT
100.0 
100.0 
100.0 










EXAMPLES 98-101









IDENTIFICATION - EXAMPLES #:











GENERIC INGREDIENTS
98
99
100
101





** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER
3.9
2.1




BUTYL (ISOPRENE-ISOBUTYLENE) ELASTOMER
5.3
6.0
8.9
3.6


POLYISOBUTYLENE ELASTOMER
12.7 
8.5
10.0 
11.1 


POLYVINYL ACETATE
14.9 
15.3 
21.3 
21.9 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN

10.1 

19.6 


GLYCEROL ESTERS OF PART HYD ROSIN

8.9

11.2 


TERPENE RESINS
21.4 

9.7
3.7


** FILLER **


CALCIUM CARBONATE
13.7 
20.9 
21.5 
6.4


TALC
1.4





** SOFTENER **


HYDROGENATED COTTONSEED OIL

4.2

5.0


HYDROGENATED SOYBEAN OIL
1.7

5.0



PARTIALLY HYDROGENATED SOYBEAN



10  


AND PALM OIL


PARTIALLY HYDROGENATED COTTONSEED OIL


15.0 



SALATRIM
17.0 
20.0 
3.2
4.2


GLYCEROL MONOSTEARATE
5.7
4.0
5.4
3.3


LECITHIN
2.3





TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 










EXAMPLES 102-106









IDENTIFICATION - EXAMPLES #:












GENERIC INGREDIENTS
102
103
104
105
106





** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER

3.2
4.1




BUTYL (ISOPRENE-ISOBUTYLENE)
7.4
7.3
11.3 
10.0 
8.3


ELASTOMER


POLYISOBUTYLENE ELASTOMER
1.9
7.5
7.9
1.9
3.6


POLYVINYL ACETATE
24.8 
21.1 
18.2 
27.6 
27.5 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN

15.3 





GLYCEROL ESTERS OF PART

2.4
26.2 




HYD ROSIN


TERPENE RESINS
25.8 
5.8
1.4
25.3 
25.3 


** FILLER **


CALCIUM CARBONATE
18.6 

13.6 
11.3 
11.3 


TALC

14.8 





** SOFTENER **


HYDROGENATED COTTONSEED OIL
2.0
4.4
1.2




HYDROGENATED SOYBEAN OIL



2.4
4.0


PARTIALLY HYDROGENATED SOYBEAN

4.0


4.2


AND PALM OIL


PARTIALLY HYDROGENATED







COTTONSEED OIL


SALATRIM
10.3 
11.4 
7.0
13.0 
8.3


GLYCEROL MONOSTEARATE
4.4
2.8
5.2
4.8
4.8


LECITHIN
4.8

3.9
3.7
2.7


TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 
100.0 










EXAMPLES 107-110









IDENTIFICATION - EXAMPLES #:











GENERIC INGREDIENTS
107
108
109
110





** NATURAL ELASTOMER **


NATURAL GUM
22.0 
25.1 
22.8 
17.6 


** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER

1.9
2.6



BUTYL (ISOPRENE-ISOBUTYLENE)
4.8
2.1
4.1
10.2 


ELASTOMER


POLYISOBUTYLENE ELASTOMER
5.7
4.7
3.2
2.1


POLYVINYL ACETATE
16.4 
24.8 
16.3 
26.9 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN
3.8
3.2
6.9
11.3 


GLYCEROL ESTERS OF PART
12.3 
12.6 
11.8 
4.8


HYD ROSIN


METHYL ESTERS OF ROSIN

2.1
1.7



TERPENE RESINS






** FILLER **


CALCIUM CARBONATE

4.4
9.3



TALC
7.1


4.6


** SOFTENER **


HYDROGENATED COTTONSEED OIL


10.0 



HYDROGENATED SOYBEAN OIL
5.0


5.6


PARTIALLY HYDROGENATED SOYBEAN
6.0
9.0
3.7
5.0


AND PALM OIL


PARTIALLY HYDROGENATED
5.0





COTTONSEED OIL


SALATRIM
5.8
3.6
4.5
5.6


GLYCEROL MONOSTEARATE
6.1
3.8

6.3


LECITHIN

2.7
3.1



TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 










EXAMPLES 111-114









IDENTIFICATION - EXAMPLES #:











GENERIC INGREDIENTS
111
112
113
114





** NATURAL ELASTOMER **


NATURAL GUM
15.7 
22.6 
22.2 
21.1 


** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER
1.9





BUTYL (ISOPRENE-ISOBUTYLENE)
3.7
5.8
5.7
6.1


ELASTOMER


POLYISOBUTYLENE ELASTOMER
4.1
3.1
3.1
2.8


POLYVINYL ACETATE
26.2 
20.4 
22.0 
18.0 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN



15.7 


GLYCEROL ESTERS OF PART
15.3 
11.7 
15.2 



HYD ROSIN


METHYL ESTERS OF ROSIN

4.0




TERPENE RESINS






** FILLER **


CALCIUM CARBONATE
12.2 
11.6 
11.4 



TALC



15.4 


** SOFTENER **


HYDROGENATED COTTONSEED OIL

2.0

9.1


HYDROGENATED SOYBEAN OIL
3.0

6.2



PARTIALLY HYDROGENATED SOYBEAN

15.0 




AND PALM OIL


PARTIALLY HYDROGENATED
9.0

5.0



COTTONSEED OIL


SALATRIM
3.1
1.5
4.9
6.0


GLYCEROL MONOSTEARATE
5.8
3.3
3.3
5.8


LECITHIN






TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 










EXAMPLES 115-119









IDENTIFICATION - EXAMPLES #:












GENERIC INGREDIENTS
115
116
117
118
119





** NATURAL ELASTOMER **


NATURAL GUM
23.8 
18.7 
14.4 
18.2 
25.2 


** SYNTHETIC ELASTOMER **


STYRENE-BUTADIENE ELASTOMER







BUTYL (ISOPRENE-ISOBUTYLENE)
3.1
6.0
9.1
6.8
2.4


ELASTOMER


POLYISOBUTYLENE ELASTOMER
7.7
5.5
3.6
5.4
4.9


POLYVINYL ACETATE
20.5 
14.8 
18.1 
15.5 
19.9 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN


11.9 

15.6 


GLYCEROL ESTERS OF PART
10.4 
15.5 
13.0 
12.7 



HYD ROSIN


METHYL ESTERS OF ROSIN
2.0


2.6



TERPENE RESINS
5.1



2.1


** FILLER **


CALCIUM CARBONATE

18.8 
14.1 
15.7 



TALC
5.3



7.1


** SOFTENER **


HYDROGENATED COTTONSEED OIL

6.5
7.0




HYDROGENATED SOYBEAN OIL
7.9


5.0
10.0 


PARTIALLY HYDROGENATED SOYBEAN


2.0




AND PALM OIL


PARTIALLY HYDROGENATED



6.0



COTTONSEED OIL


SALATRIM
7.9
6.5
6.8
5.0
8.4


GLYCEROL MONOSTEARATE
6.3
7.7

7.1
4.4


LECITHIN







TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 
100.0 










[0109]

14





TABLE 14








WAX-FREE GUM BASES FOR USE IN BUBBLE GUM


(EXAMPLES 120-128)







EXAMPLES 120-123









IDENTIFICATION - EXAMPLES #:











GENERIC INGREDIENTS
120
121
122
123





** SYNTHETIC ELASTOMER **


POLYISOBUTYLENE ELASTOMER
17.1 
11.7 
11.6 
5.4


POLYVINYL ACETATE
24.9 
29.4 
31.5 
34.8 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN
6.8
10.7 
19.8 
16.3 


GLYCEROL ESTERS OF PART






HYD ROSIN


** FILLER **


CALCIUM CARBONATE



30.2 


TALC
34.7 
34.1 
21.9 



** SOFTENER **


SALATRIM
1.1
3.4
3.0
2.0


GLYCEROL TRIACETATE
4.6
4.4
5.0
5.3


GLYCEROL MONOSTEARATE
5.8
4.3
4.9
3.9


ACETYLATED MONOGLYCERIDE
5.0
2.0
2.3
2.1


TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 










EXAMPLES 124-128









IDENTIFICATION - EXAMPLES #:












GENERIC INGREDIENTS
124
125
126
127
128





** SYNTHETIC ELASTOMER **


POLYISOBUTYLENE ELASTOMER
7.9
13.0 
7.9
11.6 
11.8 


POLYVINYL ACETATE
34.2 
37.1 
34.2 
37.8 
35.6 


** ELASTOMER PLASTICIZERS **


GLYCEROL ESTERS OF ROSIN
14.8 






GLYCEROL ESTERS OF PART

19.8 
14.8 
19.8 
19.8 


HYD ROSIN


** FILLER **


CALCIUM CARBONATE
29.8 
16.5 
29.8 




TALC



17.0 
19.7 


** SOFTENER **


SALATRIM
1.0
3.5
3.0
2.6
0.8


GLYCEROL TRIACETATE
5.3
5.6
4.3
3.0
4.0


GLYCEROL MONOSTEARATE
4.0
4.5
3.0
3.2
2.3


ACETYLATED MONOGLYCERIDE
3.0

3.0
5.0
6.0


TOTAL PERCENT
100.0 
100.0 
100.0 
100.0 
100.0 










[0110]

15





TABLE 15








WAX-FREE GUM BASES FOR USE IN CHEWING GUM


HAVING NON-TACK CHARACTERISTICS (EXAMPLES 129-140)







EXAMPLES 129-134









IDENTIFICATION - EXAMPLES #:













GENERIC INGREDIENTS
129
130
131
132
133
134





** SYNTHETIC ELASTOMER **


BUTYL (ISOPRENE-ISOBUTYLENE)



25.0
 9.0
14.1


ELASTOMER


POLYISOBUTYLENE
35.0
17.0
20.0

16.9
12.1


POLYVINYL ACETATE

17.0
30.0
 5.0
22.8
20.8


** FILLER **


CALCIUM CARBONATE
25.0
40.0
 5.0
25.0

13.9


TALC




12.0



** SOFTENERS **


HYDROGENATED SOYBEAN OIL
 5.0

15.0

14.8
 7.7


HYDROGENATED COTTONSEED OIL

 8.0

15.0
14.0
10.0


PARTIALLY HYDROGENATED SOYBEAN
20.0
 2.0

15.0

 7.0


AND PALM OIL


PARTIALLY HYDROGENATED COTTON-


10.0


 6.7


SEED OIL


SALATRIM
 5.0
 8.0
 5.0
10.0
 8.8
 4.0


GLYCEROL MONOSTEARATE
10.0

 5.0
 5.0
 1.7
 3.7


LECITHIN

 8.0














EXAMPLES 135-140









IDENTIFICATION - EXAMPLES #:













GENERIC INGREDIENTS
135
136
137
138
139
140





** SYNTHETIC ELASTOMER **


BUTYL (ISOPRENE-ISOBUTYLENE)
16.0
 9.9
 9.9
10.0
10.0
13.3


ELASTOMER


POLYISOBUTYLENE
10.0
15.5
15.5
15.9
15.9
21.2


POLYVINYL ACETATE
14.0
22.0
22.0
21.7
21.6
29.1


** FILLER **


CALCIUM CARBONATE
 5.0
12.9
12.9
13.3

17.7


TALC
10.0



13.1



** SOFTENERS **


HYDROGENATED SOYBEAN OIL

14.0
 9.0
 3.3
13.5
 6.1


HYDROGENATED COTTONSEED OIL

13.0
13.0
 3.3
13.5
 6.1


PARTIALLY HYDROGENATED SOYBEAN
 3.0

10.0


 2.0


AND PALM OIL


PARTIALLY HYDROGENATED COTTON



 9.8




SEED OIL


SALATRIM
35.0
10.0
 5.0
20.0
 9.8
 3.2


GLYCEROL MONOSTEARATE
 2.0
 2.7
 1.7
 2.7
 2.6
 1.3


LECITHIN


 1.0









It should be understood that various changes and modifications to the presently preferred embodiments described herein will be apparent to those skilled in the art. Such changes and modifications can be made without departing from the spirit and scope of the present invention and without diminishing its attendant advantages. It is therefore intended that such changes and modifications be covered by the appended claims.








Claims
  • 1. A gum base comprising: an elastomer; and at least 0.02% by weight structured triacylglycerols that include short and long chain acyl triglyceride molecules.
  • 2. The gum base of claim 1 wherein the base is wax-free.
  • 3. The gum base of claim 1 wherein the base is non-tacky.
  • 4. The gum base of claim 1 wherein the base is a bubble gum-type base.
  • 5. The gum base of claim 1 including at least one resin.
  • 6. The gum base of claim 1 including at least one softener chosen from the group consisting of: tallow; hydrogenated tallow; hydrogenated and partially hydrogenated vegetable oils; cocoa butter; glycerol monostearate; glycerol triacetate; and lecithin.
  • 7. The gum base of claim 1 wherein the structured triacylglycerols that include short and long chain acyl triglyceride molecules comprises not more than 40% by weight of the base.
  • 8. The gum base of claim 1 wherein structured triacylglycerols that include short and long chain acyl triglyceride molecules are salatrim.
  • 9. A chewing gum formulation comprising: an insoluble gum base; a water soluble portion; a flavor; and at least 0.01% by weight structured triacylglycerols that include short and long chain acyl triglyceride molecules.
  • 10. The chewing gum formulation of claim 9 including at least one softener chosen from the group consisting of: tallow; hydrogenated tallow; hydrogenated and partially hydrogenated vegetable oils; cocoa butter; glycerol monostearate; glycerol triacetate; and lecithin.
  • 11. The chewing gum formulation of claim 9 wherein the structured triacylglycerols that include short and long chain acyl triglyceride molecules comprise not more than 10% by weight of the chewing gum formulation.
  • 12. The chewing gum formulation of claim 9 wherein the formulation includes an emulsifier.
  • 13. The chewing gum formulation of claim 9 wherein the formulation includes an elastomer plasticizer.
  • 14. The chewing gum formulation of claim 9 wherein structured triacylglycerols that include short and long chain acyl triglyceride molecules are salatrim.
  • 15. The chewing gum formulation of claim 9 wherein the formulation includes lecithin.
  • 16. The chewing gum formulation of claim 9 wherein the formulation includes mint oil.
  • 17. The chewing gum of claim 9 wherein the flavor is chosen from the group consisting of mint and fruit.
  • 18. A method for creating chewing gum comprising the step of substituting for a typical plasticizer, softener, or emulsifier in a chewing gum formulation structured triacylglycerols that include short and long chain acyl triglyceride molecules.
  • 19. The method of claim 18 wherein the structur d triacylglycerols that include short and long chain acyl triglyceride molecules comprise approximately 0.01% to about 10% by weight of the chewing gum formulation.
  • 20. The method of claim 18 wherein structured triacylglycerols that include short and long chain acyl triglyceride molecules are salatrim.
  • 21. A method for reducing caloric content in a chewing gum formulation including fats/oils comprising the step of using structured triacylglycerols that include short and long chain acyl triglyceride molecules in the formulation.
  • 22. The method of claim 21 wherein structured triacylglycerols that include short and long chain acyl triglyceride molecules are salatrim.
  • 23. A gum base comprising: polyvinyl acetate; an elastomer; and at least 0.02% by weight structured triacylglycerols that include short and long chain acyl triglyceride molecules.
  • 24. The gum base of claim 23 wherein the base is wax-free.
  • 25. The gum base of claim 23 wherein the base is non-tacky.
  • 26. The gum base of claim 23 wherein the base is a bubble gum-type base.
  • 27. The gum base of claim 23 including at least one resin.
  • 28. The gum base of claim 23 including at least one softener chosen from the group consisting of: tallow; hydrogenated tallow; hydrogenated and partially hydrogenated vegetable oils; cocoa butter; glycerol monostearate; glycerol triacetate; and lecithin.
  • 29. The gum base of claim 23 wherein the structured triacylglycerols that include short and long chain acyl triglyceride molecules comprises not more than 40% by weight of the base.
  • 30. The gum base of claim 23 wherein structured triacylglycerols that include short and long chain acyl triglyceride molecules are salatrim.
  • 31. A chewing gum formulation comprising: an insoluble gum base including polyvinyl acetate and an elastomer; a water soluble portion; a flavor; and at least 0.01% by weight structured triacylglycerols that include short and long chain acyl triglyceride molecules.
  • 32. The chewing gum formulation of claim 31 wherein the flavor is chosen from the group consisting of mint and fruit.
RELATED APPLICATIONS

[0001] This is a continuation-in-part of PCT application No. PCT/US94/14611 filed on Dec. 13, 1994.

Continuations (1)
Number Date Country
Parent 09849292 May 2001 US
Child 10661223 Sep 2003 US
Continuation in Parts (1)
Number Date Country
Parent PCT/US94/14611 Dec 1994 US
Child 09849292 May 2001 US