The present invention relates to a surface mount chip resistor to be soldered on lands of a circuit board, and a method of producing thereof.
The chip resistor generally includes a rectangular parallelepiped insulating substrate, a pair of upper surface electrodes provided at both ends, respectively, in the longitudinal direction on the upper surface of the insulating substrate, a resistor provided so as to extend across the pair of upper surface electrodes, an insulating protective film for covering the resistor, a pair of lower surface electrodes provided at both ends, respectively, in the longitudinal direction on the lower surface of the insulating substrate, a pair of end face electrodes for electrically connecting the upper surface electrodes and the lower surface electrodes, external electrodes formed of plating materials and covering the end face electrodes, and the like. The chip resistor having the structure as described above is placed on the lands provided on the circuit board with the lower surface electrodes facing downward, and is surface-mounted by soldering the lands provided on the circuit board and the external electrodes provided on the chip resistor.
In the state where the chip resistor is surface-mounted as described above, when the thermal environment repeatedly changes (hereinafter, referred to as “thermal shock”), the difference between the coefficient of thermal expansion of the circuit board and that of the insulating substrate of the chip resistor causes thermal stress, and this thermal stress acting on a solder joint portion may cause cracks to form. In particular, the thermal stress caused by the difference in the coefficients of thermal expansion between the circuit board and the insulating substrate increases as the size of the substrate of the chip resistor increases, which increases the possibility of formation of the cracks in the solder joint portion. This disadvantageously reduces the thermal shock resistance.
Patent Literature 1 discloses a chip resistor in which the lower surface electrodes provided on the mounting surface (back surface) of the insulating substrate are formed to have a double layer structure including a stress relaxation layer made of a synthetic resin material formed on the insulating substrate by screen-printing and a metal thin film layer formed on the stress relaxation layer by sputtering. In the chip resistor having the structure as described above, the stress relaxation layer relaxes the thermal stress acting on a solder joint portion even upon exposure of the chip resistor to the thermal shock during surface-mounting on the circuit board, and therefore, the thermal shock resistance can be secured.
Patent Literature 1: WO-2018-123422
However, in the chip resistor according to Patent Literature 1, the metal thin film layer is formed on the surface of the stress relaxation layer made of a synthetic resin material, which reduces the strength of adhesion at the interface therebetween. This may cause a risk that the metal thin film layer peels off from the stress relaxation layer due to the internal stress of the plating material in the process of forming the external electrodes by electroplating. Furthermore, the most of the stress relaxation layer formed on the back surface of the insulating substrate is covered with the metal thin film layer, which also causes a problem that the metal thin film layer hinders the effect of relaxation of the thermal stress by the stress relaxation layer.
The present invention has been made in view of the circumstances of the prior art described above, and an object of the present invention is to provide a chip resistor having high thermal shock resistance and a method of producing thereof.
In order to achieve the object above, the present invention provides a chip resistor comprising: a rectangular parallelepiped insulating substrate that includes a component surface and a mounting surface located on mutually opposite sides in a thickness direction; a pair of upper surface electrodes that is provided at both ends, respectively, in a longitudinal direction on the component surface of the insulating substrate; a resistor that bridges between the pair of upper surface electrodes; a pair of lower surface electrodes that is provided at both ends, respectively, in the longitudinal direction on the mounting surface of the insulating substrate; a pair of resin electrode layers that is laminated on the pair of lower surface electrodes, respectively, each of the pair of resin electrode layers being made of a synthetic resin material containing conductive particles; a pair of end face electrodes that electrically connects the pair of upper surface electrodes and the pair of lower surface electrodes; and a pair of external electrodes that covers at least the pair of end face electrodes, each of the pair of external electrodes being made of a plating material, wherein the pair of lower surface electrodes is made of metal thin film layers formed as thin films on the mounting surface of the insulating substrate, respectively, and includes exposed portions exposed from the pair of resin electrode layers, respectively, and the pair of external electrodes is in contact with the exposed portions of the pair of lower surface electrodes and entire surfaces of the pair of resin electrode layers, respectively.
In the chip resistor having the structure described above, the lower surface electrodes made of metal thin film layers having the low electrical resistivity have been formed on the mounting surface of the insulating substrate and also the resin electrode layers having the electrical resistivity higher than that of the metal thin film layers have been formed with portions of the lower surface electrodes being exposed, and this stabilizes the current flowing through the resin electrode layers in the process of forming the external electrodes by electroplating and thus makes the thickness of the plating films uniform. In this process, the current can flow uniformly over the entire surfaces of the resin electrode layers due to the laminate structure in which the resin electrode layers partially overlap the portions of the lower surface electrodes instead of connecting the lower surface electrodes made of metal thin film layers only to the outer peripheries of the resin electrode layers. Furthermore, the plating layers are formed starting from the exposed portions of the lower surface electrodes having the low electrical resistivity toward the resin electrode layers having the high electrical resistivity, which can prevent the plating layers formed on the resin electrode layers from peeling off.
Thus, even when the strength of adhesion at the interfaces between the lower surface electrodes formed of the metal thin film layers and the resin electrode layers formed of the synthetic resin materials is low, due to the sandwich structure of the resin electrode layers sandwiched between the metal thin film layers and the plating materials (external electrodes), the resin electrode layers can be prevented from peeling off even in the chip resistor after being finished, and the thermal stress caused by the thermal shock can be relaxed. Furthermore, the metal thin film layers having the high thermal conductivity are directly in contact with the insulating substrate, which causes, in the chip resistor mounted on the circuit board, the heat generated in the resistor to be radiated from the insulating substrate to the circuit board side through the metal thin film layers and the solder joint portions. This can realize a chip resistor excellent in heat dissipation.
In the structure above, it is sufficient that at least portions of the lower surface electrodes are exposed without being covered with the resin electrode layers as the exposed portions. Furthermore, when forming each of the exposed portions of the lower surface electrodes into a channel shape (C-shape) so as to surround an outer periphery of each of the resin electrode layers, the exposed portions of the lower surface electrodes which are exposed from the resin electrode layers increases. This results in great improvement in heat dissipation and allows the plating layers to be formed stably.
In the structure above, when each of the pair of resin electrode layers is provided with a cutout portion that opens toward an end face of the insulating substrate, and each of the exposed portions of the pair of lower surface electrodes is formed on an outer peripheral side of each of the resin electrode layers and in the cutout portion, respectively, not only the plating layers can formed more stably, but also the breaking for dividing the large-sized substrate along the primary division grooves into strip-shaped substrates is enhanced.
In the structure above, when each of the resin electrode layers is formed at an inner position away from an end face of the insulating substrate, and each of the exposed portions of the pair of lower surface electrodes is formed into a frame shape so as to surround an entire periphery of each of the resin electrode layers, the exposed portions of the lower surface electrodes which are exposed from the resin electrode layers increase. This allows the plating layers to be formed stably.
In the structure above, the end face electrodes may be thick layers formed of conducting resin provided, for example, by coating on the ends of the insulating substrate. On the other hand, it is preferable that each of the end face electrodes is formed of a metal thin film by sputtering metal particles toward the end face of the insulating substrate, and the metal thin film covers at least a portion of each of the exposed portions of the pair of lower surface electrodes.
Furthermore, in order to achieve the object described above, the present invention provides a method of producing a chip resistor, comprising the steps of: forming, on a component surface of an insulating substrate, a resistor and upper surface electrodes connected to both ends of the resistor, respectively; forming, in a central portion of a mounting surface located on an opposite side of the component surface of the insulating substrate, a mask made of a soluble material; forming, on the mounting surface exposed from the mask, lower surface electrodes by sputtering metal particles, respectively; after removing the mask, forming resin electrode layers by printing synthetic resin materials containing conductive particles on the lower surface electrodes with portions of the lower surface electrodes being exposed, respectively; forming end face electrodes that electrically connect between the upper surface electrodes and the lower surface electrodes by sputtering metal particles on end faces of the insulating substrate, respectively; and forming external electrodes that cover the end face electrodes, the exposed portions of the lower surface electrodes, and entire surfaces of the resin electrode layers by electroplating after forming the end face electrodes, respectively.
According to the method of producing a chip resistor comprising the steps described above, the procedures of forming the lower surface electrodes by sputtering with the mask being formed on the mounting surface of the insulating substrate, and then after removing the mask using ultrasonic cleaning, forming the resin electrode layers on the lower surface electrodes are carried out. In the method above, the ultrasonic cleaning necessary for removing the mask does not adversely affect the resin electrode layers and thus the chip resistor having high thermal shock resistance can be easily produced.
According to the present invention, it is possible to provide a chip resistor having high thermal shock resistance, and also provide a method of producing thereof.
Each of
Each of
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
As illustrated in
For obtaining the insulating substrate 1, a large-sized substrate, which will be described later, is divided along divisions groove extending in a grid pattern into a plurality of substrates. The large-sized substrate from which the insulating substrate 1 is obtained is made of a ceramic substrate mainly composed of alumina (Al2O3).
The pair of upper surface electrodes 2 is obtained by screen-printing Ag-Pd paste on the upper surface of the large-sized substrate and then drying and sintering the paste.
The resistor 3 is obtained by screen-printing resistor paste, such as ruthenium oxide, on the upper surface of the large-sized substrate and then drying and sintering the paste. Both ends of the resistor 3 in the longitudinal direction overlap the pair of upper surface electrodes 2, respectively. Although not illustrated, a trimming groove for adjusting a resistance value is formed in the resistor 3.
The protective layer 4 includes an undercoat layer 4a for covering the resistor 3 and an overcoat layer 4b for covering the undercoat layer 4a. The undercoat 4a is obtained by screen-printing glass paste and then drying and sintering the paste. The overcoat layer 4b is obtained by screen-printing resin paste, such as epoxy resin or phenolic resin, and then heating and curing (baking) the paste. Note that the undercoat layer 4a is provided before the trimming groove is formed in the resistor 3, and the overcoat layer 4b is provided after the trimming groove is formed in the resistor 3.
The pair of lower surface electrodes 5 is formed by sputtering Ni—Cr, Ti—Ni, Cu, or Ni—Cu on the back surface of the large-sized substrate.
The pair of resin electrode layers 6 is formed by screen-printing synthetic resin (for example, epoxy resin or phenolic resin) paste containing conductive particles such as Ag, Ni, or Cu on the lower surface electrodes 5 and then heating and curing the paste. The lower surface electrodes 5 and the resin electrode layers 6 are formed to have a laminate structure, excluding portions of the lower surface electrodes 5, and the portions of the lower surface electrodes 5 (upper and lower end portions in
The pair of end face electrodes 7 is formed by sputtering Ni—Cr or the like, and electrically connects the upper surface electrodes 2 and the lower surface electrodes 5 which are spaced apart from each other with the end faces of the insulating substrate 1 interposed therebetween. Note that the end face electrodes 7 cover the surfaces of the upper surface electrodes 2 located near the end faces of the insulating substrate 1 while making the surfaces of the upper surface electrodes 2 other than those above and the overcoat layer 4b exposed without covering them. Furthermore, the end face electrodes 7 cover the exposed portions 5a of the lower surface electrodes 5 and portions of the resin electrode layers 6, which are located near the end faces of the insulating substrate 1, while making the exposed portions 5a other than those described above and the surfaces of the resin electrode layers 6 other than those described above exposed.
Each of the pair of external electrodes 8 is formed to have a double layer structure including an inner barrier layer 8a and an outer external connection layer 8b, and the barrier layer 8a is an Ni plating layer formed by electroplating and the external connection layer 8b is an Sn plating layer formed by electroplating. The external electrodes 8 are formed so as to cover the entire surfaces of the end face electrodes 7, the surfaces of the upper surface electrodes 2 exposed from the end face electrodes 7, and the exposed portions 5a of the lower surface electrodes 5 and the resin electrode layers 6 which are exposed from the end face electrodes 7.
Next, the processes of producing the chip resistor 10 having the structure as described above will be described with reference to
Firstly, as illustrated in step S1 of
That is, in step S2 of
Next, in step S3 of
Next, in step S4 of
Next, in step S6 of
Next, in step S6 of
Next, in step S7 of
Next, in step S8 of
The processes described above are carried out collectively for the large-sized substrate 1A. In the next process, the large-sized substrate 1A is divided by primary breaking (primary division) along the primary division grooves to obtain a strip-shaped substrate 1B.
Thereafter, in step S10 of
Next, the strip-shaped substrate 1B is divided by secondary breaking (secondary division) along the secondary division grooves to obtain a single chip 10C having the size equivalent to that of the chip resistor 10.
Next, in step S11 of
Thereafter, the single chip 1C is electroplated with Sn to form the external connection layers 8b for covering the entire surfaces of the barrier layers 8a, whereby, as illustrated in
The chip resistor 10 thus produced as illustrated in
Exposure of the chip resistor 10 to the thermal shock during the surface mounting described above causes the thermal stress due to the difference between the coefficient of thermal expansion of the circuit board 100 and that of the insulating substrate 1 of the chip resistor 10, and the thermal stress acting on the solder joint portions may cause cracks to form. However, in the chip resistor 10 according to the present embodiment, the resin electrode layers 6 made of synthetic resin materials are laminated on the lower surface electrodes 5 to prevent the resin electrode layers 6 from easily peeling off. This enables the resin electrode layers 6 to relax the thermal stress, and thus can prevent formation of cracks.
As described above, in the chip resistor 10 according to the first embodiment, the lower surface electrodes 5 made of metal thin film layers having the low electrical resistivity have been formed on the mounting surface of the insulating substrate 1 and also the resin electrode layers 6 having the electrical resistivity higher than that of the metal thin film layers have been formed with portions of the lower surface electrodes 5 being exposed, and this stabilizes the current flowing through the resin electrode layers 6 in the process of forming the external electrodes 8 by electroplating and thus makes the thickness of the plating films uniform. In this process, the current can flow uniformly over the entire surfaces of the resin electrode layers 6 due to the laminate structure in which the resin electrode layers 6 partially overlap the portions excluding the exposed portions 5a of the lower surface electrodes 5 instead of connecting the lower surface electrodes 5 made of metal thin film layers only to the outer peripheries of the resin electrode layers 6. Furthermore, the plating layers are formed starting from the exposed portions 5a of the lower surface electrodes 5 having the low electrical resistivity toward the resin electrode layers 6 having the high electrical resistivity, which can prevent the plating layers formed on the resin electrode layers 6 from peeling off.
Thus, even when the strength of adhesion at the interfaces between the lower surface electrodes 5 formed of the metal thin film layers and the resin electrode layer 6 formed of the synthetic resin materials is low, due to the sandwich structure of the resin electrode layers 6 sandwiched between the metal thin film layers (lower surface electrodes 5) and the plating materials (external electrodes 8), the resin electrode layers 6 can be prevented from peeling off even in the chip resistor 10 after being finished, and the thermal stress caused by the thermal shock can be reliably relaxed. Furthermore, the lower surface electrodes 5 formed of the metal thin film layers having the high thermal conductivity are directly in contact with the insulating substrate 1, which causes, in the chip resistor 10 mounted on the circuit board 100, the heat generated in the resistor 3 to be radiated from the insulating substrate 1 to the circuit board 100 side through the lower surface electrodes 5 and the solder joint portions. This can realize the chip resistor 10 excellent in heat dissipation.
Furthermore, in the processes of producing the chip resistor 10, according to the procedures of forming the lower surface electrodes 5 by sputtering with the mask 9 being formed on the mounting surface of the insulating substrate 1, and then after removing the mask 9 using ultrasonic cleaning, forming the resin electrode layers 6 on the lower surface electrodes 5, the ultrasonic cleaning in removing the mask 9 does not adversely affect the resin electrode layers 6. Thus, the chip resistor 10 having high thermal shock resistance can be easily produced.
The chip resistor 20 according to the second embodiment is different from the chip resistor 10 according to the first embodiment in that the exposed portions 5a of the lower surface electrodes 5 are formed closer to the central portions of the insulating substrate 1 which are farthest from the short sides thereof, while the structure other than the above is basically the same. That is, each of the pair of resin electrode layers 6 is formed so as to cover the entire surface of the lower surface electrode 5 having a rectangular shape, except the one side thereof which is close to the central portion, and the pair of lower surface electrodes 5 is formed on the mounting surface of the insulating substrate 1 with the exposed portions 5a thereof facing each other.
In the chip resistor 20 having the structure described above, the positions and shapes of the exposed portions 5a of the lower surface electrodes 5 which are exposed from the resin electrode layers 6 are different from those of the first embodiment, however, the same advantageous effects as those of the first embodiment can be obtained.
In the chip resistor 30 according to the third embodiment, each of the pair of lower surface electrodes 5 is exposed from the three sides of the resin electrode layer 6, except the one side closer to the short side of the insulating substrate 1, and each of the exposed portions 5a of the lower surface electrodes 5 is formed into a channel shape (C-shape) so as to surround the outer periphery of the resin electrode layer 6. In this structure, as compared with the cases of the first embodiment and second embodiment, the exposed portions 5a of the lower surface electrodes 5 exposed from the resin electrode layers 6 increase, which results in great improvement in heat dissipation and allows the plating layers to be formed stably.
In the chip resistor 40 according to the fourth embodiment, each of the resin electrode layers 6 is provided with a cutout portion 6a that opens toward the end face side of the insulating substrate 1, and each of the exposed portions 5a of the lower surface electrodes 5 is formed on the outer peripheral side of the resin electrode layer 6 and in the cutout portion 6a, respectively. In this structure, as compared with the case of the third embodiment, the exposed portions 5a of the lower surface electrodes 5 exposed from the resin electrode layers 6 increase, which allows the plating layers to be formed stably. Furthermore, providing the cutout portions 6a reduces the areas of the resin electrode layers 6 which are in contact with the primary division groove, which improves the breaking in primary-dividing the large-sized substrate 1A into the strip-shaped substrates 1B along the primary division grooves.
In the chip resistor 50 according to the fifth embodiment, each of the resin electrode layers 6 is formed at an inner position away from the end face of the insulating substrate 1, and each of the exposed portions 5a of the lower surface electrode 5 is formed into a frame shape so as to surround the entire periphery of the resin electrode layer 6. This structure allows the plating layers to be formed stably and also can improve the breaking in primary-division. Furthermore, applying metal particles such as Ni—Cr toward the divided faces of the strip-shaped substrate 1B by sputtering to form the end face electrodes 7 causes the sputtered particles to be formed on the exposed portions 5a of the lower surface electrodes 5 extending along the divided faces, and this enables the conductivity of the lower surface electrodes 5 and end face electrodes 7 to be stabilized.
The present invention is not limited to the embodiments described above, and various modifications can be made without departing from the concept of the present invention. The present invention covers all of the technical matters included in the technical ideas described in the claims. The embodiments described above are suitable examples, and those skilled in the art can realize various alternative examples, modifications, variations, and the like based on the contents disclosed herein, and these are included in the technical scope described in the claims.
For example, each of the exposed portions 5a of the lower surface electrodes 5 may be formed only at a position in contact with one long side of the insulating substrate 1, or each of the resin electrode layers 6 may be provided with a cutout portion which opens toward the side opposite to the end face of the insulating substrate 1 so that the pair of lower surface electrodes 5 is formed to have the shape reversed left and right with respect to the one illustrated in
1
1A
1B
1C
2
3
4
4
a
4
b
5
5
a
6
6
a
7
8
8
a
8
b
9
100
101
102
10, 20, 30, 40, 50
Number | Date | Country | Kind |
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2022-067568 | Apr 2022 | JP | national |