Claims
- 1. A chromatic-color metal flake pigment which comprises:
- (a) flakes of a metal selected from the group consisting of aluminum, bronze, stainless steel, tin and iron; and
- (b) a coating layer of titanium oxide on the surface of the metal flakes formed by hydrolyzing a hydrolyzable organic titanate ester compound and depositing the titanium oxide on said surface,
- wherein the coating layer has a thickness of 40 nm to 155 nm and the hydrolyzable organic titanate ester compound is of the formula
- R--O--Ti(OR).sub.2 --O).sub.n R
- in which R is an alkyl group having 2 to 10 carbon atoms and the subscript n is a positive integer not exceeding 10 and
- wherein the hydrolyzable organic titanate ester compound is hydrolyzed in an organic medium having a pH from 4 to 8.
- 2. The chromatic-color metal flake pigment as claimed in claim 1 wherein the metal flakes have an average particle diameter from 1 to 100 .mu.m and a thickness from 0.01 to 20 .mu.m.
- 3. A coating composition which comprises a film forming resin and as a coloring agent, from 0.1 to 70% by weight, based on the film-forming resin, of a chromatic-color metal flake pigment according to claim 1.
- 4. The coating composition as claimed in claim 3, wherein the film-forming resin is selected from the group consisting of acrylic resins, polyester resins, resin mixtures of an acrylic resin and cellulose acetate butyrate, alkyd resins, urethane resins, epoxy resins, silicone resins, polyamide resins, epoxy-modified alkyd resins, phenolic resins and mixtures thereof.
- 5. An ink composition which comprises a film-forming ingredient and as a coloring agent, from 0.1 to 70% by weight, based on the film-forming ingredient, of a chromatic-color metal flake pigment according to claim 1.
- 6. The ink composition as claimed in claim 5, wherein the film-forming ingredient is selected from the group consisting of phenolic resins, alkyd resins, polyamide resins, acrylic resins, urea resins, melamine resins, polyvinyl chloride resins, Gilsonite, linseed oil, tung oil, soybean oil mixtures thereof.
- 7. A cosmetic preparation which comprises from 0.1 to 50% by weight of a chromatic-color metal flake pigment according to claim 1 based on the overall amount of the preparation.
- 8. The cosmetic composition as claimed in claim 7 which further comprises an additional ingredient selected from the group consisting of linseed oil, sunflower seed oil, olive oil, castor oil, camellia oil, yolk oil, turtle oil, sperm oil, beeswax, spermaceti wax, lanolin, carnauba wax, montan wax, candelilla wax, stearic acid, oleic acid, lauryl alcohol, stearyl alcohol, lanolin alcohol, hexyl decanol and mixtures thereof.
- 9. A molding compound comprising a plastic resin and as a coloring agent, from 0.1 to 50% by weight of a chromatic-color metal flake pigment according to claim 1, based on the overall amount of the compound.
- 10. The chromatic-color metal flake pigment as claimed in claim 1 wherein the hydrolyzable organic titanate ester compound is selected from the group consisting of tetra-isopropoxy titanium, tetra-n-butoxy titanium, tetrakis (2-ethylhexoxy) titanium, tetra-n-pentoxy titanium, tetra-n-hexoxy titanium, tetra-n-heptoxy titanium and tetra-n-octoxy titanium.
- 11. The chromatic-color metal flake as claimed in claim 1 wherein the organic medium is an organic solvent selected from the group consisting of a monohydric lower alcohol having 1 to 6 carbon atoms, benzene, toluene, xylene and mixtures thereof.
- 12. The chromatic-color metal flake pigment as claimed in claim 11 wherein the concentration of the hydrolyzable titanate ester in the organic medium is from 0.001 to 1 mole/liter.
- 13. The chromatic-color metal flake pigment as claimed in claim 1 wherein at least 2 moles of water per mole of said organic titanate ester compound are added during said hydrolyzing.
- 14. The chromatic-color metal flake pigment as claimed in claim 1 wherein the coating layer comprises one coating.
Priority Claims (2)
Number |
Date |
Country |
Kind |
63-16657 |
Jan 1988 |
JPX |
|
63-319246 |
Dec 1988 |
JPX |
|
Parent Case Info
This application is a continuation-in-part of application Ser. No. 07/300,613, filed Jan. 23, 1991, now abandoned.
US Referenced Citations (11)
Foreign Referenced Citations (4)
Number |
Date |
Country |
351932 |
Jan 1990 |
EPX |
53-77225 |
Jul 1978 |
JPX |
61-118461 |
Jun 1986 |
JPX |
1237866 |
Jun 1971 |
GBX |
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
300613 |
Jan 1989 |
|