Claims
- 1. A pressure-sensitive or heat-sensitive recording material which comprises a support which contains or has coated thereon as color former at least one chromogenic azaphthalide of the formula ##STR28## wherein R.sub.1 and R.sub.2 independently of each other are hydrogen, C.sub.1-C.sub.12 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or are cycloalkyl, benzyl or phenyl, or benzyl or phenyl which are substituted by halogen, nitro, cyano, lower alkyl, lower alkoxy or lower alkoxycarbonyl;
- or R.sub.1 and R.sub.2 together with the nitrogen atom to which they are attached are pyrrolidinyl;
- X is hydrogen, halogen, lower alkyl, lower alkoxy, benzyl, phenyl, benzyloxy, phenoxy, or benzyl or benzyloxy which are substituted by halogen, nitro, lower alkyl or lower alkoxy;
- Y is C.sub.6 -C.sub.9 alkyl;
- Z is hydrogen, lower alkyl or phenyl; and
- the ring A is a pyridine radical and
- the benzene nucleus B is unsubstituted or substituted by halogen, cyano, nitro, lower alkyl, lower alkoxy, lower alkoxycarbonyl, amino, lower alkylamino or di-(lower alkyl)-amino.
- 2. A pressure-sensitive recording material of claim 1, wherein the azaphthalide is dissolved in an organic solvent, and which recording material further comprises at least one solid electron acceptor.
- 3. A pressure-sensitive recording material of claim 2, wherein the azaphthalide is encapsulated in microcapsules.
- 4. A pressure-sensitive recording material of claim 3, wherein the encapsulated azaphthalide is present in the form of a layer on the back of a transfer sheet and the electron acceptor is present in the form of a layer on the face of a receiving sheet.
- 5. A pressure-sensitive recording material of claim 1, which comprises the azaphthalide together with one or more other colour formers.
- 6. A heat-sensitive recording material of claim 1, which comprises in at least one layer, at least one azaphthalide colour former, at least one electron acceptor and at least one binder.
- 7. A pressure-sensitive recording material of claim 1, wherein R.sub.1 is lower alkyl, cyclohexyl or benzyl and R.sub.2 is lower alkyl or benzyl.
- 8. A pressure-sensitive recording material of claim 1, wherein X is hydrogen, benzyloxy or lower alkoxy.
- 9. A pressure-sensitive recording material of claim 1 of the formula ##STR29## wherein R.sub.3 and R.sub.4 independently of each other are lower alkyl, benzyl or benzyl which is substituted by halogen, methyl or methoxy, or R.sub.3 and R.sub.4 together with the nitrogen atom to which they are attached are pyrrolidinyl; one of Q.sub.1 and Q.sub.2 is nitrogen and the other is CH; X.sub.1 is hydrogen, lower alkoxy or benzyloxy; Y is C.sub.6 -C.sub.9 alkyl; Z.sub.1 is lower alkyl or phenyl; and W is hydrogen or halogen.
- 10. A pressure-sensitive recording material of claim 9, wherein each of R.sub.3 and R.sub.4 is lower alkyl or benzyl, or R.sub.3 and R.sub.4 together with the nitrogen atom to which they are attached are pyrrolidinyl, Z.sub.1 is methyl or phenyl, Y is C.sub.6 -C.sub.8 alkyl and W is hydrogen.
- 11. A pressure-sensitive recording material of claim 10, wherein X.sub.1 is lower alkoxy.
- 12. A pressure-sensitive recording material of claim 10, wherein R.sub.3 and R.sub.4 are methyl or ethyl, X.sub.1 is ethoxy, Z.sub.1 is methyl and Y is n-octyl.
- 13. A pressure-sensitive recording material of claim 10, wherein R.sub.3 and R.sub.4 are ethyl, X.sub.1 is ethoxy, Z is methyl, Y is octyl, Q.sub.1 is N and Q.sub.2 is CH.
Priority Claims (3)
Number |
Date |
Country |
Kind |
8250/81 |
Dec 1981 |
CHX |
|
8251/81 |
Dec 1981 |
CHX |
|
1868/83 |
Apr 1983 |
CHX |
|
CROSS REFERENCE
This is a division of application Ser. No. 502,035, filed 6/7/83, now U.S. Pat. No. 4,508,897, which in turn is a continuation-in-part of application Ser. No. 449,955, filed 12/15/82.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3936564 |
Miyazawa et al. |
Feb 1976 |
|
4480002 |
Asano et al. |
Oct 1984 |
|
Foreign Referenced Citations (2)
Number |
Date |
Country |
49-118515 |
Nov 1974 |
JPX |
2103234A |
Feb 1983 |
GBX |
Divisions (1)
|
Number |
Date |
Country |
Parent |
502035 |
Jun 1983 |
|
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
449955 |
Dec 1982 |
|