Patent Application
20130199550
1. Field of the Invention
The present invention relates to a cigarette in which a tipping member is bonded with a pressure-sensitive adhesive, and a production method thereof.
2. Description of the Related Art
In a filter-tipped cigarette which is commercially available at present, a tobacco rod is connected to a filter by sticking a tipping paper thereon with a heat-sensitive or solvent-evaporative paste. For that reason, when the tipping paper is stuck with the paste in a cigarette rolling process, the process requires a step of transferring the paste to the tipping paper and a step of drying the paste by heating it with a heater.
The heater of a cigarette rolling machine has a temperature of approximately 80 to 240° C., and if mechanical trouble occurs, products in process and materials stay around the heater, and thus they are heated to a temperature almost the same as the heater temperature.
Thus, if a substance unstable to the heat-sensitive or solvent-evaporative paste, such as a water-soluble substance, or a thermal decomposing or denaturing substance, is incorporated into the filter-tipped cigarette, the substance cannot be stably maintained, and thus a problem arises in which it adheres in the vicinity of the heater. For example, a cellulose material such as cellophane, which is used as a transparent tipping paper, is unstable to the heat-sensitive or solvent-evaporative paste, and a capsule, which is used as a flavor-containing capsule, is unstable to heat or a surfactant contained in the paste.
On the other hand, the paste used for pasting the tipping paper has been improved in this technical field. For example, Patent Document 1 discloses a vinyl acetate resin emulsion type of solvent-evaporative paste having excellent initial adhesiveness; Patent Document 2 discloses a heat-sensitive paste which is melted by heat having a low temperature; and Patent Document 3 discloses a heat-sensitive paste having resistance to triacetin. In addition, Patent Document 4 discloses that a tobacco is connected to a tobacco filter by use of a cellophane tape instead of a tipping paper.
The present inventor has confirmed by experiments that when slurry of a gelatin microcapsule, which is used as a flavor-containing capsule, is put on a slide glass and is heated, it starts to melt at 110° C., and is completely melted and turns brown at 210° C. Further, the present inventor has confirmed by experiments that when the slurry of the gelatin microcapsule is applied to a paper sheet and is heated to 180° C., it turns brown. That is, the present inventor has found that if a heat-unstable substance such as a gelatin microcapsule is subjected to a heating step according to a conventional method of producing a cigarette, the contents of the capsule may be possibly leached out, with this possibility being high in case of mechanical trouble.
In view of the problems and background arts described above, it is an object of the present invention to provide a cigarette into which a material unstable to a heat-sensitive or solvent-evaporative paste or a thermal decomposing or denaturing material can be stably incorporated, and a production method thereof.
According to the present invention, there is provided a cigarette comprising a tobacco rod comprising a tobacco filler and a cigarette paper which is wrapped around the tobacco filler; a filter comprising a filter member and a filter wrapping paper which is integrally wrapped around the filter member; and a tipping member which is bonded onto the tobacco rod and the filter with a pressure-sensitive adhesive to connect the tobacco rod and the filter.
In the cigarette of the present invention, a material having a melting point of 240° C. or less may be used as the tipping member. The cigarette of the present invention may further comprise a flavor-containing capsule in the filter or on the tipping member.
Further, according to the present invention, there is provided a method for producing the above-mentioned cigarette, which comprises preparing a tipping member which comprises a pressure-sensitive adhesive and a release liner for protecting the pressure-sensitive adhesive, on the back surface of the tipping member; exposing the pressure-sensitive adhesive by releasing the release liner from the tipping member; cutting the pressure-sensitive adhesive-exposed tipping member into a size suitable for rolling the cigarette; and wrapping the tobacco rod and the filter in the cut tipping member to connect them.
In the cigarette of the present invention, the tipping member is bonded with the pressure-sensitive adhesive, and thus a heating procedure is not required in its production process, and a substance unstable to a heat-sensitive or solvent-evaporative paste or a heat-unstable substance can be stably incorporated therein. For example, a substance unstable to the heat-sensitive or solvent-evaporative paste or a thermal decomposing or denaturing material can be applied to the tipping member itself, or can be incorporated in the filter or attached on the surface of the tipping member, as a flavor-containing capsule.
The method for producing the cigarette of the present invention uses the tipping member having the pressure-sensitive adhesive on its back surface, and thus the method does not require a step of transferring the heat-sensitive or solvent-evaporative paste or a step of drying the paste. As a result, a substance unstable to the heat-sensitive or solvent-evaporative paste and the heat-unstable substance can be stably maintained.
The present invention will be explained below with reference to drawings. The following explanations are intended to describe the present invention in detail, and are not intended to limit the present invention.
1. Cigarette
The cigarette of the present invention is characterized by bonding a tipping member with a pressure-sensitive adhesive.
The tobacco rod 11 is formed of a tobacco filler 11a and a cigarette paper 11b which is wrapped around the tobacco filler, as a usual cigarette. The tobacco rod 11 may have, for example, a diameter of 5 to 10 mm and a length of 40 to 80 mm.
The filter 12 is located at one end of the tobacco rod 11, and is formed of a filter member 12a and a filter wrapping paper 12b which is wrapped around the filter member. The filter member 12a shown in
The tipping member 13 is bonded to the entire filter wrapping paper 12b and a part of the cigarette paper 11b with a pressure-sensitive adhesive 14 so that it covers them. In the present specification, the tipping member 13 means a member having a function as a tipping paper which is generally used in a cigarette (i.e., a function of connecting a tobacco rod to a filter). In the present invention, any sheet formed from a polymer material can be used as the tipping member, in addition to a paper (i.e., a tipping paper), and thus the term “tipping member” is used instead of the term “tipping paper.” The tipping member 13 may have, for example, a length (width) of 20 to 50 mm in an axial direction of the tobacco rod, and a thickness of 10 to 100 μm. The tipping member has a number of small apertures for air permeation (ventilation apertures) in a line or multiple lines along the circumferential direction of the cigarette, or irregularly, as a tipping paper used in a general filter-tipped cigarette.
The pressure-sensitive adhesive 14 is located on a back surface of the tipping member 13, and serves to paste the tipping member. The pressure-sensitive adhesive 14 has preferably a size to cover the entire back surface of the tipping member, but it is not necessary to have the size to cover the entire back surface of the tipping member 13, if it integrally bonds the tipping member 13 to the tobacco rod 11 and the filter 12. The pressure-sensitive adhesive 14 refers to an adhesive which exhibits adhesiveness by a pressing force alone, without a procedure of heating or solidification by drying. Commercial available double-sided adhesive tapes, preferably acrylic double-sided adhesive tapes and rubber double-sided adhesive tapes may be used as the pressure-sensitive adhesive 14. For example, an acrylic adhesive tape (No. 501 L) manufactured by Nitto Denko Corporation and a rubber adhesive tape (VR-5321) manufactured by Nitto Denko Corporation may be used.
Double-sided adhesive tapes are classified into two groups: double-sided adhesive tapes having a three-layer structure in which pressure-sensitive adhesive layers are provided on both surfaces of a substrate such as a nonwoven fabric or a polyester film, and double-sided adhesive tapes having a monolayer structure which has a pressure-sensitive adhesive layer alone having no substrate. In the present invention, both types of the double-sided adhesive tapes can be used. The above acrylic adhesive tape (No. 501 L) manufactured by Nitto Denko Corporation has a three-layer structure in which acrylic pressure-sensitive adhesive layers are provided on both surfaces of a nonwoven fabric (substrate). The above rubber adhesive tape (VR-5321) manufactured by Nitto Denko Corporation has a three-layer structure in which a rubber pressure-sensitive adhesive layer is provided on one surface of a polyester film (substrate) and an acrylic pressure-sensitive adhesive layer is provided on the other surface of the substrate.
In
The cigarette of the present invention having the pressure-sensitive adhesive with such a three-layer structure can have more improved wet breaking strength of the cigarette than conventional cigarettes in which the tipping paper is bonded using a heat-sensitive adhesive, owing to the presence of the substrate 14a. The term “wet breaking strength” means a nature of a cigarette to become easily broken at an abutted part of the tobacco rod and the filter, which is caused in a situation where a tipping paper becomes wet with saliva when a smoker puts the cigarette in his/her mouth, resulting in reduced strength of the tipping paper. In addition, the cigarette of the present invention having the pressure-sensitive adhesive with such a three-layer structure can have improved opacity of the tipping paper, which leads to improved cleanliness sense and high-grade sense of the cigarette.
In the cigarette of the present invention, the tipping member 13 is bonded with the pressure-sensitive adhesive 14, and thus a heating procedure is not required in its production process, and any material including a material unstable to a heat-sensitive or solvent-evaporative paste and a heat-unstable material can be used as the tipping member.
Specifically, in the present invention, any polymer material such as a plastic film can be used as the tipping member 13, in addition to a paper (i.e., a tipping paper). For example, polymer films shown in the following table can be used.
When a polymer material having a melting point of 240° C. or less, preferably a polymer material having a melting point of 200° C. or less, for example, polyethylene or polybutylene succinate having a melting point of 150° C. or less is used as the material for the tipping member, the effects of the present invention are remarkably exhibited among the polymer materials shown in the above table. In other words, even a polymer material having a melting point of 240° C. or less can be stably used as the tipping member material in the cigarette of the present invention, because the tipping member is bonded with the pressure-sensitive adhesive and thus a heating procedure is not required in its production process. On the other hand, if each polymer material shown in the above table is subjected to a heating step according to a conventional method, the temperature of the material reaches the melting point in a heater-temperature range, and thus it is very likely to adhere in the vicinity of the heater, especially in case of mechanical trouble.
As the polymer material, synthetic papers in which polyethylene or polypropylene is mixed with a colored powder (calcium carbonate), such as YUPO manufactured by Yupo Corporation or Keeplus manufactured by TBM Co., Ltd., may also be used.
In addition to the polymer materials shown in the above table, a cellulosic material film (for example, cellophane) or a plastic film, which is used as a transparent tipping paper in a cigarette, may be used as the tipping member. When the cellulosic material film is used, the effects of the present invention are remarkably exhibited. The cellulosic material is water-soluble substance, and thus is unstable to a heat-sensitive or solvent-evaporative paste. However, such a paste is not used in the present invention, and thus it is stably used as the material for the tipping member.
The cigarette of the present invention can further include a capsule containing a flavor component in a filter or on a tipping member. As the flavor component, for example, menthol or essential oil from plants can be used.
An embodiment in which the flavor-containing capsule is included in the filter is shown in
The cigarette shown in
a tobacco rod 11 comprising a tobacco filler 11a and a cigarette paper 11b which is wrapped around the tobacco filler 11a;
a filter 12 comprising a filter member 12a in which a flavor-containing capsule 21 is embedded and a filter wrapping paper 12b which is integrally wrapped around the filter member 12a; and
a tipping member 13 which is bonded onto the tobacco rod and the filter with a pressure-sensitive adhesive 14 so that the tobacco rod 11 and the filter 12 are connected to each other.
The flavor-containing capsule 21 has a structure in which a flavor component-containing solution is enclosed with a film. The size of the flavor-containing capsule 21 may be from 2 to 5 mm in a diameter. A method for preparing the flavor-containing capsule is not particularly limited, and for example, a dropping method is preferably employed, because it enables the preparation of a flavor-containing capsule having a seamless film. This method can be performed by using a double nozzle, and simultaneously discharging the flavor-containing solution from an inner nozzle and a liquid film substance from an outer nozzle. The flavor-containing capsule 21 may be embedded in the filter member 12a in accordance with a known technique, or the flavor-containing capsule may be located in a hollow part between two filter plugs forming the filter member, the two filter plugs being separated from each other and placed to provide the hollow part therebetween. As the flavor, for example, menthol, essential oil from plants, and the like can be used. The flavor-containing solution may further contain a solvent, a colorant and other additives such as an emulsifier. As the solvent in the flavor-containing solution, for example, medium-chain triglyceride (MCT) can be used. As the film for the flavor-containing capsule, for example, starch, dextrin, polysaccharide, agar, gellan gum, gelatin, carrageenan, various natural gelling agents, glycerol, various waxes, sorbitol, calcium chloride, and the like can be used, and it can further contain a flavor or a colorant.
It is a known technique to prepare such a flavor-containing capsule and incorporate it into the filter. However, because the components forming the film of the flavor-containing capsule are thermally unstable, if they are subjected to a heating process in accordance with a conventional method for producing a cigarette, the capsule is likely to be broken and the flavor is likely to leach from the film. According to the present invention, however, they are not subjected to the heating process during the production, and thus there is an advantage in which the flavor-containing capsule can be stably maintained.
The cigarette shown in
a tobacco rod 11 comprising a tobacco filler 11a and a cigarette paper 11b which is wrapped around the tobacco filler 11a;
a filter 12 comprising a filter member 12a and a filter wrapping paper 12b which is integrally wrapped around the filter member 12a; and
a tipping member 13 which is bonded onto the tobacco rod and the filter with a pressure-sensitive adhesive 14 so that the tobacco rod 11 and the filter 12 are connected to each other, and which comprises a flavor microcapsule-containing layer 31 on its surface.
The flavor microcapsule-containing layer 31 is a layer obtained by coating the tipping member with slurry containing flavor-containing microcapsules (which is referred to as “microcapsule slurry”), and drying it. The size of the microcapsule may be from 3 to 25 μm in a diameter, and the thickness of the flavor microcapsule-containing layer 31 may be from 3 to 50 μm. The flavor microcapsule-containing layer can be formed on the tipping member by coating the tipping member with the microcapsule slurry, and subjecting it to natural air-drying or sending air to it at a room temperature to remove the solvent from the slurry, in accordance with a known technique. The flavor microcapsule-containing layer 31 may be formed on the entire surface of the tipping member, or at only a mouthpiece side on the surface of the tipping member. As the flavor, menthol, essential oil from plants, and the like can be used. The flavor-containing solution in the microcapsule may further contain a solvent, a colorant, and other additives such as an emulsifier. As the film for the microcapsule, for example, gelatin, agar, carrageenan, dextrin, various natural gelling agents, various waxes, and the like can be used.
It is a known technique to prepare such microcapsule slurry and form the flavor microcapsule-containing layer on the surface of the tipping paper. However, because the components forming the film of the microcapsule are thermally unstable, if they are subjected to a heating process in accordance with a conventional method for producing a cigarette, the capsule is likely to be broken and the flavor is likely to leach from the film. According to the present invention, however, they are not subjected to the heating process during the production, and thus there is an advantage in which the microcapsules can be stably maintained.
2. Method for Producing Cigarette
The cigarette of the present invention can be produced in any method so long as the tipping member is wrapped around the filter and the tobacco rod, and bonded thereto with the pressure-sensitive adhesive. Preferably, it can be produced by previously preparing a tipping member having a pressure-sensitive adhesive on its back surface (back surface-adhesive tipping member), and connecting the tobacco rod and the filter to each other using the back surface-adhesive tipping member.
In a preferable embodiment, the method for producing the cigarette of the present invention comprises:
(1) preparing a tipping member which comprises a pressure-sensitive adhesive and a release liner for protecting the pressure-sensitive adhesive, on its back surface;
(2) exposing the pressure-sensitive adhesive by releasing the release liner from the tipping member;
(3) cutting the pressure-sensitive adhesive-exposed tipping member into a size suitable for rolling the cigarette; and
(4) wrapping the tobacco rod and the filter in the cut tipping member to connect them.
In the step (1) described above, a tipping member is prepared which comprises, on its back surface, a pressure-sensitive adhesive and a release liner for protecting the pressure-sensitive adhesive.
Such a seal-shaped tipping member can be put in a system shown in
As described above, the method for producing the cigarette of the present invention does not include a step of transferring a heat-sensitive or solvent-evaporative paste or a step of drying the paste, and thus the system shown in
A cigarette sample was produced using the following polymer film as a tipping member.
As a pressure-sensitive adhesive, an acrylic double-sided adhesive tape (No. 501 L) or a rubber double-sided adhesive tape (VR-5321), manufactured by Nitto Denko Corporation, was used. The polymer film described above was cut into a size of 3.0 (length in axial direction of tobacco rod)×3.5 cm, and the double-sided adhesive tape is cut into a size of 3.0 cm×3.5 cm. The polymer film was stuck on the double-sided adhesive tape so that they overlapped each other to produce a back surface-adhesive tipping member with the release paper. The back surface-adhesive tipping member was wrapped around a filter (manufactured by our company) and a tobacco rod (manufactured by our company) while peeling off the release paper so that the filter and the tobacco rod were connect to each other (see
In the cigarette of the present invention, the pressure-sensitive adhesive was used, and therefore a heating procedure was not required in its production process. As a result, any material including a material unstable to a heat-sensitive or solvent-evaporative paste or a heat-unstable material could be stably used as the tipping member.
(1) Preparation of Tipping Member Including Flavor Microcapsule-Containing Layer on Its Surface
A plain paper having a thickness of about 40 μm and a basis weight of 37 gsm (a base sheet for a tipping paper, manufactured by Oji F-Tex Co., Ltd.), which had been cut into a size of 5.0 cm (length in axial direction of tobacco rod)×3.0 cm, was used as a tipping member.
Slurry containing flavor microcapsules (particle size of 3 to 25 μm) was prepared from gelatin and a flavor (peppermint oil) in water in accordance with a conventional liquid-phase method. The prepared microcapsule slurry was spray-coated on one surface of the tipping paper in an amount of 2 to 5 gsm (g/m2), and it was subjected to natural air-drying to fix it. Thus, the flavor microcapsule-containing layer was formed on the surface of the tipping paper.
(2) Production of Cigarette
In Example of the present invention, an acrylic double-sided adhesive tape (No. 501 L) manufactured by Nitto Denko Corporation was used as a pressure-sensitive adhesive. In Comparative Example, an aqueous emulsion (vinyl acetate, a moisture content of about 55%, Tobacall VP 7915S, Henkel Japan), which was a heat-sensitive adhesive, was used.
In Example of the present invention, the double-sided adhesive tape was cut into the same size as that of the tipping paper (5.0×3.0 cm), and it was stuck on a back surface of the tipping paper prepared in (1) (a surface having no flavor microcapsule-containing layer) so that the double-sided adhesive tape was overlapped with the tipping paper to produce a back surface-adhesive tipping paper with the release paper. The back surface-adhesive tipping paper was wrapped around a filter and a tobacco rod while peeling off the release paper so that the filter and the tobacco rod were connected to each other.
In Comparative Example, a back surface of the tipping paper prepared in (1) was coated with the aqueous emulsion to produce a back surface-adhesive tipping paper. The coated amount was about 0.1 g/piece. The back surface-adhesive tipping paper was wrapped around a filter and a tobacco rod so that the filter and the tobacco rod were connected to each other. After the tipping paper was wrapped, the resulting cigarette was rolled on a hot plate at a temperature of about 200° C. for 0.3 seconds to bond the tipping paper with heating, as a usual method for producing a cigarette.
As a filter, a plain filter (length×circumference=27×24.5 mm) was used, in which acetate tows were wrapped in a filter wrapping paper made of plain paper. As a tobacco rod, a tobacco rod of Mild Seven Super Light (length×circumference=57×24.8 mm) was used.
(3) Evaluation
The cigarettes produced in (2) were enclosed in a zippered aluminum bag (a laminated material in which PET/aluminum/PE were laminated in this order from the outside, Lamizip Stand type AL-14, manufactured by Seisannipponsha Ltd.; height×width+gusset=200×140+41 mm), immediately after the production. Ten cigarettes were enclosed in one zippered aluminum bag, which was used as one sample. Six cigarette samples were prepared for Example of the present invention and Comparative Example, respectively.
After the sample was allowed to stand at 22° C. for 24 hours, a sensory evaluation of odor strength of the flavor in the zippered bag was performed. It is possible to evaluate the stability of the capsule by the sensory evaluation of the odor strength of the flavor, because the gelatin capsule releases the flavor when the capsule is broken.
The sensory evaluation was performed by a pair test of the odor strength of the flavor in the zippered bag of Example of the present invention and the odor strength of the flavor in the zippered bag in Comparative Example.
The evaluation was performed by seven persons who did not engage in smoking flavor-related occupations in our company.
The results of the sensory evaluation are shown in Table below.
Table 3 shows that the odor was significantly stronger in Comparative Example (significance level of 5%). From this result, it was shown that in the cigarettes in Comparative Example, the flavor component was leached from the capsule, and it could not be stably maintained; whereas, in the cigarettes of the present invention, the gelatin microcapsule containing the flavor could be stably maintained on the surface of the tipping paper, and they have significantly higher flavor retaining property than the cigarettes in Comparative Example.
As described above, in the cigarette of the present invention, the tipping member is bonded with the pressure-sensitive adhesive, and thus a heating procedure is not required in its production process, and any material can be incorporated into the filter or attached on the surface of the tipping member as the flavor-containing capsule.
The cigarette of the present invention, consequently, can ease restriction on materials which can be used as the tipping member and materials which can be used as the flavor-containing capsule, and thereby can impart various sense of touch and functions to the cigarette.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2010-232574 | Oct 2010 | JP | national |
This application is a Continuation Application of PCT Application No. PCT/JP2011/062814, filed Jun. 3, 2011 and based upon and claiming the benefit of priority from prior Japanese Patent Application No. 2010-232574, filed Oct. 15, 2010, the entire contents of all of which are incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2011/062814 | Jun 2011 | US |
| Child | 13827536 | US |
