The invention relates to the cigarette filter containing the microfibres and to the method of its manufacturing.
The function of cigarette filters is to catch the health harmful components of cigarette smoke, especially of organic substances being produced at imperfect burning of tobacco and cigarette paper. Filters are mostly made of filtration or more precisely of crepe papers or fibrous cables or systems in its essence of parallel yarns or threads, while all executions are made of microfibres from material with minimum impact to the “taste” of cigarette, which is e.g. cellulose acetate. At the same time it is necessary, that the material and structure of cable as well as the rest of other parts of filter does not cause distinct increase in pressure gradient between both ends of filter, which could have a decisive and negative influence from the point of view of the consumer.
The general tendency is to increase the efficiency of separation of health harmful components of cigarette smoke, thus reducing the health risks connected especially with active smoking. One possibility how to increase the efficiency of separation is a change of sorptive properties of cigarette filter which leads to a substantial change of its structure and to production of divided cigarette filters. These are the filters created by several sections of cellulose acetate cable or of filtration paper, between which there is positioned a sorptive element containing a substance having advantageous sorptive properties, e.g. the granulated activated carbon. Nevertheless thanks to this change in structure of cigarette filters these show relatively high pressure loss, and moreover the demands and costs for manufacturing of such cigarette filters increase.
From the WO 2005/009150, respectively from analogical US 2005/139223 there is known the cigarette filter formed exclusively from nanofibres. Such filter has a very high specific surface and out of this arising very good sorptive and filtration properties. Nevertheless the disadvantage is its high price which prevents its usage in practice. Though the patent application describes a low pressure loss of cigarette filter, based on the knowledge of properties of nanofibres textiles it is not possible to agree with this argument, on the contrary it can be presumed, that the pressure loss of cigarette filter formed of nanofibres will be high. The WO 2005/009150 further describes the cigarette filter whose part is formed of nanofibres, namely a section of filter length or a section of filter diameter. Nevertheless these measures lower the above mentioned disadvantages partially only.
The objective of the invention is to eliminate disadvantages of the present state of the art and to form a cigarette filter with high sorptive and filtration properties, at the same time increasing the price as low as possible.
The objective of the invention has been reached by a cigarette filter containing the microfibres according to the invention whose principle consists in that it contains from 0.5 to 10% by weight of polymeric nanofibres, which are arranged between the microfibres, while according to the claim 2 it is advantageous if the nanofibres are arranged evenly among the microfibres within the whole volume of cigarette filter. The nanofibres arranged among the microfibres increase substantially the filter specific surface, at the same time due to their low ratio on the total weight of filter and arrangement of nanofibres among the microfibres they increase minimally the filter pressure loss.
The most advantageous content of nanofibres in cigarette filter is within the range of 0.5 to 3.0% by weight.
The microfibres are arranged into linear or surface configurations, while the spaces being created among these configurations, or more precisely among the configurations containing the microfibres as the main component in the quantity of 90% at minimum, or more precisely among microfibres, are according to the claim 4 filled with linear or surface textile configurations formed of nanofibres. In other advantageous case the textile configurations formed of nanofibres are arranged directly on the surface of textile configurations created by microfibres, while the characteristic dimension of textile configurations formed of nanofibres does not exceed 5 mm.
The advantage of joining the linear and surface configurations created by microfibres and nanofibres is, that the filtration material, already at relatively small content of nanofibres usually varying in units of percentage by weight, shows relatively high specific surface and at the same time thanks to a high content of microfibres it maintains nearly the same pressure gradient as the cigarette filters created exclusively by microfibres.
According to the claim 7 especially because of the manufacturing reasons, namely disjoining of production of nanofibre textile and the filter itself, it is advantageous if the textile configurations created by nanofibres are the shreds of surface nanofibre textile having dimensions up to 5×5 mm.
In one of the advantageous executions of cigarette filter according to the invention the nanofibres eventually the shreds of surface nanofibre textile are applied on the surface of a crepe paper containing microfibres in the quantity at least of 90% by weight, which is after then rolled down into a shape of cylinder creating the cigarette filter.
In the advantageous execution of cigarette filter according to the claims 9 and 10 the nanofibres or the shreds of surface textile configuration formed of nanofibres are applied on the surface and/or inside of the surface or linear textile configuration formed of microfibres, out of which the body of cigarette filter is further produced, while the linear textile configuration formed of nanofibres is with advantage represented by a microfibrous cable, microfibrous thread or microfibrous yarn.
An advantageous manufacturing method of a cigarette filter according to the invention is a method, when the nanofibres or shreds of surface textile configuration formed of nanofibres are brought to the surface of the configuration designated for production of cigarette filter created at least by 90% of microfibres, which are deposited on its surface or into its structure in the quantity from 0.5 to 10% by weight, after then the configuration with nanofibres will be rolled down or otherwise formed into the shape of cylinder creating the cigarette filter.
At this method it is advantageous if the quantity of nanofibres is within the range from 0.5 to 3.0% by weight.
Another advantageous method is depositing of nanofibres or shreds of surface nanofibrous textile on the surface of the crepe paper, which is after then rolled down through which the cigarette filter is created.
Another advantageous manufacturing method of a cigarette filter according to the invention is depositing of nanofibres or shreds of surface nanofibrous textile on the surface and/or in the volume of the surface textile configuration, which is consequently shaped into a cylinder creating the cigarette filter.
Another advantageous manufacturing method of a cigarette filter according to the invention is depositing of nanofibres or shreds of surface nanofibrous textile on the surface and/or into the volume of linear textile configuration.
Examples of embodiment of cigarette filter according to the invention are schematically shown in the attached drawings,
where the
the
the
the
the
the
the
and the
At the cigarette 1 shown in the
The cigarette filter 2 according to the above mentioned embodiment has a much more greater specific surface, thus also filtration and sorptive properties than it is at the classic cigarette filter, which is created by microfibres only, because for example the mixture, containing 99 percentage by weight of microfibres 21 having diameter of 20 micrometers and 1 percentage by weight of nanofibres 22 having diameter of 0.2 micrometer (200 nm), has a double specific surface than it is at usage of the microfibres 21 only, at the same time thanks to the possibility to regulate the size of poruses upon production of the filter 2, it enables to reach a relatively small pressure loss, which at usage of this material reaches the values less than 5% of the total pressure gradient.
Cigarette filters formed of mixture of microfibres and nanofibres that differ by proportion of individual components, their mutual arrangement and the production itself shall be described in the following text.
The cigarette filter 2 according to the
At production of the cigarette filter according to the above mentioned example of embodiment the microfibrous cable commonly used for production of cigarette filters in the rolled out status, that means in the shape of a ribbon, led by the continuously running equipment for production of nanofibres, e.g. by an electrostatic spinning device, in which it serves as the base material, on which the produced nanofibres are deposited, while the content of nanofibres in such created filtration material, which is after then in a known manner further processed to the cigarette filter, with advantage varies in the range from 0.5 to 3.0 percentage by weight.
The cigarette filter 2 according to the
Upon production of the cigarette filter according to this example of embodiment to the microfibrous cable in the rolled out status there are brought, by means of airstream, the shreds 23 of surface nanofibrous textile which are caught between the microfibres 21 of the cable and for example due to the underpressure in the space behind the rolled out microfibrous cable the shreds 23 will get among the microfibres 21 inside the rolled out cable, which is after then in a common manner formed into the tubular shape and so it creates the cigarette filter according to the
In examples of embodiment according to the
Upon production of the cigarette filter according to the
Upon production of cigarette filter according to the
In example of embodiment according to the
Upon production of cigarette filter according to the
Upon production of the cigarette filter according to the
The quantity of nanofibres 22, which the cigarette filter 2 according to the invention contains may be even higher than it is described in the given examples of embodiment, nevertheless with respect to economy of production of cigarette filters and cigarettes in general, the maximum quantity of polymeric nanofibres 22 in the cigarette filter 2 is from 0.5 to 10% by weight. Lower quantity of nanofibres 22 than 0.5% by weight brings only a small improvement of filtration and sorptive properties of the cigarette filter and quantity of nanofibres 22 greater than 10% by weight increases the filter price considerably. In consideration of filtration and sorptive properties of the cigarette filter 2 and the price availability, the most advantageous content of nanofibres 22 in the cigarette filter 2 lies within the range from 0.5 to 3.0 percentage by weight.
The invention is not limited only to the described embodiments of cigarette filters and method of their manufacturing, but it contains also their combinations and further embodiments of cigarette filters which contain the mixture of microfibres and nanofibres, when the quantity of nanofibres in the mixture varies from 0.5 to 10% by weight.
Number | Date | Country | Kind |
---|---|---|---|
PV 2005-670 | Oct 2005 | CZ | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/CZ06/00071 | 10/24/2006 | WO | 00 | 4/24/2008 |