Claims
- 1. A polymer having repeating units of the general formula: ##STR5##
- 2. A polymer in accordance with claim 1 and having the cis-configuration.
- 3. A polymer in accordance with claim 1 and having the transconfiguration.
- 4. The polymer of claim 2 wherein each R is --H, and Ar is ##STR6##
- 5. The polymer of claim 2 wherein each R is --H, and Ar is ##STR7##
- 6. The polymer of claim 2 wherein each R is --H, and Ar is ##STR8##
- 7. The polymer of claim 2 wherein R is --H and Ar is a phenylene group.
- 8. The polymer of claim 2 wherein R is --H and Ar is ##STR9##
- 9. The polymer of claim 2 wherein R is --H and Ar is ##STR10##
- 10. A method for producing a polymer having repeating units as follows: ##STR11## which comprises reacting a di-.beta.-bromobenzene of the general formula ##STR12## wherein R is as described above, with a diacetylenic compound of the general formula
- HC.tbd.C--Ar--C.tbd.CH,
- wherein Ar is as described above, in the presence of a catalyst consisting essentially of cuprous iodide and bis-triphenylphosphine palladium II dichloride, in a reaction medium.
- 11. The method of claim 10 wherein the weight ratio of said cuprous iodide to said palladium complex is about 1:2.
- 12. The method of claim 10 wherein the amount of said catalyst system is about 2 to 10 weight percent.
- 13. The method of claim 10 wherein said reaction is carried out at a temperature in the approximate range of 5.degree. to 40.degree. C.
- 14. The method of claim 13 wherein said reaction range is about 20.degree. to 25.degree. C.
- 15. The method of claim 10 wherein said reaction medium consists essentially of an aprotic solvent and about 10 to 50 percent of an HBr acceptor.
- 16. The method of claim 15 wherein said reaction medium is a mixture of N,N-dimethylacetamide and triethylamine.
RIGHTS OF THE GOVERNMENT
The invention described herein may be manufactured and used by or for the Government of the United States for all governmental purposes without the payment of any royalty.
US Referenced Citations (9)
Foreign Referenced Citations (3)
Number |
Date |
Country |
963998 |
Mar 1965 |
CAX |
1020670 |
Feb 1966 |
GBX |
238163 |
Feb 1969 |
SUX |
Non-Patent Literature Citations (1)
Entry |
F. Cassar, Journal of Organometallic Chem. 93, (1975), 253-257. |