This patent application is based on and claims priority pursuant to 35 U.S.C. §119 to Japanese Patent Application No. 2012-192413 filed on Aug. 31, 2012 in the Japan Patent Office, the entire disclosure of which is hereby incorporated by reference herein.
The present invention relates to a cleaner for use in image forming apparatuses such as printers, facsimiles and copiers. In addition, the present invention relates to an image forming apparatus using the cleaner, and to a voltage setting device.
Conventionally, tandem color image forming apparatuses in which different color toner images are formed by linearly arranged plural image forming sections, and the color toner images are transferred one by one onto an intermediate transfer medium, which is fed along the image forming sections, to form a combined color toner image thereon, have been used for producing multiple color images at a high speed. In each of the image forming sections of such tandem color image forming apparatuses, an electrostatic latent image formed on a photoreceptor serving as an image bearing member is developed by a developing device using a color toner to form a color toner image on the photoreceptor. The different color toner images thus formed on the photoreceptors of the image forming sections are transferred one by one onto an intermediate transfer medium so as to be overlaid to form a combined color toner image on the intermediate transfer medium, and the combined color toner image is secondarily transferred onto a recording medium such as paper sheets, resulting in formation of a multi-color image.
In order to remove residual toner remaining on the intermediate transfer medium even after the combined color toner image is transferred, a cleaner to remove residual toner using an electrostatic force has been proposed.
For example, JP-2009-258541-A proposes a cleaner which electrostatically removes normally-charged residual toner, which is present on an intermediate transfer medium and which is charged normally (i.e., which has a charge with the same polarity as that of the toner used), and reversely-charged residual toner, which is also present on an intermediate transfer medium and which is charged reversely.
This cleaner includes a first cleaning brush roller to remove normally-charged residual toner from the intermediate transfer medium, and a second cleaning brush roller to remove reversely-charged residual toner from the intermediate transfer medium. In addition, the cleaner includes a first counter roller, which is grounded and which is arranged so as to be contacted with the backside of the intermediate transfer medium while facing the first cleaning brush roller with the intermediate transfer medium therebetween, and a second counter roller, which is grounded and which is arranged so as to be contacted with the backside of the intermediate transfer medium while facing the second cleaning brush roller with the intermediate transfer medium therebetween.
A voltage with a polarity opposite to that of normally-charged toner is applied to the first cleaning brush roller by a power source. In this case, a potential difference is formed between the first cleaning brush roller and the first counter roller, thereby forming an electric field such that normally-charged residual toner on the intermediate transfer medium are electrostatically attracted by the first cleaning brush roller. In addition, a voltage having the same polarity as that of normally-charged toner is applied to the second cleaning brush roller by a power source. In this case, a potential difference is formed between the second cleaning brush roller and the second counter roller, thereby forming an electric field such that reversely-charged residual toner on the intermediate transfer medium are electrostatically attracted by the second cleaning brush roller.
Thus, normally-charged residual toner is electrostatically attracted by the first cleaning brush roller, and therefore the residual toner is removed from the intermediate transfer medium. In addition, reversely-charged residual toner is electrostatically attracted by the second cleaning brush roller, and therefore the residual toner is also removed from the intermediate transfer medium.
In image forming apparatuses, a test pattern of a toner (hereinafter referred to as a toner test pattern) is typically formed on the intermediate transfer medium to improve image quality.
Specifically, when images having a low image area proportion are continuously formed, the amount of toner particles (hereinafter aged toner particles) staying in the developing device for a long period of time increases. Since such aged toner particles have a deteriorated charge property, the quality of images produced by the developing device deteriorates. In order to prevent occurrence of such a problem, a toner test pattern is formed, at a predetermined time, on a non-image area of the intermediate transfer medium to use (remove) such aged toner particles staying in the developing device for a long period of time, followed by supply of a new toner to the developing device to control the toner concentration of the developer in the developing device. This operation is called as a toner refreshing operation. By performing such a toner refreshing operation, the image quality is improved. The toner test pattern formed on the intermediate transfer medium is removed therefrom by a cleaner similarly to residual toner.
In this regard, the amount of toner particles of residual toner, which remains on an intermediate transfer medium even after the secondary transfer process is performed, is about 0.05 mg/cm2 or less. In contrast, the amount of toner particles constituting a toner test pattern is about 1.0 mg/cm2. Thus, the cleaner has to have a function of removing toner particles in an amount of from 0.05 to 1.0 mg/cm2. In this regard, the cleaning current suitable for removing toner particles changes depending on the amount of the toner particles. Specifically, when the amount of toner particles to be removed is large, it is preferable to apply a relatively large current. In contrast, when the amount of toner particles is small, it is preferable to apply a relatively small current.
Therefore, the voltage applied to a cleaning brush roller is typically changed depending on whether toner particles to be removed are residual toner or a toner test pattern, so that the toner particles on the intermediate transfer medium can be satisfactorily removed therefrom. Specifically, when residual toner, which remains on the intermediate transfer medium even after the secondary transfer process is performed, is removed, a relatively low voltage is applied to the cleaning brush roller. In contrast, when a toner test pattern is removed, the voltage is switched to a relatively high voltage.
In addition, the voltage applied to the cleaning brush roller is adjusted depending on the conditions of use. Specifically, the resistances of the intermediate transfer medium and the cleaning brush roller are typically predetermined. However, the resistances tend to change due to variation of initial resistances of such members or when the members are used for a long period of time. When the resistance of the intermediate transfer medium or the cleaning brush roller falls out of the predetermined range and cleaning is performed under the normal conditions, it is possible that defective cleaning is caused.
The cleaning performance of a cleaning brush roller strongly correlates with the amount of the current flowing through the contact portion of the cleaning brush roller and the intermediate transfer medium. If the amount of the current can be maintained so as to fall in the targeted range, it is possible to maintain a high level of cleaning performance even when the resistances of the intermediate transfer medium and the cleaning brush roller change.
There is a technique in that the amount of the current flowing through the contact portion of a cleaning brush roller and an intermediate transfer medium is detected, and the setup voltage value stored in a memory is properly changed so that a targeted current flows through the contact portion of the cleaning roller and the intermediate transfer medium. By using this technique, it is considered that occurrence of defective cleaning can be prevented, because a voltage suitable for cleaning is applied to the cleaning brush roller even when the resistances of the intermediate transfer medium and the cleaning brush roller change.
However, as a result of investigation of the present inventor, it is found that when changing the voltage level in two or more levels, whether or not the voltage can be set to an optimum voltage depends on the method of changing the setup voltage.
The object of the present invention is to provide a cleaner which can satisfactorily perform cleaning on residual toner particles and a toner test pattern while setting cleaning voltage for cleaning residual toner and non-transferred toner to optimum voltages, an image forming apparatus using such a cleaner, and a voltage setting device to set the voltage to be applied to a member to an optimum voltage.
As an aspect of the present invention, a cleaner is provided which includes at least two cleaning brush members to electrostatically remove residual toner (such as toner particles remaining on an object even after a transferring process) and non-transferred toner (such as a toner test pattern) on an object to be cleaned; a memory to store setup voltage values; a voltage applicator to apply voltages to the cleaning brush members based on the setup voltage values stored in the memory; a current detector to detect the amounts of currents flowing through the contact portions of the object with the cleaning brush members; and a setup voltage changing device to change the setup voltage values based on the amounts of currents detected by the current detector. The voltage applicator applies a first voltage to at least one of the cleaning brush members to remove residual toner on the object. In addition, the voltage applicator applies a second voltage to the at least one of the cleaning brush members to remove non-transferred toner on the object, wherein the second voltage has the same polarity as that of the first voltage, and is higher than the first voltage in absolute value. The setup voltage changing device performs change of the setup voltage value for the second voltage prior to change of the setup voltage value for the first voltage.
As another aspect of the present invention, an image forming apparatus is provided which includes an image bearing member; a toner image forming device to form a toner image on the image bearing member; a primary transferring device to transfer the toner image on the image bearing member to an intermediate transfer medium; a secondary transferring device to transfer the toner image on the intermediate transfer medium to a recording medium; and the above-mentioned cleaner to remove toner on the intermediate transfer medium.
Alternatively, an image forming apparatus is provided which includes an image bearing member; a toner image forming device, a transferring device to transfer the toner image to a recording medium at a transfer position; a recording medium feeding member to feed the recording medium to the transfer position; and the above-mentioned cleaner to remove toner on the recording medium feeding member.
Alternatively, an image forming apparatus is provided which includes at least an image bearing member; a toner image forming device, and the above-mentioned cleaner to remove toner on the image bearing member.
As yet another aspect of the present invention, a voltage setting device is provided which includes at least two voltage applying members contacted with different positions of an object (such as image bearing member, intermediate transfer medium or recording medium feeding member) and to which voltages are applied based on setup voltage values stored in a memory; a current detector to detect the amounts of currents flowing through the contact portions of the voltage applying members with the object; and a setup voltage changing device to change the setup voltage values based on the amounts of currents detected by the current detector. The voltage is applied to at least one of the voltage applying members while changing the voltage levels in two or more levels. In addition, the setup voltage changing device performs change of the setup voltage value for a higher voltage prior to change of the setup voltage value for a lower voltage.
The aforementioned and other aspects, features and advantages will become apparent upon consideration of the following description of the preferred embodiments taken in conjunction with the accompanying drawings.
Initially, a tandem printer (hereinafter referred to as a printer) as an example of an image forming apparatus according to an embodiment will be described. The basic configuration of the printer will be described by reference to drawings.
The printer includes four process units 6Y, 6M, 6C and 6K, which serve as image forming devices and which respectively form yellow (Y), magenta (M), cyan (C) and black (K) toner images. The process units 6Y, 6M, 6C and 6K respectively include photoreceptors 1Y, 1M, 1C and 1K. Around the photoreceptors 1Y, 1M, 1C and 1K, chargers 2Y, 2M, 2C and 2K, developing devices 5Y, 5M, 5C and 5K, drum cleaners 4Y, 4M, 4C and 4K, and dischargers (not shown) are respectively arranged.
The process units 6Y, 6M, 6C and 6K have the same configuration except that different color toners, e.g., Y, M, C and K toners, are used therefor. An optical writing unit 3, which irradiates the photoreceptors 1 with laser light L to form electrostatic latent images thereon, is provided above the process units 6. The chargers 2, the developing devices 5 and the optical writing unit 3 serve as a toner image forming device.
A transfer unit 7 including an intermediate transfer belt 8, which is a rotatable endless image bearing member, is provided below the process units 6. The transfer unit 7 further includes plural stretching rollers, which are arranged inside the loop of the intermediate transfer belt 8, and a secondary transfer roller 18, a tension roller 16, a belt cleaner 100, and a lubricant applicator 200, which are arranged outside the loop of the intermediate transfer belt.
Inside the loop of the intermediate transfer belt, four primary transfer rollers 9Y, 9M, 9C and 9K, a driven roller 10, a driving roller 11, a secondary transfer counter roller 12, and three cleaner counter rollers 13, 14 and 15, and a lubricant applicator counter roller 17 are arranged. These rollers also serve as stretching rollers to stretch the intermediate transfer belt 8. In this regard, the cleaner counter rollers 13, 14 and 15 do not necessarily apply a tension to the intermediate transfer belt 8, and may be driven by the rotated intermediate transfer belt. The intermediate transfer belt 8 is rotated clockwise by the driving roller 11, which is rotated clockwise by a driving device (not shown).
The primary transfer rollers 9Y, 9M, 9C and 9K, which are arranged inside the loop of the intermediate transfer belt 8, and the photoreceptors 1Y, 1M, 1C and 1K sandwich the intermediate transfer belt 8, and therefore primary transfer nips for Y, M, C and K images are formed between the contact portions of the outer surface of the intermediate transfer belt 8 with the photoreceptors 1 and the contact portions of the inner surface of the intermediate transfer belt 8 with the primary transfer rollers 9. In this regard, primary transfer biases having a polarity opposite to that of charge of the toners are applied to the primary transfer rollers 9Y, 9M, 9C and 9K, respectively, by power sources (not shown).
The secondary transfer counter roller 12 arranged inside the loop of the intermediate transfer belt 8 and the secondary transfer roller 18 arranged outside the loop sandwich the intermediate transfer belt 8, thereby forming a secondary transfer nip. In this regard, a secondary transfer bias having a polarity opposite to that of charge of the toners is applied to the secondary transfer roller 18 by a power source (not shown). In this regard, a recording medium feeding belt may be provided while supported by the secondary transfer roller 18, and several support rollers so that a recording medium P is fed by the feeding belt to the secondary transfer nip at which the intermediate transfer belt 8 and the feeding belt are sandwiched by the secondary transfer roller 18 and the secondary transfer counter roller 12.
The three cleaner counter rollers 13, 14 and 15, which are arranged inside the loop of the intermediate transfer belt 8, and cleaning brush rollers 101, 104 and 107 of the belt cleaner 100 sandwich the intermediate transfer belt 8, thereby forming cleaning nips therebetween. The belt cleaner 100 and the intermediate transfer belt 8 are integrated and are replaced as a unit. However, when the belt cleaner 100 and the intermediate transfer belt 8 have different lives, it is possible that the belt cleaner 100 is provided so as to be detachably attachable to the printer independently of the intermediate transfer belt 8. The belt cleaner 100 will be described later in detail.
The printer includes a recording medium cassette to contain sheets of the recording medium P such as papers, a sheet passage having feed rollers to feed the recording medium P from the cassette toward the secondary transfer nip. In addition, the printer also includes a pair of registration rollers, which is arranged on the right side of the secondary transfer nip to feed the recording medium fed from the cassette toward the secondary transfer nip at a predetermined time so that the toner image on the intermediate transfer belt 8 is transferred onto a proper position of the recording medium P at the secondary transfer nip. Further, the printer includes a fixing device, which receives the recording medium P fed from the secondary transfer nip and which fixes the toner image to the recording medium P, on the left side of the secondary transfer nip. The printer optionally includes toner supplying devices to respectively supply the Y, M, C and K toners to the developing devices 5Y, 5M, 5C and 5K.
Recently, not only plain papers, but also papers having concaves and convexes on the surface thereof and recording papers used for thermal transferring (iron printing) have been used for image forming apparatuses. When such special papers are used as the recording medium P, defective image transferring is often caused when a toner image on the intermediate transfer belt 8 is transferred onto the special papers.
Therefore, in this printer, an elastic layer having a low hardness is formed on the intermediate transfer belt 8 so that when the intermediate transfer belt 8 is contacted with such a rough paper with the toner image therebetween, the intermediate transfer belt is easily deformed so that the surface of the intermediate transfer belt is contacted with the concaves of the rough paper. Therefore, the toner image can be satisfactorily adhered to the surface of the rough paper without increasing the transfer pressure, thereby making it possible to evenly transfer the toner image onto the rough paper without causing defective transferring (such as uneven transferring, and formation of omissions).
The intermediate transfer belt 8 of this printer includes at least a base layer, an elastic layer, and an outermost coat layer.
Suitable materials for use as the elastic layer include elastic materials such as elastic rubbers, and elastomers. Specific examples thereof include butyl rubber, fluorine-containing rubbers, acrylic rubbers, EPDM (ethylene-propylene-diene rubbers), NBR (acrylonitrile-butadiene rubbers), acrylonitrile-butadiene-styrene rubbers, natural rubbers, isoprene rubbers, styrene-butadiene rubbers, butadiene rubbers, urethane rubbers, syndiotactic 1,2-polybutadiene, epichlorohydrin rubbers, polysulfide rubbers, polynorbonene rubbers, polyurethanes, polyamides, polyureas, polyesters, and fluorine-containing resins, but are not limited thereto. These materials can be used alone or in combination.
The thickness of the elastic layer is determined depending on the hardness of the material and the layer structure, and is preferably from 0.07 mm to 0.8 mm, and more preferably from 0.25 mm to 0.5 mm. When the thickness is less than 0.07 mm, the pressure to the toner image on the intermediate transfer belt 8 seriously increases at the secondary transfer nip, thereby often causing the omission problem in that omissions are formed in the transferred toner image. In addition, the transfer rate of toner images tends to decrease.
The hardness (JIS-A hardness) of the elastic layer is preferably from 10 degree to 65 degree. The optimum hardness changes depending on the thickness of the intermediate transfer belt 8, but when the JIS-A hardness is lower than 10 degree, the omission problem tends to be caused. In contrast, when the JIS-A hardness is higher than 65 degree, it becomes difficult to stretch the intermediate transfer belt with rollers. In addition, when the intermediate transfer belt is tightly stretched for a long period of time, the belt tends to be extended, resulting in shortening of the life of the belt.
The base layer of the intermediate transfer belt 8 is preferably constituted of a resin having a small extension rate. Specific examples of the material for use in the base layer include polycarbonates, fluorine-containing resins (such as ETFE (ethylene-tetrafluoroethylene copolymers) and PVDF (polyvinylidene fluoride), styrene resins (homopolymers and copolymers of styrene and styrene derivatives) such as polystyrenes, chlorinated polystyrenes, poly-α-methylstyrenes, styrene-butadiene copolymers, styrene-vinyl chloride copolymers, styrene-vinyl acetate copolymers, styrene-maleic acid copolymers, styrene-acrylate copolymers (such as styrene-methyl acrylate copolymers, styrene-ethyl acrylate copolymers, styrene-butyl acrylate copolymers, styrene-octyl acrylate copolymers, and styrene-phenyl acrylate copolymers), styrene-methacrylate copolymers (such as styrene-methyl methacrylate copolymers, styrene-ethyl methacrylate copolymers, and styrene-phenyl methacrylate copolymers), styrene-methyl α-chloroacryalte copolymers, and styrene-acrylonitrile-acrylate; methyl methacryalte resins, butyl methacrylate resins, ethyl acrylate resins, butyl acrylate resins, modified acrylic resins (such as silicone-modified acrylic resins, vinyl chloride-modified acrylic resins, and acrylic-urethane resins), vinyl chloride resins, vinyl chloride-vinyl acetate copolymers, rosin-modified maleic resins, phenolic resins, epoxy resins, polyester resins, polyester polyurethane resins, polyethylene resins, polypropylene resins, polybutadiene resins, polyvinylidene chloride resins, ionomer resins, polyurethane resins, silicone resins, ketone resins, ethylene-ethylacrylate copolymers, xylene resins, polyvinyl butyral resins, polyamide resins, and modified polyphenyleneoxide resins, but are not limited thereto. These materials can be used alone or in combination.
In order to prevent extension of the elastic layer, which is typically constituted of a material such as rubber having a large extension rate, a core layer constituted of a material such a cloth can be formed between the base layer and the elastic layer.
Specific examples of the material for use in the core layer include natural fibers such as cotton and silk; synthetic fibers such as polyester fibers, nylon fibers, acrylic fibers, polyolefin fibers, polyvinyl alcohol fibers, polyvinyl chloride fibers, polyvinylidene chloride fibers, polyurethane fibers, polyacetal fibers, polyfluoroethylene fibers, and phenolic fibers; inorganic fibers such as carbon fibers, and glass fibers; and metal fibers such as iron fibers, and copper fibers, but are not limited thereto. These materials can be used alone or in combination.
The yarn of the cloth is not particularly limited, and any known yarns such as yarn in which one or more filaments are twisted, single-twisted yarn, double-twisted yarn, and two-folded yarn can be used. These yarns can be used alone or in combination. In addition, the yarn can be subjected to an electroconductive treatment. Any woven cloths such as stockinet can be used for the core layer. In addition, union cloths can also be used, and cloths subjected to an electroconductive treatment can be used.
The outermost coat layer of the intermediate transfer belt is formed by coating to cover the elastic layer, and preferably has a smooth surface.
Materials having low adhesion to toner is preferably used for the outermost coat layer to enhance the secondary transferring property of toner images. For example, one or more of polyurethane resins, polyester resins, and epoxy resins; and one or more of materials having low surface energy while having good lubricity such as fluorine-containing resins, fluorine compounds, carbon fluoride, titanium oxide, and silicon carbide, can be used for the outermost coat layer. When particulate materials are used, particles having different particle sizes can be dispersed in the layer. It is possible to form a layer of fluorine by subjecting a fluorine-containing rubber to a heat treatment so that the resultant outermost layer has low surface energy.
In order to adjust the resistance of the base layer, the elastic layer, and the outermost coat layer, carbon black, graphite, powders of metals such as aluminum and nickel, and electroconductive metal oxides such as tin oxide, titanium oxide, antimony oxide, indium oxide, potassium titanate, antimony oxide-tin oxide complex oxides (ATO), indium oxide-tin oxide complex oxides (ITO) can be used. In this regard, the metal oxides may be covered with a particulate insulating material such as barium sulfate, magnesium silicate, and calcium carbonate. The resistance adjusting material is not limited to these materials.
The surface of the intermediate transfer belt 8 is coated with a lubricant by the lubricant applicator 200 to protect the surface. The lubricant applicator 200 includes a solid lubricant 202 such as block of zinc stearate, and a brush roller 201 which is contacted with the solid lubricant 202 while rotated to scrape off the lubricant and which applies the lubricant to the surface of the intermediate transfer belt 8. This printer includes the lubricant applicator 200, but the image forming apparatus does not necessarily include such a lubricant applicator depending on choice of toner, choice of the material of the intermediate transfer belt, and the friction coefficient of the surface of the intermediate transfer belt.
Next, the image formatting operation of the printer will be described.
When image information is sent from a personal computer or the like, the printer rotates the driving roller 11 to rotate the intermediate transfer belt 8. The stretching rollers other than the driving roller 11 are driven by the intermediate transfer belt 8. At the same time, the photoreceptors 1 of the process units 6 are rotated. The surfaces of the photoreceptors 1 are respectively charged by the chargers 2, and then irradiated with laser light L to form electrostatic latent images thereon.
The electrostatic latent images thus formed on the photoreceptors 1 are developed by the developing devices 5 to form Y, M, C and K toner images on the photoreceptors. The Y, M, C and K toner images are transferred onto the outer surface of the intermediate transfer belt 8 so as to be overlaid, thereby forming a combined color toner image on the outer surface of the intermediate transfer belt.
Meanwhile, the recording medium P is fed one by one from the recording medium cassette toward the pair of registration rollers. The registration rollers are timely rotated so that the combined color toner image on the intermediate transfer belt 8 is transferred onto a proper position of the recording medium P at the secondary transfer nip. Thus, a full color toner image is formed on the recording medium P. The recording medium P bearing the full color toner image thereon is fed to the fixing device to fix the full color toner image, thereby forming a full color image.
After the Y, M, C and K toner images are transferred onto the intermediate transfer belt 8, the surfaces of the photoreceptors 1 are subjected to a cleaning treatment to remove residual toner particles therefrom. After the photoreceptors 1 are discharged by the discharging lamps, the photoreceptors are charged again by the chargers 2 to perform the next image formation. After the combined color toner image is transferred from the intermediate transfer belt 8 to the recording medium P, the surface of the intermediate transfer belt 8 is cleaned by the belt cleaner 100 to remove residual toner particles therefrom.
An optical sensor unit 150 is provided on the right side of the K process unit 6K so as to be opposed to the outer surface of the intermediate transfer belt with a predetermined distance. As illustrated in
The printer includes a controller (not shown), which detects a toner image on the intermediate transfer belt 8 or the image density (i.e., weight of toner per a unit area) of the toner image based on the output voltage from the optical sensors 151Y, 151M, 151C and 151K.
Whenever the printer is turned on or a predetermined number of prints are formed, process control (image quality control) is performed to control the printer so as to be in a proper state. Specifically, the printer performs check of operation of each device, setting of operation conditions, and control for maintaining good image quality based on the results of detection of images by the optical sensors. The control for maintaining good image quality includes image density control for optimize the image density and misalignment correction processing in which the positions of color images are adjusted to correct the misalignment of the color images.
In the image density control, half tone pattern color images Sk, Sm, Sc and Sy are automatically formed on positions in which the color images face the corresponding optical sensors 151K, 151M, 151C, 151Y, respectively. Each halftone pattern image includes ten toner patches of 2 cm×2 cm which have different image densities.
When each half tone image Sk, Sm, Sc and Sy is formed, the potential of the photoreceptor charged by the charger 2 is gradually increased unlike the charging process in which the photoreceptor is evenly charged to have a predetermined potential. Next, the photoreceptor 1 is scanned with laser light to form electrostatic latent images of the patches on the photoreceptor. The electrostatic latent images are developed by the developing devices 5 to form the toner patches. In this regard, each of the development biases applied to the developing rollers of the developing devices 5 is gradually increased.
Thus, Y, M, C and K half tone pattern images are formed on the photoreceptors 1. These half tone pattern images are primarily transferred onto the intermediate transfer belt 8 so as to be arranged in the width direction of the intermediate transfer belt at regular intervals.
In this regard, the weight of the toner image having the lowest image density is about 0.1 mg/cm2, and the weight of the toner image having the highest image density is about 0.55 mg/cm2. In addition, the −Q(charge quantity)/d(diameter) property of the toner is a normal charge polarity, and the polarity of the toner is the same.
When the toner patches Sk, Sm, Sc and Sy pass under the respective optical sensors 151, the optical sensors receive light reflected from the toner patches. In this regard, as the image density of the toner patches increases, the amount of reflected light decreases.
Next, the amounts (weights) of the toner constituting the toner patches are calculated from the output voltage from the optical sensor using a voltage-toner amount conversion algorithm. The image forming conditions are adjusted based on the thus determined amounts of the toner. Specifically, the relation between the toner amounts of the toner patches and the development potentials when the toner patches are formed is graphed to obtain a function (y=ax+b) using a regression analysis method. By assigning a target image density to the function, a proper development bias is calculated. Thus, the development biases for the developing devices 5Y, 5M, 5C and 5K are determined.
A memory of the controller stores an image forming condition data table concerning the relation between the development bias (in tens of levels) and the potentials of the photoreceptor. A development bias, which is nearest to the above-determined development bias, is selected from the data table, and the charge potential of the photoreceptor corresponding to the development bias is determined.
In the misalignment correction processing, a chevron patch PV, which is constituted of Y, M, C and K color images as illustrated in
The Y, M, C and K color images of the chevron patches PV formed on both the end portions of the intermediate transfer belt 8 are detected to determine the positions of each toner image in the main scanning direction (MD) and the sub-scanning direction (SD), error in magnification ratio of each image in the main scanning direction, and skew of each image from the main scanning direction are detected. In this regard, the main scanning direction means the direction corresponding to the width direction of the photoreceptor, along which laser light reflected from a polygon mirror scans the surface of the photoreceptor.
The Y, M, C and K toner images of the chevron patch PV are detected by the optical sensors 151 to determine the time differences (tky, tkm and tkc) between the K image and each of the Y, M and C images. As illustrated in
The data of the time differences (tky, tkm and tkc) are compared with the theoretical values thereof to determine the displacement of each toner image in the sub-scanning direction, i.e., the mis-registration, is determined. Based on the thus determined mis-registration, the optical image writing timing is adjusted by changing the reflection surface of the polygon mirror to reduce the mis-registration (when the reflection surface is changed to the adjacent reflection surface, the change is a change of one unit). In addition, the slant (skew) of each of the Y, M, C and K toner images is determined based on the mis-registrations on both the end portions of the intermediate transfer belt 8. Next, correction of the optical face tangle error of the polygon mirror is performed based on the results to reduce the skew of the toner images.
As mentioned above, the optical image writing timing is adjusted and the optical face tangle error is corrected based on the times at which the toner images of the chevron patches PV are detected to reduce the mis-registration and the skew of the images. This processing is a misalignment correction processing. By performing this misalignment correction processing, occurrence of the misalignment problem in that positions of the color toner images change with time due to change of the environmental temperature can be prevented.
When images with a low image area proportion are continuously produced, the amount of the aged toner, which stays in the developing device 5 for a long period of time, increases, and therefore the charge property of the toner in the developing device deteriorates, thereby producing images having poor image quality (due to deterioration of developing ability and transferring property of the toner). Therefore, in order to prevent increase of the amount of such aged toners, the printer has a refresh mode in which toner images are formed on non-image areas of the photoreceptors 1 at predetermined times to use the toners in the developing devices 5 while supplying new toners to the developing devices to control the toner concentration in the developing devices.
The controller stores the consumption of the Y, M, C and K toners in the developing devices 5Y, 5M, 5C and 5K, and the operating times of the developing devices. At a predetermined time (i.e., after the developing devices are operated for a predetermined time), the controller checks whether the toner consumption is less than a threshold value for each developing device. If the toner consumption in a developing device is less than the threshold value, the controller performs the refresh mode on the developing device.
When the refresh mode is performed, a test pattern of a toner is formed on a non-image area (an area between two adjacent images) of the photoreceptor 1. The test patterns of the toners are transferred onto the intermediate transfer belt 8 as illustrated in
In
Length of the test pattern in the sub-scanning direction (SD): 15 mm
Length of the test pattern in the main scanning direction (MD): 330 mm
In
Length of the test pattern in the belt moving direction (BD): 10 mm
Length of the test pattern in the main scanning direction (MD): 330 mm
Length between the tip of the test pattern of the Y toner and the tip of the test pattern of the M toner in the belt moving direction (BD): 5 mm
Length between the tip of the test pattern of the M toner and the tip of the test pattern of the C toner in the belt moving direction (BD): 5 mm
Length between the tip of the test pattern of the C toner and the tip of the test pattern of the K toner in the belt moving direction (BD): 5 mm
In
Length of the test pattern in the belt moving direction (BD): 20 mm
Length of the test pattern in the main scanning direction (MD): 330 mm
Length between the tip of the test pattern of the Y toner and the tip of the test pattern of the M toner in the belt moving direction (BD): 5 mm
Length between the tip of the test pattern of the M toner and the tip of the test pattern of the C toner in the belt moving direction (BD): 5 mm
Length between the tip of the test pattern of the C toner and the tip of the test pattern of the K toner in the belt moving direction (BD): 5 mm
The length of the test pattern of toner in the belt moving direction is determined based on the history of the general image forming operation. Therefore, the length of the test pattern in the belt moving direction is not limited to a certain length such as 15 mm, and the length is from 0 to 15 mm for each test pattern. In this regard, the lengths of the Y, M, C and K test patterns are independent of each other.
The toner weight of the test patter is determined based on the ratio (C/O) of the toner consumption (C) to the operating time (O) of the developing device 5, and the maximum toner weight is about 1.2 mg/cm2. When the −Q/d property of the test pattern of a toner transferred onto the intermediate transfer belt 8 is measured, it is confirmed that the toner has substantially a normal charge polarity. The length of the test pattern in the main scanning direction MD is set to be 330 mm in this embodiment.
The halftone images, the chevron patches, and the test patterns formed on the intermediate transfer belt are collected by the belt cleaner 100. In this case, the belt cleaner 100 has to remove a large amount of toners from the intermediate transfer belt. However, it is difficult for conventional cleaners such as combination cleaners of a polarity controller and a brush roller, and combination cleaners of a brush roller to remove a positive toner and a brush roller to remove a negative toner to remove a large amount of non-transferred toner at one time. In this case, the residual toner remaining on the intermediate transfer belt is transferred onto the recording medium P in the next image forming operation, resulting in formation of a defective image.
The belt cleaner 100 of the image forming apparatus according to an embodiment can remove such half tone images, chevron patches, and test patterns formed on the intermediate transfer belt at one time. Hereinafter, the belt cleaner 100 will be described in detail.
Referring to
The pre-cleaning portion 100a includes a pre-cleaning brush roller 101 serving as a pre-cleaning member, a toner collecting roller 102 serving as a collecting member for pre-cleaning to collect the toner adhered to the pre-cleaning brush roller 101, and a scraping blade 103 which serves as a scraper and which is contacted with the toner collecting roller 102 to scrape off the toner adhered to the surface of the toner collecting roller 102.
Almost all the toner particles constituting a non-transferred toner image are normally charged (in this case, the toners are negatively charged). Therefore, a positive voltage, which is opposite to the polarity of the normally charged toner, is applied to the pre-cleaning brush roller 101 to electrostatically removed negatively charged toner particles remaining on the intermediate transfer belt 8. In addition, a positive voltage greater than the positive voltage applied to the pre-cleaning brush roller 101 is applied to the toner collecting roller 102 to satisfactorily collect the toner adhered to the pre-cleaning brush roller 101. The voltage applied to the pre-cleaning brush roller 101 is adjusted so that 90% of the toner particles constituting the non-transferred toner image can be removed by the pre-cleaning brush roller.
The belt cleaner 100 further includes a feeding screw 110 to feed the collected toner to a waste toner tank (not shown) provided in the main body of the image forming apparatus.
The reversely-charged toner cleaning portion 100b includes a reversely-charged toner cleaning brush roller 104 serving as a reversely-charged toner cleaning member to electrostatically remove reversely charged toner particles, a reversely-charged toner collecting roller 105, which serves as a reversely-charged toner collecting member to collect the toner adhered to the reversely-charged toner cleaning brush roller 104, and a second scraping blade 106, which serves as a scraper and which is contacted with the reversely-charged toner collecting roller 105 to scrape off the reversely-charged toner adhered to the surface of the reversely-charged toner collecting roller 105.
A negative voltage is applied to the reversely-charged toner cleaning brush roller 104, and another negative voltage, whose absolute value is greater than that of the voltage applied to the brush roller 104, is applied to the reversely-charged toner collecting roller 105. In addition, this reversely-charged toner cleaner 100b has a function of a polarity controller, which imparts a negative charge to the residual toner particles on the intermediate transfer belt 8 to control the residual toner particles so as to have the normal polarity (i.e., the negative polarity, in this case).
The normally-charged toner cleaning portion 100c includes a normally-charged toner cleaning brush roller 107 serving as a normally-charged toner cleaning member to electrostatically remove normally charged toner particles, a normally-charged toner collecting roller 108, which serves as a normally-charged toner collecting member to collect the toner adhered to the normally-charged toner cleaning brush roller 107, and a third scraping blade 109, which serves as a scraper and which is contacted with the normally-charged toner collecting roller 108 to scrape off the normally-charged toner adhered to the surface of the normally-charged toner collecting roller 108.
A positive voltage is applied to the normally-charged toner cleaning brush roller 107, and another positive voltage, which is greater than the positive voltage applied to the brush roller 107, is applied to the normally-charged toner collecting roller 108.
As illustrated in
The pre-cleaning portion 100a and the reversely-charged toner cleaning portion 100b are separated from each other by a first insulating seal member 112, which is contacted with the pre-cleaning brush roller 101. Therefore, occurrence of problems such that discharging occurs between the pre-cleaning brush roller 101 and the reversely-charged toner cleaning brush roller 104; and the toner collected by the reversely-charged toner cleaning portion 100b is adhered again to the pre-cleaning brush roller 101 can be prevented.
The reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c are separated from each other by a second insulating seal member 113, which is contacted with the reversely-charged toner cleaning brush roller 104. Therefore, occurrence of problems such that discharging occurs between the reversely-charged toner cleaning brush roller 104 and the normally-charged toner cleaning brush roller 107; and the toner collected by the normally-charged toner cleaning portion 100c is adhered again to the reversely-charged toner cleaning brush roller 104 can be prevented.
In addition, at the exit of the belt cleaner 100, a third insulating seal member 114 is provided, which is contacted with the normally-charged toner cleaning brush roller 107. Therefore, occurrence of a problem such that discharging occurs between the normally-charged toner cleaning brush roller 107 and the tension roller 16 can be prevented.
Further, the belt cleaner 100 includes an entrance seal 111, and a waste toner case. The waste toner case retains the toner collected by the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c. In addition, the waste toner case is detachably attached to the belt cleaner 100. Therefore, when a maintenance operation is performed, the waste toner case is detached from the belt cleaner 100 to dispose of the waste toner contained in the waste toner case.
In this belt cleaner 100, the toner collected by the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c is contained in the waste toner case. However, the waste toner disposal method is not limited thereto.
For example, the following method can also be used. Specifically, a feeding member to feed the collected toner to the feeding screw 110 is provided, or the bottom surface of the belt cleaner 100 is slanted to feed the collected toner to the feeding screw 110, so that the toner collected by the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c is fed by the feeding screw 110 to the waste toner tank (not shown) provided in the main body of the image forming apparatus. Alternatively, a second feeding screw (not shown) may be provided which feeds the toner collected by the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c to the waste toner tank provided in the main body of the image forming apparatus.
Each of the cleaning brush rollers 101, 104 and 107 has a metal rotation shaft, which is rotatably supported, and a brush portion constituted of plural raised fibers provided on the outer periphery of the metal rotation shaft. The outer diameter of the brush rollers 101, 104 and 107 is from 15 mm to 16 mm. The fibers have a double-layer structure such that electroconductive carbon is used for the inner portion of the fibers, and an insulating material such as polyester resins is used for the surface portion thereof. Therefore, the potential of the core portion of the fibers is substantially the same as the potential of the voltage applied to the cleaning brush rollers. Accordingly, the toner can be electrostatically attracted by the surface of the fibers of the brush rollers. Thus, the residual toner on the intermediate transfer belt 8 is electrostatically adhered to the fibers of the cleaning brush rollers 101, 104 and 107 due to the voltage applied to the brush rollers.
The fibers are not limited thereto, and may be constituted by an electroconductive material. In addition, the fibers may be provided on the rotation shaft so as to be slanted relative to the normal line of the rotation shaft.
Further, it is possible that the double-layer fibers are used for the pre-cleaning brush roller 101 and the normally-charged toner cleaning brush roller 107, and the fibers made of an electroconductive material are used for the reversely-charged toner cleaning brush roller 104.
When fibers made of an electroconductive material are sued for the reversely-charged toner cleaning brush roller 104, charges can be easily injected from the cleaning brush roller 104 into the toner, thereby making it possible to control the polarity of the toner on the intermediate transfer belt 8 to have the normal polarity (i.e., negative polarity in this case). When the double-layer fibers are used for the pre-cleaning brush roller 101 and the normally-charged toner cleaning brush roller 107, injection of charges into the toner can be prevented, thereby preventing occurrence of a problem in that the toner is reversely charged (i.e., the toner is positively charged). Using this method prevents occurrence of a problem in that toner particles, which cannot be electrostatically removed by the pre-cleaning brush roller 101 and the normally-charged toner cleaning brush roller 107, are formed on the intermediate transfer belt 8.
The cleaning brush rollers 101, 104 and 107 are contacted with the intermediate transfer belt 8 in such a manner that the length of the fibers of the brush rollers are 1 mm longer than the gap between the brush rollers and the intermediate transfer belt. Since the cleaning brush rollers 101, 104 and 107 is rotated by a driving device (not shown) in a direction opposite to the moving direction of the intermediate transfer belt 8 (i.e., the brush rollers counter the intermediate transfer belt), the velocity difference between the brush rollers and the intermediate transfer belt can be increased. Therefore, chance of contact of a portion of the intermediate transfer belt 8 with the brush rollers 101, 104 and 107 can be increased, thereby making it possible to satisfactorily remove the residual toner from the intermediate transfer belt.
A SUS (stainless steel) roller is used for the toner collecting rollers 102, 105 and 108 of the belt cleaner 100. However, the material of the rollers is not limited thereto, and any materials can be used therefor as long as the toner collecting rollers can have a function of transferring the toner adhered to the cleaning brush rollers to the collecting rollers due to the potential difference between the fibers of the brush rollers and the collecting rollers.
For example, each of the toner collecting rollers 102, 105 and 108 can have a structure such that an electroconductive shaft is covered with a high resistance elastic tube having a thickness of from a few micrometers to 100 μm or coated with an insulating material, so that the resultant roller has a volume resistivity of from 1012 to 1014 Ω·cm.
Using a SUS roller for the toner collecting rollers 102, 105 and 108 has merits such that costs of the rollers can be reduced, and in addition the voltage applied to the rollers can be reduced, resulting in electric power saving.
Using a roller having a volume resistivity of from 1012 to 1014 Ω·cm has a merit such that when collecting the toner with the collecting rollers, injection of charges into the toner can be prevented, thereby preventing the toner from having the same polarity as that of the voltage applied to the colleting rollers, resulting in prevention of reduction of the toner collection rate.
The details of the cleaning brush rollers 101, 104 and 107 used of this belt cleaner 100 are as follows.
Material of brush: Electroconductive polyester (i.e., the inner portion of the fiber includes electroconductive carbon, and the surface thereof is polyester resin, namely double-layer fiber)
Resistance of brush: 106 to 108Ω
Density of fibers in brush: 60,000 to 150,000 pieces/inch2 (i.e., 93 to 232.5 pieces/mm2)
Diameter of fibers: about 25 μm to 35 μm
Lateral-buckling preventing treatment for brush: None
Diameter of brush roller: 14 mm to 20 mm
Setting of brush rollers: The brush rollers are contacted with the intermediate transfer belt in such a manner that the length of fibers is 1 to 1.5 mm longer than the gap between the brush rollers and the intermediate transfer belt.
The voltage applied to the pre-cleaning brush roller 101 is set to a voltage at which a large amount of non-transferred toner image is adhered to the intermediate transfer belt 8 can be satisfactorily removed. The voltage applied to the reversely-charged toner cleaning brush roller 104 is set to a relatively high voltage at which charges can be injected into the residual toner on the intermediate transfer belt 8. The conditions such as density of fibers in the brush, resistance of the brush, diameter of the fibers, applied voltage, material of the fibers, setting of the brush rollers can be optimized depending on the system for which the brush rollers are used, and therefore the conditions are not limited to the above-mentioned conditions. Suitable materials for use as the fibers include nylon, acrylic, and polyester resins.
The conditions of the collecting rollers 102, 105 and 108 are as follows.
Material of core of rollers: SUS303
Setting of collecting rollers: The collecting rollers are contacted with the brush rollers in such a manner that the length of fibers is 1 to 1.5 mm longer than the gap between the collecting rollers and the corresponding brush rollers.
Since the conditions such as material of the collecting rollers, setting of the collecting rollers and the applied voltage can be optimized depending on the system for which the brush rollers are used, the conditions are not limited to the above-mentioned conditions.
The conditions of the scraping blades 103, 106 and 109 are as follows.
Material of blades: SUS304
Contact angle of blades: 20°
Thickness of blades: 0.1 mm
Setting of blades: The blades are contacted with the corresponding collecting rollers in such a manner that the length of the blade is 0.5 to 1.5 mm longer than the gap between the blades and the corresponding collecting rollers.
Since the conditions such as contact angle, thickness of blades and setting of blades can be optimized depending on the system for which the blades are used, the conditions are not limited to the above-mentioned conditions.
Next, the cleaning operation of the belt cleaner 100 will be described.
Referring to
The negatively-charged toner particles adhered to the pre-cleaning brush roller 101 are fed by the rotated pre-cleaning brush roller to the contact portion of the brush roller and the pre-cleaning collection roller 102, to which a positive voltage higher than the voltage applied to the pre-cleaning brush roller 101 is applied. Therefore, the toner particles on the brush roller 101 are electrostatically transferred onto the pre-cleaning collecting roller 102 due to the electric filed formed by the difference in potential between the brush roller and the collecting roller. The negatively-charged toner particles thus transferred onto the pre-cleaning collecting roller 102 are scraped off by the first scraping blade 103, and the toner particles thus scraped off are discharged from the belt cleaner 100 by the feeding screw 110.
Toner particles (such as negatively- or positively-charged toner particles in the non-transferred toner image, and positively-charged residual toners), which remain on the intermediate transfer belt 8 without being removed by the pre-cleaning brush roller 101, are fed to the reversely-charged toner cleaning brush roller 104.
Since a voltage having the same polarity (negative polarity in this case) as that of the normal toner particles is applied to the reversely-charged toner cleaning brush roller 104, charge injection or discharging is caused between the brush roller 104 and the toner particles, and thereby the toner particles are allowed to have a negative polarity. In addition, toner particles, which maintain a positive charge even after charge injection or discharging, are electrostatically adhered to the reversely-charged toner cleaning brush roller 104 due to the electric field formed by the difference in potential between the brush roller 104 and the intermediate transfer belt 8.
The positively-charged toner particles adhered to the reversely-charged toner cleaning brush roller 104 are fed by the rotated brush roller to the contact portion of the brush roller and the reversely-charged toner collecting roller 105, to which a negative voltage greater (in absolute value) than the voltage applied to the brush roller 104 is applied. Therefore, the toner particles on the brush roller 104 are electrostatically transferred onto the collecting roller 105 due to the electric filed formed by the difference in potential between the brush roller and the collecting roller. The positively-charged toner particles thus transferred onto the collecting roller 105 are scraped off by the second scraping blade 106, and the toner particles thus scraped off are discharged from the belt cleaner 100 by the feeding screw 110.
Toner particles (such as negatively-charged toner particles), which remain on the intermediate transfer belt 8 without being removed by the pre-cleaning brush roller 101 and the reversely-charged toner cleaning brush roller 104, are fed to the normally-charged toner cleaning brush roller 107. In this regard, the toner particles fed to the brush roller 107 are allowed to have a negative charge by the reversely-charged toner cleaning brush roller 104.
Since substantially all the toner particles on the intermediate transfer belt 8 have been removed therefrom by the brush rollers 101 and 104, the amount of the toner particles fed to the normally-charged toner cleaning brush roller 107 is small. The small amount of toner particles remaining on the intermediate transfer belt 8 are electrostatically adhered to the normally-charged toner cleaning brush roller 107, and then transferred onto the normally-charged toner collecting roller 108. The transferred toner particles are scraped off with the third scraping blade 109.
Thus, in the belt cleaner 100, a greater part of the negatively-charged toner particles constituting the non-transferred toner image are removed by the pre-cleaning brush roller 101, and therefore the amount of the toner particles fed to the reversely-charged toner cleaning brush roller 104 and the normally-charged toner cleaning brush roller 107 can be reduced.
The toner particles fed to the normally-charged toner cleaning brush roller 107 are toner particles, which have not been removed by the pre-cleaning brush roller 101 and the reversely-charged toner cleaning brush roller 104. Therefore, the amount of the toner particles fed to the normally-charged toner cleaning brush roller 107 is small. In addition, the toner particles are negatively charged by the reversely-charged toner cleaning brush roller 104. Therefore, the toner particles can be satisfactorily removed by the normally-charged toner cleaning brush roller 107. Therefore, even when a non-transferred toner image including a large amount of toner particles is formed on the intermediate transfer belt 8, the toner image can be satisfactorily removed from the intermediate transfer belt.
In addition, the residual toner particles, whose amount is less than the amount of toner particles constituting the non-transferred toner image, can be satisfactorily removed by the three brush rollers 101, 104 and 107.
In the belt cleaner 100, the reversely-charged toner cleaning brush roller 104 removes reversely (positively) charged toner particles on the intermediate transfer belt 8. However, the reversely-charged toner cleaning portion 100b can be replaced with a polarity controller, which controls the polarity of toner particles on the intermediate transfer belt without removing the positively-charged toner particles. In this case, the toner particles on the intermediate transfer belt 8 are allowed to have a negative polarity by the polarity controller, and the negatively-charged toner particles are fed to the normally-charged toner cleaning brush roller 107 by the rotated intermediate transfer belt. The thus fed negatively-charged toner particles are removed by the normally-charged toner cleaning brush roller 107.
Suitable devices for use as the polarity controller include electroconductive brushes, electroconductive blades and corona chargers. The polarity of the toner particles controlled by the polarity controller is not limited to the negative polarity, and can be positive polarity. In this case, a cleaning brush roller, to which a negative voltage is applied, is arranged on the downstream side from the polarity controller relative to the moving direction (MD) of the intermediate transfer belt 8 to remove the positively charged toner particles from the intermediate transfer belt 8. Even in such a belt cleaner, toner particles of the non-transferred toner image can be roughly removed by the pre-cleaning brush roller 101, the amount of the toner particles fed to the polarity controller is small.
Thus, the polarity controller can control the toner particles remaining on the intermediate transfer belt 8 to have a predetermined polarity. Therefore, the toner particles having the predetermined polarity can be electrostatically removed by the cleaning brush roller provided on the downstream side from the polarity controller. Accordingly, even when a non-transferred toner image, which includes a large amount of toner particles, is fed to the belt cleaner 100, the toner particles can be satisfactorily removed from the intermediate transfer belt 8.
In addition, a voltage is applied to each of the collecting rollers 102, 105 and 108 and each of the cleaning brushes 101, 104 and 107. However, it is possible that a voltage is applied to each of the collecting rollers. In this case, since the collecting rollers are contacted with the corresponding brush rollers and a voltage is applied to the collecting rollers, a voltage, which is slightly lower than the voltage applied to the collecting rollers due to potential drop caused by the resistance of the fibers of the brush rollers, is applied to the cleaning brush rollers. Therefore, a potential difference is formed between the collecting rollers and the cleaning brush rollers, and thereby the toner particles can be electrostatically transferred from the brush rollers 101, 104 and 107 to the corresponding collecting rollers 102. 105 and 108.
Having generally described this invention, further understanding can be obtained by reference to certain specific examples which are provided herein for the purpose of illustration only and are not intended to be limiting. In the descriptions in the following examples, the numbers represent weight ratios in parts, unless otherwise specified.
The belt cleaner 100 has to remove toner particles in an amount of from about 0.05 mg/cm2 (such as residual toner particles) to about 1.0 mg/cm2 (such as toner particles constituting a non-transferred toner image) from the intermediate transfer belt. The targeted cleaning current, at which cleaning can be performed most optically, changes depending on the amount of the toner particles on the intermediate transfer belt. Namely, as the amount of the toner particles increases, the targeted cleaning current increases. In this regard, the cleaning current means a current flowing a contact portion of each of the cleaning brush rollers 101, 104 and 107 with the intermediate transfer belt 8. An example of the targeted cleaning current is shown in Table 1 below.
The process linear speed of this printer is changed from 100 to 760 mm/s, and is set to 350 mm/s in this example.
In order that cleaning currents optimal for removing the residual toner particles and the non-transferred toner image flow, the voltages applied to the pre-cleaning brush roller 101 and the pre-cleaning collecting roller 102 are changed as illustrated in
In contrast, when the brush roller 101 faces a portion of the intermediate transfer belt corresponding to a non-image portion (NIP) (which is a portion between two adjacent image portions and in which a test pattern of a toner, which is not to be transferred to the recording medium P, is formed), the voltage applied to each of the pre-cleaning brush roller 101 and the pre-cleaning toner collecting roller 102 is switched to a relatively high voltage. This voltage switching is performed just before the test pattern on the non-image portion reaches the pre-cleaning portion 100a
In this example, the voltages applied to the pre-cleaning brush roller 101 and the pre-cleaning toner collecting roller 102 are changed. When no test patter is formed in the non-image portion (NIP), the voltage switching is not performed.
The operation of changing the setup voltage value for brush rollers and collecting rollers of the belt cleaner 100 is changed at a time in which the intermediate transfer belt 8 and the belt cleaner 100 are driven and toner particles are not present in the portion of the intermediate transfer belt facing the belt cleaner. In this case, the power sources 130, 131, 132, 133, 134 and 135 respectively apply predetermined voltages to the cleaning brush rollers 101, 104 and 107 and the collecting rollers 102, 105 and 108.
For example, when the setup voltages to be applied to the pre-cleaning brush roller 101 and the pre-cleaning toner collecting roller 102 are changed, the current flowing a contact portion of the pre-cleaning brush roller 101 with the intermediate transfer belt 8 is detected. i.e., the currents IB1 and IC1 flowing the power sources 130 and 131 are detected. Next, the applied voltages are determined so that the total of the currents IB1 and IC1 becomes the targeted current, and the setup voltages to be applied to the brush roller 101 and the collecting roller 102 are changed based on the thus determined voltages.
Thereafter, the voltages are applied to the pre-cleaning brush roller 101 and the pre-cleaning toner collecting roller 102 based on these setup voltage values.
The timing of the above-mentioned setup voltage changing operation is not limited to the time in which the process control is performed, and can be performed after a predetermined time elapses, or at a time in which a predetermined number of prints are produced, or ambient temperature or humidity exceeds the predetermined threshold temperature or humidity.
In this example, the order of the setup voltage changing operations is as follows. Specifically, initially, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a is performed, and then the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed. Next, the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b is performed, and finally the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c is performed. In this regard, one setup voltage changing operation is performed 100 ms after the previous setup changing operation including the processing time. Further, when the setup voltage changing operation is performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the voltage for removing a non-transferred toner image is applied to the pre-cleaning portion 100a.
As a result of the investigation of the present inventor, it is found that when the setup voltage changing operation is initially performed on the pre-cleaning portion 100a (for residual toner particles), the voltage tends to be set to a relatively high voltage.
The toner particles caught by the pre-cleaning brush roller 101 are collected by the pre-cleaning toner collecting roller 102, but a small amount of toner particles remain in the brush. Therefore, toner particles accumulate in the brush when the brush roller 101 is used for a long period of time. In this case, the apparent resistance of the brush of the pre-cleaning brush roller 101 increases.
In this case, when a high voltage (i.e., a voltage for removing a non-transferred toner image) is applied to the pre-cleaning brush roller 101, the polarity of the toner particles in the brush is reversed, and therefore the toner particles are discharged from the brush, resulting in re-adhesion to the intermediate transfer belt 8. Since the toner particles in the brush release therefrom, the apparent resistance of the brush of the pre-cleaning brush roller 101 becomes lower than in the case where the toner particles are present in the brush.
In contrast, when a relatively low voltage (i.e., a voltage for removing residual toner particles) is applied, the polarity of the toner particles in the brush is not easily reversed. Therefore, the phenomenon in that the toner particles in the brush release from the brush and is adhered again to the intermediate transfer belt hardly occurs.
In consideration of these results, a case where the setup voltage changing operation for the voltage for removing residual toner particles is initially performed, and then the setup voltage changing operation for the voltage for removing a non-transferred toner image is performed is considered. In the initial setup voltage changing operation, the setup voltage changing operation is performed so that the targeted current can be obtained under a condition such that the pre-cleaning brush roller 101 has a relatively high apparent resistance due to accumulation of toner particles therein.
In the second setup voltage changing operation for the voltage for removing a non-transferred toner image, the toner particles in the brush are adhered again to the intermediate transfer belt 8. Therefore, the setup voltage changing operation is performed under a condition such that the pre-cleaning brush roller 101 has a relatively low apparent resistance compared to the first case mentioned above.
Thereafter, the setup voltage changing operations for the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c are performed under the condition such that the pre-cleaning brush roller 101 has a relatively low apparent resistance.
When an image forming operation is performed after performing the series of setup voltage changing operations, the apparent resistance of the brush of the pre-cleaning brush roller 101 is relatively low compared to that in the case where the setup voltage changing operation for the voltage for removing residual toner particles. Therefore, when the setup voltage is applied, a current greater than the targeted current flows through the pre-cleaning portion 100a. Namely, the setup voltage is higher than a proper voltage.
When a current greater than the targeted current flows in the pre-cleaning portion 100a, toner particles on the intermediate transfer belt 8 cannot be easily removed by the pre-cleaning brush roller 101, and the amount of the toner particles remaining on the intermediate transfer belt 8, which are fed to the reversely-charged toner cleaning portion 100b and the normally-charge toner cleaning portion 100c, increases. In this case, the burden on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c increases, thereby causing a problem in that the lives of the reversely-charged toner cleaning brush roller 104 and the normally-charged toner cleaning brush roller 107 shorten, and the life of the belt cleaner shortens.
In addition, when the amount of toner particles fed to the reversely-charged toner cleaning portion 100b and the normally-charge toner cleaning portion 100c increases to an extent such that the amount is greater than the amount of toner particles which the brush rollers 104 and 107 can remove, a defective cleaning problem in that the toner particles on the intermediate transfer belt 8 cannot be satisfactorily removed is caused.
In contrast, when the setup voltage changing operation for the voltage for removing a non-transferred toner image is initially performed, and then the setup voltage changing operation for the voltage for removing residual toner particles is performed, the problem in that the voltage is set to a high voltage is not caused.
For the reason mentioned above, the setup voltage changing operation for the voltage for removing a non-transferred toner image is performed under a condition that the apparent resistance of the brush of the pre-cleaning brush roller 101 is relatively low. In addition, the next setup voltage changing operation for the voltage for removing residual toner particles is performed under the same condition. Further, the following setup voltage changing operations for the reversely-charged toner cleaning portion 100b and the normally-charge toner cleaning portion 100e are also performed under the same condition.
When a normal image forming operation is performed after performing the series of setup voltage changing operations, the apparent resistance of the brush of the pre-cleaning brush roller 101 is still relatively low. Thus, the apparent resistance of the brush of the pre-cleaning brush roller 101 is the same in the voltage setting operation and the normal image forming operation. Therefore, by applying the setup voltage for removing residual toner particles, the targeted current can be flowed, and thereby satisfactory cleaning can be performed by the pre-cleaning portion 100a.
As mentioned above, in the setup voltage changing operation for the pre-cleaning portion 100a, by performing the setup voltage changing operation for the voltage for removing a non-transferred toner image prior to the setup voltage changing operation for the voltage for removing residual toner particles, both the voltages can be set to respective optimum voltages.
As illustrated in
In this example, the order of the setup voltage changing operations is as follows. Specifically, initially, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a is performed, and then the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b is performed. Next, the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c is performed, and finally the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed. In this regard, one setup voltage changing operation is performed 100 ms after the previous setup changing operation including the processing time. Further, when the setup voltage changing operation is performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the voltage for removing a non-transferred toner image is applied to the pre-cleaning portion 100a.
In the pre-cleaning portion 100a, the time period in which the voltage for removing residual toner particles is applied is longer than the time period in which the voltage for removing a non-transferred toner image is applied. Therefore, in this example, importance is attached to the setup voltage changing operation for the voltage for removing residual toner particles.
As mentioned above, in this example, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a, the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b, and the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c are performed prior to the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a. Therefore, after the conditions of the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c are stabilized, setting of the voltage for removing residual toner particles with the pre-cleaning portion 100a, which is most significant for the operation of the belt cleaner 100, can be optimally performed.
In this example, the order of the setup voltage changing operations is as follows. Specifically, initially, the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b is performed, and then the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c is performed. Next, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a is performed, and finally the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed. In this regard, one setup voltage changing operation is performed 100 ms after the previous setup changing operation including the processing time. Further, when the setup voltage changing operation is performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the voltage for removing a non-transferred toner image is applied to the pre-cleaning portion 100a.
As mentioned above, in this example, the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b, and the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c are performed prior to the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a, and the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a. Therefore, after the conditions of the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c are stabilized, setting of the voltages for removing residual toner particles and a non-transferred toner image with the pre-cleaning portion 100a, which is most significant for the operation of the belt cleaner 100, can be optimally performed.
In this example, the order of the setup voltage changing operations is as follows. Specifically, initially, the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c is performed, and then the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b is performed. Next, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a is performed, and finally the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed. In this regard, one setup voltage changing operation is performed 100 ms after the previous setup changing operation including the processing time. Further, when the setup voltage changing operation is performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the voltage for removing a non-transferred toner image is applied to the pre-cleaning portion 100a.
There is a possibility that the voltages applied to the cleaning portions 100a, 100b and 100c are largely deviated from the optimum voltages before the setup voltage changing operations. Therefore, it is possible that the toner particles in the brushes of the brush rollers 101, 104 and 107 are reversely charged, and the toner particles are adhered again to the intermediate transfer belt 8 (this problem is hereinafter referred to as a toner re-adhesion problem). The toner particles adhered again to the intermediate transfer belt 8 are 11d to the pre-cleaning brush roller 101 as the intermediate transfer belt rotates. When the setup voltage changing operation is performed on the pre-cleaning portion 100a under such a condition that the toner particles adhered again to the intermediate transfer belt 8 are fed to the pre-cleaning brush roller 101, the precision of the setup voltage changing operation deteriorates.
Since the greater part of the toner particles fed again to the pre-cleaning portion 100a is removed by the pre-cleaning portion, toner is hardly fed to the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c. Therefore, in this example, initially the voltages for the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, to which toner is hardly fed, are optimally set, so that the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c do not cause the toner re-adhesion problem. In this case, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a can be performed more optimally because no toner is fed to the pre-cleaning portion 100a.
In this example, the order of the setup voltage changing operations is as follows. Specifically, initially the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed, and then the setup voltage changing operation for the voltage for removing toner particles with the reversely-charged toner cleaning portion 100b is performed. Next, the setup voltage changing operation for the voltage for removing toner particles with the normally-charged toner cleaning portion 100c is performed, and then the setup voltage changing operation lor the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a is performed. Finally, the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed again. In this regard, one setup voltage changing operation is performed 100 ms after the previous setup changing operation including the processing time.
When the setup voltage changing operation is performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the voltage for removing residual toner particles is applied to the pre-cleaning portion 100a.
There is a possibility that the voltage applied to the cleaning portion 100a to remove residual toner particles is largely deviated from the optimum voltage before the setup voltage changing operation. Therefore, it is possible that the current flowing a contact portion of the pre-cleaning brush roller 101 with the intermediate transfer belt 8 is largely deviated from the targeted current. In this case, the current flowing from the pre-cleaning portion 100a to the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c is largely different from that in a case where the current flowing a contact portion of the pre-cleaning brush roller 101 with the intermediate transfer belt 8 is the targeted current, thereby making it impossible to optimally perform the setup voltage changing operations on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, resulting in occurrence of defective cleaning.
In this example, before the setup voltage changing operations are performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the setup voltage changing operation for the voltage for removing residual toner particles with the pre-cleaning portion 100a is performed. By using this method, the voltage applied for removing residual toner particles is hardly deviated from the optimal voltage, and therefore the setup voltage changing operations can be optimally performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c.
In addition, after the setup voltage changing operations are performed on the reversely-charged toner cleaning portion 100b and the normally-charged toner cleaning portion 100c, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a is performed. By using this method, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the pre-cleaning portion 100a can be performed more optimally because no toner is fed to the pre-cleaning portion 100a.
In this example, the order of the setup voltage changing operations is the same as that in Example 1, but the setup voltage changing operations are performed on the cleaning portions 100a, 100b and 100c while applying the secondary transfer voltage to the secondary transfer portion. By using this method, the setup voltage changing operations for the cleaning portions 100a, 100b and 100c can be optimally performed because the influence of the secondary transfer voltage applied to the intermediate transfer belt 8 at the secondary transfer portion is taken into consideration.
In this example, the order of the setup voltage changing operations is the same as that in Example 1, but the setup voltage changing operations are performed on the cleaning portions 100a, 100b and 100c while separating the primary transfer rollers 9 from the intermediate transfer belt 8. By using this method, there are no residual toner particles on the intermediate transfer belt 8, which are formed thereon due to background development of the developing devices 5, and thereby the setup voltage changing operations can be optimally performed without the influence of toner.
The belt cleaner 120 includes a first cleaning portion 120a to remove toner particles having a normal polarity (i.e., negative polarity in this case) on the intermediate transfer belt 8, and a second cleaning portion 120b to remove toner particles having a reverse polarity (i.e., positive polarity in this case) on the intermediate transfer belt 8.
The first cleaning portion 120a includes a first cleaning brush roller 121, a first toner collecting roller 122, and a first scraping blade 123. The first cleaning brush roller 121 includes a rotatably supported metal shaft, and a brush roller portion, which is provided on the surface of the metal shaft so as to be erected and which is constituted of plural fibers (electroconductive fibers).
The second cleaning portion 120b is arranged on a downstream side form the first cleaning portion 120a relative to the moving direction of the intermediate transfer belt 8, and includes a second cleaning brush roller 124, a second toner collecting roller 125, and a second scraping blade 126. The second cleaning brush roller 124 includes a rotatably supported metal shaft, and a brush roller portion, which is provided on the surface of the metal shall so as to be erected and which is constituted of plural fibers (electroconductive fibers).
In addition, the belt cleaner 120 includes a feeding screw 127 to feed the toner collected by the first cleaning portion 120a and the second cleaning portion 120b to an end of the casing of the belt cleaner 120 to discharge the toner from the casing. The toner discharged from the belt cleaner 120 by the feeding screw 127 falls into a waste toner tank or is returned to the developing device 5.
One example of the operation condition of the belt cleaner 120 is illustrated in Table 2 below.
The amount of toner fed to the first cleaning portion 120a changes in a wide range of from 0.05 to 1.0 mg/cm2. Therefore, two kinds of targeted currents, i.e., a target current for removing a non-transferred toner image including a relatively large amount of toner, and another target current for removing residual toner particles, the amount of which is relatively small, are set.
Since the second cleaning portion 120b cleans the surface of the intermediate transfer belt 8 after the surface is cleaned by the first cleaning portion 12a, the amount of toner on the intermediate transfer belt 8 to be removed by the second cleaning portion is small, and therefore one targeted current is set therefor.
In this example, two levels of target currents are set for the first cleaning portions (i.e. the target current for removing a non-transferred toner image, and the target current for removing residual toner particles), but the level is not limited thereto. For example, the target current can be classified into three or more levels depending on the amount of the toner on the intermediate transfer belt 8.
The current flowing cleaning portions, in which toner is transferred from the intermediate transfer belt 8 to the cleaning brush rollers 121 and 124, contributes to cleaning.
For example, in the first cleaning portion 120a, the current flowing through a point A illustrated in
In
In this example, the order of the setup voltage changing operations is as follows.
Initially, the setup voltage changing operation for the voltage for removing a non-transferred toner image with the first cleaning portion 120a is performed, and then the setup voltage changing operation for the voltage for removing residual toner particles with the first cleaning portion 120a is performed. Finally, the setup voltage changing operation for the voltage for removing toner particles with the second cleaning portion 120b is performed.
When the setup voltage changing operation for the voltage for removing residual toner particles with the first cleaning portion 120a is initially performed, the voltage tends to be set to a relatively high voltage similarly to the above-mentioned belt cleaner 100. As a result, the burden on the second cleaning portion 120b increases. In this regard, when the setup voltage changing operation is performed on the second cleaning portion 120b, the voltage for removing residual toner particles is applied to the first cleaning portion 120a.
Next, the toner for use in the printer will be described.
In order to form fine dot images with a resolution of not less than 600 dpi, the toner preferably has a volume average particle diameter of from 3 μm to 6 μm, and a Dv/Dn ratio of the volume average particle diameter (Dv) to the number average particle diameter (Dn) of from 1.00 to 1.40. In this regard, as the Dv/Dn ratio approaches 1.00, the toner has a shaper particle diameter distribution. Such a toner as having a small particle diameter and a sharp particle diameter distribution has a sharp charge quantity distribution, and therefore high quality toner images without background development can be produced. In addition, when an electrostatic transferring method is used, the transferring rate can be enhanced.
The toner preferably has a first shape factor SF-1 of from 100 to 180, and a second shape factor SF-2 of from 100 to 180.
SF-1={(MXLNG)2/(AREA)}×(100π/4) (1)
wherein MXLNG represents the maximum diameter of the projected image of a toner particle formed on a two-dimensional plane, and AREA represents the area of the projected image.
When the first shape factor SF-1 is 100, the toner particle is spherical. As the shape factor SF-1 increases, the shape of the toner particle becomes more irregular.
SF-2={(PERI)2/(AREA)}×(100/4π) (2)
wherein PERI represents the peripheral length of the projected image of a toner particle formed on a two-dimensional plane, and AREA represents the area of the projected image.
When the SF-2 is 100, the toner particles have a smooth surface (i.e., the toner has no concavity and convexity). As the SF-2 increases, the toner particle has a rougher surface.
The first and second shape factors SF-1 and SF-2 are determined by the following method:
(1) particles of a toner are photographed using a scanning electron microscope (S-800, manufactured by Hitachi Ltd.); and
(2) photograph images of one hundred toner particles are analyzed using an image analyzer (LUZEX 3 manufactured by Nireco Corp.) to determine the first and second shape factors SF-1 and SF-2.
When the shape of the toner approaches spherical form, toner particles make a point contact with each other. Therefore, the adsorption force between toner particles weakens, and thereby the fluidity of the toner is increased. In addition, adsorption force between toner particles and a photoreceptor weakens, and thereby the transfer rate of the toner is increased. When one of the shape factors SF-1 and SF-2 exceeds 180, the transfer rate of the toner deteriorates, and therefore it is not preferable.
Toners used for color printers are preferably prepared by a method including preparing a toner component liquid in which at least a polyester prepolymer having a nitrogen-containing functional group, a polyester, a colorant and a release agent is dissolved or dispersed in an organic solvent; and subjecting the toner component liquid to crosslinking and/or polymer chain growth reaction in an aqueous medium to form toner particles. Hereinafter the toner constituents of the toner, and the preparation method will be described.
Polyester can be prepared by subjecting a polyalcohol and a polycarboxylic acid to a polycondensation reaction.
Dihydric alcohols (DIO), and tri- or more-hydric alcohols (TO) can be used as the polyalcohol. Among these polyalcohols, dihydric alcohols, or combinations of a dihydric alcohol and a small amount of a tri- or more-hydric alcohol can be preferably used.
Specific examples of such dihydric alcohols (DIO) include alkylene glycols such as ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,4-butane diol, and 1,6-hexane diol; alkylene ether glycols such as diethylene glycol, triethylene glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, and polytetramethylene ether glycol; alicyclic diols such as 1,4-cyclohexane dimethanol, and hydrogenated bisphenol A; bisphenol compounds such as bisphenol A, bisphenol F, and bisphenol S; alkylene oxide (such as ethylene oxide, propylene oxide, and butylene oxide) adducts of the alicyclic diols; and alkylene oxide (such as ethylene oxide, propylene oxide, and butylene oxide) adducts of the bisphenol compounds.
Among these dihydric alcohols, alkylene glycols having 2 to 12 carbon atoms, and alkylene oxide adducts of bisphenol compounds are preferable, and alkylene oxide adducts of bisphenol compounds, and combinations of an alkylene oxide adduct of a bisphenol compound and an alkylene glycol having 2 to 12 carbon atoms are more preferable.
Specific examples of the tri- or more-hydric alcohols (TO) include aliphatic alcohols having three or more hydroxyl groups such as glycerin, trimethylol ethane, trimethylol propane, pentaerythritol, and sorbitol; polyphenols having three or more hydroxyl groups such as trisphenol PA, phenol novolac, and cresol novolac; and alkylene oxide (such as ethylene oxide, propylene oxide, and butylene oxide) adducts of the polyphenols.
Dicarboxylic acids and polycarboxylic acids having three or more carboxyl groups are used as the polycarboxylic acid. Among these polycarboxylic acids, dicarboxylic acids, or combinations of a dicarboxylic acid and a small amount of a polycarboxylic having three or more carboxyl groups acid are preferable.
Specific examples of the dicarboxylic acids include alkylene dicarboxylic acids such as succinic acid, adipic acid, and sebacic acid; alkenylene dicarboxylic acids such as maleic acid, and fumaric acid; and aromatic dicarboxylic acids such as phthalic acid, isophthalic acid, terephthalic acid, and naphthalene dicarboxylic acids. Among these dicarboxylic acids, alkenylene dicarboxylic acids having from 4 to 20 carbon atoms, and aromatic dicarboxylic acids having from 8 to 20 carbon atoms are preferably used.
Specific examples of the polycarboxylic acids having three or more carboxyl groups include aromatic polycarboxylic acids having from 9 to 20 carbon atoms such as trimellitic acid, and pyromellitic acid.
Anhydrides and lower alkyl esters (such as methyl esters, ethyl esters and isopropyl esters) of the above-mentioned acids can also be used.
Suitable mixing ratio of a polyol to a polycarboxylic acid (i.e., an equivalence ratio [OH]/[COOH]) of the hydroxyl group of a polyol to the carboxyl group of a polycarboxylic acid) is from 2/1 to 1/1, preferably from 1.5/1 to 1/1, and more preferably from 1.3/1 to 1.02/1.
The polycondensation reaction of a polyol (PO) with a polycarboxylic acid (PC) is performed, for example, by heating the components to a temperature of from 150 to 280° C. in the presence of a known esterification catalyst such as tetrabutoxy titanate and dibutyltin oxide while optionally removing generated water under a reduced pressure to prepare a polyester resin having a hydroxyl group. The polyester preferably has a hydroxyl value of not less than 5 mgKOH/g, and an acid value of from 1 to 30 mgKOH/g, and preferably from 5 to 20 mgKOH/g. When a polyester having an acid value is used, the resultant toner can have a negative charging property. In addition, the toner has good affinity for recording papers, resulting in enhancement of the low temperature fixability of the toner. However, when the acid value is greater than 30 mgKOH/g, stability of the charging property deteriorates particularly when the environmental conditions change. The polyester has a weight average molecular weight of from 10,000 to 400,000, and preferably from 20,000 to 200,000. When the weight average molecular weight is less than 10,000, the offset resistance of the toner tends to deteriorate. In contrast, when the weight average molecular weight is greater than 400,000, the low temperature fixability of the toner tends to deteriorate.
Urea-modified polyesters can also preferably used as the polyester as well as the above-mentioned unmodified polyesters prepared by a polycondensation reaction. Urea-modified polyesters can be prepared by reacting a polyisocyanate compound (PIC) with a carboxyl group of a hydroxyl group present at the end of the above-mentioned unmodified polyester to prepare a polyester prepolymer (A) having an isocyanate group, and then reacting an amine compound with the prepolymer (A) to perform a crosslinking and/or a polymer chain growth reaction.
Specific examples of the polyisocyanate compounds (PIC) include, but are not limited thereto, aliphatic polyisocyanates (such as tetramethylene diisocyanate, hexamethylene diisocyanate, and 2,6-diisocyanato methylcaproate); alicyclic polyisocyanates (such as isophorone diisocyanate, and cyclohexylmethane diisocyanate); aromatic didicosycantes (such as tolylene diisocyanate, and diphenylmethane diisocyanate); aromatic aliphatic diisocyanates (such as α, α, α′, α′-tetramethyl xylylene diisocyanate); isocyanurates; and blocked isocyanates such as polyisocyanates blocked with a phenol derivative, an oxime, or a caprolactam. These compounds can be used alone or in combination.
When synthesizing a polyester prepolymer having an isocyanate group, suitable mixing ratio of a polyisocyanate to a polyester having a hydroxyl group (i.e., an equivalence ratio [NCO]/[OH] of the isocyanate group of a polyisocyanate (PIC) to the hydroxyl group of a polyester) is from 5/1 to 1/1, preferably from 4/1 to 1.2/1, and more preferably from 2.5/1 to 1.5/1. When the ratio [NCO]/[OH] is greater than 5/1, the low temperature fixability of the toner tends to deteriorate. In contrast, when the ratio [NCO]/[OH] is less than 1/1, the urea content of the urea-modified polyester decreases, resulting in deterioration of the hot offset resistance of the toner. The content of the unit obtained from a polyisocyanate in the polyester prepolymer (A) having a polyisocyanate group is from 0.5 to 40% by weight, preferably from 1 to 30% by weight, and more preferably from 2 to 20% by weight.
When the content is less than 0.5% by weight, the hot offset resistance of the toner tends to deteriorate, and in addition it is hard to impart a good combination of high temperature fixability and low temperature fixability to the toner. In contrast, when the content is greater than 40% by weight, the low temperature fixability tends to deteriorate.
The number of the isocyanate group in a polyester prepolymer is generally not less than 1, preferably from 1.5 to 3 in average, and more preferably from 1.8 to 2.5 in average. When the number is less than 1, the molecular weight of the urea-modified polyester decreases, resulting in deterioration of the hot offset resistance of the toner.
By reacting a compound having an amino group with the polyester prepolymer (A), a urea-modified polyester resin can be prepared. Specific examples of the compound having an amino group include diamines (B1), polyamines (B2) having three or more amino groups, amino alcohols (B3), amino mercaptans (B4), amino acids (B5), and blocked amines in which amino groups of the above-mentioned amine compounds B1-B5 are blocked.
Specific examples of the diamines (B1) include aromatic diamines (such as phenylene diamine, diethyltoluene diamine, and 4,4′-diaminodiphenyl methane); alicyclic diamines (such as 4,4′-diamino-3,3′-dimethyldicyclohexyl methane, diaminocyclohexane, and isophorone diamine); and aliphatic diamines (such as ethylene diamine, tetramethylene diamine, and hexamethylene diamine).
Specific examples of the polyamines (B2) having three or more amino groups include diethylene triamine, and triethylene tetramine. Specific examples of the amino alcohols (B3) include ethanol amine, and hydroxyethyl aniline. Specific examples of the amino mercaptans (B4) include aminoethyl mercaptan, and aminopropyl mercaptan. Specific examples of the amino acids (B5) include amino propionic acid, and amino caproic acid. Specific examples of the blocked amines (B6) include ketimine compounds obtained from the amines B1-B5 and ketones such as acetone, methyl ethyl ketone, and methyl isobutyl ketone, and oxazolidine compounds.
Among these amine compounds (B), diamines (B1) and combinations of a diamine (B1) and a small amount of polyamine (B2) are preferable.
The mixing ratio of a polyester prepolymer (A) having an isocyanate group to an amine compound (B) (i.e., an equivalence ratio [NCO]/[NHx] of the isocyanate group of a polyester prepolymer (A) to the amino group of an amine (B)) is from 1/2 to 2/1, preferably from 1/1.5 to 1.5/1, and more preferably from 1/1.2 to 1.2/1. When the ratio is greater than 2/1 or less than 1/2, the molecular weight of the urea-modified polyester decreases, resulting in deterioration of the hot offset resistance of the toner.
The urea-modified polyester can include a urethane bond as well as a urea bond. The molar ratio of the urea bond to the urethane bond is from 100/0 to 10/90, preferably from 80/20 to 20/80, and more preferably from 60/40 to 30/70. When the molar ratio of the urea bond is less than 10%, the hot offset resistance of the toner tends to deteriorate.
Urea-modified polyester can be prepared by a one shot method or the like. Specifically, a polyalcohol (PO) and a polycarboxylic acid (PC) are heated to a temperature of form 150 to 280° C. in the presence of an esterification catalyst such as tetrabutoxy titanate and dibutyltin oxide while optionally removing generated water at a reduced pressure to prepare a polyester resin having a hydroxyl group. Next, the polyester is reacted with a polyisocyanate (PIC) at a temperature of from 40 to 140° C. to prepare a polyester prepolymer (A) having all isocyanate group. Further, the polyester prepolymer (A) is reacted with an amine compound (B) at a temperature of from 0 to 140° C. to prepare a urea-modified polyester.
When the PIC is reacted or the compounds (A) and (B) are reacted, a solvent can be used if desired. Specific examples of the solvent include solvents inactive with an isocyanate compound (PIC) such as aromatic solvents (e.g., toluene and xylene); ketones (e.g. acetone, methyl ethyle ketone, and methyl isobutyl ketone); esters (e.g., ethyl acetate); amides (e.g., dimethylformamide, and dimethylacetamide); and ethers (e.g., tetrahydrofuran).
When the polyester prepolymer (A) and the amine compound (B) are subjected to crosslinking and/or polymer chain growth reaction, a reaction terminator can be used if desired to control the molecular weight of the urea-modified polyester. Specific examples of such a terminator include monoamines such as diethylamine, dibutylamine, butylamine, laurylamine, and blocked amines such as ketimine compounds in which the above-mentioned amines are blocked with a ketone compound.
The weight average molecular weight of the urea-modified polyester is not less than 10,000, preferably from 20,000 to 10,000,000, and more preferably from 30,000 to 1,000,000.
When the weight average molecular weight is less than 10,000, the hot offset resistance of the toner deteriorates. The number average molecular weight of the urea-modified polyester resin is not particularly limited if the above-mentioned unmodified polyester is used, and importance is attached to the weight average molecular weight. When a urea-modified polyester is used alone, the number average molecular weight thereof is from 2,000 to 15,000, preferably from 2,000 to 10,000, and more preferably from 2,000 to 8,000. When the number average molecular weight is greater than 20,000, the low temperature fixability of the toner tends to deteriorate, glossiness of toner images tends to deteriorate when the toner is used for full color image forming apparatuses.
It is preferable to use a combination of an unmodified polyester and a urea-modified polyester, because the low temperature fixability of the toner can be enhanced, and in addition the glossiness of toner images can be enhanced when the toner is used for full color image forming apparatuses. In this regard, the unmodified polyester resin can include a chemical bond other than a urea bond.
When a combination of an unmodified polyester and a urea-modified polyester is used, the polyesters are preferably compatible with each other at least partially to impart a good combination of low temperature fixability and hot offset resistance to the toner. Therefore, it is preferable that the polyesters are similar in composition.
The weight ratio of an unmodified polyester to a urea-modified polyester is from 20/80 to 95/5, preferably from 70/30 to 95/5, more preferably from 75/25 to 95/5, and even more preferably from 80/20 to 93/7. When the content of a urea-modified polyester is less than 5% by weight, the hot offset resistance of the toner tends to deteriorate, and it is hard to impart a good combination of high temperature preservability and low temperature fixability to the toner.
The binder resin of the toner, which includes an unmodified polyester to a urea-modified polyester, preferably has a glass transition temperature (Tg) of from 45 to 65° C. and preferably from 45 to 60° C. When the Tg is lower than 45° C., the heat resistance of the toner tends to deteriorate. When the Tg is higher than 65° C. the low temperature fixability of the toner tends to deteriorate.
Since a urea-modified polyester tends to present in a surface portion of toner particles, a better high temperature preservability can be imparted to the toner than in a case where a general polyester is used as a binder resin of toner even when the glass transition temperature of the urea-modified polyester is relatively low.
Suitable materials for use as the colorant of the toner include known dyes and pigments. Specific examples of such dyes and pigments include carbon black, Nigrosine dyes, black iron oxide, NAPHTHOL YELLOW S, HANSA YELLOW 10G, HANSA YELLOW 5G, HANSA YELLOW G, Cadmium Yellow, yellow iron oxide, loess, chrome yellow, Titan Yellow, polyazo yellow, Oil Yellow, HANSA YELLOW GR, HANSA YELLOW A, HANSA YELLOW RN, HANSA YELLOW R, PIGMENT YELLOW L, BENZIDINE YELLOW G, BENZIDINE YELLOW GR, PERMANENT YELLOW NCG, VULCAN FAST YELLOW 5G, VULCAN FAST YELLOW R, Tartrazine Lake, Quinoline Yellow LAKE, ANTHRAZANE YELLOW BGL, isoindolinone yellow, red iron oxide, red lead, orange lead, cadmium red, cadmium mercury red, antimony orange. Permanent Red 4R, Para Red, Fire Red, p-chloro-o-nitroaniline red, Lithol Fast Scarlet G, Brilliant Fast Scarlet, Brilliant Carmine BS, PERMANENT RED F2R, PERMANENT RED F4R, PERMANENT RED FRL, PERMANENT RED FRLL, PERMANENT RED F4RH, Fast Scarlet VI), VULCAN FAST RUBINE B, Brilliant Scarlet G, LITHOL RUBINE GX, Permanent Red F5R, Brilliant Carmine 6B, Pigment Scarlet 3B, Bordeaux 5B, Toluidine Maroon, PERMANENT BORDEAUX F2K, HELIO BORDEAUX BL, Bordeaux 10B, BON MAROON LIGHT, BON MAROON MEDIUM, Eosin Lake, Rhodamine Lake B, Rhodamine Lake Y, Alizarine Lake, Thioindigo Red B, Thioindigo Maroon, Oil Red, Quinacridone Red, Pyrazolone Red, polyazo red, Chrome Vermilion, Benzidine Orange, perynone orange, Oil Orange, cobalt blue, cerulean blue, Alkali Blue Lake, Peacock Blue Lake, Victoria Blue Lake, metal-free Phthalocyanine Blue, Phthalocyanine Blue, Fast Sky Blue, INDANTHRENE BLUE RS, INDANTHRENE BLUE BC, Indigo, ultramarine, Prussian blue, Anthraquinone Blue, Fast Violet B, Methyl Violet Lake, cobalt violet, manganese violet, dioxane violet, Anthraquinone Violet, Chrome Green, zinc green, chromium oxide, viridian, emerald green, Pigment Green B, Naphthol Green B, Green Gold, Acid Green Lake, Malachite Green Lake, Phthalocyanine Green, Anthraquinone Green, titanium oxide, zinc oxide, lithopone and the like. These materials are used alone or in combination.
The content of such a colorant in the toner is preferably from 1 to 15% by weight, and more preferably from 3 to 10% by weight of the toner.
Master batches, which are complexes of a colorant with a resin (binder resin), can be used as the colorant of the toner. Specific examples of the resin for use in the master batches include homopolymers of styrene or styrene derivatives such as polystyrene, poly-p-chlorostyrene, and polyvinyl toluene; copolymers of styrene and vinyl compounds; polymethyl methacrylate, polybutyl methacrylate, polyvinyl chloride, polyvinyl acetate, polyethylene, polypropylene, polyester, epoxy resins, epoxy polyol resins, polyurethane, polyamide, polyvinyl butyral, polyacrylic acid resins, rosin, modified rosins, terpene resins, aliphatic or alicyclic hydrocarbon resins, aromatic petroleum resins, chlorinated paraffin, and paraffin waxes. These resins can be used alone or in combination.
Any known charge controlling agents can be used for the toner. Suitable materials for use as the charge controlling agent include Nigrosine dyes, triphenyl methane dyes, chromium-containing metal complex dyes, molybdic acid chelate pigments. Rhodamine dyes, alkoxyamines, quaternary ammonium salts (including fluorine-modified quaternary ammonium salts), alkylamides, phosphor and its compounds, tungsten and its compounds, fluorine-containing surfactants, metal salts of salicylic acid, metal salts of salicylic acid derivatives, copper phthalocyanine, perylene, quinacridone, azo pigments, and polymers having a functional group such as a sulfonate group, a carboxyl group, and a quaternary ammonium salt group.
Specific examples of marketed charge controlling agents include BONTRON 03 (Nigrosine dye), BONTRON P-51 (quaternary ammonium salt), BONTRON S-34 (metal-containing azo dye), BONTRON E-82 (metal complex of oxynaphthoic acid), BONTRON E-84 (metal complex of salicylic acid), and BONTRON E-89 (phenolic condensation product), which are manufactured by Orient Chemical Industries Co., Ltd.; TP-302 and TP-415 (molybdenum complex of quaternary ammonium salt), which are manufactured by Hodogaya Chemical Co., Ltd.; COPY CHARGE PSY VP2038 (quaternary ammonium salt), COPY BLUE PR (triphenyl methane derivative), COPY CHARGE NEG VP2036 and COPY CHARGE NX VP434 (quaternary ammonium salt), which are manufactured by Hoechst AG; and LRA-901 and LR-147 (boron complex), which are manufactured by Japan Carlit Co., Ltd.
Among these charge controlling agents, materials capable of negatively charging the toner are preferable.
The added amount of such a charge controlling agent is determined depending on choice of binder resin, presence or absence of additives, and the toner preparation method including the dispersing method, and is not unambiguously determined. However, the added amount is preferably from 0.1 to 10 parts by weight, and more preferably from 0.2 to 5 parts by weight, based on 100 parts by weight of the binder resin. When the added amount is greater than 10 parts by weight, the toner tends to have an excessively large charge property, thereby increasing electrostatic attraction between the toner and a developing roller, resulting in deterioration of fluidity of the toner (developer) and decrease of image density.
Waxes having a low melting point of from 50 to 120° C. are preferably used because such a wax satisfactorily serves as a release agent when being dispersed in a binder resin, and when a toner image is fixed, the release agent is present between a fixing roller and the toner image, thereby enhancing the hot offset resistance of the toner. Therefore, the toner can be used without applying a release agent such as oils to the fixing roller.
Specific examples of the release agent for use in the toner include, but are not limited thereto, vegetable waxes such as carnauba waxes, cotton waxes, Japan waxes, and rice waxes; animal waxes such as bees waxes, and lanolin; mineral waxes such as ozocerite and ceresin waxes; petroleum waxes such as paraffin waxes, microcrystalline waxes, and petrolatum; synthesized hydrocarbon waxes such as Fischer-Tropsch waxes, and polyethylene waxes; synthesized waxes such as esters, ketones and ethers; amides and imides such as 12-hydroxystearamide, stearamide, phthalic anhydride imide, and chlorinated hydrocarbons; and low molecular weight crystalline polymers having a long alkyl group in a side chain thereof such as homopolymers or copolymers of polyacrylate (e.g., poly(n-stearyl methacrylate), poly(n-lauryl methacrylate), and n-stearyl acrylate—ethyl methacrylate copolymers.
The charge controlling agent and the release agent can be melted and kneaded together with the master batch and the binder resin when the toner is prepared by a dry method. Alternatively, the components may be dissolved or dispersed in an organic solvent when the toner is prepared by a wet method.
In order to enhance the fluidity, the developing property and the charge property of loner particles, a particulate inorganic material can be used as an external additive. Such a particulate inorganic material preferably has an average primary particle diameter of from 5 nm to 2 μm, and more preferably from 5 nm to 500 nm. The BET specific surface area of the particulate inorganic material is preferably from 20 to 500 m2/g. The content of the particulate inorganic material in the toner is generally from 0.01 to 5.0% by weight, and preferably from 0.01 to 2.0% by weight.
Specific examples of the particulate inorganic material include, but are not limited thereto, silica, alumina, titanium oxide, barium titanate, magnesium titanate, calcium titanate, strontium titanate, zinc oxide, tin oxide, quartz sand, clay, mica, wollastonite, diatom earth, chromium oxide, cerium oxide, red iron oxide, antimony trioxide, magnesium oxide, zirconium oxide, barium oxide, barium carbonate, calcium carbonate, silicon carbide, and silicon nitride. These materials can be used alone or in combination.
Among these particulate inorganic materials, combinations of a hydrophobized particulate silica and a hydrophobized particulate titanium oxide are preferably used. Particularly, when a particulate material having an average particle diameter of not greater than 0.5 nm is mixed with toner particles while agitated, the electrostatic force and van der Waals attraction between the inorganic material and the toner particles are dramatically enhanced. Therefore, even when the toner is agitated in a developing device to charge the toner so as to have the desired charge quantity, the inorganic material is not released from the toner particles. Therefore, high quality images can be produced by the toner without forming defective images such as white dot images while the amount of residual toner particles is reduced. Particulate titanium oxides have good environmental stability and impart good image density stability to the toner, but tend to deteriorate the charge rising property of the toner. Therefore, when the added amount of a titanium oxide is greater than that of a silica, the charge rising property of the toner tends to deteriorate.
However, when the added amount of such a combination external additive including a hydrophobized silica and a hydrophobized titanium oxide is in a range of from 0.3 to 1.5% by weight, the charge rising property of the toner does not deteriorate, and the desired charge rising property can be imparted to the toner. Namely, even when copying operations are repeatedly performed using the toner, high quality images can be produced stably.
Next, the method for preparing the toner will be described. The following method is a preferable method, but the method for preparing the toner is not limited thereto.
(1) Initially, a colorant, an unmodified polyester, a polyester prepolymer having an isocyanate group, and a release agent are dispersed in an organic solvent to prepare a toner component liquid.
The organic solvent preferably has a boiling point of not higher than 100° C. so that the solvent can be easily removed after toner particles are prepared. Specific examples of the organic solvent include toluene, xylene, benzene, carbon tetrachloride, methylene chloride, 1,2-dichloroethane, 1,1,2-trichloroethane, trichloroethylene, chloroform, monochlorobenzene, dichloroethylidene, methyl acetate, ethyl acetate, methyl ethyl ketone, and methyl isobutyl ketone. These organic solvents can be used alone or in combination. Among these organic solvents, aromatic solvents such as toluene, and xylene, and halogenated hydrocarbons such as methylene chloride, 1,2-dichloroethane, chloroform and carbon tetrachloride are preferable.
The amount of the organic solvent is from 0 to 300 parts by weight, preferably from 0 to 100 parts by weight, and more preferably from 25 to 70 parts by weight, based on 100 parts by weight of the polyester prepolymer used.
(2) The toner component liquid is emulsified in an aqueous medium in the presence of a surfactant, and a particulate resin.
Water is typically used as the aqueous medium, and the aqueous medium can optionally include an organic solvent such as alcohols (e.g., methanol, isopropyl alcohol, and ethylene glycol), dimethylformamide, tetrahydrofuran, cellosolves (e.g., methyl cellosolve), and lower ketones (e.g., acetone and methyl ethyl ketone).
The amount of the aqueous medium is generally from 50 to 2,000 parts by weight, and preferably from 100 to 1,000 parts by weight, based on 100 parts by weight of the toner component liquid. When the amount of the aqueous medium is less than 50 parts by weight, it is hard to satisfactorily disperse the toner component liquid in the aqueous medium. In contrast, using an aqueous medium in an amount of greater than 20,000 parts by weight is not economical.
In order to satisfactorily disperse the toner component liquid in the aqueous medium, a dispersant such as surfactants and particulate resins can be added in the aqueous medium.
Suitable materials for use as the surfactant include anionic surfactants such as alkylbenzenesulfonic acid salts, α-olefin sulfonic acid salts, and phosphoric acid salts; catinic surfactants such as amine salts (e.g., alkyl amine salts, amino alcohol fatty acid derivatives, polyamine fatty acid derivatives, and imidazoline), and quaternary ammonium salts (e.g. alkyltrimethyl ammonium salts, dialkyldimethyl ammonium salts, alkyldimethylbenzyl ammonium salts, pyridinium salts, alkylisoquinolinium salts, and benzethonium chloride); nonionic surfactants such as fatty acid amide derivatives, and polyalcohol derivatives; and ampholytic surfactants such as alanine, dodecylbis(aminoethyl)glycin, bis(octylaminoethyle)glycin, and N-alkyl-N,N-dimethylammonium betaine.
By using a surfactant having a fluoroalkyl group, the effect can be produced even when the added amount of the surfactant is small.
Specific examples of the anionic surfactants having a fluoroalkyl group include fluoroalkyl(C2-10) carboxylic acids and their metal salts, disodium perfluorooctanesulfonylglutamate, sodium 3-{ω-fluoroalkyl(C6-C11)oxy}-1-alkyl(C3-C4) sulfonates, sodium 3-{ω-fluoroalkanoyl(C6-C8)-N-ethylamino}-1-propanesulfonates, fluoroalkyl(C11-C20)carboxylic acids and their metal salts, perfluoroalkyl(C7-C13)carboxylic acids and their metal salts, perfluoroalkyl(C4-C12)sulfonates and their metal salts, perfluorooctanesulfonic acid diethanol amides,
Specific examples of marketed products of such anionic surfactants having a fluoroalkyl group include SARFRON S-111, S-112 and S-113, which are manufactured by Asahi Glass Co., Ltd.; FLUORAD FC-93, FC-95, FC-98 and FC-129, which are manufactured by Sumitomo 3M Ltd.; UNIDYNE DS-101 and DS-102, which are manufactured by Daikin Industries, Ltd.; MEGAFACE F-110, F-120, F-113, F-191, F-812 and F-833 which are manufactured by DIC Corp.; ECTOP EF-102, 103, 104, 105, 112, 123A, 123B, 306A, 501, 201 and 204, which are manufactured by Tohchem Products Co. Ltd.; FUTARGENT F-100 and F150 manufactured by Neos Co., Ltd.; etc.
Specific examples of the cationic surfactants having a fluoroalkyl group include primary, secondary and tertiary aliphatic amino acids, aliphatic quaternary ammonium salts such as propyltrimethylammonium salts of perfluoroalkyl(C6-C10)sulfoneamide, benzalkonium salts, benzethonium chloride, pyridinium salts, and imidazolinium salts, all of which have a fluoroalkyl group.
Specific examples of marketed products of such cationic surfactants having a fluoroalkyl group include SARFRON S-121 (from Asahi Glass Co., Ltd.); FLUORAD FC-135 (from Sumitomo 3M Ltd.); UNIDYNE DS-202 (from Daikin Industries. Ltd.); MEGAFACE F-150 and F-824 (from DIC Corp.); ECTOP EF-132 (from Tohchem Products Co., Ltd.); and FUTARGENT F-300 (from Neos Co., Ltd.).
In order to stabilize toner particles, which are formed in the aqueous medium, a particulate resin is added to the aqueous medium. Such a particulate resin is preferably added in an amount such that the surface of the toner particles is covered with the particulate resin at a covering rate of from 10 to 90%. Specific examples of such a particulate resin include particulate polymethyl methacrylate having a particle diameter of 1 μm or 3 μm, particulate polystyrene having a particle diameter of 0.5 μm or 2 μm, and particulate poly(styrene-acrylonitrile) having a particle diameter of 1 μm. Specific examples of marketed products of such particulate resins include PB-200H (from Kao Corp.), SGP and SGP-30 (from Soken Chemical Engineering Co., Ltd.), and TECHNOPOLYMER SB and MICROPEARL (from Sekisui Chemical Co., Ltd.).
In addition, inorganic dispersants such as tricalcium phosphate, calcium carbonate, titanium oxide, colloidal silica, and hydroxyapatite can also be used.
Polymeric protection colloids can also be used as the dispersant in combination with such an inorganic dispersant. Specific examples of such polymeric protection colloids include polymers and copolymers prepared by using monomers such as monomers having a carboxyl group (e.g., acrylic acid, methacrylic acid, α-cyanoacrylic acid, α-cyanomethacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, and maleic anhydride), acrylic monomers having a hydroxyl group (e.g., β-hydroxyethyl acrylate, β-hydroxyethyl methacrylate, β-hydroxypropyl acrylate, β-hydroxypropyl methacrylate, γ-hydroxypropyl acrylate, γ-hydroxypropyl methacrylate, 3-chloro-2-hydroxypropyl acrylate, 3-chloro-2-hydroxypropyl methacrylate, diethyleneglycolmonoacrylic acid esters, diethyleneglycolmonomethacrylic acid esters, glycerinmonoacrylic acid esters, glycerinmonomethacrylic acid esters, N-methylolacrylamide, and N-methylolmethacrylamide), vinyl alkyl ethers (e.g., vinyl methyl ether, vinyl ethyl ether, and vinyl propyl ether), esters of vinyl alcohol with a compound having a carboxyl group (e.g., vinyl acetate, vinyl propionate, and vinyl butyrate), amides and methylol compounds thereof (e.g, acrylamide, methacrylamide, and diacetoneacrylamide acids), monomers having a chlorocarbonyl group (e.g., acrylic acid chloride, and methacrylic acid chloride), and monomers having a nitrogen atom or an alicyclic ring having a nitrogen atom (e.g., vinyl pyridine, vinyl pyrrolidone, vinyl imidazole, and ethylene imine).
In addition, polymers such as polyoxyethylene compounds (e.g., polyoxyethylene, polyoxypropylene, polyoxyethylenealkyl amines, polyoxypropylenealkyl amines, polyoxyethylenealkyl amides, polyoxypropylenealkyl amides, polyoxyethylene nonylphenyl ethers, polyoxyethylene laurylphenyl ethers, polyoxyethylene stearylphenyl esters, and polyoxyethylene nonylphenyl esters); and cellulose compounds such as methyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose, can also be used as the polymeric protective colloid.
Known mixers and dispersing machines such as low speed shearing type dispersing machines, high speed shearing type dispersing machines, friction type dispersing machines, high pressure jet type dispersing machines and ultrasonic dispersing machine can be used for dispersing the toner component liquid in the aqueous medium. Among these dispersing machines, high speed shearing type dispersing machines are preferably used in order to prepare a dispersion including particles having an average particle diameter of from 2 to 20 μm.
When high shearing type dispersing machines are used, the rotation speed of rotors is not particularly limited, but the rotation speed is generally from 1,000 to 30,000 rpm and preferably from 5,000 to 20,000 rpm. In addition, the dispersing time is also not particularly limited, but the dispersing time is generally from 0.1 to 5 minutes. The temperature in the dispersing process is generally 0 to 150° C. (under pressure), and preferably from 40 to 98° C.
(3) When preparing the emulsion, an amine (B) is added thereto to react the amine with the polyester prepolymer (A) having an isocyanate group. In this reaction, a crosslinking reaction and/or a polymer chain growth reaction is performed. The reaction time is determined depending on the reactivity of the isocyanate of the prepolymer (A) used with the amine used. However, the reaction time is typically from 10 minutes to 40 hours, and preferably from 2 hours to 20 hours. The reaction temperature is typically from 0 to 150° C. and preferably from 40 to 98° C. In addition, known catalysts such as dibutyltin laurate and dioctyltin laurate can be added, if desired, when the reaction is performed.
(4) After the reaction, the organic solvent is removed from the emulsified dispersion (reaction product), and the resultant particles are washed and dried to prepare toner particles. In order to remove the organic solvent, the reaction product is gradually heated while agitated to form a laminar flow, and then the reaction product is heated in a temperature range while agitated strongly to remove the organic solvent, thereby forming toner particles having a spindle form. In this regard, when a dispersion stabilizer soluble in acids and alkalis such as calcium phosphate is used, calcium phosphate adhered to the toner particles is dissolved by an acid such as hydrochloric acid, and then the toner particles are washed with water to remove calcium phosphate from the toner particles. In addition, such a dispersion stabilizer can be removed by a decomposition method using an enzyme.
(5) After a charge controlling agent is attached to the thus prepared toner particles, and an particulate inorganic material such as silica and titanium oxide is added to the toner particles as an external additive, resulting in formation of a toner. Attachment of the charge controlling agent and the particulate inorganic material is performed by a known method using a mixer or the like.
By using this method, toner having a small average particle diameter and a sharp particle diameter distribution can be easily prepared. In addition, by performing agitation while controlling the agitation strength in the organic solvent removing process, the shape of the toner particles can be freely changed so as to be from spherical shape to rugby ball shape. In addition, the surface of the toner particles can also be freely changed so as to be from smooth surface to wrinkled surface.
The shape of the toner particles is a nearly-spherical shape, and is represented by the below-mentioned method.
The lengths and thickness r1, r2 and r3 are measured by a method in which a toner particle is observed with a scanning electron microscope (SEM) while changing the viewing angle.
The above-mentioned cleaner for use as the belt cleaner 100 can also be used for a feeding belt cleaner 500 to clean the surface of a feeding belt 51 of a recording medium feeding device 50 illustrated in
In the printer illustrated in
By applying the above-mentioned cleaner for use as the belt cleaner 100 to the feeding belt cleaner 500, the toner test pattern can be satisfactorily removed from the feeding belt 51, and therefore occurrence of a problem in that the backside of the recording medium P is contaminated by toner particles can be prevented.
The above-mentioned cleaner for use as the belt cleaner 100 can also be used for a drum cleaner 4 illustrated in
The present application is not limited to the above-mentioned examples. The present application includes the following embodiments, which produce the following specific effects.
In a cleaner (such as the belt cleaner 100) including at least two cleaning brush members (such as the cleaning brush rollers 101, 104 and 107) to electrostatically remove residual toner and non-transferred toner on an object to be cleaned such as the intermediate transfer belt 8; a memory (such as the memory 31) to store information on setup voltage values; a voltage applicator (such as the power sources 130a-135a) to apply voltages to the cleaning brush members based on the setup voltage values stored in the memory; a current detector (such as the current detectors 130b-135b) to detect the amounts of currents flowing through the contact portions of the object with the cleaning brush members; and a setup voltage changing device (such as the controller 30) to change the setup voltage values based on the amounts of currents detected by the current detector, the voltage applying device applies a first voltage to at least one of the cleaning brush members to remove residual toner (toner particles remaining on the object without being transferred), and the voltage applying device applies a second voltage to the cleaning brush member to remove non-transferred toner (such as the toner test pattern), wherein the second voltage has the same polarity as that of the first voltage, and the absolute value of the second voltage is greater than that of the first voltage. The setup voltage changing device performs change of the setup voltage value for the second voltage prior to change of the setup voltage value for the first voltage. Therefore, in this cleaner, optimum voltages can be applied in the residual toner cleaning operation and the non-transferred toner image cleaning operation.
In the cleaner mentioned above in Embodiment A, three cleaning brush members are provided. The three cleaning brush members include a first cleaning brush member (such as the pre-cleaning brush roller 101), to which a voltage having a polarity opposite to the normal charge polarity of the toner is applied to electrostatically remove normally-charged toner on the surface of the object to be cleaned; a second cleaning brush member (such as the reversely-charged toner cleaning brush roller 104), which is arranged on a downstream side from the first cleaning brush member relative to the moving direction of the object and to which a voltage having the same polarity as the normal charge polarity of the toner is applied to remove reversely-charged toner on the surface of the object; and a third cleaning brush member (such as the normally-charged toner cleaning brush roller 107), which is arranged on a downstream side from the second cleaning brush member relative to the moving direction of the object and to which a voltage having a polarity opposite to the normal charge polarity of the toner is applied to electrostatically remove normally-charged toner on the surface of the object. Since a greater part of the non-transferred toner is normally-charged toner particles, the normally-charged toner particles are roughly removed by the first cleaning brush member, and therefore the amount of residual toner fed to the second and third cleaning brush members is small. Therefore, the second and third cleaning brush members can easily remove residual toner from the object to be cleaned, thereby preventing occurrence of defective cleaning.
In the cleaner mentioned above in Embodiment B, the voltage applicator applies a voltage to the first cleaning brush roller while changing the voltage level in at least two levels including a first voltage for removing residual toner and a second voltage for removing non-transferred toner. In this case, the residual toner particles and the non-transferred toner can be satisfactorily removed from the object to be cleaned.
In an image forming apparatus (such as the printer illustrated in
In the image forming apparatus mentioned above in Embodiment D, an elastic belt is used for the intermediate transfer medium. In this case, toner images on the intermediate transfer medium can be satisfactorily transferred onto the recording medium even when the recording medium has rough surface, thereby making it possible to form images with good evenness.
In an image forming apparatus (such as the printer illustrated in
In an image forming apparatus (such as the printer illustrated in
In the image forming apparatus mentioned above in Embodiment D, E, F or G, the toner has a first shape factor SF-1 of from 100 to 180. In this case, high quality images can be produced.
In a voltage setting device including a voltage applicator including at least two voltage applying members (such as the cleaning brush rollers) which are contacted with an object (such as the image bearing member (e.g., the photoreceptor 1 and the intermediate transfer belt 8) and the recording medium feeding belt 51) and to which voltages are applied based on the setup voltage values stored in a memory (such as the memory 31); a current detector (such as the current detectors 130b-135b) to detect currents flowing through the contact portions of the at least two voltage applying members with the object; and a setup voltage changing device (such as the controller 30) to change the setup voltage values based on the amounts of the currents detected by the current detector, the voltage is applied to at least one of the voltage applying members while changing the voltage level in two or more levels including a first voltage and a second voltage higher than the first voltage in absolute value, and the setup voltage changing device performs change of the setup voltage value for the second voltage prior to change of the setup voltage value for the first voltage. In this case, proper voltages can be set for the setup voltages.
As mentioned above, when the setup voltage changing device changes the setup voltage, the setup voltage changing device performs change of the setup voltage for the second voltage applied for removing non-transferred toner prior to change of the setup voltage for the first voltage, which is applied for removing residual toner and which is lower than the second voltage. In this case, a beneficial effect such that the first and second voltages can be set to optimum voltages can be produced.
Additional modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims the invention may be practiced other than as specifically described herein.
Number | Date | Country | Kind |
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2012-192413 | Aug 2012 | JP | national |