This disclosure relates generally to production of clean textiles and, more particularly, cleaning articles—such as wipers, flat and string type mops, and swabs—made of a recycled or “upcycled” material for use in a cleanroom and sterile cleanroom environment, and methods for producing such cleaning articles.
Cleanrooms are used in various settings. These include semiconductor fabrication plants, pharmaceutical and medical device manufacturing facilities, compounding pharmacies, aerospace laboratories, and similar places where extreme cleanliness is required.
Cleanrooms are maintained in isolated areas of a building. In this respect, cleanrooms typically have highly specialized air cooling, ventilation and filtration systems to prevent the entry of air-borne particles. Individuals who enter a cleanroom will wear special clothing and gloves. Such individuals may also use specialized notebooks and writing instruments.
It may desirable to clean equipment within a cleanroom. For example, in semiconductor fabrication cleanrooms, surfaces must be frequently wiped or mopped. In order to clean, wipers, mops, and cleaning solutions may be used. For such applications, the cleaning articles themselves should be exceptionally particle-free, and should have a high degree of wet strength and structural integrity. In this way, the cleaning substrates do not disintegrate when used to clean surfaces, even when dampened by or saturated with a cleaning liquid.
Products used in sensitive areas such as semiconductor fabrication cleanrooms and pharmaceutical manufacturing facilities are carefully selected for certain characteristics. These include low particle emission levels, low levels of ionic contaminants, adsorptiveness, and resistance to degradation by wear or exposure to cleaning materials. The contamination which is to be controlled is often called “micro-contamination” because it consists of small physical contaminants. Such contaminants include matter of a size between that of bacteria and viruses, and chemical contaminants in very low concentrations, typically measured in parts per million or even parts per billion.
Micro-contaminants are usually one of several types: physical particles, ions and microbials, and “extractables.” Extractables are impurities leached from the fibers of a cleaning article. Previously, The Texwipe Company of Upper Saddle River, N.J. (now Texwipe, Division of Illinois Tool Works, of Kernersville, N.C.) has developed wipers especially suited for use in particle-controlled environment. See, e.g., U.S. Pat. Nos. 4,888,229, 5,271,995, and 6,062,381, each to Paley, et al., the disclosures of which are incorporated herein by reference in their entireties to the extent permitted by law. See also U.S. Pat. No. 5,229,181 to Daiber et al. These patents disclose wipers for cleanroom use.
There exists a need for cleaning articles (such as wipers, mops, and swabs) made from recycled or “upcycled” materials.
According to an aspect of the present disclosure, a cleaning article made from recycled material may comprise at least one layer of a fabric, wherein the fabric is formed from at least 50% recycled yarn, and the remainder of the fabric, if any, is formed from virgin yarn. The edges of the at least one layer are sealed or cut.
According to another aspect of the present disclosure, a package of wipers may comprise a sheet material container, wherein the container contains a strip or roll of wipers delineated from one another by lines of weakness, and an industrial cleaning liquid absorbed into the wipers. The container may be a dispenser bag or a canister. The container may comprise an outlet fixture forming a restricted outlet opening through which the wipers can be pulled with substantial resistance so as to allow a wiper extending through the outlet opening to be withdrawn and torn free from the strip when pulled out through the outlet opening. The wiper may comprise at least one layer of a fabric. The fabric may be formed from at least 50% recycled yarn, and the remainder of the fabric, if any, may be formed from virgin yarn. The edges of the at least one layer are sealed or cut. The industrial cleaning liquid may comprise a solvent.
According to another aspect of the present disclosure, a method for preparing a cleaning article made from recycled material may comprise weaving, knitting, or bonding recycled polyester yarn formed from recycled polyethylene terephthalate (rPET) bottles to form a cleaning article made from recycled material, wherein the cleaning article comprises at least one layer of a fabric, and wherein the fabric is formed from at least 50% recycled polyester yarn, and the remainder of the fabric, if any, is formed from virgin yarn. The edges of the at least one layer are sealed or cut.
It is to be understood that both the foregoing general description and the following detailed description describe various embodiments and are intended to provide an overview or framework for understanding the nature and character of the claimed subject matter. The accompanying drawings are included to provide a further understanding of the various embodiments, and are incorporated into and constitute a part of this specification. The drawings illustrate the various embodiments described herein, and together with the description serve to explain the principles and operations of the claimed subject matter.
The following is a description of the examples depicted in the accompanying drawings. The figures are not necessarily to scale, and certain features and certain views of the figures may be exaggerated in scale or in schematic for clarity or conciseness.
The foregoing summary, as well as the following detailed description, will be better understood when read in conjunction with the figures. It should be understood that the claims are not limited to the arrangements and instrumentality shown in the figures. Furthermore, the appearance shown in the figures is one of many ornamental appearances that can be employed to achieve the stated functions of the apparatus.
In the following detailed description, specific details may be set forth to provide a thorough understanding of the embodiments of the present disclosure. However, it will be clear to one skilled in the art when disclosed examples may be practiced without some or all of these specific details. For the sake of brevity, well-known features or processes may not be described in detail. In addition, like or identical reference numerals may be used to identify common or similar elements.
One or more specific embodiments of the present disclosure will be described below. In an effort to provide a concise description of these embodiments, all features with an actual implementation may not be described in the specification. It should be appreciated that in the development of any such actual implementation, as in any engineering or design project, numerous implementation-specific decisions must be made to achieve the developers' specific goals, such as compliance with system-related and business-related constraints, which may vary from one implementation to another. Moreover, it should be appreciated that such a development effort might be complex and time consuming, but would nevertheless be a routine undertaking of design, fabrication, and manufacture for those of ordinary skill having the benefit of this disclosure.
When introducing elements of various embodiments of the present disclosure, the articles “a,” “an,” “the,” and “said” are intended to mean that there are one or more of the elements. The terms “comprising,” “including,” and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements.
Cleanroom applications may benefit from using cleaning articles such as wipers, mops, and swabs to clean surfaces. However, such cleaning articles are not typically made from a recycled material.
Cleaning articles according to the present disclosure may be made from a fabric comprising recycled or “upcycled” polyethylene terephthalate (rPET). Upcycling, also known as creative reuse, is the process of transforming by-products, waste materials, useless, or unwanted products into new materials or products of better quality and environmental value. Here, PET bottles that might otherwise become landfill are being reused as cleaning articles such as cleanroom wipers, mops, and swabs.
One advantage of forming cleaning articles such as wipers from recycled PET (rPET) bottles is that there is an overall reduction in the energy consumption required to produce the cleaning article. In fact, the energy consumption may be reduced by as much as 45%.
Cleaning articles according to the present disclosure may be formed of a fabric comprising a yarn that is polyester, nylon, or a polyester/nylon blend. Polyester may be in the form of filament polyester yarn , spun, or staple polyester yarn. Similarly, nylon may be in the form of filament nylon yarn, spun, or staple nylon yarn. An example cleaning article according to the present disclosure may comprise at least 50% recycled yarn. For example, a cleaning article could be formed of 50% recycled yarn and 50% virgin yarn. Alternatively, an example cleaning article could be formed of fabric that comprises between 1% to 100% polyester yarn (for example 60%, 70%, 80%, or 90% recycled yarn).
Cleaning articles according to the present disclosure may be used for various applications, particularly cleanroom applications, including: wiping and cleaning surfaces, equipment, and parts; spill control; applying and removing lubricants, adhesives, residues, and other solutions including disinfectants; cleaning with solvents; cleaning gloves, notebooks, phones or any other item entering a cleanroom; and lining trays for holding, protecting, drying and storing of parts, equipment and devices.
Cleaning articles according to the present disclosure may be cleanroom laundered and packaged providing ultra-low levels of ions and non-volatile residues and designed for use on various surfaces. The cleaning articles should not easily snag or abrade releasing particles and fibers. The cleaning articles should have excellent chemical resistance for compatibility with a variety of solutions. Cleaning articles according to the present disclosure may have fabric with properties as shown in Table 1.
Cleaning articles according to the present disclosure may comprise fabric that has a sorption capacity of at least 100 mL per m2 (for example, 150-200 mL per m2, or 300-400 mL per m2 or 500-600 mL per m2 or 530 mL per m2). The fabric may have a sorption rate of 0.3 seconds or less. The basis weight of the fabric may be 300 g per m2 or less (for example, 100-150 g per m2, 150-200 g per m2, or 200-250 g per m2 or 160 g per m2).
Cleaning articles, such as wipers, made with rPET and virgin PET, respectively, may have properties as shown in Table 2. The ion content may be measured by ion chromatography. For example, cleaning articles made with rPET may have a lower sorption capacity than cleaning articles made with virgin PET, while retaining sufficient sorption capacity to be useful as a cleaning article. The basis weight and sorption rate of the cleaning articles may be similar. While there may be some differences in ion values, the differences are not significant to the performance of the cleaning articles.
As it is shown most clearly in
The outlet fixture 18 (
The cap base 24 has four pie-shaped flexible plastic tabs 32 which project radially inwardly on the inside of the base 24, with slots 34 separating the projections 32 from one another. Five tabs 32 forming a “star” pattern also can be used. The projections 32 form a restrictive outlet opening structure 30 which impedes the movement of wiper material, such as the wiper 28, when it is pulled outwardly through the outlet opening. The projections 32 bend and flex (as shown in
The structure 24 has internal threads and is screwed onto an outlet spout 26 (see
Opening the Bag
When the package 10 (shown in
As it is shown in
As it is shown in
As it is shown in
Outlet Fixture Structure
Referring to
The spout structure 26 includes a bottom flange 62 extending outwardly which is bonded to the edges of a circular hole cut in the material 13 of the top portion of the bag. The material of the outlet fixture 18 preferably is polyethylene. The inner surface of the bag material also is polyethylene so that the bag and outlet fixture are easily thermally bonded together.
Wiper Material
As noted above, the wiper material is formed into an elongated strip, a portion of which is shown in
The material of which the strip is made depends upon the use to which the wipers are to be put. For uses in which extremely particle-free wipers are not required, such as in cleaning automobiles, airplanes and other vehicles prior to painting, or at other times, a highly suitable material is a hydroentangled mixture of synthetic fibers and cellulose fibers such as that sold under the trademark “TechniCloth” by the Texwipe Company.
Other usable materials include those which are absorbent, do not fall apart easily when moistened, are resistant to the solvents absorbed into them and are sufficiently inexpensive for the use. The materials also should be capable of using perforations to facilitate tearing.
According to the present disclosure, the materials should be formed of a fabric comprising at least 50% recycled yarn. For example, a cleaning article could be formed of 50% recycled yarn and 50% virgin yarn. Alternatively, an example cleaning article could be formed of fabric that comprises between 1% to 100% polyester yarn (for example 60%, 70%, 80%, or 90% recycled yarn).
Cleaning Liquid
Preferably, the wipers in the roll 40 are pre-moistened when packaged at the factory. This is done by encasing the roll in the bag, and pouring a pre-measured quantity of cleaning liquid into the bag before sealing it with the seal 68. Preferably, the end 28 of the first wiper is pulled outwardly from the center core to a position where it is adjacent the outlet spout 26 so that it can be easily grasped by a user.
The cleaning liquid can be any of a wide variety of liquids used for cleaning purposes, including water, isopropyl alcohol, etc.
For many applications, such as for cleaning the surfaces of aircraft and automobiles before painting, it is preferred to use more aggressive cleaning solvents such as acetone, MPK, MEK or mixtures of those substances together with naphtha and other aromatic hydrocarbons. Such aggressive solvents often are deleterious to the materials of which typical prior art wiper tubs are made.
The quantity of cleaning liquid absorbed into the wiper material varies depending upon the use to which it is to be put. Thus, the quantity can be anywhere from enough to moisten the entire roll, which is approximately 20 to 25 percent of saturation (“wetted”), up to or exceeding absorbive capacity (“saturation”).
In some uses to which the wipers may be put, the cleaning substance will comprise or contain a biocide to be used in killing germs. Such wipers often are used in pharmaceutical manufacturing to clean and sterilize working surfaces. Therefore, the term “cleaning liquid” as used herein includes biocides or mixtures of biocides with other liquids.
Bag Material
In accordance with one aspect of the present disclosure, the material of which the bag containing the wiper roll is made, consists of a laminate including at least one layer of metal foil, preferably aluminum foil, to serve as a vapor barrier, and a plurality of plastic layers.
As it is shown in
The laminate differs from prior laminates for similar bags primarily in the addition of the inner layer 72 of polyester between the polyethylene layer and the foil layer.
Applicant has recognized that the polyethylene is brittle and tends to crack under normal handling and that such cracks also tend to cause the metal foil to tear. The polyester layer is more flexible and minimizes the tearing of the foil.
The laminate is known for use in bags for iodine solution used in hospitals, etc., but is not believed to be known for use in wiper bags.
The laminate also is strong and tough enough to resist tearing when a wiper is being pulled out of the bag.
Portability
The pocket 80 also can represent a tool pouch or shop apron worn around a worker's waist, or a receptacle for holding the dispenser 10 at a workstation.
Although the preferred form of the bag shown in
Zip-Pack
Rather than a circular hole into which a dispenser fixture is secured, as in the embodiment shown in
A disposable label using pressure sensitive adhesive (PSA) 94 covers the zipper structure for shipping and storage until ready for use.
As is it shown in
The wipers 102 are pre-moistened with pre-determined quantities of liquid cleaning solutions as with the wipers described above and stored in roll form.
When the user desires to remove a wiper from the bag 90 for use, the disposable label 94 is removed and discarded, and the zipper pull 96 is moved from its closed position to the opposite end, the upper edge of the top wall 12 is lifted up, as shown in dashed lines 100 in
The zipper type package shown in
The opening through which wipers can be withdrawn is much larger and easier to use. The zipper uses no adhesives which can stick to the hands and gloves of the user. In addition, it is not necessary to make certain that the surfaces onto which the prior adhesive strip is attached are smooth so as not to leave any gaps in the closure of the package. Thus, it is easier to securely close the bag.
In addition, the slider 96 can be easier to operate, especially if the user is wearing gloves, than an adhesive strip, which might require one to push his or her fingernails underneath the edge of the strip to lift it, thus requiring the removal of gloves.
Preferably, the material of which the walls of the bag 90 are made is the same as that for the bag shown in
Wipers according to the present disclosure may come in various sizes, such as (length×width): 4″×4″, 6″×6″, 9″×9″, 9″×31″, 9″×32″, 12″×12″, and 24″×44″. The wipers may be packaged in bags or boxes containing multiple wipers (for example, 25, 50, 75, 100, 150, 200, or 300 wipers per bag). Wipers may be packaged dry or pre-wetted and in sterile dry and pre-wetted forms. Pre-wetted wipers may be wetted with a degreaser or a solvent such as isopropyl alcohol (IPA), such as a 70% IPA blend, or acetone.
While the present disclosure has been described with reference to certain implementations, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the scope of the present method or system. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the present disclosure without departing from its scope. For example, systems, blocks, or other components of disclosed examples may be combined, divided, re-arranged, or otherwise modified. Therefore, the present disclosure is not limited to the particular implementations disclosed. Instead, the present disclosure will include all implementations falling within the scope of the appended claims, both literally and under the doctrine of equivalents.
This application claims benefit of priority to U.S. provisional patent application No. 63/009,254, entitled “CLEANING ARTICLES MADE OF RECYCLED MATERIAL AND METHODS FOR PRODUCING SUCH CLEANING ARTICLES”, filed Apr. 13, 2020, the contents of which are herein incorporated by reference in their entirety.
Number | Date | Country | |
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63009254 | Apr 2020 | US |