Claims
- 1. A moldable copolyoxadiazole comprising the following structure: ##STR3## wherein the ratio A units to a mixture of B units and C units is about 1:99 to about 99:1 and the ratio of B units to C units is about 1:99 to about 99:1.
- 2. The copolyoxadiazole of claim 1 in the form of a molded object.
- 3. The copolyoxadiazole of claim 1 in the form of a fiber.
- 4. The copolyoxadiazole of claim 1 in the form of a film.
- 5. The copolyoxadiazole of claim 1 in the form of a coating.
- 6. The copolyoxadiazole of claim 1 in the form of a felt.
- 7. The copolyoxadiazole of claim 1 in the form of a laminate.
- 8. A moldable copolyoxadiazole comprising the following structure: ##STR4## wherein the ratio of A units to B units is about 1:99 to about 99:1.
- 9. The copolyoxadiazole of claim 8 in the form of a molded object.
- 10. The copolyoxadiazole of claim 8 in the form of a fiber.
- 11. The copolyoxadiazole of claim 8 in the form of a film.
- 12. The copolyoxadiazole of claim 8 in the form of a coating.
- 13. The copolyoxadiazole of claim 8 in the form of a felt.
- 14. The copolyoxadiazole of claim 8 in the form of a laminate.
- 15. A moldable copolyoxadiazole comprising the following structure: ##STR5## wherein the ratio of A units to C units is about 1:99 to about 99:1.
- 16. The copolyoxadiazole of claim 15 in the form of a moled object.
- 17. The copolyoxadiazole of claim 15 in the form of a fiber.
- 18. The copolyoxadiazole of claim 15 in the form of a film.
- 19. The copolyoxadiazole of claim 15 in the form of a coating.
- 20. The copolyoxadiazole of claim 15 in the form of a felt.
- 21. The copolyoxadiazole of claim 15 in the form of a laminate.
- 22. The copolyoxadiazole of claim 1 wherein the copolyoxadiazole has an inherent viscosity of about 2.1 to about 6.0 determined at a concentration of 0.5 grams per deciliter in 100% sulfuric acid at 25.degree. C.
- 23. The copolyoxadiazole of claim 22 in the form of a molded object.
- 24. The copolyoxadiazole of claim 22 in the form of a fiber.
- 25. The copolyoxadiazole of claim 22 in the form of a film.
- 26. The copolyoxadiazole of claim 22 in the form of a coating.
- 27. The copolyoxadiazole of claim 22 in the form of a felt.
- 28. The copolyoxadiazole of claim 22 in the form of laminate.
- 29. The copolyoxadiazole of claim 8 wherein the copolyoxadiazole has an inherent viscosity of about 2.1 to about 6.0 determined at a concentration of 0.5 grams per deciliter in 100% sulfuric acid at 25.degree. C.
- 30. The copolyoxadiazole of claim 29 in the form of a molded object.
- 31. The copolyoxadiazole of claim 29 in the form of a fiber.
- 32. The copolyoxadiazole of claim 29 in the form of a film.
- 33. The copolyoxadiazole of claim 29 in the form of a coating.
- 34. The copolyoxadiazole of claim 29 in the form of a felt.
- 35. The copolyoxadiazole of claim 29 in the form of a laminate.
- 36. The copolyoxadiazole of claim 15 wherein the copolyoxadiazole has an inherent viscosity of about 2.1 to about 6.0 determined at a concentration of 0.5 grams per deciliter in 100% sulfuric acid at 25.degree. C.
- 37. The copolyoxadiazole of claim 36 in the form of a molded object.
- 38. The copolyoxadiazole of claim 36 in the form of a fiber.
- 39. The copolyoxadiazole of claim 36 in the form of a film.
- 40. The copolyoxadiazole of claim 36 in the form of a coating.
- 41. The copolyoxadiazole of claim 36 in the form of a felt.
- 42. The copolyoxadiazole of claim 36 in the form of a laminate.
BACKGROUND OF THE INVENTION
This application is a continuation-in-part application of patent application Ser. No. 424,607 filed Sept. 27, 1982, now abandoned.
The field of this invention relates to novel copolyoxadiazoles (Co-POD's) most of which are soluble in organic solvents such as m-cresol and useful as coatings, molded objects, films and fibers.
In the prior art, the article by Y. Iwakura, et al., in The Journal of Polymer Science (A) 3, page 45 (1965), a method for the synthesis of polyoxadiazoles from hydrazine sulfate and simple diacids, such as terephthalic acid is disclosed. Other prior art references include the article by R. S. Jones, et al., in The Journal of Applied Polymer Science, Vol. 25, pages 315-321 (1980), British Patent Specification No. 1,455,776; Canadian Pat. No. 882,785 and the article by S. K. Varma, et al., in The Journal of Applied Polymer Science, Vol. 26, pages 571-577 (1981) and U.S. Pat. No. 3,238,183.
The following Japanese patents further illustrate the prior art: J79,029,509-B42; J79,034,732-B47; J80,027,918-C34 and J50,037,778-W28.
None of the foregoing references contemplates polyoxadiazoles soluble in m-cresol and useful as coatings, molded objects and films. In the book Thermally Stable Polymers by P. E. Cassidy; Marcel Dekker, Inc., New York, 1980, p. 188, the author states that "fully aromatic polyoxadiazoles are soluble only in strong acids, such as concentrated sulfuric or trifluoroacetic acid."
US Referenced Citations (3)
Continuation in Parts (1)
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Number |
Date |
Country |
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424607 |
Sep 1982 |
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